Element Geochemistry Research Articles

Anatomy of Niger and Benue river sediments from clay to granule: grain-size dependence and provenance budgets, Nigeria

ABSTRACT This study explores in detail the complexity of textural–compositional relationships in fluvial sediments. To this aim, fifteen size fractions (from clay to granule) of three sediment samples characterized by virtually identical size distribution from the Niger and Benue rivers in central Nigeria were separately analyzed by multiple methods (optical microscopy, manual and semi-automated Raman spectroscopy, X-ray diffraction, elemental geochemistry, Nd isotopes). The independent mineralogical and geochemical datasets thus obtained allowed us to investigate processes of sediment generation for five diverse size modes (clay, fine cohesive silt, very coarse frictional silt, very fine sand, coarse sand) derived in different proportions from different sources (wind-blown dust, soils and paleosols, fine-grained and coarse-grained siliciclastic units, igneous and metamorphic bedrocks). Controls on the size distribution of detrital minerals (settling equivalence, size inheritance, weathering, mechanical durability, and chemical durability through multiple sedimentary cycles) were examined, specifically focusing on tectosilicates and on the long-standing petrological problem of feldspar–grain-size relations. Various factors determine the composition of different size modes: kaolinite-dominated clay derives from both deeply weathered soils or paleosols and distant Saharan sources; cohesive silt is largely recycled from mudrocks and soils formed in sedimentary basins. The proportion of detritus derived first-cycle from basement rocks increases from very coarse silt to very fine sand, whereas the coarse-sand mode is quartz-dominated with scarce plagioclase and amphibole and local occurrence of garnet, staurolite, monazite, or xenotime reflecting a combined influence of size inheritance from igneous (pegmatite) and metamorphic sources, mechanical and chemical durability, and recycling from coarse-grained siliciclastic units. Sediment budgets based on mineralogical, geochemical, and geochronological signatures consistently indicate dominance of Benue sediment supply, although the contribution from the Niger mainstem to the Niger Delta is inferred to have been notably greater in the wetter past, before clastic fluxes dropped in response to the aridification of the Sahel.

Deep embedded clustering: Delineating multivariate geochemical anomalies in the Feizabad region

The objective of this research was to identify geochemical anomalies associated with mineralization in the Feizabad region using deep embedded clustering (DEC). Two approaches were employed: using all geochemical elements (non-selective) and using factor scores (selective) to construct input data. Results showed that the non-selective approach was highly successful in identifying anomalies, not only confirming known mineral occurrences (KMO) but also introducing new exploration targets. Additionally, model evaluation using the success rate curve (SRC) confirmed its high predictive power. This method is particularly useful in green field. The DEC model, by combining deep neural networks (DNN) and clustering algorithms, reveals complex patterns in geochemical data. This algorithm increases clustering accuracy through automatic data clustering, gradual input of large data, and compatibility with imbalanced data. Furthermore, by simultaneously integrating feature learning and clustering, it provides higher optimization and accuracy. The anomalies identified by the DEC model are consistent with granodiorite units in the region and may indicate the potential for mineralization in the study area. Additionally, the identified targets are associated with granitoids, hydrothermal alteration zones, and intrusive rocks.

From paleolake to peatland: Paleo environmental changes over glacial and interglacial cycles (Mid-Pleistocene) in the Colônia Basin, Brazil

Diatom and geochemical elements were used to analyze the transition from lake to peatland in the Colônia basin, São Paulo, Brazil; local versus regional driving factors were examined. Sediment core COL17–1, section 1470–800 cm depth shows five distinct diatom intervals offering insights into environmental changes and ecological characteristics based on sediment sources, diatom productivity, and bog wetness. Colônia basin evolution exhibited a progressive transition from mineral elements, associated with catchment instability during the lake stage, to higher levels of organic-rich sediments towards the uppermost section of the core. This shift was accompanied by the increasing presence of elements reflecting redox/productivity dynamics under changing conditions. Simultaneously, Br concentrations increased during peat formation indicating alterations in organic matter were influenced by atmospheric circulation and precipitation. During the transition from lake to peatland, the paleolake shallowing process showed successive colonization by benthic acidophilus diatom taxa, indicating a broader littoral zone and subsequent disappearance of diatoms under dry conditions. After a benthic stage, the diatom content shifted to one of planktonic dominance characterized by Aulacoseira sp., marking the return to cold-wet conditions and a moderately deep, flooded environment. Subsequently, the basin evolved into a completely flooded, turbulent peatland dominated by the Aulacoseira granulata complex. An uppermost layer sterile in diatom was associated with warmer and drier conditions and decrease in the concentration of mineral elements. Present results compared with core CO14 and Lake Titicaca showed benthic-rich levels during the penultimate glacial period and low benthic abundances. This differed the glacial-interglacial transition from those of COL17–1, which was dominated by planktonic-rich levels, suggesting the need for either a reassessment of our age model or the influence of local factors on diatom content. These findings highlight the sensitivity of diatoms to climate shifts, particularly in tropical regions, across different glacial-interglacial cycles.

Trace element geochemistry and zircon U-Pb geochronology of mafic sills from the Karagwe Ankolean Belt of northwestern Tanzania: Implications for petrogenesis and Ni-Cu-Co prospectivity

In northwestern Tanzania, mafic sills intruded the Akanyaru and Kagera Supergroup rocks in the Mesoproterozoic Karagwe-Ankolean Belt (KAB). Trace element geochemistry and UPb geochronology results are reported to unravel petrogenetic and geochronological evolution of the sills in order to place constraints on Ni-Cu-Co prospectivity of the KAB. The sills are subalkaline gabbronorite and dolerite. They are relatively evolved Mg# = 43–69, with transitional metal contents lower than juvenile mafic-ultramafic rocks of the Kabanga-Musongati Alignment (KMA) intrusions. The sills can be subdivided into western and eastern swarms that display similar geochemical characteristics, including enrichment in LREE (Light Rare Earth Elements), LILE (Large Ion Lithophile Elements), Pb, Th, and U relative to HFSE (High Field Strength Elements). They are characterised by depletions of Nb-Ta-Ti in primitive mantle normalised spiderplots, enrichments in LREE and relatively flat MREE and HREE with negative Eu anomalies Eu/Eu* = 0.74–0.94 in chondrite normalised REE spiderplots. Together with elemental trace element ratios Nb/Yb, Th/Yb, Zr/Nb, Ba/Nb, and Nb-Yb-Ti index suggest derivation of the mafic sills from a sub-continental lithospheric mantle source followed by fractional crystallisation and crustal contamination.Zircon UPb geochronology yields a concordant weighted age of 1424 ± 13 Ma for a gabbronorite in the western sills and an upper age intercept of 1411 ± 54 Ma for a dolerite in the eastern sills. The emplacement ages are similar to those of the KMA and the Lake Victoria Dolerite Dyke Swarm (LVDDS). Temporal and geochemical similarities with the KMA and LVDDS supports for emplacement of the mafic sills in an intracratonic rift setting. Although the KAB sills are relatively more geochemically evolved, they share similar evolutionary path with Ni-Cu-Co mineralised juvenile KMA intrusions, sensu stricto interaction with sulphur bearing country rocks. We suggest that trace elements geochemistry including chalcophile elemental ratios (Ni/Cr and Cu/Zn) of the sills be applied as vectors to locate prospective Ni-Cu-Co targets in the KAB.

ADVANCING INDIVIDUAL FORAMINIFERA ANALYSIS BY COMBINING MOLECULAR, MORPHOMETRIC, AND TRACE ELEMENT GEOCHEMISTRY

ABSTRACT Planktic foraminifera are widely used as paleoclimate proxies. Foraminiferal species are identified morphologically, but research has revealed that many species contain cryptic genetic diversity. Here, we advance a workflow analyzing the genetics, morphology, and geochemistry from individual foraminifera specimens, using Globigerina bulloides as the test species. The impact of the DNA extraction process is assessed by comparing the trace element geochemistry and test morphometrics of DNA extracted vs. control specimens. Imaging revealed highly variable morphologies within the same genotype. Physical properties of the test were not influenced by extraction. DNA extraction did not impact Mg/Ca and B/Ca trace element ratios, common proxies for paleothermometry and carbonate chemistry, respectively. However, DNA extraction did slightly elevate some trace element ratios (Zn, Ba, and Sr) and suggests that additional cleaning may be required. This workflow provides a roadmap for obtaining genetic, morphometric, and geochemical data from the same specimens, and for elucidating cryptic diversity within species.

Late Holocene extraordinary palaeoflood events and their climatological context in the Shahe River, Huaihe River Basin, China

Palaeoflood events represent immediate hydrological responses to extreme climate change. A loess-paleosol sedimentary profile containing three overbank flood deposits (OFD1, OFD2, and OFD3) layers that recorded palaeoflood events was discovered on the platform scarp of the Shahe River, a tributary of the Huaihe River through a field investigation. Sediment samples were collected, and their physicochemical properties, as well as optically stimulated luminescence (OSL) dating, were analyzed. The results indicated that OFD1, OFD2, and OFD3 were indeed overbank flood deposits influenced by hydrodynamic forces. However, OFD3 and OFD1 consisted primarily of sand (>60 %) in terms of particle size composition, whereas paleosol (S0), transitional loess (Lt), and Malan loess (L1) mainly comprised silt (>70 %). Moreover, the magnetic susceptibility values of OFD3 and OFD1 exceeded those of S0, Lt, and L1. The contents of Na2O, K2O, and SiO2 were higher, while their contents of Al2O3 and Fe2O3 were lower in OFD3 and OFD1. These suggested that OFD3 and OFD1 may originate from weathered bedrock materials transported from the upper reaches of the Shahe River under significant hydrodynamic forces. The particle size composition, magnetic susceptibility value, and geochemical element composition of OFD2 were similar to those of S0, Lt, and L1 but diverged significantly from those of OFD1 and OFD3, indicating that OFD2 originated from loess and soil sediments widely distributed on both sides of the valley. Through OSL dating and stratigraphic chronological framework of the sedimentary profile, these three extraordinary palaeoflood events in the Huaihe River Basin occurred during the late Holocene, ∼1470 a. The analysis of high-resolution climate proxy indicators, atmospheric circulation factors, and global mean temperature demonstrated a direct correlation between these extreme flood events and abrupt climate changes during ∼ 1470 a. This period corresponded to severe climate deterioration during the Northern and Southern Dynasties (589–420 CE) in China. These findings are crucial for enhancing our understanding of regional hydrological climate responses to global changes.

Provenance Characteristics from the Mesozoic to Cenozoic Era and Their Implications for Basin-Mountain System Evolution in the Southwestern Junggar Basin: Insights from Field Outcrop Observations in the Tostai Area

The Mesozoic-Cenozoic formations in the southwestern Junggar Basin are a key target for oil and gas exploration. However, complex provenance conditions hinder comprehensive understanding of sedimentary reservoirs. Based on petrology and elemental geochemistry analysis of field outcrops in the Tostai area. Research was conducted on the tectonic background, sediment transport distances, compositions of parent rocks and evolutionary Characteristics of Provenance Conditions in the provenance areas. It is generally believed that there have been three notable shifts in basin-mountain relationships during this period. Initially, from the Triassic to Jurassic, the Northern Tianshan magmatic rock area predominated as the primary provenance, with decreasing basin-mountain proximity and predominantly magmatic rock sediment composition indicating near provenance. Subsequently, heightened Cretaceous tectonic activity in the Tianshan Mountains led to significant uplift of metamorphic rock regions in the Middle Tianshan Mountains, gradually becoming the provenance for the study area. This increased distance between provenance and sedimentary areas, marked by a substantial presence of metamorphic rocks in sediments indicating far provenance. Lastly, the Cenozoic Himalayan movement resulted in vigorous uplift of the magmatic rock area in the northern Tianshan Mountains, reestablishing it as the primary provenance. This minimized basin-mountain distance, leading to deposition of near-provenance transported alluvial fans, braided rivers, and predominantly magmatic rock sediments.

Mineralogy and Major Element Geochemistry of the Oligocene Barail Group Sandstones from the Sylhet Trough, Bengal Basin: Provenance and Tectonic Implications

The origin of Oligocene sediments in the Bengal Basin and associated tectonic setting remain poorly understood. This study investigates the framework mineralogy and major element geochemistry of the Barail Group sandstones from the Sylhet Trough within the Bengal Basin to clarify the provenance and tectonic history of the Oligocene. Modal analysis (Q83F7L10) and geochemical data support a classification of sublitharenite to subarkose, some with Fe enrichment. The heavy mineral assemblage is dominated by opaque minerals, followed by ultrastable minerals with zircon > tourmaline > rutile. The sub-angular to sub-rounded sand grains with a compositionally moderate mature nature suggest that the sediments were deposited close to the source area. The mineralogical and geochemical provenance discrimination diagram suggests contributions from felsic igneous, sedimentary/metasedimentary, and low-grade metamorphic sources, with detritus derived from the Indian craton and proto-Himalaya region. Data suggest moderate to intense chemical weathering, indicative of low relief and a sub-humid to humid climate in the source area. The tectonic analyses indicate that the Bengal Basin transitioned from a predominantly passive margin to an active tectonic margin setting during the Oligocene.

The paleo-oceanic environment and organic matter enrichment mechanism of the early Cambrian in the southern Lower Yangtze platform, China

This study focuses on the Lower Yangtze Platform located in southern Anhui Province, focusing on the black shale of the early Cambrian Hetang Formation as the primary research subject. Three field sections representing distinct sedimentary structural units were selected for investigation. Analytical methodologies encompassing organic geochemistry, elemental geochemistry, and scanning electron microscopy were employed to reconstruct paleo-oceanic environmental conditions. These analyses aimed to elucidate the characteristics of marine surface productivity and identify the factors controlling organic matter formation, thereby establishing a model for organic matter accumulation processes. These findings suggest that the Jiangnan paleo-uplift exerted differentiated control over organic matter formation and accumulation. Specifically, the barrier function of the paleo-uplift fostered a relatively enclosed and restricted water environment in certain regions, which proved conducive to the formation, accumulation, and preservation of organic matter. Furthermore, the paleo-upwelling system and hydrothermal groundwater circulation triggered by the activation of the Jiangnan deep fault played crucial roles in controlling the formation and accumulation of organic matter in the early Cambrian. Notably, the research also revealed that intermittent hydrothermal activity had a dual impact on organic matter accumulation within various paleo-oceanic settings. This process potentially facilitated organic matter enrichment and led to the dilution of organic matter concentrations.

Geochemistry of platinum group elements in the ocean

Geochemistry of platinum group elements in the ocean

A New Sphalerite Thermometer Based on Machine Learning with Trace Element Geochemistry

A New Sphalerite Thermometer Based on Machine Learning with Trace Element Geochemistry

Genesis of Yongping copper deposit in the Qin-Hang Metallogenic Belt, SE China: Insights from sulfide geochemistry and sulfur isotopic data

Yongping copper deposit is a large-scale polymetallic mine that contains 1.6 Mt of proven Cu metal reserves with an average grade of 0.74 % and contributes significantly to China’s production of copper. This deposit is situated in the eastern part of the Qin-Hang Metallogenic Belt (Jiangxi province, SE China) at the contact zone between the Yangtze Cu–Mo metallogenic belt and the Jiangxi W–Sn–REE metallogenic belt. The thick stratiform and lenticular-shaped orebodies are hosted in the Carboniferous Yejiawan Formation, consisting of sandstone, limestone, mudstone, and chert-rich clastic rocks. Dominant metal-bearing minerals are chalcopyrite and pyrite with a minor amount of sphalerite, tetrahedrite, galena, molybdenite, pyrrhotite, magnetite, hematite, and scheelite. Although intensive research has been done on its geological setting, geochemical characteristics, and geodynamic evolution over the past thirty years, the origin and depositional environments have remained controversial. In the current research, in situ trace element geochemistry and sulfur isotope analyses, coupled with microscopic investigation, were conducted on sulfide minerals using the LA-ICP-MS technique. The results display that Yongping pyrite rich in Co, As, Ni, Zn, Cu, and Te and deplete in other trace elements. Sphalerite rich in Fe, Mn, Cu, and Cd, followed by In, Co and Ga. The calculation results of formula T(°C) = (Fe/Zn + 0.2953)/(0.0013) reveal that sphalerite was formed in medium–high temperature conditions (262 °C–377 °C). The δ34SV-CDT values of studied sulfides (pyrite, chalcopyrite, sphalerite, and tetrahedrite) varied from −1.52 ‰ to 5.13 ‰ with an average of 2.36 ‰, which are highly consistent with those recorded from porphyritic biotite granite stock of Shizitou (from 2.20 ‰ to 4.5 ‰), suggesting a dominantly magmatic origin. Collectively, trace element compositions of analyzed sphalerite and pyrite from the Yongping area exhibit characteristics of typical skarn deposits. Combined with previous studies, we can conclude that the Yongping Cu deposit is a skarn deposit that was most likely formed by contact metasomatism after the intrusion of the Jurassic Huoshaogang-Shizitou granitic stock into the Carboniferous Yejiawan Formation.

Onset and tempo of ignimbrite flare-up volcanism in the eastern and central Mogollon-Datil volcanic field, southern New Mexico, USA

The Cenozoic ignimbrite flare-up (40–18 Ma) generated multiple volcanic fields in the southwestern United States and northern Mexico resulting from asthenospheric mantle upwelling after removal of the Farallon slab. The correlation of tuffs to one another and to source calderas within these volcanic fields is essential for determining spatiotemporal patterns in volcanism and magma geochemistry, which have been used to deduce migration of the Farallon slab at depth and associated mantle melting. However, the correlation of Eocene–Oligocene tuffs in the southwestern U.S. is difficult because of post-emplacement erosion and faulting. This study focuses on spatiotemporal patterns of the initial episode of ignimbrite flare-up activity (ca. 36.5–33.8 Ma) in the Mogollon-Datil volcanic field in south-central New Mexico, USA. We show that alkali feldspar major and trace element geochemistry is an effective tool for correlating tuffs when combined with high-precision, single-crystal 40Ar/39Ar geochronology and bulk-rock geochemistry. Using these data, we correlate several tuff units and differentiate other tuffs that have the same eruption age but very different geochemistry, and we conclude that there was a broadly northwestward migration in volcanism over time. The new tuff correlations are used to investigate spatiotemporal variations in magma geochemistry, erupted volumes, and recurrence intervals during the initial episode of Mogollon-Datil volcanic field volcanism. Early-erupted tuffs restricted to the eastern Mogollon-Datil volcanic field share similarities with western U.S. topaz rhyolites, which suggests that the silicic magmas were generated by partial melting of mafic lower crustal rocks. We also find differences in the compositions, crystallinities, and mineral assemblages between the early- and late-erupted tuffs. The early-erupted tuffs tend to have single-feldspar mineralogies, lower feldspar Or contents, large negative Eu anomalies, and low-whole–rock Ba concentrations. Conversely, late-erupted tuffs have two feldspar plus quartz assemblages, lesser Eu anomalies, higher whole-rock Ba concentrations, and feldspars have higher Or contents. Thus, we suggest that for some of the early eruptions, after magmas underwent crystal fractionation in the crust, the silicic melt largely separated from the crystalline mush prior to eruption, whereas late-erupted tuff magmas underwent crystal fractionation at near the eutectic minimum and were remobilized and erupted with a larger proportion of their crystalline mush. Using our new ages, correlations, and previously published data, we find that the initial phase of Mogollon-Datil volcanic field volcanism produced at least 15 eruptions between 36.5 Ma and 33.8 Ma, with a minimum total erupted volume of ~1350 km3 and an average recurrence interval of 170 k.y. However, eruptions were generally smaller in volume (most <15 km3) than in other coeval fields, and most eruptions (n = 11) occurred in the first 1.2 m.y. (ca. 36.5–35.3 Ma) of activity. Altogether, our work sheds new light on variations in the composition, timing, and migration of volcanism during the initial phase of Mogollon-Datil volcanic field activity and highlights the utility of feldspar geochemistry in both “fingerprinting” tuffs and elucidating magma evolution.

Chemostratigraphic characterization of the Lower Paleozoic Amdeh Formation outcrops and correlation to the subsurface Haima Supergroup and Nimr Group, Sultanate of Oman

A chemostratigraphic correlation between the siliciclastic Lower Paleozoic Amdeh Formation outcrops of the Saih Hatat area, just south of Muscat, and the hydrocarbon-bearing Haima Supergroup and Nimr Group of subsurface Oman is presented. The Amdeh Formation is a 3.4 km-thick succession of Cambrian to Ordovician-aged sandstones and shales, divided into five lithological members (Am1–Am5). The Amdeh Formation type section was sampled throughout for inorganic elemental geochemistry, quantitative mineralogy and U–Pb zircon geochronology. A robust chemostratigraphic framework for the equivalent Haima Supergroup and Nimr Group intervals, defined in the subsurface, is utilized to correlate with the Amdeh Formation. The Amdeh is interpreted to be a basinward, fully marine, time equivalent of the subsurface Haradh (and likely also the Karim), Amin, Miqrat, Al Bashair, Barik, Mabrouk, Barakat, Ghudun and Saih Nihayda formations. This correlation is based on the identification of key mineralogical, depositional, provenance and sequence stratigraphic events within the inorganic geochemical data, guided by outcrop observations of depositional facies and key surfaces, and existing biostratigraphy. Positioned beyond the northern edge of the Ghaba Salt Basin, the Amdeh Formation outcrops provide important constraints on subsurface reservoir distribution, palaeogeography and basin evolution, factors that are relevant to deep gas prospectivity.

Study on the relationship between shale organic matter development and paleowater depth—A new understanding of the condensed section

Recent studies dispute the long-standing belief that highly organic-rich shales are predominantly linked to condensed section (CS) at the maximum flooding surface (MFS), proposing instead that they more commonly develop in shallow waters along basin margins. This hypothesis, however, has not been thoroughly investigated. Our study, focusing on the pivotal regions of the Longmaxi Formation and the Chang 7 Member for marine and continental shale exploration in China, integrates sequence stratigraphy with analyses of total organic carbon (TOC) and elemental geochemistry to pinpoint the environments conducive to the formation of organic-rich shales. The most organic-rich intervals, specifically the bottom of the Longmaxi Formation and the mid-to-lower Chang 73 sub-member, are located within the transgressive systems tract (TST), showing higher TOC levels in the middle to lower TST, compared to the CS of the MFS. The formation of high organic matter shale is related to warm, humid, and dysoxic shallow waters with minimal terrigenous influx and high primary productivity. We found a pronounced inverse relationship between organic matter concentration and water depth, with deeper waters promoting the decomposition and recycling of organic matter during sedimentation, thereby diminishing the TOC content. Moreover, volcanic activity also affected the organic enrichment in the Chang 7 Member. With high primary productivity, organic matter tends to accumulate in dysoxic slope zones. Consequently, high-organic content shale intervals are generally situated in shallow, dysoxic water environments, suggesting that the CS of the MFS may actually represent organic-poor intervals with limited source rock potential. The results of this study are of great significance for shale oil and gas exploration in China, and provide a new direction for the discovery of shale oil and gas sweet spots.

Elemental Geochemistry and Pb Isotopic Compositions of the Thick No. 7 Coal Seam in the Datun Mining Area, China

Thick coal seams recorded abundant petrological, geochemical, and mineralogical information regarding their formation, which in turn can reflect the characteristics of the coal-forming environments, provenance attributes, paleoclimate, and so on. In order to explore the geochemical and lead isotope characteristics of thick coal seams, the No. 7 coal seam in the Datun mining area, Jiangsu Province of China, was selected as the research object. In this work, 29 samples (including coal, roof, and floor rock samples) were collected from three coal mines in the Datun mining area. Through an analysis of the mineral composition and element geochemical characteristics in the coal samples, the enrichment degree of trace elements and modes of rare earth elements were determined. The genetic mechanism of abnormal enrichment of enriched elements is discussed, especially the modes of occurrence and isotope characteristics of Pb. The results showed the following: (1) The main minerals in the coal samples include quartz, potassium feldspar, plagioclase, calcite, dolomite, pyrite, gypsum, and clay minerals, with clay minerals, calcite, quartz, and dolomite being the most common. (2) The major element oxides in coal mainly include SiO2, Al2O3, Fe2O3, MgO, CaO, Na2O, K2O, TiO2, P2O5, and FeO. In the vertical direction, the variation of SiO2, Al2O3, Fe2O3, MgO, K2O, and FeO in coal samples from the three coal mines is consistent. The average value of Al2O3/TiO2 in the samples of Kongzhuang, Longdong, and Yaoqiao coal mines is 28.09–50.52, which basically locates the samples in the felsic source area, such that the sediment source is considered to be felsic source rock. (3) Elements U, La, Pb, and other elements are more enriched in Kongzhuang coal mine samples; elements Th, U, La, Pb, and other elements are more enriched in the Longdong coal mine samples; and elements Th, U, La, Pb, and other elements are more enriched in the Yaoqiao coal mine samples. Furthermore, W is enriched in Yaoqiao mine samples and is highly enriched in Longdong mine samples. The mining area is generally rich in the elements U, La, and Pb. The distribution curves of rare earth elements in the three mines are inclined to the right, with negative Eu anomalies. The enrichment is of the light rare earth enrichment type. (4) Pb isotope data show that the samples from the three mines are mainly distributed in the orogenic belt and the subduction zone lead source areas, where the upper crust and the mantle are mixed, with individual sample points distributed in the mantle and upper crust lead source areas.

Tracking palaeotemperatures in Coniacian–Maastrichtian seas

In this study the stable isotopes of belemnites, are presented from the Coniacian–Maastrichtian interval (∼76–66 Ma) derived from the chalks of Yorkshire and Norfolk, UK, deposited on the western North Atlantic shelf. Cathodoluminescence and elemental geochemistry of the belemnites reveals that most of the rostra were well preserved. If interpreted in terms of temperature, our oxygen isotope record reveals that during the Coniacian (at ∼43 °N) the climate was relatively warm, with maximum mean temperatures of ∼26 °C, followed by cooling to <∼21 °C during the Campanian and Maastrichtian. This overall stratigraphic trend is similar to other records, suggesting that the cooling pattern was not a regional trend and, therefore, driven predominantly by global mechanisms. Within our belemnite data, we also observe a decline in δ13C at the Campanian- Maastrichtian boundary, again consistent with other records. This trend has been interpreted as a result of an increased ratio of organic to inorganic carbon introduced into the oceans, driven by increased weathering and reworking of organic-rich sediments exposed on continental shelves during a sea-level fall. The latter related to a build-up of polar ice. Although our oxygen isotope data point to a cooling this was not necessarily linked to polar ice formation.

New Geochemical and Geochronological Constraints on the Genesis of the Imourkhssen Cu±Mo±Au±Ag Porphyry Deposit (Ouzellagh-Siroua Salient, Anti-Atlas, Morocco): Geodynamic and Metallogenic Implications

The Imourkhssen porphyry Cu±Mo±Au±Ag deposit is located at the Ouzellagh-Siroua Salient (OSS) straddling the boundary between the central Anti-Atlas and the central High Atlas. It is characterized by a typical porphyry-style mineralization. The volcanic rocks are intruded by numerous magmatic rocks of the Ouarzazate Group (580–539 Ma), referred to as the Late Ediacaran magmatic suites (LEMS). Of these, the Askaoun, Imourkhssen, and Imourgane granites are the most significant as they are related to the porphyry mineralization. The entire set is intruded by the Zaghar mafic dyke swarms. Zircon U-Pb dating of the Imourkhssen granite and the ore-bearing granite porphyry shows that these intrusive rocks were emplaced at 558 ± 1 and 550 ± 2 Ma, respectively. Moreover, the whole-rock major and trace element geochemistry reveal a high-K calc-alkaline I-type composition, consistent with an emplacement in a post-collisional setting under a trans-tensional tectonic regime. Ore bodies are hosted by the Askaoun granodiorite as well as the Imourgane granite. The mineralization occurs as fine-grained dissemination and infills of hydrothermally altered NNE–SSW to N–S trending veins and veinlets. Ore-related hydrothermal alteration consists of potassic, chlorite-sericite, serecitic, and propylitic mineral assemblages along with pervasive silicification and pyritization, providing a porphyry-style alteration pattern. The ore periods comprise supergene and magmatic-hydrothermal periods. The latter includes primary dissemination and secondary NNE–SSW to N–S ore-bearing system stages. The occurrence of molybdenite is either restricted to the potassic and chlorite-sericite alteration zones of the ore-bearing granite as fine disseminations or alternatively as veinlet infills within the propylitic halos. The molybdenite occurrences along with pyrite, chalcopyrite, galena, and tennantite dissemination are assigned to the primary ore stage, while the NNE–SSW to N–S ore-bearing system is related to the secondary ore stage. It consists of pyrite, chalcopyrite, bornite, covellite, diagenite, sphalerite, hematite, galena, gold, and chenguodaite. The predominance of cockade and crack-and-seal textures suggest multiple episodes of ore-forming fluid circulations under epithermal conditions. The supergene stage is achieved by subordinate malachite, azurite, barite, hematite, epsomite, and chrysocolla. From the descriptions above, we argue that the Imourkhssen Cu±Mo±Au±Ag mineralization shares many mineralogical and paragenetic attributes of porphyry-copper deposits.

Multi-Proxy Environmental Reconstruction of the Covacha de los Zarpazos in Galería Site (Atapuerca, Spain)

Magnetic properties of iron oxides provide invaluable data for environmental reconstruction during sediment deposition. Encouraged by the results of our previous studies in the near Gran Dolina site, we investigate the GI waterlain facies sediments that fill Galería Complex cave (Sierra de Atapuerca, Spain), in particular the Covacha de los Zarpazos cave considering two vertical profiles at different walls and comparing them with two profiles previously analysed. For the first time in this cave, we propose a correlation among these two walls based on the low field susceptibility values. An environmental reconstruction is proposed based on the pedogenesis and weathering processes, and water activity influencing the composition, concentration and grain size of magnetic minerals. In order to have a more comprehensive interpretation, elemental geochemistry was also analysed. The results allow to identify three different sections with the alternation of environmental characteristics.

Organic Matter Enrichment in Jurassic Hydrocarbon Source Rocks from the Turpan-Hami Basin: Insights from Organic and Elemental Geochemistry.

Petroleum can be generated by thermal cracking of organic matter within sediments, and the organic matter within sediments plays the dominant role in determining oil and gas generation. Organic matter within sediments is characterized by various sources, such as sapropelic organic matter from algal, microbial, and planktonic organisms and humic organic matter from higher plants. Paleo-productivity, terrestrial influx, and depositional environments could obviously influence the enrichment processes of the organic matter within sediments. Organic and elemental geochemical proxies can investigate the sedimentary process and reflect the enrichment characteristics of organic matter. In this study, hydrocarbon source rocks from the Shuixigou Group were collected from the Taibei Sag of the Turpan-Hami Basin, rock-eval pyrolysis was conducted, and stable carbon isotope composition of organic carbon and major and trace element distributions were measured. Based on this, the type and maturation of organic matter, paleo-productivity, terrestrial influx, and depositional paleo-environments were investigated. The results show that the Jurassic hydrocarbon source rocks are characterized by type III kerogen and are in the oil-window stage of maturation. The depositional paleo-environments of hydrocarbon source rocks in different formations are not remarkably different. The water bodies have freshwater oxidizing environments, and the paleo-climatic characteristics are warm and humid. However, the paleo-productivity of samples from the lower Jurassic Sangonghe Formation is higher than samples from other formations. Overall, the organic matter enrichment in Jurassic hydrocarbon source rocks of the Turpan-Hami Basin could be mutually controlled by the paleo-productivity and depositional paleo-environments. The results of this study could provide theoretical insight into deep petroleum exploration and resource evaluation in the Turpan-Hami Basin.