Terahertz Generation Research Articles

Characterization of organic crystals for second-harmonic generation.

Second-harmonic generation (SHG) is a common technique with many applications. Common inorganic single-crystalline materials used to produce SHG light are effective using short IR/visible wavelengths but generally do not perform well at longer, technologically relevant IR wavelengths such as 1300, 1550, and 2000 nm. Efficient SHG materials possess many of the same key material properties as terahertz (THz) generators, and certain single-crystalline organic THz generation materials have been reported to perform at longer IR wavelengths. Consequently, this work focuses on characterizing three efficient organic THz generators for SHG, namely, DAST (trans-4-[4-(dimethylamino)-N-methylstilbazolium] p-tosylate), DSTMS (4-N,N-dimethylamino-4'-N'-methylstilbazolium 2,4,6-trimethylbenzenesulfonate), and the recently discovered generator PNPA ((E)-4-((4-nitrobenzylidene)amino)-N-phenylaniline). All three of these crystals outperform the beta-barium borate (BBO), an inorganic material commonly used for SHG, using IR pump wavelengths (1200-2000 nm).

Narrow linewidth and wideband tunable continuous-wave terahertz generator based on difference frequency generation with DAST crystal.

A narrow linewidth and wideband tunable continuous-wave terahertz generator with DAST crystal has been demonstrated in this paper. Two narrow-linewidth CW fiber lasers were used as the pump sources for difference frequency generation. The terahertz wave can be continuously tunable in the range of 1.1-3 THz. The maximum output power of 2.79nW was obtained at 2.568 THz. The linewidth of the output THz wave was estimated to be 56.5 MHz by fitting transmission spectrum of CO gas at 450 Pa pressure around 80.52 cm-1 with the Vogit gas model. Furthermore, the output spectra at room temperature and pressure was in good agreement with the air absorption lines in Hitran database. Moreover, the narrower absorption characteristic spectrum of 2-Deoxy-D-Glucose sample has been obtained through the spectrum measurements. Therefore, it could promote the practical prospect of tunable CW-THz source, which will have good potential in THz high-precision spectroscopic detection and multispectral imaging.

Generating Angular-Varying Time Delays of THz Pulses via Direct Space-to-Time Mapping of Metasurface Structures.

We experimentally demonstrate the generation of double terahertz (THz) pulses with tailored angular-dependent time delays from a nonlinear metasurface excited by a near-infrared femtosecond pulse. The tailored temporal properties of the generated pulses emerge from a direct mapping of the nonlinear spatial response of the metasurface to the emitted THz temporal profile. We utilize the Pancharatnam-Berry phase to implement symmetric and antisymmetric metasurface configurations and show that the emitted patterns present spatiotemporal "X-shaped" profiles after collimation by a parabolic mirror, with angular-dependent pulse delays corresponding to the intended design. In addition, we show that the addition of polarization multiplexing presents the opportunity to achieve a full range of elliptical THz polarizations. Double pulse generation and spatiotemporal shaping of THz waves in general show potential for THz spectroscopy and molecular dynamics applications, particularly in pump-probe experiments.

Terahertz to near infrared radiation generation using two-colour counter and co-polarized laser pulses propagating in homogeneous plasma

This study deals with the generation of terahertz (THz) to near infrared (NIR) radiation fields using two-colour linearly polarized copropagating laser pulses having either counter or co-polarization state. The frequency difference between the two laser pulses is considered to be integral multiple of the plasma frequency. Perturbation technique and quasistatic approximation have been used to obtain radiation field equations. Analytical and two-dimensional particle in cell simulation studies of the proposed configuration show that the transverse and axial plasma electron velocities arising due to nonlinear coupling of the two pulses are responsible for generation of off-axis linearly polarized radiation fields which propagate through plasma into vacuum. The frequency of generated radiation is ∼40 THz (∼60 THz), when the frequency difference of the laser pulses is two (three) times the plasma frequency. Analytical results are validated using VSim particle in cell simulation code.

An Improvement of the Cherenkov THz Generation Scheme Using Convex Silicon Prism-Lens Adapters

The terahertz (THz) generation efficiency in the Cherenkov optical rectification scheme can be improved significantly if the silicon adaptor, mounted at the lateral surface of a nonlinear crystal, has a convex output surface with proper geometry. We demonstrate and compare with the results of direct experiments a method for theoretically modeling the angular distributions of the spectral power of THz radiation in the case of different Si adaptors, constructed by mounting plano-spherical lenses on a conventional flat Si prism. The applied method of theoretical modeling shows its usefulness in choosing the best Si adapter geometry.

Efficient and Continuous Carrier-Envelope Phase Control for Terahertz Lightwave-Driven Scanning Probe Microscopy.

The fundamental understanding of quantum dynamics in advanced materials requires precise characterization at the limit of spatiotemporal resolution. Ultrafast scanning tunneling microscopy is a powerful tool combining the benefits of picosecond time resolution provided by single-cycle terahertz (THz) pulses and atomic spatial resolution of a scanning tunneling microscope (STM). For the selective excitation of localized electronic states, the transient field profile must be tailored to the energetic structure of the system. Here, we present an advanced THz-STM setup combining multi-MHz repetition rates, strong THz near fields, and continuous carrier-envelope phase (CEP) control of the transient waveform. In particular, we employ frustrated total internal reflection as an efficient and cost-effective method for precise CEP control of single-cycle THz pulses with >60% field transmissivity, high pointing stability, and continuous phase shifting of up to 0.75 π in the far and near field. Efficient THz generation and dispersion management enable peak THz voltages at the tip-sample junction exceeding 20 V at 1 MHz and 1 V at 41 MHz. The system comprises two distinct THz generation arms, which facilitate individual pulse shaping and amplitude modulation. This unique feature enables the flexible implementation of various THz pump-probe schemes, thereby facilitating the study of electronic and excitonic excited-state propagation in nanostructures and low-dimensional materials systems. Scalability of the repetition rate up to 41 MHz, combined with a state-of-the-art low-temperature STM, paves the way toward the investigation of dynamical processes in atomic quantum systems at their native length and time scales.

Gallium arsenide whispering gallery mode resonators for terahertz photonics.

As the field of terahertz (THz) photonics advances, we present a monolithic gallium arsenide (GaAs) disk-shaped whispering gallery mode resonator that has potential as a component in THz nonlinear optics. GaAs is a material with significant optical nonlinearity which can be enhanced when the crystal is shaped into a microdisk resonator. A 4-mm-disk-resonator was fabricated using single-point diamond turning and was characterized to obtain a quality (Q) factor of 2.21k at ∼150 GHz and 1.41k at ∼300 GHz. We also demonstrated the blue-shifting of up to ∼0.3 GHz of the THz modes using a block of metal. This post-fabrication degree of freedom could be useful for phase-matching requirements for nonlinear optical processes, such as detection based on optical up-conversion of THz radiation. This proof-of-concept demonstration can pave the way for the implementation of a compact, tunable and efficient device which could be integrated into nonlinear photonic platforms for THz generation, manipulation and detection.

High-field THz source centered at 2.6 THz.

We demonstrate a table-top high-field terahertz (THz) source based on optical rectification of a collimated near-infrared pulse in gallium phosphide (GaP) to produce peak fields above 300 kV/cm with a spectrum centered at 2.6 THz. The experimental configuration, based on tilted-pulse-front phase matching, is implemented with a phase grating etched directly onto the front surface of the GaP crystal. Although the THz generation efficiency starts showing a saturation onset as the near-infrared pulse energy reaches 0.57 mJ, we can expect our configuration to yield THz peak fields up to 866 kV/cm when a 5 mJ generation NIR pulse is used. This work paves the way towards broadband, high-field THz sources able to access a new class of THz coherent control and nonlinear phenomena driven at frequencies above 2 THz.

Layer‐controlled nonlinear terahertz valleytronics in two‐dimensional semimetal and semiconductor PtSe2

AbstractPlatinum diselenide () is a promising two‐dimensional (2D) material for the terahertz (THz) range as, unlike other transition metal dichalcogenides (TMDs), its bandgap can be uniquely tuned from a semiconductor in the near‐infrared to a semimetal with the number of atomic layers. This gives the material unique THz photonic properties that can be layer‐engineered. Here, we demonstrate that a controlled THz nonlinearity—tuned from monolayer to bulk —can be realized in wafer size polycrystalline through the generation of ultrafast photocurrents and the engineering of the bandstructure valleys. This is combined with the layer interaction with the substrate for a broken material centrosymmetry, permitting a second order nonlinearity. Further, we show layer dependent circular dichroism, where the sign of the ultrafast currents and hence the phase of the emitted THz pulse can be controlled through the excitation of different bandstructure valleys. In particular, we show that a semimetal has a strong dichroism that is absent in the monolayer and few layer semiconducting limit. The microscopic origins of this TMD bandstructure engineering are highlighted through detailed DFT simulations, and shows the circular dichroism can be controlled when becomes a semimetal and when the K‐valleys can be excited. As well as showing that is a promising material for THz generation through layer controlled optical nonlinearities, this work opens up a new class of circular dichroism materials beyond the monolayer limit that has been the case of traditional TMDs, and impacting a range of domains from THz valleytronics, THz spintronics to harmonic generation.image

Enhanced THz Generation From Interdigitated Quantum Dot Based Photoconductive Antenna Operating in a Quasi-Ballistic Regime

In this paper, we present a new approach for the enhancement of pulsed terahertz (THz) generation in quantum dot (QD) based photoconductive antennas (PCA). We demonstrate the benefits of the combination of a QD substrate based PCA and an interdigitated electrodes topology which allows the photocarriers to reach the antenna terminals in a quasi-ballistic regime and immediately contribute to the THz emission. A 50-fold increase in the generated THz power is observed. Such enhancement is made possible by unique combination of QD substrate properties, such as very high electric and thermal breakdown ruggedness, high carrier mobility, and yet short carrier lifetimes, compared to typical low temperature grown materials. We expect this solution to become favourable for development of powerful compact THz emitters.

978 Nm All-Polarization-Maintaining Mode-Locked Fiber Laser Based on Phase-Biased Nonlinear Amplifying Loop Mirror

Terahertz (THz) wave generation based on ultrafast laser are one of the most predominant and popular technologies. In particular, for THz generation by photoconductor antenna and optical rectification, higher optical to THz conversion efficiency usually requires ultrafast laser excitation into semiconductor or nonlinear crystal, therefore it is of great desire to develop ultrafast laser with high performance. CW Yb-doped lasers at 980 nm have been applied to generate THz wave range from 0.5 to 6 THz by DFG technique. To meet the demand of some THz wave generation (e.g. BNA crystal, gold nanoplasma), 980 nm ultrafast fiber laser are ideal pump sources and in desire to be developed. Here we demonstrate a 978 nm robust all-polarization-maintaining (PM) picosecond fiber laser mode- locked by phase-biased nonlinear amplifying loop mirror (PB- NALM). By introducing a nonreciprocal - <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"><tex-math notation="LaTeX">$\pi$</tex-math></inline-formula> /2 phase shifter into the fiber loop, a self-starting stable mode-locking is obtained with the center wavelength of 978.14 nm and a 3-dB bandwidth of 0.43 nm. The pulse duration is 8.1 ps corresponding to the time bandwidth product (TBP) of 1.09. The maximum average output power is 14.5 mW with a repetition rate of 45.438 MHz. After a master oscillator power amplification system, the 978 nm average output power reaches 2.12 W, which is then injected into a PPLN crystal for second harmonic generation and 52 mW 489 nm ultrashort lasers is obtained. This is, to the best of our knowledge, the first report of PB-NALM-based mode-locked fiber laser at 978 nm. The 978 nm ultrafast fiber laser and SHG to 489 nm have great potential in terahertz emission by shorter NIR and blue light.

Terahertz quasi-perfect vortex beams

We have successfully demonstrated the generation of terahertz (THz) quasi-perfect vortex beams (quasi-PVBs) at 0.3 THz. These THz quasi-PVBs can carry not only an individual orbital angular momentum (OAM) mode but also a multiplexed one. The 3D printed spiral axicon and multiplexed spiral axicon were used to generate THz quasi-PVBs carrying individual and multiplexed OAM modes, respectively. The individual and multiplexed OAM modes are verified using a focal hyperbolic lens method and a modified coordinate transformation method, respectively. A THz quasi-PVB with the multiplexing of multiple different OAM modes holds promise for coupling to a receiver port with a fixed annular index profile, thereby increasing the number of communication channels. These works have potential applications in compact terahertz systems, such as mode division multiplexing, which further enhances the system's capacity.

Recording the angular dispersion of a terahertz beam into its frequency spectrum for fast measurements.

The frequency-dependent divergence angle of terahertz (THz) beams is a crucial aspect in understanding the generation and transmission of broadband THz waves. However, traditional beam profiling methods, such as 1D or 2D translation/rotation scanning detection, are time-consuming and wasteful of THz energy, making them unsuitable for fast measurement applications, such as single-shot THz generation and detection. Here, we proposed a simple solution that involves passing the THz beam through a core-anti-resonant reflective (CARR) cavity (e.g., a paper tube). The spatial information of the beam is then recorded into its frequency spectrum, which can be easily detected by a following traditional THz time-domain spectroscopy (TDS) system or a single-shot sampling setup. Our method enables the acquisition of the angular dispersion without repetitive measurements, and represents a significant step forward in fast and efficient achievement of spatial properties of broadband THz beams.

Enhancement of Terahertz Emission by Silver Nanoparticles in a Liquid Medium.

Due to higher molecular density, lower ionization potential, and a better self-healing property compared with gases, liquid targets have been used for laser-induced terahertz generation for many years. In this work, a liquid target used for terahertz radiation is embedded with silver nanoparticles (Ag NPs), which makes the material have both the fluidity of liquids and conductivity of metals. Meanwhile, the experimental setup is easier to implement than that of liquid metals. Polyvinyl alcohol (PVA) is used as a stabilizing agent to avoid precipitation formation. It is observed that the power of 0.5 THz radiation from the Ag NP suspension is five times stronger than that from liquid water in identical experimental conditions. In addition, the reusability of the material is investigated using multiple excitations. UV-visible spectroscopy and TEM imaging are carried out to analyze the target material after each excitation. As a result, quasispherical Ag NP suspensions show good reusability for several excitations and only a decrease in particle concentration is observed. By contrast, the chain-like Ag NP suspension shows poor stability due to PVA damage caused by intense laser pulses, so it cannot be used in a recyclable manner.

Interdigitated Photoconductive Antenna Pumped by Reconfigurable Structured Light for Terahertz Emission and Modulation

To improve the terahertz (THz) generation of the interdigitated photoconductive antenna (iPCA), we demonstrate, for the first time, a novel design to pump the emission arrays by reconfigurable structured light generated by a spatial light modulator. The pump light is modulated into shapes to match the antenna’s every other electrode gap which has unidirectional bias field. This design makes full used of the pump power and avoids THz pulses with opposite polarity which causes the unwanted destructive interference in the far-field. Coherent combining efficiencies of THz electric field of 92.23%, 74.94%, and 61.73% are achieved for two-, three-, and five-element pumping, respectively. In addition, real-time phase reversal of THz emission can be achieved by adjusting the pump light location. This system could inspire new and challenging applications in the phase and amplitude control of the THz field, and the enhancement of the THz signal output.

Nondepleted Time-Domain Method for Simulating Difference Frequency Generation From Metallic Metasurfaces

Difference frequency generation (DFG) is an essential phenomenon for generating far-infrared (FIR) and broadband terahertz (THz) waves, which cannot be generated by either alternating current flow-driven antennas for microwave source or pumped materials for higher frequency lights. Metallic nonlinear metasurfaces (NLMSs) as a new platform for generating THz sources were intensively developed. In this work, a nondepleted time-domain model derived from the Maxwell-hydrodynamic model is proposed where linear and nonlinear responses in metallic structures under an intense excitation are separated. By using the proposed model, only linear and low-frequency DFG signals will be considered, which makes this model suitable for unconditionally stable time-domain algorithms. A finite-difference time-domain (FDTD) method is employed to solve a set of multiphysics equations based on the proposed model. The stability of the algorithm is apparent. We validate our method by simulating THz generations from metallic NLMSs and benchmark the approach with previous numerical studies as well as our recent experimental results. In addition, the implementation of solving the DFG response can be remarkably accelerated by using the unconditionally stable algorithm.

Strong polarization-controlled terahertz generation by bi-elliptical polarized laser fields

Terahertz generation from atoms driven by two color linearly polarized (LP) and circularly polarized (CP) laser fields have been well investigated. In this work, based on the photocurrent model, we investigate theoretically the intensity and polarization characteristics of terahertz waves radiated by the bi-elliptical polarized two-color laser fields with orthogonal or parallel major axes. We show that polarization-controlled, including circularly polarized terahertz waves with sufficient intensity comparable to that of co-rotating CP or parallel LP laser field, can be generated by using a longer-wavelength few-cycle bi-elliptical field. Our simulations also show that THz energy and ellipticity can be dramatically improved with dual-color elliptical field with tiny or large ellipticity, compared with that with two-color orthogonal LP field and counter-rotating CP laser field, respectively. Bi-elliptical polarized laser field provides a huge parameter space allowing for far-reaching control of THz emission.

Optimized terahertz pulse generation with chirped pump pulses from an echelon-based tilted-pulse-front (TPF) scheme.

We successfully demonstrated the generation of single-cycle terahertz (THz) pulses through tilted-pulse-front (TPF) pumping using a reflective echelon in a lithium niobate crystal. By optimizing the pump pulse duration using a chirp, we achieved a maximum pump-to-THz conversion efficiency of 0.39%. However, we observed that the saturation behavior began at a relatively low pump energy (0.37 mJ), corresponding to a pump intensity of 22 GW/cm2. To elucidate this behavior, we measured the near- and far-field THz beam profiles and found variations in their beam characteristics, such as the beam size, location, and divergence angle in the plane of the tilted pulse direction, with the pump energy (intensity). This nonlinear behavior is attributed to the reduced effective interaction length, which ultimately leads to the saturation of THz generation. The results obtained from our study suggest that it is feasible to develop an effective THz source using echelon-based TPF pumping while also considering the impact of nonlinear saturation effects.

An interplay between optical rectification and transient photocurrent effect on THz pulse generation from bulk MoS2 layered crystal

Development of novel schemes for efficient terahertz (THz) generation from transition metal dichalcogenides are useful for realizing integrated THz devices based on them and also, understanding of the related fundamental processes from such studies will guide to suitable designs. Here, we report the THz emission efficiency of bulk MoS2 layered crystal at varying femtosecond excitation wavelengths, from 550 nm to the telecommunication wavelength of 1550 nm. By using both the below bandgap excitation at longer wavelengths and the above bandgap excitation at shorter wavelengths, we resolve THz emission contributions from resonant and non-resonant optical rectification (OR) processes, and the surface field induced transient photocurrent effect (TPE). A relatively much larger contribution to THz emission from the TPE than the resonant OR is measured for the above bandgap excitation. We have measured a clear difference between the resonant and nonresonant OR processes. The pure OR part is exclusively determined from detailed experiments using excitation intensity, polarization angle, and azimuthal angle dependent measurements. For the above bandgap excitation, the THz emission gets highly saturated with the increasing excitation intensity. Also, the value of the saturation intensity increases (decreases) with the excitation photon energy (wavelength). Interestingly, we find that the linear polarization angle and the azimuthal angle dependent THz signal due to resonant OR is π/2 phase offset relative to that due to the nonresonant OR.

Enhanced terahertz generation by controlling electron trajectory with chirp laser field

Enhanced terahertz generation by controlling electron trajectory with chirp laser field