Groundwater is a crucial natural resource with significant economic importance, supporting industrial activities, irrigation, and drinking water supplies. However, its extensive use for these purposes depletes water tables, which diminishes its future availability and leads to increased salinity, stream depletion, and land subsidence. A study was conducted to evaluate and map groundwater quality across different blocks in Salem district viz., Salem, Gangavalli, Thalaivasal, Attur, Pethanaickenpalayam, Valappady, Ayothiyapattinam, Yercaud, Panamarathupatty, Veerapandi, Edappadi, Sankari, Kadayampatti, Kolathur, Konganapuram, Magudanchavadi, Mecheri, Nangavalli, Omalur, and Tharamangalam. Sampling was conducted in February 2024, during which a total of 200 samples were collected and examined for pH, electrical conductivity, cations like Ca2+, Mg2+, Na+ and K+, anions like CO32-, HCO3-, SO42-, and Cl-. Based on the ionic concentration, the water quality parameters are derived such as Sodium Adsorption Ratio(SAR) and Residual Sodium Carbonate (RSC). The pH and EC values were ranged from 7.08 to 8.58 and 0.74 to 2.75 dS/m, respectively. The residual sodium carbonate (RSC) concentration ranged from -7.3 to 10.1 meq/L, while the sodium adsorption ratio (SAR) ranged from 0.7 to 9.7 meq/L. According to the CSSRI, Karnal Water Quality Classification, approximately 66.5 % of the samples fit into the good quality category, approximately 13% of the samples fit into the alkaline water category, and 20% of the samples fit into the saline water category in the Salem district. Using this classification, thematic maps depicting groundwater quality in the Salem district were generated with ArcGIS software. The study concludes that the majority of the samples are classified as good-quality water, while saline and alkali water emerge as the next major concern. Using this saline water for irrigation can change the soil's physical properties and lower agricultural productivity. Thus, it's crucial to apply soil amendments like gypsum and provide proper drainage to avoid long-term soil damage.