Generation Of Waste Products Research Articles

The Use of Composite Polymeric Materials to Increase the Effectiveness of Ship Ventilation Systems

The article presented the use of composite polymeric materials to increase the effectiveness of ship ventilation systems in the process of its machining. As the result of the research, the author considered that, it is important to evaluate and anticipate all possible factors (technical, technological, ergonomic, environmental) associated with the negative impact of excessive production waste generation (chips and dust) in the workplace at the design stages of technological processes for machining parts made of composite materials. The research results determined the possibility of using composite polymer materials for manufacturing the structures of ship ventilation systems, as well as other ship systems.

Determination of ochratoxin A in coffee and tea samples by coupling second-order multivariate calibration and fluorescence spectroscopy

A new method to quantify the mycotoxin ochratoxin A (OTA) in coffee and tea samples is proposed based on second-order multivariate calibration and excitation-emission fluorescence matrix (EEFM) data. Experimental conditions were optimized by studying the effect of pH and various organized media on the fluorescence signal of OTA. For each analysed matrix (coffee grains and tea leaves), several sample pretreatments and calibration methods (external or standard addition) and data processing by chemometric models (e.g., parallel factor analysis/PARAFAC and multivariate curve resolution-alternating least squares/MCR-ALS) were evaluated and discussed. The MCR-ALS algorithm provided an adequate fit to the data for both samples, while PARAFAC was satisfactory only for the tea samples. Regarding the figures of merit, the limits of detection were in the range of 0.2–0.3 ng mL−1; furthermore, low relative prediction errors, between 2% and 4%, were achieved in both the fortified and real samples. Accordingly, the proposed methodology was applied to analyse fortified roasted and green coffee and real tea leaf samples. Satisfactory recoveries were achieved (ranging from 92 to 110%), and the obtained concentrations were in agreement with the values obtained by the reference method (based on high-performance liquid chromatography with fluorescence detection/HPLC-FLD). In addition, all samples contained OTA levels lower than the maximum permissible levels. Finally, the proposed strategy allows the use of green analytical chemistry principles; for instance, the use of organic solvents and the generation of waste products were significantly lower than for similar analytical methods reported in the literature.

Determination of Kresoxim-Methyl in Water and in Grapes by High-Performance Liquid Chromatography (HPLC) Using Photochemical-Induced Fluorescence and Dispersive Liquid-Liquid Microextraction (DLLME)

A high-performance chromatographic method was developed to determine the fungicide kresoxim-methyl. Off-line photochemical derivatization was used to induce the formation of a stable and fluorescent product since the fungicide does not present natural fluorescence. Intense fluorescence at 370/430 nm was achieved by treating the analyte in solution at pH 6 to ultraviolet light for 45 s. The chromatographic conditions included isocratic elution with 50/50% (v/v) acetonitrile/water and the photochemical product appeared at a retention time of 7.2 min. The short and long term stabilities of the photoproduct were evaluated and variation of less than 5% was achieved. The limits of detection in water samples and in grapes samples were 0.019 mg kg−1 and 0.065 mg kg−1 of kresoxim- methyl residue, respectively. The linear response covered three orders of magnitude up to 10.6 mg kg−1 of kresoxim-methyl. The robustness was evaluated through a Box–Behnken experimental design showing the insignificance of all factors and their interactions. The potential interference of tebuconazole for the determination of kresoxim-methyl was studied. The use of the dispersive liquid-liquid microextraction (DLLME) allowed recoveries between 80% and 101% depending on concentration with the minimum generation of waste products.

The Role of Investment and Innovation Activities of Coal Mining Enterprises in Increasing the Level of Environmental Safety of Country and Region

The key role of investment and innovation activities of coal industry enterprises in improving the environmental safety of regions specializing in coal mining is substantiated in the article. The coal industry enterprises are recognized by the world scientific community as the absolute leader in the field of negative impact on the environment and industrial production waste generation. In this regard, one of the most important tasks of increasing the investment and innovation activities of coal companies, the introduction of modern technologies should be not only an increase in labor productivity and production efficiency, but also a reduction of anthropogenic impact on the environment. Despite the obviousness of the presented thesis, the trends characterizing the coal industry as the most inert and low-innovative sphere, which follows the path of extensive development, continue to dominate. The insignificant increase in investments in fixed assets, periodically followed by a recession, the reduction of trapped and neutralized air polluting substances, the lack of demand for innovations in the coal industry, as well as their low impact on ensuring compliance with modern technical standards, procedures and rules, bear evidence of low responsibility of business entities and inefficient measures of state economic policy in the field of improving environmental safety in the commodity-dependent regions.

Determination of the Integral Content of the Components of Substances in the Control, Recording, and Monitoring of Production and Generation of Waste Products in Industrial Quantities

The problem of finding the integral content of the components of substances and materials for a given volume and mass of a substance (material) at certain moments or time intervals based on weighted average estimates is considered. The solution of the problem is important for control, recording, and monitoring of production of substances in industrial-scale volumes, generation of waste, including emissions and discharges. Formulas are given for calculating the total standard uncertainty of weighted average estimates, taking into account the uncertainty of the values of the weighting coefficients of the estimates, due to the uncertainty of the mass measurements of the analyte.

Mitochondrial dysregulation and glycolytic insufficiency functionally impair CD8 T cells infiltrating human renal cell carcinoma.

Cancer cells can inhibit effector T cells (Teff) through both immunomodulatory receptors and the impact of cancer metabolism on the tumor microenvironment. Indeed, Teff require high rates of glucose metabolism, and consumption of essential nutrients or generation of waste products by tumor cells may impede essential T cell metabolic pathways. Clear cell renal cell carcinoma (ccRCC) is characterized by loss of the tumor suppressor von Hippel-Lindau (VHL) and altered cancer cell metabolism. Here, we assessed how ccRCC influences the metabolism and activation of primary patient ccRCC tumor infiltrating lymphocytes (TIL). CD8 TIL were abundant in ccRCC, but they were phenotypically distinct and both functionally and metabolically impaired. ccRCC CD8 TIL were unable to efficiently uptake glucose or perform glycolysis and had small, fragmented mitochondria that were hyperpolarized and generated large amounts of ROS. Elevated ROS was associated with downregulated mitochondrial SOD2. CD8 T cells with hyperpolarized mitochondria were also visible in the blood of ccRCC patients. Importantly, provision of pyruvate to bypass glycolytic defects or scavengers to neutralize mitochondrial ROS could partially restore TIL activation. Thus, strategies to improve metabolic function of ccRCC CD8 TIL may promote the immune response to ccRCC.

From waste products to raw materials for the development of new foods

This paper reports on a study into using waste products from the food industry as raw materials for food manufacture. The Value project funded by the European Regional Development Fund compiled information on the generation of waste products from the vegetable processing industry, together with their treatment and recovery. Best available technologies for using the waste for food manufacture were identified. Diagnoses on current waste generation, management, legislation and technologies were used to conduct pilot studies. Waste products were chosen for their recovery potential, importance and the needs of the food industry. This paper focuses on the extraction of high-value-added products from food waste, which can be used as natural additives in food manufacture to provide fibre content and antioxidant properties.

Aerobic granulation for wastewater bioremediation: A review

AbstractRapid industrialisation and urbanisation releases numerous toxic compounds into natural water bodies, polluting these pristine fresh water resources. This is a subject of great concern, and the attention of environmentalists around the world has been increased towards this problem in recent years. Several techniques have been proposed for efficient wastewater treatment, most of them presenting some limitations, such as poor capacity, the generation of waste products, incomplete mineralisation and a high operating cost. Currently, aerobic granulation treatments are considered to be the most effective and economic alternative. Aerobic granulation is a process of microbial self‐immobilisation that results into a cell‐structured shape, characterised by dense biomass. Aerobic granules have a number of advantages over conventional bioflocs, such as a round and compact structure, good settling ability, high biomass retention and the ability to withstand high organic loading rates. Aerobic granulation technology has been demonstrated to be useful for a wide variety of wastewaters, including industrial, nutrient‐rich and toxic. This paper presents a state‐of‐the‐art review of effective aerobic granulation technology for wastewater treatment selected from the point‐of‐view of basic concepts of aerobic granulation, characterisation and factors that affect aerobic granulation, demonstrating the effectiveness of the cell‐immobilisation (aerobic granulation) technique. © 2012 Canadian Society for Chemical Engineering