Gasoline Direct Injection Engine Exhaust Research Articles

Chemical characterization of size-selected nanoparticles emitted by a gasoline direct injection engine: Impact of a catalytic stripper

This work combines laser desorption/ionization mass spectrometry (L2MS) and advanced statistical techniques to reveal the impact of a catalytic stripper (CS) on the chemical composition (at the molecular level) of a gasoline direct injection engine exhaust, and follow the evolution of size-dependent chemical characteristics over the whole particles size range (10–560nm). The gas phase and polydisperse particles making up the exhaust are separated and sampled on distinct substrates using an original homebuilt two-filter system, while size-selected particles are collected using a cascade impactor and separated into 13 different size bins (smallest diameters 10–18nm). We demonstrate that a fine molecular-level characterization of the exhaust particulate matter is necessary to assess the effect of the CS, especially for the smallest ultra-fine particles carrying the largest volatile fraction.

Potential of Ceria-Zirconia-Based Materials in Carbon Soot Oxidation for Gasoline Particulate Filters

ZrO2 and Ce0.8Zr0.2O2 mixed oxides were prepared and tested in the oxidation of carbon soot at different oxygen partial pressures and degrees of catalyst/soot contact to investigate their activity under typical gasoline direct injection (GDI) operating conditions. Under reductive atmospheres, generation of oxygen vacancies occurs in Ce0.8Zr0.2O2, while no reduction is observed on ZrO2. Both materials can oxidize carbon under high oxygen partial pressures; however, at low oxygen partial pressures, the presence of carbon can contribute to the reduction of the catalyst and formation of oxygen vacancies, which can then be used for soot oxidation, increasing the overall performance. This mechanism is more efficient in Ce0.8Zr0.2O2 than ZrO2, and depends heavily on the interaction and the degree of contact between soot and catalyst. Thus, the ability to form oxygen vacancies at lower temperatures is particularly helpful to oxidize soot at low oxygen partial pressures, and with higher CO2 selectivity under conditions typically found in GDI engine exhaust gases.

Design and evaluation of a sintered metal fiber filter for gasoline direct injection engine exhaust aftertreatment

A novel metal fiber gasoline particulate filter (GPF) is designed and evaluated as a potential improvement to the traditional automotive wall flow substrate. A procedure based on single fiber efficiency theory and the Kuwabara flow model for fibrous filter media is developed to optimize filter design. The prototype design is derived from two constraints, namely to maximize PM removal efficiency while minimizing filter backpressure. Metal fibers are chosen that tolerate gasoline engine exhaust temperatures and pleating is used to fulfill size limits dictated by vehicle space constraints. Two prototypes are evaluated by vehicle and engine dynamometer testing. These tests reveal PM filtration efficiencies of greater than 78% for both the FTP and US06 drive cycles, with an average backpressure of approximately 1 kPa over a US06 drive cycle on a 2.0 L GDI light duty vehicle. Measured PM removal efficiencies at constant exhaust temperature and flowrate agree well with model predictions. Backpressure predictions agree withs measurements after accounting for GPF entrance and exit effects. The metal fiber GPF performance is discussed relative to the current state of the art wall flow filters and the limited literature data on metal foam filters. Whereas the fibrous media offers excellent efficiency and backpressure penalty, achieving surface areas comparable to wall flow substrates remains a challenge for practical implementation.

Carbonaceous aerosol sampling of gasoline direct injection engine exhaust with an integrated organic gas and particle sampler

Positive and negative artifacts of particle-phase organic carbon (p-OC) and the polycyclic aromatic hydrocarbons (PAHs) in gasoline direct injection (GDI) engine exhaust particulate matter (PM) were assessed using an integrated organic gas and particle sampler (IOGAPS). Three configurations (denuder + sorbent impregnated filters (SIFs), upstream Zefluor filter + denuder + SIFs, and standard filter pack + SIFs) were used to collect GDI exhaust samples at cold start and highway cruise operating conditions with no aftertreatment. Approximately 35% of the measured GDI p-OC was attributed to positive artifacts; negative artifacts were not detectable due to low overall SVOC concentrations. GDI engine exhaust PAH concentrations were approximately 10 times higher during cold start than highway cruise. At highway cruise, pyrene and fluoranthene were the dominant PAHs in the undenuded filter pack; downstream of the denuder benzo(a)anthracene was the dominant PAH. From a comparison of our findings to published PAH emission factors we estimate that three-way catalyst conversion efficiencies of PAHs were approximately 80% for 3 of the 15 PAHs measured during highway cruise operation. These conversion efficiencies may be considerably lower during cold start operation when the three-way catalyst has not reached its operating temperature. Our previous work showed that adverse biological responses to GDI engine exhaust exposure may be dominated by the particle phase when measured downstream of a Teflon filter. Understanding the partitioning characteristics of PAHs may help elucidate specific PAHs contributing to this effect.

Comparison of Airway Responses Induced in a Mouse Model by the Gas and Particulate Fractions of Gasoline Direct Injection Engine Exhaust.

Diesel exhaust has been associated with asthma, but its response to other engine emissions is not clear. The increasing prevalence of vehicles with gasoline direct injection (GDI) engines motivated this study, and the objective was to evaluate pulmonary responses induced by acute exposure to GDI engine exhaust in an allergic asthma murine model. Mice were sensitized with an allergen to induce airway hyperresponsiveness or treated with saline (non-allergic group). Animals were challenged for 2-h to exhaust from a laboratory GDI engine operated at conditions equivalent to a highway cruise. Exhaust was filtered to assess responses induced by the particulate and gas fractions. Short-term exposure to particulate matter from GDI engine exhaust induced upregulation of genes related to polycyclic aromatic hydrocarbon (PAH) metabolism (Cyp1b1) and inflammation (TNFα) in the lungs of non-allergic mice. High molecular weight PAHs dominated the particulate fraction of the exhaust, and this response was therefore likely attributable to the presence of these PAHs. The particle fraction of GDI engine exhaust further contributed to enhanced methacholine responsiveness in the central and peripheral tissues in animals with airway hyperresponsiveness. As GDI engines gain prevalence in the vehicle fleet, understanding the health impacts of their emissions becomes increasingly important.

Murine precision-cut lung slices exhibit acute responses following exposure to gasoline direct injection engine emissions

Gasoline direct injection (GDI) engines are increasingly prevalent in the global vehicle fleet. Particulate matter emissions from GDI engines are elevated compared to conventional gasoline engines. The pulmonary effects of these higher particulate emissions are unclear. This study investigated the pulmonary responses induced by GDI engine exhaust using an ex vivo model. The physiochemical properties of GDI engine exhaust were assessed. Precision cut lung slices were prepared using Balb/c mice to evaluate the pulmonary response induced by one-hour exposure to engine-out exhaust from a laboratory GDI engine operated at conditions equivalent to vehicle highway cruise conditions. Lung slices were exposed at an air-liquid interface using an electrostatic aerosol in vitro exposure system. Particulate and gaseous exhaust was fractionated to contrast mRNA production related to polycyclic aromatic hydrocarbon (PAH) metabolism and oxidative stress. Exposure to GDI engine exhaust upregulated genes involved in PAH metabolism, including Cyp1a1 (2.71, SE=0.22), and Cyp1b1 (3.24, SE=0.12) compared to HEPA filtered air (p<0.05). GDI engine exhaust further increased Cyp1b1 expression compared to filtered GDI engine exhaust (i.e., gas fraction only), suggesting this response was associated with the particulate fraction. Exhaust particulate was dominated by high molecular weight PAHs. Hmox1, an oxidative stress marker, exhibited increased expression after exposure to GDI (1.63, SE=0.03) and filtered GDI (1.55, SE=0.04) engine exhaust compared to HEPA filtered air (p<0.05), likely attributable to a combination of the gas and particulate fractions. Exposure to GDI engine exhaust contributes to upregulation of genes related to the metabolism of PAHs and oxidative stress.

Development of a soot particle model with PAHs as precursors through simulations and experiments

In the present study, the polycyclic aromatic hydrocarbons (PAHs) and soot particulates emitted from a gasoline direct injection (GDI) engine were sampled and analyzed. The results show that the vapor-phase PAHs and particulate-bound PAHs exist in GDI engine exhaust emissions. Soot particles are formed by the agglomeration of the quasi-spherical primary carbon particles, and the size of the PAH cluster is close to that of the core of the primary carbon particles. To predict soot particulates evolution in the engine cylinder, a reduced toluene reference fuel (TRF)-PAH chemical mechanism consisting of iso-octane, n-heptane and toluene as gasoline surrogate fuels for the GDI engine combustion simulation was developed. The reduced mechanism contains 232 reactions and 85 species, including 17 species and 40 elementary reactions, related to the PAH formation, which could well capture the oxidation characteristics of ignition delays and laminar flame speeds, as well as PAH emissions from the GDI engine. Then, a mathematical soot growth model coupled with the reduced TRF-PAH mechanism was developed based on the method of moment. The obtained experimental soot emissions were well predicted by this soot model. The distribution of particle number density was consistent with the distribution of A4 and C2H2, and the growth and distribution of soot mass was determined by the particle surface growth due to C2H2, the nuclear reaction of A4 and the particle surface oxidation reaction.

An experimental study of polycyclic aromatic hydrocarbons and soot emissions from a GDI engine fueled with commercial gasoline

This study investigated the chemical characteristics of polycyclic aromatic hydrocarbons (PAHs) and soot particulates emitted from a gasoline direct injection (GDI) engine. The microcosmic morphology of the soot particulate and the correlations between PAH species and the primary carbon particles were studied during dynamometer testing of different engine operating conditions using our purpose-built sampling system. The obtained extracts of PAH samplings and soot samplings were analyzed qualitatively and quantitatively using gas chromatograph–mass spectrometry (GC–MS) and field-emission transmission electron microscopy (FE-TEM). The vapor-phase and particulate-bound PAHs exist in the GDI engine exhaust emissions. PAHs with two and three rings exist nearly entirely in the gas phase, whereas five or more fused rings are predominantly adsorbed on soot particles. The intermediate 4-ring PAHs exist in the two PAH phase. Naphthalene is the most abundant polyaromatic hydrocarbon that was detected in the exhaust vapor-phase PAHs, which was approximately three orders of magnitude higher than the PAHs in the particulate phase. PAHs and soot emissions could be significantly reduced by increasing the injection pressure and by introducing the exhaust gas into the cylinders. Particulate-bound PAHs A4–A6 were suitable for estimating soot emissions from GDI engines. Soot particles are formed by the agglomeration of the quasi-sphere primary carbon particles. Most of the primary carbon particles exhibit an onion-shell nanostructure, with less disordered and amorphous structures.

A source-independent empirical correction procedure for the fast mobility and engine exhaust particle sizers

The TSI Fast Mobility Particle Sizer (FMPS) and Engine Exhaust Particle Sizer (EEPS) provide size distributions for 6–560 nm particles with a time resolution suitable for characterizing transient particle sources; however, the accuracy of these instruments can be source dependent, due to influences of particle morphology. The aim of this study was to develop a source-independent correction protocol for the FMPS and EEPS. The correction protocol consists of: (1) broadening the >80 nm size range of the distribution to account for under-sizing by the FMPS and EEPS; (2) applying an existing correction protocol in the 8–93 nm size range; and (3) dividing each size bin by the ratio of total concentration measured by the FMPS or EEPS and a water-based Condensation Particle Counter (CPC) as a surrogate scaling factor to account for particle morphology. Efficacy of the correction protocol was assessed for three sources: urban ambient air, diluted gasoline direct injection engine exhaust, and diluted diesel engine exhaust. Linear regression against a reference instrument, the Scanning Mobility Particle Sizer (SMPS), before and after applying the correction protocol demonstrated that the correction ensured agreement within 20%.

Novel Characterization of GDI Engine Exhaust for Gasoline and Mid-Level Gasoline-Alcohol Blends

Gasoline direct injection (GDI) engines can offer improved fuel economy and higher performance over their port fuelinjected (PFI) counterparts, and are now appearing in increasingly more U.S. and European vehicles. Small displacement, turbocharged GDI engines are replacing large displacement engines, particularly in light-duty trucks and sport utility vehicles, in order for manufacturers to meet more stringent fuel economy standards. GDI engines typically emit the most particulate matter (PM) during periods of rich operation such as start-up and acceleration, and emissions of air toxics are also more likely during this condition. A 2.0 L GDI engine was operated at lambda of 0.91 at typical loads for acceleration (2600 rpm, 8 bar BMEP) on three different fuels; an 87 anti-knock index (AKI) gasoline (E0), 30% ethanol blended with the 87 AKI fuel (E30), and 48% isobutanol blended with the 87 AKI fuel. E30 was chosen to maximize octane enhancement while minimizing ethanol-blend level and iBu48 was chosen to match the same fuel oxygen level as E30. Particle size and number, organic carbon and elemental carbon (OC/EC), soot HC speciation, and aldehydes and ketones were all analyzed during the experiment. A new method for soot HC speciation is introduced using a direct, thermal desorption/pyrolysis inlet for the gas chromatograph (GC). Results showed high levels of aromatic compounds were present in the PM, including downstream of the catalyst, and the aldehydes were dominated by the alcohol blending.