Generation Research Articles

Investigation of ion dynamics of laser ablated single and colliding carbon plasmas using Faraday cup

We report a comparative study of a single plasma and a colliding laser produced plasma, investigated using a Faraday cup. An enhancement in ion emission and stagnation is observed in colliding plasma plume compared to single plasma plume. We observed that fast ion generation in laser ablated plasma can be achieved at large laser intensity on to the target. As laser intensity increases ionic yield increases for both colliding and single plume and at a fixed laser intensity ionic yield decreases with increase in ambient pressure. The double peak structure is observed in the ion signal at large fluence where the peaks correspond to fast and slow species. A Faraday cup composed of nine collectors is used to measure the spatial/angular distribution of ion of expanding plasma plume. Ionic yield is found to be larger in the colliding plasma plume than the single plasma plume at all spatial/angular positions.

Characterization of a Modulated X-ray Source for Ion Mobility Spectrometry.

As a highly deployed field instrument for the detection of narcotics, explosives, and chemical warfare agents, drift tube ion mobility spectrometry relies heavily upon the performance of the ionization source and mechanism of ion beam modulation. For this instrumental platform, ion chemistry plays a critical role in the performance of the instrument from a sensitivity and selectivity perspective; however, a range of instrumental components also occupy pivotal roles. Most notably, the mechanism of ion modulation or ion gating is a primary contributor to peak width in a drift tube ion mobility experiment. Unfortunately, physical ion gates rarely perform perfectly, and in addition to serving as physical impediments to ion transmission, their modulation also has undesirable field effects. Using a recently developed modulated, non-radioactive X-ray source, we detail the performance of an ion mobility spectrometry (IMS) system that is free of a gating structure and utilizes the pulsed nature of the modulated X-ray source (MXS) for both ion generation and initiation of the IMS experiment. After investigating the influence of pulse duration and spatial X-ray beam width on the analytical performance of the instrument, the possibility of using multiplexing with a shutterless system is explored. By increasing ion throughput, the observed multiplexing gain compared to a signal-averaged spectrum approaches the theoretical maximum and illustrates the capability of the MXS-IMS system to realize significant signal to noise improvements.

Hybridized Ag-CuCrO2 Nanostructured Composites for Enhanced Gas Sensing

Because of the special layered structure and catalytic properties, delafossite CuCrO2 has been extensively studied and can obtain outstanding performance by noble metal coupling. In this work, the Ag-decorated CuCrO2 hybridizations have been elaborated by a thermal evaporation method. Surface morphology characterization and chemical state analysis were combined to indicate that the isolated island distribution of Ag nanoclusters and the generation of a divalent copper ion may result in an improvement in the gas response toward 100 ppm volatile organic compounds, such as formaldehyde (38.7%), methanol (56.8%), and acetone (76.3%). First-principle calculations were carried out to demonstrate the sensing mechanism of the Ag-decorated CuCrO2, where the remarkable change in geometry and electronic structure provided the active interface and noble metal catalysis effect promoting the target gas adsorption and reaction process. Therefore, in this work, we propose that the thermal evaporation can be utilized to act as a controllable modification method to construct nanostructure gas sensors, and the fundamental enhancement mechanism is useful to guide the design of efficient delafossite-based composite catalysts.

Influence of unipolar pulse time offset between Ti and Zr dual cathodes in closed magnetic field high power impulse magnetron sputtering

Titanium/zirconium dual cathodes with a closed magnetic field configuration were used in unipolar high power impulse magnetron sputtering (HiPIMS). Different pulse width (pulse on time) and pulse time offset between the negative voltage pulses of two targets were applied. The target discharge current waveforms and consequent substrate current waveforms were recorded and compared. The results show that both ion fluxes emitted from the Ti and Zr cathodes increase with the argon pressure. However, the ion flux emitted from the Zr cathode increases more substantially at high argon pressure. The closed magnetic field raises the target discharge current and ion flux to the substrate when the pulses of the two targets are simultaneous synchronized, or followed closely. The TiZr film composition is influenced by the HiPIMS discharge behavior of each target material more than by the average power ratio of each target. For low working pressure and short pulse width, simultaneous synchronization of the pulses on the two targets might effectively use the electrons drifting between the dual targets to enhance the generation of ions from both targets. For high working pressure and long target pulse width, setting pulses on two targets following closely is recommended to additionally utilize the runaway ions as pre-ionized media for the follow-up pulse on the adjacent target.

Pulsed laser irradiation induces the generation of alloy cluster ions for the screening of protease activity

Pulsed laser irradiation can cause the fragmentation of nanoparticles, which generates cluster ions. This allows nanoparticles to be adopted as mass tag/signal amplifiers in laser desorption/ionization mass spectrometry (LDI-MS) bioassays. Herein, we demonstrate the potential of using the signal from alloy cluster ions in bioassays through a fibrin clot model to determine the activity of thrombin. A mixed solution of silver and gold nanoparticles functionalized with fibrinogen (Fg‒Ag NPs/Fg‒Au NPs) treated with thrombin can form clots composed of aggregated fibrin-Au NPs/Ag NPs. These clots analyzed with LDI-MS are noted to form intense Ag–Au alloy cluster ions, especially [Ag2Au]+, which were used to detect thrombin concentration with a dynamic range of 2.5–50 pM in human plasma. This sensing platform was further employed for the screening of direct thrombin inhibitors. This work developed a novel bioassay utilizing metallic gas-phase reactions generated from pulsed laser irradiation of aggregated nanoparticles to monitor enzymatic activity and to screen inhibitors. We believe that LDS-MS can serve as a new platform for gas-phase reaction-based bioassays.

Generation of energetic ions with non-Maxwellian energy distribution from a double-layer target irradiated by an ultra-intense laser pulse

Generation of energetic ions with non-Maxwellian energy distribution from a double-layer target irradiated by an ultra-intense laser pulse

Visible Light-Promoted Diazoacetates and Nitriles Generating Nitrilium Ions Trapped by Benzotriazoles and Carboxylic Acids.

A visible light-promoted generation of nitrilium ions from diazoacetates and nitriles has been developed. The reaction utilized visible light transformation of diazoacetates to the free carbene that could be trapped by nitriles to generate nitrilium ions, followed by nucleophilic attack on the benzotriazoles and carboxylic acids. This protocol provides an efficient and practical approach to N-imidoylbenzotriazoles and diacylglycine esters in good to excellent yields.

Mid-Infrared Laser Generation of Zn1-xMnxSe and Zn1-xMgxSe (x ≈ 0.3) Single Crystals Co-Doped by Cr2+ and Fe2+ Ions-Comparison of Different Excitation Wavelengths.

Two different mid-infrared (mid-IR) solid-state crystalline laser active media of Cr, Fe:ZnMnSe and Cr, Fe:ZnMgSe with similar amounts of manganese or magnesium ions of x ≈ 0.3 were investigated at cryogenic temperatures for three different excitation wavelengths: Q-switched Er:YLF laser at the wavelength of 1.73 m, Q-switched Er:YAG laser at 2.94 m, and the gain-switched Fe:ZnSe laser operated at a liquid nitrogen temperature of 78 K at ∼4.05 m. The temperature dependence of spectral and laser characteristics was measured. Depending on the excitation wavelength and the selected output coupler, both laser systems were able to generate radiation by Cr or by Fe ions under direct excitation or indirectly by the Cr→ Fe energy transfer mechanism. Laser generation of Fe ions in Cr, Fe:ZnMnSe and Cr, Fe:ZnMgSe (x ≈ 0.3) crystals at the wavelengths of ∼4.4 and ∼4.8 m at a temperature of 78 K was achieved, respectively. The excitation of Fe ions in both samples by direct 2.94 m as well as ∼4.05 m radiation or indirectly via the Cr→ Fe ions’ energy transfer-based mechanism by 1.73 m radiation was demonstrated. Based on the obtained results, the possibility of developing novel coherent laser systems in mid-IR regions (∼2.3–2.5 and ∼4.4–4.9 m) based on AB matrices was presented.

Effects of aromatic molecules inside argon clusters on the formation of multiply charged atomic ions in moderately intense nanosecond laser fields.

We report the effect of two molecular species, fluorene (C13H10, Fl) and 1, 3, 5-trichlorobenzene (C6H3Cl3, 3ClB), embedded in atomic argon clusters, on the generation of multiply charged atomic ions (MCAIs) in moderately intense nanosecond laser fields at 532nm. The near resonant-enhancement of two photon absorption in the two aromatic species produces only a few low charge state (+2) atomic ions in a neat molecular cluster, but the enclosure of the same cluster with layers of Ar can significantly increase the charge state of MCAIs. The yields of singly charged atomic ions from the molecular species, such as H+, C+, and Cl+, are positively correlated with the number of molecules inside the Ar cluster, but the yields of the MCAI and Ar+ demonstrate opposite behaviors. A higher number of aromatic molecules are actually detrimental to the production of Ar+ and MCAIs. The results of exponential fittings of the yields of MCAIs at different laser intensities reveal a systematic change for the exponent of Ar+: with increasing concentrations of 3ClB in Ar clusters, the exponent decreases and eventually reaches the same value as those of MCAIs. These results are consistent with our previous hypothesis that the formation mechanism of MCAIs may be different from that of singly charged species and that the strong resonance of Ar3 + may play an important role in the overall energy absorption. Moreover, the effect of the molecular core seems to change the formation mechanism of Ar+ to that of MCAIs.

Generation and motion of pickup ions in the upstream regionof Mars

Generation and motion of pickup ions in the upstream regionof Mars

A Theoretical Investigation into pH of Neat Water at the Nanoscopic Scale Via Rexpon Force Field and Stochastic Simulations

Design of durable solar CO2 conversion devices requires a mechanistic understanding of molecular-level reactions at the electrode-electrolyte interface that lead to interfacial degradation.[1] This interface often incorporates such features as a porous and rough surface to maximize active area and enhance catalytic performance. However, this roughness may introduce local water pool inclusions, whose size may have an unforeseen, detrimental impact on device durability due to their local pH being very different from the bulk pH. It is well-recognized that for water pools containing less than molecules, the solution pH cannot be defined in the conventional sense because the pools are too small to support stable water ion concentrations near neutral pH. Rather, the water ion concentrations fluctuate to very high values for short periods of time. To better understand pH in small pools, we combine theoretical calculations using QM/MD and stochastic simulations [3]. We combined Ab initio MD and the accurate RexPoN force field [2] simulation to quantify the thermodynamic free energy to create water ion pairs through the reaction as a function of the water pool size. The free energies are used to calculate the equilibrium constants for this reaction and the ion pair generation and recombination rate constants. The rate constants are then used as inputs to the stochastic simulations to gain insights into ion pair generation frequency and lifetime statistics over extended periods of time (hours). Proton and hydroxide diffusion are also incorporated in the stochastic simulation to understand how far water ions may travel from where they are generated. The results show that the combination of Grotthuss and vehicular diffusion mechanisms for H3O+ and OH- can lead to unequal distributions at an adjacent interface. We will discuss how the stochastic generation and recombination of water ions influences buffer chemistry and dissolved CO2 chemistry.Reference[1] S. Nitopi, E. Bertheussen, S.B. Scott, X. Liu, A.K. Engstfeld, S. Horch, B. Seger, I.E.L. Stephens, K. Chan, C. Hahn, J.K. Nørskov, T.F. Jaramillo, I. Chorkendorff, Progress and Perspectives of Electrochemical CO2 Reduction on Copper in Aqueous Electrolyte, Chem. Rev. 119 (2019) 7610–7672. https://doi.org/10.1021/acs.chemrev.8b00705.[2] S. Naserifar, W.A. Goddard, The quantum mechanics-based polarizable force field for water simulations, J. Chem. Phys. 149 (2018). https://doi.org/10.1063/1.5042658.[3] W.D. Hinsberg, F.A. Houle, Kinetiscope, (n.d.). http://www.hinsberg.net/kinetiscope.

Simulation of Cathode Catalyst Durability Under Fuel Cell Vehicle Operation - the Effect of Fuel Cell Stack Size

The concerns regarding climate change have made the researchers seek a clean alternative for the fossil fuel vehicles. Fuel cell vehicles (FCVs) are considered to be promising candidates owing to their efficient energy conversion and zero-carbon emission. However, a number of obstacles such as high cost and limited hydrogen infrastructure have made the FCVs commercialization process challenging. Polymer electrolyte membrane fuel cells (PEMFCs) have been proven promising for transportation applications. For heavy duty transportation applications, the PEMFC durability is also not yet proven, and extrapolating from lab data to real-world field operating conditions remains a significant challenge [1].In this work, the cathode catalyst degradation in PEMFC is studied to estimate the effect of stack size on fuel cell durability in the FCV application. Platinum dissolution and redeposition, platinum oxidation and platinum ion formation during the fuel cell operation are modeled using the Butler-Volmer approach presented in [2]. A drive cycle recorded based on a real-life transit bus operation in the city of Victoria is utilized to calculate the input fuel cell voltage profile based on the methodology presented by Ahmadi and Kjeang [3]. According to this methodology, the required cell power density is calculated using Newton’s second law considering the air flow drag force as a counteracting force against the vehicle movement. Then, the required voltage cycle is obtained by employing a polarization curve characterizing the fuel cell performance. Finally, the change of remaining electrochemically active surface area (ECSA) with time is calculated as the output of the model. The fuel cell is assumed to operate at 80 ℃ and the cell active area is considered to be 500 cm2. Simple Tafel kinetics is then used to determine the fuel cell voltage loss. A 10% voltage drop at 0.6 A/cm2 is considered as the failure criterion for the cathode lifetime. Moreover, the effect of the fuel cell stack size is studied. By increasing fuel cell stack size, the required cell power density drops, leading to a decrease in the voltage cycle amplitude while the voltage cycle period remains the same. According to the empirical kinetic rate equation, the catalyst degradation exponentially increases with increasing the voltage. Therefore, a higher degradation rate is observed for a catalyst operating on a voltage cycle with a lower amplitude while the period and the upper potential limit (UPL) are maintained the same, causing a significant platinum ion generation. Fig. 1 shows the change of remaining ECSA over time and resulting fuel cell lifetime for three stack sizes which are represented by the stack nominal powers. The results show that the fuel cell lifetime will be roughly doubled when the stack size is reduced by half. Stack sizing is thus an important consideration for fuel cell durability in the FCV application.In this regard, predicting fuel cell lifetime is a crucial step in commercializing FCVs. The present modeling framework could be utilized by FCV developers to predict lifetime for new products instead of carrying out time-consuming lifetime experiments. The factors influencing fuel cell durability can also be investigated using the present model framework to develop durables cells and stacks for a targeted FCV application. Acknowledgements This research was supported by the Natural Sciences and Engineering Research Council of Canada, Canada Research Chairs, and Simon Fraser University Community Trust Endowment Fund.

Determining the dynamics of electromagnetic fields, air ionization, low-frequency sound and their normalization in premises for computer equipment

This paper reports a study into the quantitative values and dynamics of physical factors in premises and workplaces of stationary and portable computers. The factors that are practically not perceived by the senses of operators were investigated. It is established that modern monitors do not generate electromagnetic fields of hygienically significant levels. System units generate electric fields (18‒22 V/m) and magnetic fields (220‒245 nT) that are approaching the maximum permissible. Sources of uninterruptible power supply and fluorescent lighting systems generate excess magnetic fields (up to 2250 nT and 2300 nT), respectively. The main excessive factor for portable computers is electric fields (up to 9 kV/m), which is the cause of air deionization in the user's zone of stay. It is shown that one system unit in the normative volume of the room (20 m3) deionizes air (into 100 cm-3 positive and 200 cm-3 negative). The generation of ions by modernized laser printers and photocopiers of various models (up to 1500 cm-3 and 2800 cm-3, respectively) was investigated. The distances at which the ionic composition of the air corresponds to the background values (1.0‒1.5 m) were determined. That requires the introduction of artificial air ionization in workplaces of users and a decrease in the levels of electrostatic fields. The spectral composition and amplitudes of magnetic fields of external power supplies of laptop computers were determined. It is shown that the difference in sound levels measured on the scales "Lin" and "A" reaches 24 dB, which indicates a significant impact of infrasound on users. Membrane-type protective panels configured for maximum resonant frequencies of low-frequency sound and infrasound have been proposed

Microwave-prepared Ti/RuO2-IrO2 anodes: Influence of IrO2 content on atrazine removal

Electrochemical oxidation is a promising technology for treating wastewater, although the search for new efficient and economically viable electrode materials is still necessary. Within this context, mixed metal oxide anodes appear as excellent alternatives, but their formulation is still an important point to study, looking for obtaining low-cost materials with high electrocatalytic efficiencies. In the search for these highly-efficient anodes, here, we prepared three different coatings (RuO2)0.7(IrO2)0.3, (RuO2)0.8(IrO2)0.2, and (RuO2)0.9(IrO2)0.1 using microwave hybrid heating. All the prepared anodes exhibit excellent physical and electrochemical properties. However, as the proportion of IrO2 increases in the anode, the voltammetric charge and the contribution of the internal active sites increase, as well as the capacity for the electrochemical generation of hypochlorite ions. The electrochemical treatment of atrazine was performed using the synthesized electrodes and applying different current densities (20, 40, 60 mA cm–2). Faster and more efficient electrochemical oxidation occurs by applying 20 mA cm–2, regardless of the anode used, and the (RuO2)0.7(IrO2)0.3 anode reaches the best performance. Finally, an important figure of merit was analyzed, the electrical energy by one order of magnitude (EEO) used to remove atrazine. The anode (RuO2)0.7(IrO2)0.3 reduced the EEO down to two folds for the optimal current density (20 mA cm–2) compared with the other anodes studied, highlighting its good features for treating effluents contaminated with pesticides.

A novel Sillén-structured Bi-based oxybromide: CdBiO2Br ultrathin nanosheets for enhanced photocatalytic activity

: According to the typical Sillén-structured BiOBr, a simple solvothermal method was used to successfully synthesize Sillén-structured bimetallic oxyhalide CdBiO2Br with the existence of 1-hexadecyl-3-methylimidazolium bromide ([C16mim]Br), a kind of reactive ionic liquid. The introduction of the metal cadmium, which can form Sillén-structured bimetallic oxyhalide, made the alternating structure of BiOBr originally [Bi2O2]2+ and bilayer Br- modified to that of [CdBiO2]+ and monolayer Br-. So that the distance between layer and layer is greatly shortened, which facilitates the migration and separation of photogenerated carriers and promotes the generation of more reactive oxygen species. After modification, the band positions of CdBiO2Br materials can make more full use of visible light and more favorable utilization of solar resources. As confirmed by radical trapping analysis and ESR analysis, superoxide radical (·O2 -) and hole (h+) acted the major part during photocatalysis. The possible intermediate products that appeared during the degradation progress were analyzed by LC-MS. Moreover, the generation of superoxide ions was quantitatively analyzed by nitroblue tetrazolium chloride (NBT). In this paper, we present an ultra-thin layered material for visible light catalysis, which enlightens a feasible scheme for the research and development of new layered photocatalytic materials.

Microanalysis of Brain Angiotensin Peptides Using Ultrasensitive Capillary Electrophoresis Trapped Ion Mobility Mass Spectrometry.

While the role of the renin-angiotensin system (RAS) in peripheral circulation is well characterized, we still lack an in-depth understanding of its role within the brain. This knowledge gap is sustained by lacking technologies for trace-level angiotensin detection throughout tissues, such as the brain. To provide a bridging solution, we enhanced capillary electrophoresis (CE) nanoflow electrospray ionization (ESI) with large-volume sample stacking and employed trapped ion mobility time-of-flight (timsTOF) tandem HRMS detection. A dynamic pH junction helped stack approximately 10 times more of the sample than optimal using the field-amplified reference. In conjunction, the efficiency of ion generation was maximized by a cone-jet nanospray on a low sheath-flow tapered-tip nano-electrospray emitter. The platform provided additional peptide-dependent information, the collision cross section, to filter chemical noise and improve sequence identification and detection limits. The lower limit of detection reached sub-picomolar or ∼30 zmol (∼18,000 copies) level. All nine targeted angiotensin peptides in mouse tissue samples were detectable and quantifiable from the paraventricular nucleus (PVN) of the hypothalamus even after removal of circulatory blood components (perfusion). We anticipate CE-ESI with timsTOF HRMS to be broadly applicable for the ultrasensitive detection of brain peptidomes in pursuit of a better understanding of the brain.

Electrostatic Spray Disinfection Using Nano-Engineered Solution on Frequently Touched Surfaces in Indoor and Outdoor Environments.

The COVID-19 pandemic has resulted in high demand for disinfection technologies. However, the corresponding spray technologies are still not completely optimized for disinfection purposes. There are important problems, like the irregular coverage and dripping of disinfectant solutions on hard and vertical surfaces. In this study, we highlight two major points. Firstly, we discuss the effectiveness of the electrostatic spray deposition (ESD) of nanoparticle-based disinfectant solutions for systematic and long-lasting disinfection. Secondly, we show that, based on the type of material of the substrate, the effectiveness of ESD varies. Accordingly, 12 frequently touched surface materials were sprayed using a range of electrostatic spray system parameters, including ion generator voltage, nozzle spray size and distance of spray. It was observed that for most cases, the surfaces become completely covered with the nanoparticles within 10 s. Acrylic, Teflon, PVC, and polypropylene surfaces show a distinct effect of ESD and non-ESD sprays. The nanoparticles form a uniform layer with better surface coverage in case of electrostatic deposition. Quantitative variations and correlations show that 1.5 feet of working distance, an 80 m spray nozzle diameter and an ion generator voltage of 3–7 kV ensures a DEF (differential electric field) that corresponds to an optimized charge-to-mass ratio, ensuring efficient coverage of nanoparticles.

Methodical Approach to Inactivate Any Microbial Element like SARS-CoV2.

The proposed paper discusses Far UVC could assassinate microbes without harming healthy tissues. The plasma ion generation will increase the ion (O2−) generation in abundance along with hydrogen ion (H+), and at the same time, the negative hydroxyl radical (OH−) formed will merge with the positive (H+) ion of the virus to break the structure of it. The silver nanoparticle which is present in the diffuser with thermostat support is very effective for destroying the microbial elements by heating the gel present within the diffuser. The gel will mix in the environment, and it will also increase the activity of T cell generation and act as an immunoglobulin booster in the human body while inhaling it. In the proposed device, we are using warm humidified CO2 strategic therapy in low dose which is able to suppress any microbial element like SARS-CoV2.

Industrially microfabricated ion trap with 1 eV trap depth

Scaling trapped-ion quantum computing will require robust trapping of at least hundreds of ions over long periods, while increasing the complexity and functionality of the trap itself. Symmetric three-dimensional (3D) structures enable high trap depth, but microfabrication techniques are generally better suited to planar structures that produce less ideal conditions for trapping. We present an ion trap fabricated on stacked eight-inch wafers in a large-scale micro-electro-mechanical system microfabrication process that provides reproducible traps at a large volume. Electrodes are patterned on the surfaces of two opposing wafers bonded to a spacer, forming a 3D structure with 2.5 μm standard deviation in alignment across the stack. We implement a design achieving a trap depth of 1 eV for a 40Ca+ ion held at 200 μm from either electrode plane. We characterize traps, achieving measurement agreement with simulations to within ±5% for mode frequencies spanning 0.6–3.8 MHz, and evaluate stray electric field across multiple trapping sites. We measure motional heating rates over an extensive range of trap frequencies, and temperatures, observing 40 phonons/s at 1 MHz and 185 K. This fabrication method provides a highly scalable approach for producing a new generation of 3D ion traps.

Fragmentation pathways of deprotonated ortho-hydroxybenzyl alcohol.

The ortho, meta, and para isomers of hydroxybenzyl alcohol can be unequivocally distinguished by the collision-induced dissociation mass spectra of their anions. The presence of a prominent peak at m/z 121 for an elimination of a dihydrogen molecule renders the ortho-isomer spectrum markedly different from those of its meta and para congeners. Investigations carried out with deuterium-labeled isotopologues of the ortho isomer verified that the labile hydrogen atom on the hydroxyl group and one of the benzylic hydrogen atoms are specifically removed in the formation of the m/z 121 ion. The ortho-isomer spectrum also showed a prominent peak at m/z 93. Experimental data indicated that the m/z 93 product ion originates either from a two-step H2and CO elimination mechanism or from a direct loss of a HCHO molecule from the precursor anion. The intensity ratio of the m/z 93 and 94 peaks in the spectrum recorded from the m/z 124 ion generated from a sample of o-hydroxybenzyl alcohol dissolved in D2O supported the notion that the direct HCHO loss is the more dominant pathway for the generation of the phenolate ion under low activation conditions. In contrast, the two-step mechanism becomes the more dominant pathway under high collisional activation conditions. The spectrum also showed a weak peak at m/z 105 for a water loss. Based on computational data, the m/z 105 ion generated in this way appears to be a composite generated from a common ion-neutral complex intermediate in which a hydroxyl anion is positioned equidistantly between one of the benzylic hydrogens and a nearby hydrogen atom of the benzene ring. Upon activation, the complex dissociates to form either a phenide or a quinone methide anion. The reaction forming a carbon dioxide adduct under ion-mobility conditions was used to support the proposed water-loss mechanism.