An integrated geophysical method combining very low frequency electromagnetic (VLF-EM) and vertical electrical sounding (VES) methods were carried out around Adaland, Southwestern Nigeria, located within latitude 7° 54’ 0” and longitude 4° 43’ 0”, with a view to investigate the possible impact of dumpsite on groundwater. This is the major study in the environment to offer extensive evidence regarding the suitability of obtaining quality groundwater. In this research, eight VLF-EM and twelve VES data sets were generated, which were then used to estimate the linear structure, bedrock formation, subsurface geological characteristics, and identification of leachate pathways. The VLF-EM data were analyzed by employing Karous_Hjelt and Microsoft Excel, while the VES data were investigated using the WinRESIST software. TheVLF-EM results confirmed the presence of conductive zones, which might be due to fracture, fault and contact zones or weathered basements. The lithological units acquired from the electrical resistivity results revealed four geoelectrical layers such as topsoil, weathered-based, fractured basement and fresh basement. However, the identified weathered layers and fractured basements from the geoelectrical sections and the corresponding Karous and Hjelt (K-H) pseudo sectionresults around the dumpsite, constitute the main passages for the possible impact of the open dumpsite on groundwater quality, since leachates from the dumpsite could slowly percolate downwards from the topsoil to the water table. Therefore, the impact of the dumpsite on the groundwater is caused by the inadequate clay materials, near-surface features such as fractures/faults, and lateral in-homogeneity. Thus, integrating both methods has been recommended in site characterization for accessing quality groundwater around a dumpsite environment.