Glass Coatings Research Articles

Extended Failure Mode and Effects Analysis for Development of Hot Desert Test Cycle Proposal

ABSTRACTA growing number of gigawatt‐scale photovoltaic (PV) power plants are being established in hot desert regions worldwide, which are favored for their vast available land, high solar irradiance, long sunshine hours, and relatively low maintenance needs. This study combines insights from global PV experts on degradation rates, failure mode and effects analysis (FMEA), and desert weather conditions to develop a hot desert test cycle (HDTC). The average degradation rate for PV modules installed in hot desert regions over the past 10 years is estimated to be around 1.63% per year. Eighteen failure modes were identified and analyzed using FMEA. According to the results, the main degradation mechanisms include UV light‐induced degradation (UVLID), thermomechanical failures in interconnects and fingers, light‐elevated temperature‐induced degradation (LeTID), and abrasion of the glass and antireflection coatings. A radar map comparison shows that desert environments experience UV exposure, ambient, and module temperatures that are more than twice as high as those in moderate climates. The HDTC protocol was developed based on FMEA results and desert‐specific weather conditions. It includes tests for desert UV exposure, temperature cycles, mechanical loads, and sand/brush abrasions. To ensure consistency across countries, there is a plan to establish an internationally recognized standard that complements existing IEC standards. As the industry grows, desert regions are expected to place greater emphasis on adopting desert‐specific testing standards for the qualification and evaluation of PV modules.

Fe-based metallic glass coatings with suppressed cracks and enhanced wear resistance prepared by extreme high-speed laser cladding

Fe-based metallic glass (MG) coatings draw great attentions due to their excellent wear resistance. The recently developed extreme high-speed laser cladding (EHLC) provides a promising method for their fabrication but limited by the strong tendency to crack. Besides that, the deep insight into the structure evolution and the failure mechanism of the coating is still lacked. Thus, the understanding of the crack origin and the prevention of crack are of great importance. In the present work, Fe-Mo-Cr-Y-C-B MG coatings with adjustable glassy phase content were successfully fabricated by EHLC. The microstructure characterization of the coatings reveals that the cracks is main caused by the hard and brittle nanocrystalline phases precipitations of monoclinic Mo12Fe22C10 and (Fe, Cr)23C6 carbides in the heat affected zone. Therefore, the cracking of the coatings can be effectively reduced by increasing the glassy phase content. Subsequently, the hardness distribution, wear performance and wear mechanism of the coatings were investigated. The results showed that increasing the glassy phase content can effectively achieve low wear rate. The prepared Fe-Mo-Cr-Y-C-B MG coatings exhibit abrasion loss as low as 3.54·10−6 mm3 (N m)−1, which is an order of magnitude lower than that of the 45# steel substrate. The wear of the coatings is primarily attributed to the fatigue wear accompanied with slighting oxidative wear. By suppressing the brittle precipitated crystalline phases in the coating, the fatigue wear can be reduced and the wear resistance of the coatings can be improved. The present work provides insights into the crack prevention and were performance improvement of the Fe-based MG coatings prepared by EHLC.

A Study of the Optical Properties and Stability of Cs0.33WO3 with Different Particle Sizes for Energy-Efficient Window Films in Building Glazing

Cs0.33WO3 (CWO) is a widely used inorganic material in window films and glass coatings, known for its excellent near-infrared radiation (NIR) blocking property and high visible light transmittance (Tvis). However, the stability of NIR blocking and the optical properties of CWO in the process of application is an urgent and important problem, because significant changes in optical results can impact the related products, such as window films, glass coatings, and so on. In this paper, the particle sizes and optical properties of CWO are tested to study the light stability and their relative relations. The results indicate that CWO particle sizes between 130 nm and 100 nm (D90, the point where 90% of the particles have a diameter smaller than the specified value) exhibit high stability in terms of NIR blocking and visible light transmittance (Tvis). CWO particles with D90 < 100 nm experience a greater reduction in NIR blocking, though this ability significantly recovers upon exposure to sunlight, making these coatings particularly suitable for use in tropical and subtropical climates.

Fabrication, Microstructure and Plasma Resistance Behavior of Y-Al-Si-O (YAS) Glass-Ceramics Coated on Alumina Ceramics.

This study investigates the fabrication, microstructural characteristics and plasma resistance of Y-Al-Si-O (YAS) glass-ceramics coated on alumina ceramics. YAS frits were initially prepared using a melt-quenching method, then homogenously milled and coated onto alumina ceramics. The melt-coating process was conducted at 1650 °C for 1 h. The composition and microstructure of the glass frits and coatings were thoroughly characterized using X-ray diffraction, scanning electron microscopy, and energy-dispersive X-ray spectroscopy. These analyses revealed a dense microstructure with a polycrystalline structure predominantly composed of Y3Al5O12 (YAG) phase and a minor phase of Y2Si2O7. The YAS coatings on alumina revealed a dense layer with strong adhesion to the substrate. Subsequently, the coatings underwent C4F6/Ar/O2 plasma treatment for 1 h. Plasma exposure tests demonstrated that the YAS-coated alumina exhibited significantly better etching resistance compared to uncoated alumina, with minimal surface damage observed on the YAS coating, confirming its protective properties against plasma. The superior plasma resistance of YAS coatings is attributed to the predominance of its YAG phase. This research offers a more stable and cost-efficient solution for protecting ceramics in demanding plasma environments.

Electrophoretic Deposition of Bioactive Glass Coatings for Bone Implant Applications: A Review

This literature review deals with the electrophoretic deposition of bioactive glass coatings on metallic substrates to produce bone implants. Biocompatible metallic materials, such as titanium alloys or stainless steels, are commonly used to replace hard tissue functions because their mechanical properties are appropriate for load-bearing applications. However, metallic materials barely react in the body. They need a bioactive surface coating to trigger beneficial biological and chemical reactions in the physiological environment. Bioactive coatings aim to improve bone bonding, shorten the healing process after implantation, and extend the lifespan of the implant. Bioactive glasses, such as 45S5, 58S, S53P4, 13-93, or 70S30C, are amorphous materials made of a mixture of oxides that are accepted by the human body. They are used as coatings to improve the surface reactivity of metallic bone implants. Their high bioactivity in the physiological environment induces the formation of strong chemical bonding at the interface between the metallic implant and the surrounding bone tissue. Electrophoretic deposition is one of the most effective solutions to deposit uniform bioactive glass coatings at low temperatures. This article begins with a review of the different compositions of bioactive glasses described in the scientific literature for their ability to support hard tissue repair. The second part details the different stages of the bioactivity process occurring at the surface of bioactive glasses immersed in a physiological environment. Then, the mechanisms involved in the electrophoretic deposition of bioactive glass coatings on metallic bone implants are described. The last part of the article details the current developments in the process of improving the properties of bioactive glass coatings by adding biocompatible elements to the glassy structure.

High-temperature aqueous corrosion of MO–Na2O–B2O3–SiO2 glass and glass-ceramic coatings on metallic substrates: Effect of alkaline earth metals M2+= {Ca2+, Sr2+, Ba2+}

This investigation aims to assess the impact of 2 A alkaline-earth oxides on the alteration of glass/glass-ceramic coatings on steel under conditions of exposure to hot water. Experiments involved integrating CaO, SrO, and BaO into sodium-borosilicate glass systems after that a melting-quenching process to obtain frits. Coated and sinter-crystallized samples denoted as GC-Ca, GC-Sr, and GCC-Ba were exposed to hot aqueous corrosion according to DIN 4753–3 at 95 °C, which determined weight loss after 42 days. ICP-MS analyzed aqueous solutions for element leaching. Results indicated that glass-ceramic coatings (GCC-Ba) outperformed glass coating(GC-Ca, GC-Sr). GCC-Ba demonstrated enhanced stability, attributed to limited ion exchange and diffusion at high temperatures, enhancing corrosion resistance, supported by sanbornite crystal phase presence. Total element release by ICP-MS and 42 days of hot water corrosion coatings' weight loss after 42-day corrosion test lined up: GC-Sr > GC-Ca > GCC-Ba.

Tailored Bioactive Glass Coating: Navigating Devitrification Toward a Superior Implant Performance.

The development of well-adherent, amorphous, and bioactive glass coatings for metallic implants remains a critical challenge in biomedical engineering. Traditional bioactive glasses are susceptible to crystallization and exhibit a thermal expansion mismatch with implant materials. This study introduces a novel approach to overcome these limitations by employing systematic Na2O substitution with CaO in borosilicate glasses. In-depth structural analysis (MD simulations, Raman spectroscopy, and NMR) reveals a denser network with smaller silicate rings, enhancing thermal stability, reducing thermal expansion, and influencing dissolution kinetics. This tailored composition exhibited optimal bioactivity (in vitro formation of bone-like apatite within 3 days) and a coefficient of thermal expansion closely matching Ti-6Al-4V, a widely used implant material. Furthermore, a consolidation process, meticulously designed with insights from crystallization kinetics and the viscosity-temperature relationship, yielded a crack-free, amorphous coating on Ti-6Al-4V substrates. This novel coating demonstrates excellent cytocompatibility and strong antibacterial action, suggesting superior clinical potential compared with existing technologies.

Corrosion study of glass coated high strength low alloy steel

In the present study, the glass slurry coating to a high-strength low-alloy steel (HSLA) substrate was investigated for corrosion resistance material. The crystallographic phases, degree of crystallinity, lattice parameters, and potential changes due to the coating process, and microstructural changes such as visual inspection of the surface, revealing thickness, uniformity, adhesion, potential defects, and elemental composition of the bare and coated steel were investigated by using the X-ray diffraction (XRD) and scanning electron microscopy and electron dispersive spectroscopy (SEM/EDS). The electrochemical behavior of the bare and coated steel samples was compared using potentiodynamic polarization and electrochemical impedance spectroscopy at various immersion periods in a 3.5 wt.% of sodium chloride (NaCl) solution. The higher corrosion resistance and lower corrosion rates of the coated steel surfaces were observed. The protection effectiveness of coatings is evaluated by examining their impedance and polarization characteristics. The effectiveness of the glass coatings in inhibiting corrosion is attributed to their role as a physical barrier and their ability to release corrosion inhibitors into the surrounding electrolyte. This information can be crucial for real-world applications requiring corrosion resistance.

High-temperature melt-infiltration preparation and erosion behavior of γ-Y2Si2O7 /Y2O3–SiO2–Al2O3 glass coating on porous Si3N4 ceramics

Dense γ-Y2Si2O7/Y2O3–SiO2–Al2O3 glass coatings were prepared on porous Si3N4 ceramics using high-temperature melt-infiltration preparation method to improve their stability in service environments, specifically including water resistance and erosion wear resistance. Evolution of structure and mechanical properties during coating preparation was studied. Damage mechanism in erosion wear process was illustrated by putting the coated samples into a high-speed water flow with quartz particles. Dense double-layer microstructure could be formed when sintering at 1350–1450 °C for 1 h. The proportion of each phase inside the coating material prepared by various sintering temperatures was different, resulting in different elastic modulus and hardness, and ultimately affected the erosion resistance of the coatings. The “plasticity index” (E/H value) of γ-Y2Si2O7/Y2O3–SiO2–Al2O3 glass coating prepared at lower temperature (1350 and 1400 °C) was low, and the erosion failure of the coating was brittleness mode, leading to an obvious decrease on waterproof performance after erosion test. While coating prepared at higher temperature (1450 °C) showed a better erosion resistance. After erosion for 2 h, water absorption of coating surface was changed by only 1.34 %. Micro-morphology of the coating was almost unchanged before and after erosion, maintaining excellent waterproof performance.

Hydrophobic antireflective coatings based on the synergistic effect of hollow and solid silica for application in photovoltaic modules

Photovoltaic glass coatings with multiple functions, such as strong broad-spectrum antireflectivity, effective self-cleaning, anti-abrasiveness, stability, and durability, have great potential for improving and ensuring the outdoor operation of photovoltaic modules. In this study, alkali-catalyzed hollow and solid silica nanoparticles were mixed at controlled ratios by sol-gel method, and the resulting solution was modified with HMDS to improve hydrophobicity, and obtain refractive indices ranging from 1.45 to 1.13. Subsequently, based on the principle of gradient refractive index, a trilayer hydrophobic antireflective (TLHA) coating was developed, comprising a top layer (n = 1.13), a middle layer (n = 1.27), and a bottom layer (n = 1.44). The TLHA coating exhibited an average transmittance of 97.77 % in the wavelength range of 380–1800 nm, with a peak transmittance of 98.97 % at 572 nm, and a hydrophobic contact angle of 144°. Additionally, after 144 h of thermal cycling and 600 abrasion cycles, the average transmittance of the TLHA coating decreased by 2.43 % and 1.63 %, respectively, in the 380–1800 nm range, and the coating's pencil hardness reached 5 H. And further application results showed that the crystalline silicon micro-modules with the TLHA coating could exhibit a 7.63 % and 5.24 % increase in Jsc, as calculated from EQE and J-V curves respectively, and a 5.34 % increase in PCE, compared to modules without the TLHA coating. These results highlight the extensive applicability of the TLHA coating in enhancing outdoor photovoltaic operation efficiency, durability, and wear resistance.

FP-LAPW calculations of the structural, and optoelectronic properties of vanadium silicide compound for optoelectronic applications

Optoelectronic devices play an essential part in our daily lives by seamlessly integrating optics and electronics, leading to technologies such as smartphones, solar cells, and optical communication. In this study, the structural and optoelectronic characteristics of the hexagonal vanadium silicide are determined using the density functional theory (DFT). The structural parameters such as the zero-pressure bulk modulus B0, its pressure derivative B0′; equilibrium energy, and the volume of the primitive cell at equilibrium V0 are compared with experiment results. The metallic character of VSi2 is confirmed by calculating the density of states and band structure. Moreover, the optical properties like the dielectric function, reflectivity, energy loss function, refractive index, absorption coefficient, and optical conductivity are studied deeply, using the Drude model, within the energy interval from 0 to 14 eV and they are compared with experiment results of a polycrystalline and single crystal. However, the phonon dispersion spectrum shows the presence of imaginary modes, which indicates instability in the structure of vanadium silicide. The results indicate that the VSi2 material has the potential to be used in many applications, including mirrors, glass coatings, optoelectronic devices, optical networks, electronics, optical communications, and waveguide components.

Enhancement of fracture toughness of sol-gel silica glass coating by small amount of silver particle dispersion

Glass coatings find application across diverse fields, offering chemical resistance, insulation, and hardness to substrates. Toughness enhancement of glass coatings is strongly required to maintain these functions in the practical applications. In this study, we propose a novel approach to improve fracture toughness of glass coating by incorporating silver particles into it prepared via the sol-gel method. Samples with 0–2.0 vol% of 73 nm and 730 nm Ag particles in the precursor solution were obtained. The resulting samples exhibited high transparency, minimal change in Young's modulus, and considerably improved fracture toughness. At 73 nm and 730 nm, the maximum fracture toughness occurred at 0.5 vol% and 1.0 vol%, respectively, with a 1.4- and 1.8-fold increase compared to the original coating. This approach shows promise for enhancing glass coating toughness with minimal additive amounts and negligible loss of coating properties.

Investigation of gamma radiation shielding and antimicrobial properties of PbO-doped ZnO and TiO2 composites

Gamma radiation is utilized in various fields, such as food shelf-life preservation, medicine, and industry. The protection against ionizing radiation, such as gamma radiation, is a crucial matter. Ionizing radiation is harmful to both the environment and living organisms, leading to cellular mutations, organ damage, equipment malfunctions, and other adverse effects. To achieve radiation protection, shielding methods are employed. Materials that prevent bacterial growth and contamination should also be developed in all areas. In our study, glass substrates were coated using the rotational coating method. In this study, the antimicrobial and radiation protection properties of glass coatings prepared with ZnPb (50% ZnO + 50% PbO) and TiPb (50% TiO2 + 50% PbO) ratios were investigated. For radiation protection properties, mass attenuation coefficient (MAC) values were calculated using the Geant4-GATE and XCOM simulations, and the results were compared with the experimental data. Calculations were performed at 511, 662, 1173, 1274, and 1332 keV energy levels. A colony counting method was employed to determine the antibacterial effectiveness of Pb-doped TiO2 and ZnO. The antibacterial efficacy of Pb-doped TiO2 and ZnO films was tested against Staphylococcus aureus (ATCC 25923) and Escherichia coli (ATCC 25922) bacteria. It was found that these films were effective only against Staphylococcus aureus bacteria. The antimicrobial efficiency of the nanocomposites was evaluated against various bacterial strains, highlighting significant inhibitory properties, particularly for TiO2 and ZnO nanocomposites against S. aureus. This emphasizes their potential as antimicrobial agents.

STUDY OF THE INFLUENCE OF FRIT VISCOSITY ON THE MELTING CHARACTERISTICS OF GLAZES FOR SINGLE-FIRED CERAMIC TILES

The need to expand the assortment of ceramic tiles and ceramic granite by modifying the structure and texture of glass coatings with special properties using the technology of one-time firing, taking into account the aspects of resource and energy saving and environmental friendliness of widely used finishing materials, is analyzed. The need to create new types of ceramic tiles and ceramic granite in domestic production, taking into account the needs of the fuel and energy complex and the domestic raw material base in the event of emergency situations, has been determined. The purpose and tasks of the work are formulated, which determine the need to study the fusible characteristics of glazes and their viscosity for ceramic tiles for one-time firing. The peculiarities of frit compositions are analyzed and the requirements for surface properties are established to ensure a defect-free glaze coating for one-stage firing of ceramic tiles. High-calcium zinc aluminum silicate frits with a short interval of formation of a vitreous coating during single firing with different textures on PJSC «Kharkiv Tile Plant». The change in the characteristics of the change in viscosity and melting point of frit during the formation of glass-crystalline coatings, depending on the chemical composition and phase transformations during heat treatment, was analyzed. It was determined that ensuring crystallization viscosity η = 108,1-8,5 Pa·s in the area of ​​nucleation temperatures 1050-1150 °С for experimental frits indicates intensive formation and growth of crystalline phases and is decisive for ensuring their melting in the range of temperatures 1100 -1200 °С. It was established that the rapid increase in the viscosity of frit determines the rapid change in the characteristic melting curves in a narrow temperature range when ensuring successive stages of softening, forming a sphere, a hemisphere and melting is an indicator of the possibility of using the developed frits by single firing technology. The use of developed frits in single firing technology will significantly increase the competitiveness of domestic ceramic tiles and contribute to the stabilization of the market in the conditions of sustainable development of the country.

Influence of temperature on the nanomechanical characteristics and wear performance of FeCrMoNiBCuSiC coating

This paper introduced a metallic glass coating, Fe50.5Cr20Mo15Ni5B4.5Cu2.5Si1.8C0.6 (wt%), deposited via high velocity oxygen-fuel (HVOF) spraying. The phase composition, thermodynamic stability, microstructure, nanomechanical characteristics, and wear performance at different temperatures were investigated. The coating exhibited an amorphous/nanocrystalline structure and a crystallization temperature of 632 ℃. The hardness and creep displacements were (11.01 ± 1.24) GPa and 23 nm, respectively. After annealing at 300 ℃ and 600 ℃, the corresponding hardness increased to (15.12 ± 1.20) GPa and (17.24 ± 1.49) GPa, while the creep displacements decreased to 7 nm and 5 nm. The wear rate showed a positive correlation with temperature (T1/2), while the friction coefficient displayed a negative correlation. This study provided new insights into the elevated-temperature wear characteristics of Fe-based metallic glass coatings.

Strength Increase of Alumina Foams by a Sodium Aluminosilicate Glass Coating with Subsequent Na+ ↔ K+ Ion Exchange (Gorilla Glass Coating)

Reticulated alumina ceramic foams manufactured by the Schwartzwalder technique are coated with a sodium aluminosilicate glass using an aqueous precursor containing alumina particles and sodium silicate. After a heat treatment, a well‐adhering glass layer with a thickness between 10 and 120 μm is obtained. Besides the strut surface, the glass phase also penetrates the hollow strut cavities as well as strut cracks. The total porosity of the glass‐coated foams is between 88% and 90%, and the open cellular structure is not negatively affected by the glass coating. The compressive strength increases by a factor of two under consideration of the decrease in total porosity; a compressive strength in the order of magnitude of 2 MPa is feasible. An ion exchange of Na+ by K+ into the glass coating layer (chemical strengthening) is successfully demonstrated, but does not result in an additional improvement of the compressive strength.

Investigation of the Effect of Bioactive Glass Coating on the Corrosion Behavior of Pre-treated Ti6Al4V Alloy

Titanium alloys, especially Ti6Al4V, are widely used in in-body implants due to their superior mechanical properties, corrosion resistance and biocompatibility. However, due to their higher modulus of elasticity than bone, they do not bond well with the bone structure, leading to loosening. In addition, they contain the elements Al and V, both of which are dangerous when released into the body. Therefore, these alloys are subjected to a number of surface treatments to improve their surface properties. In this study, Ti6Al4V alloys were produced by selective laser melting in dimensions of 10x10x2 mm3 and then surface treated. The alloy surfaces were first anodized and then coated with 45S5 bioglass powder. After all surface processes, structural analyzes were performed and the effectiveness of the coating was examined. The untreated and coated samples were subjected to corrosion tests by cyclic polarization method and their corrosion behaviors were investigated.

Do Implant Coatings Affect Healing of Placed Implants? An Umbrella Review.

To analyze the available evidence and assess the effect of different implant coatings on healing outcomes. Using the PICOS strategy, a structured question was formed. A protocol was agreed upon and registered with PROSPERO (no. CRD42022321926). The MEDLINE, Embase, Cochrane Database of Systematic Reviews, Scopus, Web of Science, Pubmed, and ScienceDirect databases were searched using a structured strategy. Study selection was independently carried out in duplicate, first by title and abstract, then by full-text assessment. Quality and risk of bias were independently assessed in duplicate using AMSTAR 2 and ROBIS. Data extraction was independently undertaken in duplicate using a predefined extraction form. The search yielded 11 systematic reviews for inclusion. The most commonly assessed coatings were based on calcium phosphate-including hydroxyapatite (HA), brushite, and bioabsorbable nano-HA-followed by bisphosphonate, then bioactive glass coatings. Included reviews most frequently assessed marginal bone loss (MBL), bone-to-implant contact (BIC), and survival/success rates. There was considerable heterogeneity and small sample sizes. The quality assessment suggested low confidence in the reviews and high risk of bias. The included reviews provide weak evidence that implant coatings improve osseointegration and reduce MBL following implant placement. There was weak evidence for progressive complications for calcium phosphate coatings. Further research and long-term multicenter controlled clinical trials with improved standardization and control of bias are required to better understand the effects of coating implants.

Effect of laser power on the structure and wear performance of laser additively manufactured Cu45Zr45Al6Ti4 metallic glass coating

Laser powder bed fusion (LPBF) technology presents significant potential for the production of metallic glass (MG) coatings. This work investigated the influence of laser power on the structure and wear performance of a CuZr-based metallic glass coating with composition of Cu45Zr45Al6Ti4 on Ti substrate. It was observed that the melt pool, which serves as the fundamental building block for constructing MG coatings in LPBF, undergoes a transition from conduction mode to keyhole mode, and subsequently to extended mode with increasing laser power. The MG coatings prepared using low power laser (140 W) and medium power laser (240 W) both exhibited a nearly fully amorphous state. However, at a laser power of 360 W, noticeable crystallization occurred in the coating, as evidenced by SEM observation. The wear rate of Cu45Zr45Al6Ti4 MG coating was measured to be 4.67 × 10−6 mm3·N−1·m−1, which is significantly lower than that of the Ti substrate (6.38 × 10−4 mm3·N−1·m−1). This study reveals the relationship between the laser power and morphology of the melt pool, as well as the structure and wear performance of the LPBF-fabricated MG coatings, offering guidance for optimizing the laser additive manufacturing process of wear-resistant MG coatings.

Thermochromic Nanocellulose Films for Temperature-Adaptive Passive Cooling.

Energy efficiency in habitation spaces is a pivotal topic for maintaining energy sufficiency, cutting climate impact, and facilitating economic savings; thus, there is a critical need for solutions aimed at tackling this problem. One viable approach involves complementing active cooling methods with powerless or passive cooling ones. Moreover, considerable scope remains for the development of passive radiative cooling solutions based on sustainable materials. Cellulose, characterized by its abundance, renewability, and biodegradability, emerges as a promising material for this purpose due to its notable radiative cooling potential exploiting the mid-infrared (MIR) atmospheric transmission window (8-13 μm). In this work, we propose the utilization of thermochromic (TC) materials in conjunction with cellulose nanofibrils (CNF) to confer temperature-dependent adaptivity to hybrid CNF films. We employ a concept where high reflection, coupled with MIR emission in the heated state, facilitates cooling, while high visible light absorption in the cold state allows heating, thus enabling adaptive thermal regulation. CNF films were doped with black-to-leuco TC particles, and a thin silver layer was optionally applied to the films. The films exhibited a rapid transition (within 1 s) in their optical properties at ∼22 °C, becoming transparent above the transition temperature. Visible range transmittance of all samples ranged from 60 to 90%, with pronounced absorption in the 8-13 μm range. The cooling potential of the films was measured at 1-4 °C without any Ag layer and ∼10 °C with a Ag layer. In outdoor field testing, a peak cooling value of 12 °C was achieved during bright sunshine, which is comparable to a commercial solar film. A simulation model was also built based on the experimental results. The concept presented in this study extends beyond applications as standalone films but has applicability also in glass coatings. Overall, this work opens the door for a novel application opportunity for green cellulose-based materials.