Magma Generation Research Articles

A negligible role for forearc serpentinites and mélange diapirism in contributing halogens to Mariana arc magmas

Trace element enrichment in arc lavas has traditionally been linked to the presence of slab-derived materials introduced by a combination of aqueous slab-fluids derived from altered oceanic crust (AOC) and subducted lithosphere and sediment-melts. However, an alternative is that slab material could be mobilised in mélange diapirs formed from forearc serpentinites admixed with sediments and AOC in a subduction channel. In order to further constrain the relative importance of slab-fluids, sediment-melts and mélange diapirs in the Marianas and track how the contributions of these components evolves across the arc, we selected submarine volcanic glasses from pillow rinds recovered from the Southeast Mariana Forearc Rift, and the Mariana arc and backarc basin. The glasses are all enriched in halogens and other fluid mobile elements relative to immobile elements of similar compatibility, demonstrating a strong subduction signature. Irrespective of their position in the arc, the lavas all have Br/Cl weight ratios of 0.0016–0.0037 and I/Cl of 8.3 × 10−6–127 × 10−6, which encompasses a similar range as reported for arc and backarc glasses from the SW Pacific. The Br/Cl and I/Cl of the subduction component overlaps with altered ocean crust suggesting dehydration of altered ocean crust (± lithospheric serpentinites) as the dominant source of halogens and related slab-fluids. The Br/Cl and I/Cl of the Marianas glasses are much lower than forearc serpentinites from the Marianas, which does not favour a role for either dehydration of forearc serpentinites entrained with the subducting slab or direct melting of mélange diapirs formed from serpentinised forearc material. The halogen data are most easily reconciled with the conventional model for arc magma generation, in which halogen-bearing aqueous fluids are progressively released from a dehydrating subducting slab. The importance of sediment-melts and/or forearc serpentinites in significantly contributing to the subduction zone budgets of other elements is not precluded, but the high halogen content of forearc serpentinites means that direct melting of mélange diapirs is unlikely.

Zircons reveal the history of fluctuations in oxidation state of crustal magmatism and supercontinent cycle

We apply a zircon redox index to a global compilation of detrital zircons to track the variation of oxidation state, expressed as ΔFMQ, through Earth’s history. Those from I-type rocks, which comprise mantle and crustal igneous protoliths, including tonalite–trondhjemite–granodiorites (TTGs), generally have a high oxidation state (ΔFMQ > 0). In contrast, zircons from igneous rocks derived from supracrustal source rocks (S-type) are commonly reduced (ΔFMQ < 0). With the probability density function derived from the Gaussian-Kernel-Density-Estimation, we use the maximum likelihood estimation (MLE) to distinguish S-type from I-type zircons through Earth’s history using zircon redox. Voluminous S-type magma production shows a ca. 600 Ma cyclicity that is closely related to the supercontinent cycle. We link a cyclic drop in redox values after 2.6 Ga to periodic S-type magma generation associated with burial and melting of metasedimentary rocks during supercontinent assembly and amalgamation. The ΔFMQ of the detrital zircons rise at ∼3.5 Ga followed by a consistent average ΔFMQ > 0 over the last 3 Ga. Given that the redox state of magmas is independent of crustal thickness and silica variation, and elevated values are likely more closely related to tectonic setting, we suggest that the consistent average ΔFMQ > 0 from ca. 3.5 Ga onwards relates to recycling of oceanic lithosphere back into the mantle in what eventually became established as subduction zones. The more reduced magmas associated with sedimentary sources, became established at 2.6 Ga, presumably in response to continental rocks rising above sea-level, and follow peaks of productivity associated with the supercontinent cycle.

Petrogenesis of Late Cretaceous A-type plutonic rocks from the Eastern Pontides Orogenic Belt (NE Turkey): constraints from zircon U-Pb geochronology, zircon Lu-Hf and whole-rock Sr-Nd-Pb-Hf isotopes

ABSTRACT The Late Cretaceous magmatic history of the Eastern Pontides Orogenic Belt (NE Turkey) was generally characterized by common I-type and lesser A-type plutons in varying size and composition. Of these, A-type plutons from the Şebinkarahisar (Giresun) area yield SHRIMP zircon U-Pb age of 77.36 ± 0.96 Ma. The rocks of these plutons display a wide range of SiO2 contents (53.63 to 70.96 wt.%) and Mg-numbers (6.2–32.19) with A-type affinities characterized by enrichment in K2O and Na2O, Ga, Zr, and strong negative Eu anomalies. They also show arc-type petrochemical features including enrichment of large-ion lithophile elements (e.g. Cs, K, Rb) and light rare earth elements (LaN/LuN = 6.27–15.61), but depletion in high strength field elements (e.g. Nb, Ta, Ti, and P). The (87Sr/86Sr)i ratios and ɛNd(i) values of the studied rocks are in the range of 0.705129 to 0.0705347 and −3.64 to −3.12, respectively, while bulk rock ɛHf(i) values are between 1.86 and 4.36. They are characterized by positive zircon ɛHf(i) (1.74 to 10.88) plotting between the chondrite and depleted mantle evolutionary line values. Our data combined with the previous studies suggest that the magmas, that formed the Late Cretaceous plutons, were generated in an extensional tectonic environment due to slap roll-back and trench ward migration of the subduction zone to the south. The generation of hybrid magmas forming the studied plutons is in response to the melts derived from a metasomatized lithospheric mantle source, a relatively deeper mantle source, and the juvenile crust along with the heat transfer and decompression. Multi-sourced magmas rise through the continental crust and reach the final composition by predominantly fractional crystallization processes.

Volcanic debris avalanche deposits and their significance in the architecture and evolution of the Miocene-Quaternary Călimani-Gurghiu-Harghita volcanic range (Eastern Transylvania, Romania)

The Călimani-Gurghiu-Harghita volcanic range (CGH) represents the surface manifestation of the post-collisional magmatism that followed the docking of its basement, the Dacia Mega Unit, onto the East European margin. Between ca. 11 and 0.3 Ma, detachment of subducted slab, magma generation, and volcanic activity in CGH propagated south-southeastward, sub-parallel with the collisional Eastern Carpathian Orogen, resulting in the construction of a series of mostly composite volcanoes dominated by calc-alkaline lavas and pyroclastic products. The generally well-preserved axial row of the CGH volcanic edifices is accompanied by voluminous volcaniclastic deposits of which sources and emplacement history persist as a matter of debate. In the standard view reflected in regional scale geologic maps, these deposits represent products of complete erosion of hypothetical earlier volcanoes. Other interpretation, however, suggest that they are at least partially constituted by voluminous volcanic debris avalanche deposits (VDADs).By combining evidence from field observation and GIS analysis with published and new data from petrography, bulk-rock geochemistry, and K/Ar geochronology, here we demonstrate that VDADs vastly dominate these volcanoclastic deposits. In addition to two previously identified VDADs (Western Călimani and Vârghiş), we show that further six VDADs (Eastern Călimani, Fâncel-Lăpuşna, Ostoroş, Ivo-Cocoizaş, Luci, and Pilişca) were generated due to the sector failure of a series of CGH volcanoes, most of which still preserve well-distinguishable collapse scars. Based on our estimates, debris avalanches with volumes between <1 km3 and > 100 km3 displaced 0.4–39% of the source edifices, transferring nearly a third of their cumulated volcanic output to the observed volcaniclastic deposits.K/Ar age constraints suggest VDAD formation closely followed in space and time the migrating volcanic activity between ca. 7.8 and 1.5 Ma. Relying on this age pattern, collapse scar orientations, and VDAD runout directions, we propose that regional scale deformation of the Dacia lithosphere imposed by progressive detachment of the underlying subducted slab, manifested on the surface as a transient subsidence–uplift couple traveling along CGH as well as opening of intramountain basins at the eastern flank of the range, was responsible for basement tilting and faulting that destabilised the CGH volcanic edifices. Seismic activity associated with slab detachment and shallow crustal fault system as well as explosive volcanic eruptions may have triggered the collapse of these edifices, leading to the generation of the VDADs.

Mantle contributions to granitoids associated with Sn mineralization: Geochemical and isotopic evidence from the giant Dachang deposit, South China

Major Sn deposits are commonly linked to crust-derived and highly evolved granites, with magma generation aided by mantle heating. However, whether and how the mantle components contribute to Sn polymetallic mineralization remains unclear. In this study, in combination with a compilation of equivalent data in the region, we provide new constraints on this issue based on detailed investigations on the petrogenesis and metallogenic significance of granitoids including the causative batholith and later granodiorite porphyry dike in the giant Dachang Sn deposit from South China. The former has zircon U-Pb ages of 93–91 Ma and belongs to highly evolved S-type biotite granite, which experienced fractionation of massive feldspar. The latter shows zircon U-Pb ages of 90 Ma and displays I-type granite features. The batholith was mainly derived from the dehydration melting of biotite in the metasedimentary sources, as revealed by the relatively low whole-rock Pb contents (<30 ppm) and high Ba/Pb ratios (2.71–17.1) and initial T(ti-zr) of 790 ℃. Compared with the adjacent crust-derived S-type granites (−24.8 – −5.1) and I-type granites (−11.0 to −5.2), the Dachang S-type biotite granites present higher zircon εHf(t) values (−9.1 to −2.1). Furthermore, the low magmatic zircon δ18O values (6.2 ‰) and higher apatite LREE (3277–4114 ppm) and Sr (1137–1357 ppm) contents than of arc-type basic rocks were discerned. These characteristics jointly hint the contributions of mantle components. The higher initial T(ti-zr) (>850 °C), whole-rock Mg# (52 to 58), apatite εNd(t) (−9.2 to −6.5) and zircon εHf(t) (−7.6 to 2.5) values but lower zircon δ18O values (6.33 to 8.30 ‰) of the later granodiorite porphyry dike than those of the batholith also suggest that mantle material was involved in the generation of the dikes, which is evident by the variational features of zircon and apatite trace elements. In addition, at the zircon Hf <12000 ppm and Eu/Eu* > 0.05, the higher zircon ΔFMQ values (mostly from −1.8 to 2.0) and H2O contents (100–1100 ppm) of the Dachang granitoids than the pure crust-derived S-type granites (ΔFMQ = mostly from −3.7 to −1.5; H2O < 100 ppm) imply that mantle materials involved are relatively rich in water and oxidized. These suggest that the addition of mantle components is conducive to the extraction of Sn from metasedimentary sources, and moderately facilitates the increase of oxygen fugacity which still maintains the incompatibility of Sn in magmas with ΔFMQ < 2. Also, the involvement of mantle components upgrades the H2O contents in S-type magmas, favoring the migration of ore-forming elements from magmas to hydrothermal fluids. The sediment-derived causative granites displayed higher εHf(t) and εNd(t) values with greater Sn tonnages of their associated world-class Sn polymetallic deposits, supporting the opinion that the contributions of mantle components play an important role in the generation of giant Sn deposits.

HELIUM ISOTOPIC COMPOSITION IN ALKALINE INTRUSIONS OF THE HOVSGOL AREA, NORTHWESTERN MONGOLIA

The helium isotope composition of fluid inclusions has been studied in magnetite from alkaline and subalkaline intrusions of the Hovsgol area in NW Mongolia. The measured content of 4He is in the range from 6.6 × 10–7 to 114 × 10–7 см3/г. The 3He/4He isotopic ratio of most samples varies within 0.23–0.59 Ra and may indicate the presence of helium from different sources in the magmatogenic fluid. The largest amount of mantle He (2.51 Ra) is hosted by the magnetite of the subalkaline gabbro. During the generation of primary magma, which probably involved either SCLM-type material or a plume-like reservoir less enriched in 3He, the mantle component accounted for approximately 40–60%. In the evolution of foid and alkali-syenite melts, its share did not exceed ~10–15% due to mixing with crustal radiogenic He. We assume that the intrusions interacted with fragments of Precambrian accretionary-collisional complexes of the Tuva-Mongolian terrane. Such mixing of He isotopes in melts and fluids may be regarded as circumstantial evidence supporting the development of mantle magmatism at the active continental margin.

Petrology and Geochemistry of Adak Island Plutonic Xenoliths: Implications for Primitive Magma Generation and Crustal Differentiation in the Aleutian Island Arc

Abstract Deep crustal cumulates in arcs offer a window into the chemistry and crystallization conditions (P–T–H2O–fO2) of primitive basalts in the upper mantle and lower crust and can be studied in ancient exhumed terranes or in xenoliths erupted in young arc lavas. Here, we expand on previous studies and thoroughly characterize the extensive xenolith suites erupted from the Mt. Moffett and Mt. Adagdak volcanic centers (Adak Island, Central Aleutians), which range from primitive ultramafic cumulates to more evolved amphibole gabbros and hornblendites. We present detailed petrography as well as in situ trace and major element mineral chemistry. We use these data to calculate pressure, temperature, and fO2 estimates for the xenoliths, and compare these findings to experimental results to understand the crystallization sequence and P–T–H2O–fO2 under which the cumulates formed. The Moffett crystallization sequence is defined by early amphibole fractionation and an abrupt shift in oxide compositions from chromite to magnetite, while the Adagdak suite is characterized by simultaneous saturation of amphibole+plagioclase and oxide compositions that become increasingly aluminous before magnetite saturation. Olivine–spinel oxybarometry of the Adagdak xenoliths indicates that they are oxidized relative to mid-ocean ridge basalt (MORB:FMQ +0.1 to +2.1). Highly fractionated REE and elevated Sr/Y ratios are observed in clinopyroxene from the most primitive cumulates, consistent with a contribution from a basaltic eclogite melt. This basaltic eclogite melt is hypothesized to come from partial melting of the slab or through melting of basalt introduced into the subarc mantle through forearc subduction erosion. These signatures are greatly diminished in the more evolved lithologies, which can be explained through fractionation of plagioclase and amphibole. Our findings support the presence of a complex magmatic plumbing system beneath Adak, with Mt. Moffett and Mt. Adagdak volcanic centers tapping compositionally distinct sources. More broadly, our results are consistent with studies suggesting that low-degree basaltic eclogite melts through slab melting or forearc subduction erosion contribute to arc magmas in the Aleutians, although the associated geochemical signatures are easily obscured by differentiation in the crust.

LATE CENOZOIC MAGMATISM ON THE WILHELM ARCHIPELAGO, GRAHAM COAST OF THE ANTARCTIC PENINSULA

Manifestations of the recent magmatism were discovered in the Wilhelm Archipelago near the Ukrainian research station in the West Antarctica. There are small subvolcanic dykes that intrude Paleocene granitoids on the Barchans, Forge, Booth and Dannebrog Islands. The authors studied the occurrence, petrography and geochemistry of the dyke rocks in order to find out the peculiarities of their formation. The studied dykes are typical post-plutonic fissure intrusions injected in the host granitoids after their complete consolidation and cooling. Moreover, the host granitoids were not only cooled before the dyking but they were also exhumed at the beginning of the Neogene due to of the processes of tectonic uplift and erosion. Field observation and some other features point out to the Late Neogene or Quaternary age of the dykes. Their intrusion occurred at the shallow depths. During formation, at least part of the dykes was connected with the earth’s surface. So, they were conduits for fissured volcanic eruptions. The geochemical features of the most widespread basaltic dykes call into question their genetic connection with quantitatively subordinate dykes of andesitic and dacitic composition. They probably had different sources of magma generation that were related to different geotectonic processes. Andesitic and dacitic dykes may represent the final outburst of subduction-related calc-alkaline magmatism. On the other hand, the connection between subduction processes and Late Cenozoic basaltic dyking is not obvious and requires additional research.

The Volcanic and Radial Expansion/Contraction History of the Moon Simulated by Numerical Models of Magmatism in the Convective Mantle

AbstractTo understand the evolution of the Moon, we numerically modeled mantle convection and magmatism in a two‐dimensional polar rectangular mantle. Magmatism occurs as an upward permeable flow of magma generated by decompression melting through the convecting matrix. The mantle is assumed to be initially enriched in heat‐producing elements (HPEs) and compositionally dense ilmenite‐bearing cumulates (IBC) at its base. Here, we newly show that magma generation and migration play a crucial role in the calculated volcanic and radial expansion/contraction history. Magma is generated in the deep mantle by internal heating for the first several hundred million years. A large volume of the generated magma ascends to the surface as partially molten plumes driven by melt buoyancy; the magma generation and ascent cause a volcanic activity and radial expansion of the Moon with the peak at 3.5–4 Gyr ago. Eventually, the Moon begins to radially contract when the mantle solidifies by cooling from the surface boundary. As the mantle is cooled, the activity of partially molten plumes declines but continues for billions of years after the peak because some basal materials enriched in the dense IBC components hold HPEs. The calculated volcanic and radial expansion/contraction history is consistent with the observed history of the Moon. Our simulations suggest that a substantial fraction of the mantle was solid, and there was a basal layer enriched in HPEs and the IBC components at the beginning of the history of the Moon.

Determination of the oxidation state of primary melts using two proxies

Although many studies have demonstrated that arc magmas are more oxidized than mid-ocean ridge (MORB) and oceanic island basalts (OIB), the oxidation state of their mantle source is still debated. This ongoing debate is mainly due to contradictory fO2 values obtained from different proxies (e.g., Fe3+/ΣFe of olivine-hosted melt inclusions and glasses; Zn/ΣFe, V/Sc, V/Ga of lavas). On the one hand, some studies using V/Sc, V/Ga and Zn/ΣFe of lavas tend to show that the oxidation state of the mantle beneath arcs cannot be distinguished from that of the MORB mantle. On the other, Fe3+/ΣFe of glasses and olivine-hosted melt inclusions suggest that the sub-arc mantle is more oxidized than the mantle beneath ridges. Here, we estimate the oxygen fugacity of high-Mg olivine-hosted melt inclusions from various mid-ocean ridges and arcs, from one hot spot (Reunion Island) and Mount Etna using two fO2 proxies: the Fe3+/ΣFe of melts and the partition coefficient of V between olivine and melt (DvOl/Melt). After assessing the role of secondary processes such as volatile degassing and fractional crystallization on the fO2 of melts and reconstructing primary melt compositions, we show that (1) fO2 values derived from Fe3+/ΣFe and DvOl/Melt are comparable and (2) arc and Mount Etna primary melts are more oxidized than mid-ocean ridge and Reunion Island primary melts. We then demonstrate, from Zr/Nb, that the observed variability in primary melt fO2 is not due to chemical variability of the mantle source. Finally, the correlations between incompatible trace element ratios such as Th/La, Ba/La, Ba/Th and La/Yb and the fO2 of primary melts reveal a link between the oxidized nature of arc and Mount Etna primary magmas to slab fluid and/or sediment melt influence. Our arc dataset displays a variety of subduction influences, from fluid-dominated (Aoba and Mount Meager) to sediment melt-dominated (La Sommata) influences. The origin of the oxidation of Mount Etna magmas is more complicated to identify and the nature of the oxidized metasomatic fluids that likely percolated through the mantle source before magma generation is yet to be determined.

A wealth of P–T–t information from metasediments in the HP–UHP terrane of the Pohorje Mountains, Slovenia, elucidates the evolution of the Eastern Alps

AbstractContrasting views exist in regard of the evolution of metamorphic rocks in the southeastern Pohorje Mountains (Mts), located in the southeastern Eastern Alps. Major debated points are whether micaschists have experienced ultrahigh‐pressure metamorphism in the Late Cretaceous (Eo‐Alpine) and whether they were continuously exhumed or experienced a multiple subduction–exhumation process from that time on. Therefore, we studied micaschist sample 18Slo39 with two generations of garnet and phengitic muscovite from this area. Our detailed study of this rock included petrographic observations, chemical analyses of minerals with the electron microprobe, pseudosection modelling, conventional geothermometry, and monazite in‐situ U‐Th‐Pb dating using laser‐ablation inductively coupled plasma (ICP) mass spectrometry. The following results were obtained: The studied micaschist was subject to a peak pressure of 1.31 ± 0.14 GPa at 603 ± 26°C in Eo‐Alpine times: 90.62 ± 2.78 (2σ) Ma (Stage I). Contact metamorphism at pressure–temperature conditions of 0.66 ± 0.10 GPa and 577 ± 23°C was induced by the intrusion of the Pohorje pluton (Stage III). We determined an early Miocene age of 18.33 ± 0.43 (2σ) Ma for this intrusion. Based on this study and the previously reported data for a micaschist (16Slo12) taken in the vicinity of sample 18Slo39, a geodynamic model is proposed for the region of the Pohorje Mts considering Eo‐Alpine subduction of oceanic crust and European continental crust, of which the micaschist was part of. Another high‐pressure event in the Eocene (Stage II) was the result of intracontinental subduction because of transpression by the Periadriatic fault system that separates the Eastern Alps from the Southern Alps. This type of subduction gave rise to magma generation and ascent to form the Pohorje pluton, which caused contact metamorphism in its vicinity.

Geochronology and geochemistry of early Paleozoic granitic and coeval mafic rocks from the Tannuola terrane (Tuva, Russia): Implications for transition from a subduction to post-collisional setting in the northern part of the Central Asian Orogenic Belt

Early Paleozoic magmatism of the Tannuola terrane located in the northern Central Asian Orogenic Belt is important to understanding the transition from subduction to post-collision settings. In this study, we report in situ zircon U-Pb ages, whole rock geochemistry, and Sr-Nd isotopic data from the mafic and granitic rocks of the eastern Tannuola terrane to better characterize their petrogenesis and to investigate changing of the tectonic setting and geodynamic evolution. Zircon U-Pb ages reveal three magmatic episodes for about 60 Ma from ∼510 to ∼450 Ma, that can be divided into the late Cambrian (∼510–490 Ma), the Early Ordovician (∼480–470 Ma) and the Middle-Late Ordovician (∼460–450 Ma) stages. The late Cambrian episode emplaced the mafic, intermediate and granitic rocks with volcanic arc affinity. The late Cambrian mafic rocks of the Tannuola terrane may originate from melting of mantle source that contain asthenosphere and subarc enriched mantle metasomatized by melts derived from sinking oceanic slab. Geochemical and isotopic compositions indicate the late Cambrian intermediate-granitic rocks are most consistent with an origin from a mixed source including fractionation of mantle-derived magmas and crustal-derived components. The Early Ordovician episode reveal bimodal intrusions containing mafic rocks and adakite-like granitic rocks implying the transition from a thinner to a thicker lower crust. The Early Ordovician mafic rocks are formed as a result of high degree melting of mantle source including dominantly depleted mantle and subordinate mantle metasomatized by fluid components while coeval granitic rocks were derived from partial melting of the high Sr/Y mafic rocks. The latest Middle-Late Ordovician magmatic episode emplaced high-K calc-alkaline ferroan granitic rocks that were formed through the partial melting the juvenile Neoproterozoic sources.These three episodes of magmatism identified in the eastern Tannuola terrane are interpreted as reflecting the transition from subduction to post-collision settings during the early Paleozoic. The emplacement of voluminous magmatic rocks was induced by several stages of asthenospheric upwelling in various geodynamic settings. The late Cambrian episode of magmatism was triggered by the slab break-off while subsequent Early Ordovician episode followed the switch to a collisional setting with thickening of the lower crust and the intrusion of mantle-induced bimodal magmatism. During the post-collisional stage, the large-scale lithospheric delamination provides the magma generation for the Middle-Late Ordovician granitic rocks.

He Isotopic Composition of Alkaline Intrusions of the Hovsgol Area, Northwestern Mongolia

The He isotopic composition of fluid inclusions in magnetite of alkaline and subalkaline intrusion of the Hovsgol region, Northwestern Mongolia, is studied. The measured 4He content varies from 6.6 × 10–7 to 114 × 10–7 cm3/g. The 3He/4He isotope ratio of most samples is 0.23–0.59 Ra indicating the presence of He from different sources in magmatic fluid. The maximum of mantle He (2.51 Ra) is observed in magnetite of subalkali gabbro. The mantle He component was ~40–60% during the generation of parental magma with possible involvement of subcontinental lithospheric mantle material or a plume-like reservoir less enriched in 3He. The mantle He component did not exceed 10–15% during the evolution of the foidoitic and alkali-syenitic melts because of mixing with crustal radiogenic He. We suggest the interaction of intrusions with fragments of the Precambrian accretionary–collision complexes of the Tuva–Mongolian Terrane. This mixing of He isotopes in melts and fluids can serve as indirect evidence of the development of mantle magmatism at the active continental margin.

Magnesian Andesites from Kibblewhite Volcano in the Kermadec Arc, New Zealand

Abstract Primary andesitic magmas could be an important component of arc magma genesis and might have played a key role in the advent of continents. Recent studies hypothesized that primary andesitic magmas occur in the oceanic arc, where the crust is thin. The Kermadec arc has the thinnest crust among all the studied oceanic arcs (&amp;lt;15 km in thickness); however, there are no studies that corroborate the formation of primary andesitic magmas in the arc. The aim of this study is to develop a better understanding of primary andesites in oceanic arcs through the petrology of the Kermadec arc. Here, we present the petrology of volcanic rocks dredged from the Kibblewhite Volcano in the Kermadec arc during the R/V SONNE SO-255 expedition in 2017. Magma types range from andesite to rhyolite at the Kibblewhite Volcano, but basalts dominate at the neighboring cones. This study focuses on magnesian andesites from the northeastern flank of this volcano. The magnesian andesites are nearly aphyric and plagioclase free but contain microphenocrysts of olivine (Fo84–86) and clinopyroxene (Mg# = 81–87). Using olivine addition models, the primary magmas were estimated to contain 55–56 wt % SiO2 and 10–12 wt % MgO, similar to the high-Mg andesites observed in other convergent plate margins, indicating the generation of primary andesitic magma beneath the Kibblewhite Volcano. The trace element and isotopic characteristics of the magnesian andesites are typical of volcanic rocks from the Kermadec arc. This indicates that the subduction of a young plate or melting of a pyroxenitic source is not necessary to produce magnesian andesites. Instead, we propose that the magnesian andesites were produced by the direct melting of the uppermost mantle of the Kermadec arc. The thin crust of the Kermadec arc should yield low-pressure conditions in the uppermost mantle, allowing the sub-arc mantle to generate primary andesitic melts. This study supports the hypothesis that primary andesitic magmas generate in the arc where the crust is thin and provides a new insight into the magma genesis of the Kermadec arc.

Origins of magmatism in the Okinawa Trough: Fe–Sr–Nd–Pb–Hf isotopic constraints

ABSTRACT The Okinawa Trough is an incipient back-arc basin formed by the subduction of the Philippine Sea Plate beneath the Eurasian Plate and is a natural laboratory for studying basin evolution, magmatism, and crust-mantle interactions during the early stages of back-arc spreading. Back-arc spreading and recent magmatism are occurring mainly in the Middle Okinawa Trough (MOT) and Southern Okinawa Trough (SOT). In order to investigate the magmatism in the Okinawa Trough, volcanic rock samples from the MOT and SOT were analysed for Fe – Sr – Nd – Pb – Hf isotopic compositions. The Fe isotopic compositions of basaltic andesite samples from the SOT are similar to or lower than MORBs. The fluid/melt derived from the subducted slab, especially the fluid dehydrated from slab serpentinites and sediment-derived melts, entered the overlying depleted mantle wedge and participated in magma generation, which resulted in the low δ56Fe values of the SOT basaltic magmas. The δ56Fe values of volcanic rocks from the MOT increase with increasing SiO2 contents, suggesting a gradual enrichment of heavy Fe isotopes during the evolution of the magma as it ascended to the surface. While the Sr – Nd – Pb – Hf isotopic compositions do not vary significantly, suggesting that the different samples are the products of different degrees of crystal fractionation of comagma. The fractional crystallization of olivine, pyroxene, and ilmenite minerals, which enrich in light Fe isotopes, resulted in the gradual increase in Fe isotopic values of magma during its evolution. The dacites and rhyolites from the southernmost Okinawa Trough have the similar δ56Fe values with the basaltic andesite and the basalt from the SOT and MOT, accompanied by significantly lower Nd and Hf isotope ratios relative to basalts, reflecting that the contamination of crustal materials would not change the magma in Fe isotope compositions evidently. Compared with the MOT, the volcanic rocks from the SOT was more affected by subduction components on their underlying mantle, and those from the southernmost experienced more contamination by crustal materials in the evolving magma.

Chromium isotope variations in garnet-facies mantle rocks and their minerals: Implications for Cr isotope behavior in high-temperature processes

Previous work on Cr isotope composition of the lithospheric mantle focused on shallow spinel-facies peridotites and invoked the effects of partial melting and metasomatism. However, little is known on the Cr isotope composition and behavior in the deeper and more voluminous garnet-facies mantle, notably during generation and passage of magmas and fluids. Here, we present Cr isotope data for 26 garnet and ten spinel whole-rock peridotite xenoliths (mainly harzburgites) from the Udachnaya kimberlite on the Siberian craton and minerals from five of them, as well as for minerals of 14 eclogites and four garnet clinopyroxenites from the Dabie orogen in eastern China. Garnet (Gt) and clinopyroxene (Cpx) are major Cr hosts in the mantle. Our ionic modeling suggests the following order of 53Cr/52Cr values in coexisting minerals: garnet ≈ spinel > Cpx > olivine. Cr isotopes are equally partitioned between garnet and Cpx in four peridotites, while garnet is enriched in heavy Cr in one peridotite and all the eclogites (Δ53CrGt-Cpx 0.01‰ to 0.27‰, av. 0.10‰), but depleted in heavy Cr in the pyroxenites (Δ53CrGt-Cpx −0.03‰ to −0.16‰, av. −0.10‰). The Δ53CrGt-Cpx variations are attributed to effects of chemical composition, equilibration temperature and oxygen fugacity on equilibrium Cr isotope fractionation. Further, the anomalous Δ53CrGt-Cpx values in the Dabie pyroxenites and one peridotite may indicate disequilibrium inter-mineral isotope fractionation via kinetic diffusion during phase transitions as a result of pressure-temperature (P-T) changes and metasomatism.The whole-rock δ53Cr range in the garnet peridotites (−0.27 to 0.13‰; average −0.08 ± 0.18‰, 2 SD, n = 25, excluding an outlier with −0.86‰) overlaps bulk silicate Earth estimates whereas the spinel peridotites tend to have higher δ53Cr (−0.12 to 0.16‰; av. 0.02 ± 0.20‰, 2 SD, n = 10). While these rocks are residues of high degrees (30–40%) of melt extraction, their range contrasts with limited equilibrium Cr isotope fractionation we calculated for melting residues of both spinel and garnet peridotites (Δ53Crresidue-source < 0.03‰). The δ53Cr values in the spinel peridotites show correlations with modal abundances of Cpx, garnet and spinel, as well as major and trace element composition. We posit that the Cr isotope variations in these peridotites are somehow linked to solid–melt and inter-mineral diffusive exchanges during P-T changes, deformation and ingress of metasomatic media previously documented in the Udachnaya peridotites. The average δ53Cr value (−0.09 ± 0.16‰, 2 SD, n = 31) for garnet peridotites (excluding U9) in this and previous studies is similar to those previously obtained for (mainly off-craton) spinel peridotites and komatiites, and appears to be representative of the Cr isotope composition for bulk mantle. Numerical modeling for mantle magmas derived at different depths and by different melting degrees of garnet and spinel peridotites and eclogites yields a narrow δ53Cr range, possibly affected by oxygen fugacity.

Magmatic evolution during proto-oceanic rifting at Alu, Dalafilla and Borale Volcanoes (Afar) determined by trace element and Sr-Nd-Pb isotope geochemistry

Continental rifting and associated magmatism can eventually result in the formation of new ocean basins. However, the characteristics of magmatism in the latest stages of rifting are poorly understood. The Erta-Ale volcanic segment (EAVS) in the Danakil Depression of Afar, Ethiopia, provides a unique natural laboratory in which to investigate how magma generation evolves during the shift from continental rifting to oceanic spreading. Here we present new trace element data combined with Sr-Nd-Pb isotope ratios for three volcanoes, Alu, Dalafilla and Borale, in the north of the EAVS. These data shed light on the changes in melt production and storage that occur at this late stage in the rifting cycle. Elevated Ce/Pb and ΔNb (33–48, 0.25–0.47 respectively) of the basalts, alongside Sr-Nd-Pb isotope geochemistry indicate the presence of a HIMU component, supplied by the Afar plume, together with contamination by the crust. Melting conditions, estimated using the trace element ratios, Smn/Ybn, Dyn/Ybn and Cen/Smn, indicate that magmas were primarily derived from spinel lherzolite (85–90%) with minor garnet lherzolite (10–15%) with a melt fraction of ~4%. Melt-mantle equilibrium depths are estimated to be on the order of 64 to 83 km, shallower than that previously inferred within Afar. We suggest that this is likely a result of the increased plate thinning beneath the EAVS compared to other parts of Afar. Basaltic volcanics are found to exhibit heterogeneous Sr-Nd-Pb isotope compositions whilst more evolved rocks (i.e., SiO2 ≥52 wt%) exhibit consistent radiogenic compositions. This indicates that homogenisation of all melt compositions occurs prior to or during melt differentiation, with the latter process occurring rapidly in the upper crust with minimal crustal contamination. Overall whilst the Afar plume appears to be the dominant mantle component in the volcanic rocks, the melt characteristics and magmatic storage conditions beneath the EAVS shows variability that is likely controlled by a dynamic interplay between rifting and mantle processes.

Hafnium isotope systematics of zircon in high-grade metamorphic rocks of the Anabar shield, Siberia: Radiogenic Hf without mantle input?

The timing for the onset of plate tectonics, along with the secular changes in the tectonic settings of continental crust formation, continue to be debated. Recent interpretations based on the increase in zircon 176Hf/177Hf ratios at the time of crystallisation (expressed as εHf(t) with respect to chondritic evolution) have been used to ascertain changes in geodynamic settings in the early Earth, specifically in the 3.8–3.6 Ga interval. This increase is widely interpreted as a change in magma generation, from source(s) dominated by ancient crust to source(s) dominated by juvenile inputs from the mantle. At issue, Hf isotope variations remain limited in the early Earth due to the long decay of the LuHf system. This feature, along with the scarcity of rocks and minerals of Eo/Mesoarchaean and Hadean ages, generate large uncertainties over the nature and the timing of the interactions between mantle and crustal reservoirs. The distinction between mantle and crustal sources becomes much clearer in the Palaeoproterozoic, and the study of ancient terranes with several billion years of protracted crustal evolution may hold the key to unlock complex mantle–crust interactions. Here we investigate high-grade metamorphic rocks from the Anabar shield, which contain zircons that crystallised between the Eoarchaean (oldest core at 3814 ± 16 Ma) and the Palaeoproterozoic (youngest core at 2251 ± 15 Ma and youngest rim at 1910 ± 21 Ma). The combination of in situ UPb and Hf isotope analyses in zircon indicates the formation of the continental crust in the Siberian Craton in the Eoarchaean, and a conspicuous metamorphic event at 2.0–1.9 Ga. We demonstrate that 2.0–1.9 Ga zircon ages reflect recrystallisation processes under subsolidus conditions, involving the breakdown of high-Lu/Hf minerals (i.e. garnet and pyroxene). The εHf(t) shift at 2.0–1.9 Ga towards more radiogenic values may not be related to a change in magmatic style and sources, but rather to resetting of the LuHf system in response to heating and metamorphic reactions on a mineral scale. Our findings challenge the widely-evoked mechanism of changes in tectonic style and magma sources to account for vertical arrays in the εHf(t) versus crystallisation age space. This calls for considering alternative options, including those based on petrographic data, when interpreting Hf isotope variations in the Hadean/Archaean detrital zircon record.

Constraints on the origin of the cenozoic intraplate aldama volcanic field, tamaulipas, NE México

The Cenozoic Aldama Volcanic Field (8–0.24 Ma) is located on the southeastern margin of the Sierra de Tamaulipas and is the largest field of the Eastern Mexican Alkaline Province. It contains cinder cones, tuff rings, maars, and simple cones, as well as widespread lava flows. The volcanic rocks are geochemically characterized as alkali basalts, subalkaline basalts, trachybasalts (potassic and hawaiites), latites to trachytes, and grouped in six rock types according to their Mg-content and normative composition: (a) Alkaline near-primary rocks, (b) Alkaline basic rocks, (c) Alkaline intermediate rocks, (d) Subalkaline near-primary rocks, (e) Subalkaline basic rocks, and (f) Subalkaline intermediate rocks.Trace elements and isotopic ratios show that the source of the basaltic melts displays asthenospheric characteristics and stability conditions, indicating that the partial melting (<5%) occurred in lithospheric levels within the spinel stability depth. The coexistence in time and space of alkaline and subalkaline rocks could be explained by selective alkali metasomatism of a regional HFSE and REE-enriched OIB-like source. The magma generation occurred in a typical continental intraplate setting, associated with mantle disturbances produced by the eclogitization and detachment of the Hess conjugate subducted under NE Mexico. Some alkaline and subalkaline melts evolved to intermediate members by fractional crystallization.

Paleocene A-type igneous suites in the Sikhote-Alin (the East Asian continental margin): Petrological, geochronological, isotopic, and geodynamic constraints

Global geodynamic reconstruction models of the Pacific margin of Asia refer to materials collected throughout Japan, Korea and northeastern China, but they lack data on southern Sikhote-Alin. Therewith, the Sikhote-Alin orogenic belt (NE Asia) constituted a single eastern margin of the paleo-Asian continent with the abovementioned territories in the Paleocene. New isotopic, geochemical, and geochronological data show that Paleocene igneous activity (∼61–55 Ma) is widely developed in southern Sikhote-Alin. Bulk rock compositions of the igneous rocks of this period yield ferroan, peraluminous, calc-alkaline to alkaline affinities, highly abundant LILE and HFSE (with pronounced Ba, Sr, Eu, and Ti negative anomalies) and depleted HREE. The initial melts, displaying Zr + Y + Ce + Nb > 350 ppm and 10,000 × Ga/Al > 2.6, derived from an OIB-like mantle source crystallised under fairly reducing conditions (below FMQ buffer), and yield high temperature of zircon saturation (>850 °C), indicating typical A-type granite and related volcanic rock features. It is logical to associate variations in A-type rock geochemical composition with an enrichment of the upper part of the magma chamber with fluid-mobile components involving a redistribution of major and trace elements through fluid-magmatic differentiation. Strong depletion in Ca, Mg, Ba, Sr, Eu in the A-type rocks is caused by an outflow of these elements by an oxidizing, initially reduced, acidic fluid beyond the zone of magma generation. Whole-rock Sr-Nd isotope data argue for the generation of the A-type rocks by melting of dominantly a juvenile mantle component with a subordinate component of the ancient crust. Isotope variations of igneous rocks of the reference area: 87Sr/86Sr(t) (0.7024–0.7118), εNd(t) (−0.9 to −5.1) and TDM2 (934–1277 Ma), result from the mixing of the OIB-like mantle source with selective melts or from the metapelite contamination of the Samarka terrane accretionary prism and of the Zhuravlevka-Amur turbidite basin, later followed by fluid-magmatic differentiation that led to the formation of anatectic or hybrid melts. We further suggest that the origin of the A-type granites and related volcanic rocks is the result of the oblique interaction of oceanic and continental plates. This interaction accounts for the simultaneous formation of tears in the slab, enabling sub-slab asthenospheric upwelling, and strike-slip fault-related extensional structures in the overriding continental plate.