Gasket Material Research Articles

Measuring very low radiation doses in PTFE for nuclear forensic enrichment reconstruction

Every country that has made nuclear weapons has used uranium enrichment to do so. Despite the centrality of this technology to international security, there is still no reliable physical marker of past enrichment in the open literature that can be used to perform forensic verification of historically produced weapons on gas centrifuges. We show that the extremely low radioactivity from uranium alpha emissions during enrichment leaves detectable and irreversible calorimetric signatures in the common enrichment gasket material PTFE, allowing for historical reconstruction of past enrichment activities at a sensitivity better than one weapon's quantity of highly enriched uranium. Fast scanning calorimetry also enables the measurement of recrystallization enthalpies of sequentially microtomed slices, confirming the magnitude and the type of radiation exposure while also providing detection of tampering and a method for analyzing field samples useful for treaty verification. This work opens the door for common items to be turned into precise dosimeters to detect the past presence of radioactivity, nuclear materials, and related activities with high confidence.

A novel means to generate high pressure.

Diamond anvil cells are the most popular means of generating pressures above 2GPa. However, in many experiments, such as nuclear magnetic resonance and x-ray absorption, the metallic pressurizing gasket (which confines much of the sample) represents an occluding barrier that requires a low Z gasket material (e.g., Be), a split gasket, or other means to enable better coupling of the sample to electromagnetic radiation. In this paper, we demonstrate a novel method for generating high pressures that confines the sample just above the plane of the gasket by using a diamond with a laser hole drilled into the center of the tip. The sample is then confined by the hole, which is sealed by a flat gasket that fits over the hole. When load is applied to the diamonds, metal flows from the deformed gasket into the hole thereby pressurizing the sample similarly to how a piston pressurizes gas inside a cylinder. The pressurized sample is above the metallic gasket plane just inside the tip of the diamond, and thus easily accessible via x rays or visible light that skims just above the plane of the gasket providing an enhanced aperture of radiation collection. We have demonstrated the utility of this method by obtaining Raman spectra of SnC2O4 and x-ray diffraction spectra of seleno-DL-cystine, all at high pressures.

Effect of gasket material on flange face corrosion

Bolted flanged joints play a crucial role in connecting pressure vessels and piping systems. The corrosion of the flange surface is one of the most common causes of leakage failure in bolted flanged joints. This research investigates the effect of three gasket materials on the corrosion behavior of 321 stainless steel flange material using a novel setup specially designed for corrosion quantification of such assemblies. The results show that graphite gaskets cause more corrosion to flange surfaces under the same working conditions compared to graphite gaskets with metal foil inserts and virgin polytetrafluoroethylene (PTFE) gaskets. The mechanism of flange face corrosion is that, for PTFE gaskets, corrosion propagation mainly occurs at the gasket inner diameter and propagates through the depth of the flange while, for graphite gaskets, corrosion occurs on the whole contact surface of the flange and the gasket.

Study on the sealing performance of high-pressure flanges by a magnetic measurement method of bolt axial force

Under high-pressure conditions, flange sealing often fails due to inadequate bolt pre-tension, leading to unstable pressurization or leakage. Assessing the integrity of high-pressure flange sealing presents challenges, constrained by operational conditions, complex equipment integration, and associated costs. This study introduces a method to evaluate flange sealing using magnetic measurements of bolt axial forces. A novel device developed using the magnetoelastic method efficiently and conveniently measures these forces under various internal pressures. The results show a linear relationship between magnetic signals and bolt axial forces at nominal pressures, whereas excessively high pressures cause anomalous changes in magnetic signals, indicative of bolt plastic deformation. Finite element simulation analyzed the changes in bolt axial force and gasket contact stress due to internal pressures, leading to an empirical formula that correlates these variables under varying pressures. The study also explored the impact of uneven pre-tensioning and gasket material on sealing contact stress. A sealing contact surface model, established based on actual roughness profile parameters, enabled the simulation and formulation of an exponential relationship between contact stress and sealing clearance. This foundation facilitated the creation of a leakage prediction model that incorporates bolt axial force parameters, thus enabling a quantitative assessment of flange sealing performance. This research provides a practical approach to evaluating the sealing performance of operational high-pressure flanges.

Mitigation of Silicon Contamination in Fuel Cell Gasket Materials through Silica Surface Treatment.

Gaskets and seals are essential components in the operation of proton exchange membrane (PEM) fuel cells and are required for keeping hydrogen and air/oxygen within their individual compartments. The durability of these gaskets and seals is necessary, as it influences not only the lifespan but also the electrochemical efficiency of the PEM fuel cell. In this study, the cause of silicon leaching from silicone gaskets under simulated fuel cell conditions was investigated. Additionally, to reduce silicon leaching, the silica surface was treated with methyltrimethoxysilane, vinyltriethoxysilane, and (3,3,3-trifluoropropyl)trimethoxysilane. Changes in the silica surface chemistry were investigated by scanning electron microscopy, energy dispersive X-ray spectroscopy, thermogravimetric analysis, elemental analysis, X-ray photoelectron spectroscopy, and Fourier transform infrared spectroscopy. Inductively coupled plasma-optical emission spectroscopy analysis revealed that surface-treated silica was highly effective in reducing silicon leaching.

The combined research of ultra-high vacuum CF flange joints' sealing parameters considering plastic properties of materials

Computer simulation and experimental research of the tightening processes of ultrahigh vacuum CF flange joints have been carried out. Finite element analyses were carried out considering the plastic properties of materials. The analysis variable parameters are flanges' knife edge angle between the shelves (Wheeler's and CERN's models), tip rounding radiuses, and gasket material state (annealed and hard). Curves of changes in the stress and strain intensities of the edge nodes of the flanges' knife edge were obtained. Essential sealing parameters of the ultrahigh vacuum system were also studied, such as the height of the knife edge, the length of the knife-edge trace on the gasket (in the radial direction), and the gap between two flanges. The mentioned sealing parameters' measurements were carried out by the combined method. The latter is a parameters' measurement of both computer simulation and experimental samples and a comparison of the obtained results. It should be noted that the sealing parameters were studied for several tightening cycles of the flanges to research their changes in case of multiple uses. The vital value of this research is obtained empirical functions for calculating the height of the flanges' knife edge based on the tightening cycles.

An Improved Fixture to Quantify Corrosion in Bolted Flanged Gasketed Joints

Abstract This study discusses the corrosion behavior of bolted flanged gasketed joint systems. A novel fixture is proposed to quantify the corrosion at the gasket–flange interface under service conditions. Due to the presence of crevices and potential differences between gaskets and flanges, corrosion widely occurs in such joints. Crevice corrosion and galvanic corrosion can create paths to leakage of the pressurized fluid and may cause catastrophic failure. Corrosion in bolted gasketed joints was investigated previously; however, the effects of the operating conditions were not reported. Operating conditions include fluid flow, pressure, pH, conductivity, temperature, and average gasket contact stress. This study starts by introducing a new experimental setup to examine the corrosion behavior of bolted flanged gasketed joints. The developed fixture consists of a pressurized bolted gasketed joint that enables real-time monitoring and recording of the corrosion parameters under the influence of service conditions. Second, potentiodynamic polarization testing is conducted to measure the corrosion rate and obtain data on the corrosion behavior of a pair of flange and gasket materials. These tests are performed using the novel setup that reproduces the behavior of industrial bolted flanged gasketed joint systems. It consists of a working electrode (flange material), a reference electrode (Ag/AgCl), and an auxiliary electrode (a stainless steel rod). Three types of graphite gaskets compressed in the fixture are subject to electrochemical corrosion tests with a 0.6 M NaCl solution. The morphology of the specimen's corroded surfaces is examined via confocal laser microscopy.

FEA Assessment of Contact Pressure and Von Mises Stress in Gasket Material Suitability for PEMFCs in Electric Vehicles

Ensuring the safety of electric vehicles is paramount, and one critical concern is the potential for hazardous hydrogen fuel leaks caused by the degradation of Proton-Exchange Membrane Fuel Cell (PEMFC) gasket materials. This study employs advanced techniques to address this issue. We leverage Finite Element Analysis (FEA) to rigorously assess the suitability of gasket materials for PEMFC applications, focusing on two crucial conditions: ageing and tensile stress. To achieve this, we introduce a comprehensive “dual degradation framework” that considers the effects of contact pressure and von Mises stress. These factors are instrumental in evaluating the performance and durability of Liquid Silicon Rubber (LSR) and Ethylene Propylene Diene Monomer (EPDM) materials. Our findings reveal the Yeoh model as the most accurate and efficient choice for ageing simulations, boasting a minimal Mean Absolute Percentage Error (MAPE) and computational time of just 0.27 s. In contrast, the Ogden model, while accurate, requires more computational resources. In assessing overall model performance using MAE, Root Mean Square Error (RMSE), and R-squared metrics, both LSR and EPDM materials proved promising, with LSR exhibiting superior performance in most areas. Furthermore, our study incorporates uniaxial tensile testing, which yields RMSE and MAE values of 0.30% and 0.40%, respectively. These results provide valuable insights into material behaviour under tensile stress. Our research underscores the pivotal role of FEA in identifying optimal gasket materials for PEMFC applications. Notably, LSR is a superior choice, demonstrating enhanced FEA modelling performance under ageing and tensile conditions. These findings promise to significantly contribute to developing safer and more reliable electric vehicles by advancing gasket material design.

Antigorite Dehydration under Compression and Shear Loadings in a Rotational Diamond Anvil Cell

Mineral dehydration in the subduction zone enormously affects Earth’s geodynamics and the global geochemical cycles of elements. This work uses Raman spectroscopy and X-ray diffraction to investigate the dehydration process of antigorite under compression and shear loading conditions in a rotational diamond anvil cell (RDAC) at room temperature. In order to compare the shear effects, T301 stainless steel and Kapton plastic are applied as the gasket materials. In the experiment using a high-strength T301 stainless steel gasket, two new broad OH-stretching peaks of H2O and H3O2− appear at 3303 and 3558 cm−1, respectively, at 1.7 GPa. The original sharp OH-stretching peaks of antigorite at 3668 and 3699 cm−1 remain, while the central pressure is increased to 8.0 GPa, and the largest pressure gradient is about 2.5 GPa in the sample chamber. In another experiment with a low-strength gasket of Kapton plastic, two new OH-stretching broad peaks of H2O and H3O2− also start to appear at 3303 and 3558 cm−1, respectively, at a lower pressure of 0.3 GPa, but the original sharp OH-stretching peaks of antigorite at 3668 and 3699 cm−1 almost completely vanish as the central pressure reaches 3.0 GPa, with the largest pressure gradient at around 4.8 GPa. The comparison between the two experiments shows that antigorite is easier to dehydrate in the chamber of a Kapton plastic gasket with a larger gradient of shear stress. However, its axial compression stress is lower. The high-pressure Raman spectra of MgO2(OH)4 octahedron and SiO4 tetrahedron in the low wavenumber zones (100–1200 cm−1) combined with the micro-beam X-ray diffraction spectrum of the recovered product strongly support the structural breakdown of antigorite. This investigation reveals that the water-bearing silicate minerals have strong shear dehydration in the cold subduction zone of the plate, which has important applications in predicting the physical and chemical properties of subduction zones and deducing the rate of plate subduction.

Influence of Manufactured-Part Design and Gasket Material on the Tightness of Flanged Joints Under Sharp Thermal Cycles in the Environment

Influence of Manufactured-Part Design and Gasket Material on the Tightness of Flanged Joints Under Sharp Thermal Cycles in the Environment

Microwave heating of graphene nanoplatelet polymer composites: Experimental and finite element study

AbstractCompared with contemporary electrofusion techniques that use embedded wires for Joule heating, microwave heating may facilitate the joining of thermoplastic polymer components, promising shortened fusion periods, superior heating uniformity, and reduced energy consumption. This study investigates the fabrication of multifunctional polylactide acid (PLA) composites with strong microwave absorption using graphene nanoplatelets (GNP). GNP/PLA nanocomposites were fabricated using a two‐step scalable manufacturing method, that is, solution blending and hot compression molding. The GNP content of the composites ranged from 0% to 8% by weight. The samples were characterized for dielectric permittivity, heat capacity, and electrical and thermal conductivity. Thermal imaging was used to investigate the efficacy of microwave heating in GNP/PLA nanocomposites as a function of microwave power and filler weight fractions. The microwave heating process in GNP composites was studied using multi‐physics finite element software. The experimental results were compared to numerical model predictions for maximum temperature and microwave energy absorbed. The produced nanocomposites were discovered to have strong microwave absorption characteristics and hence rapid heating, making this type of composite a prospective choice for gasket materials that facilitate fusion bonding for thermoplastic‐based components via localized heating.

DESIGN OF PLATE HEAT EXCHANGER FOR HEAT TREATMENT INDUSTRY

This study discusses the design of plate type heat exchangers (PHE). Conventional heat exchangers have many drawbacks, including difficult maintenance, high cost, and increased area usage. In contrast, plate heat exchangers have a number of benefits over traditional heat exchangers. Because the liquid spreads across the plate, PHE has a bigger surface area. The study discusses and explains the design of the plate type heat exchanger, plate material, chevron angle, and gasket material since the plate allows for faster heat transmission. Key Words: Plate heat exchanger, Design, materials.

Rate-dependent ratcheting characteristics of high density polyethylene subjected to cyclic pulsating compression

Monotonic and pulsating cyclic compression tests were performed systematically based on high density polyethylene (HDPE). The compressive creep behaviors were further implemented to compare with the ratcheting deformation under the same peak stress level. Monotonic compression experiments reveal that HDPE shows obvious four-stage characteristics which are sensitive to temperature, but independent of the stress rate when the temperature is greater than 80 °C. Interestingly, the strain range during the stage III always starts at 7.4% and ends at 62.6% under various temperatures and stress rates. Moreover, the compressive ratcheting behavior of HDPE significantly depends on temperature T, peak stress σp, stress rate σ˙, stress amplitude Δσ and stress ratio R, especially when T ≥ 80 °C, σp ≥15 MPa, σ˙ ≤0.1 MPa/s and R ≥ 0.8. Additionally, decreasing the stress rate or increasing the temperature will decrease the compressive modulus of HDPE. An approximate linear relationship between the creep strain rate and the ratcheting strain rate under different temperatures and stress ratios was observed. The compressive deformation characteristics of HDPE were compared with that of some other gasket materials, a universal phenomenon is found that the compressive ratcheting evolution with time can be characterized by creep approximately under the same loading peak stress, stress rate and temperature for various gasket materials when the stress ratio is greater than zero, which indicates that the ratcheting deformation for gaskets under cyclic loads may be estimated by the corresponding static creep strain in practical engineering.

Mechanical Aging Test and Sealing Performance of Thermoplastic Vulcanizate as Sealing Gasket in Automotive Fuel Cell Applications.

Ethylene-propylene-diene monomer (EPDM) rubber is one of the rapidly developing synthetic rubbers for use as a gasket material in proton exchange membrane (PEM) fuel cell applications. Despite its excellent elastic and sealing properties, EPDM faces challenges such as molding processability and recycling ability. To overcome these challenges, thermoplastic vulcanizate (TPV), which comprises vulcanized EPDM in polypropylene matrix, was investigated as a gasket material for PEM fuel cell applications. TPV showed better long-term stability in terms of tension and compression set behaviors under accelerated aging conditions than EPDM. Additionally, TPV exhibited significantly higher crosslinking density and surface hardness than EPDM, regardless of the test temperature and aging time. TPV and EPDM showed similar leakage rates for the entire range of test inlet pressure values, regardless of the applied temperature. Therefore, we can conclude that TPV exhibits a similar sealing capability with more stable mechanical properties compared with commercialized EPDM gaskets in terms of He leakage performance.

Numerical Simulation of Assembly Process and Sealing Reliability of T-Rubber Gasket Pipe Joints

Underground pipelines are vital parts to urban water supply, gas supply, and other lifeline systems, affecting the sustainable development of cities to a great extent. The pipeline joint, which is a weak link, may be seriously damaged during natural disasters such as earthquakes. The failure of pipe joints can cause leakage accidents, resulting in system failure and interruption, and even some secondary disasters. Herein, based on uniaxial and plane tensile test results of a T-rubber gasket material, the assembly process and sealing performance of a T-rubber gasket joint of a ductile iron pipe are numerically simulated using the Ogden third-order strain energy density function to fit the material constant. The simulation accounts for severe nonlinearities, including large deformations, hyperelasticity, and complex contacts. The effects of the assembly friction coefficient, assembly depth, and radial clearance deviation of the socket and spigot on the seal contact pressure are analyzed. The results suggest that the entire history of the deformation and stress variations during assembly can be clearly visualized and accurately calculated. For the different friction coefficients, the assembly depth corresponding to the sliding friction condition of the spigot pipe was 74 mm, while the minimum pushing force required to assemble the T-rubber gasket joint of a DN300 ductile iron pipe was 6.8 kN at the ideal situation with a friction coefficient of 0. The effective contact pressure of the rubber gasket seepage surface under various operating conditions is much higher than the normal pressure of municipal pipelines, thus indicating that the rubber gasket joint exhibits the ideal sealing performance. Furthermore, a certain deviation, which is about 20 mm, is allowed for the assembly depth of the rubber gasket joint such that the axial displacement of the pipe joint can be adapted under an earthquake or ground displacement.

Effects of Fixed Edge Conditions on the Load Resistance of Single Glass Lites

The load resistance (LR) of glass lites is determined in the United States by use of standards based on a probabilistic model of glass breakage. These standards generally restrict design to rectangular glass lites continuously supported along one, two, three, or four sides. In addition, these standards treat single glass lites as simply supported flat rectangular plates. Historically, rigid window frames supported single glass lites holding them in place with neoprene or similar gasket material. This attachment method approximated simply supported edges that rotate about an axis parallel to the simply supported edges, deform in the plane of the glass lite, and do not deflect out-of-plane. Advances in structural silicone make it possible to produce rectangular single flat glass lites with edge fixity somewhere between that of simply supported edges and fully fixed edges. The authors applied the glass failure prediction model (GFPM) to a nonlinear finite-element model developed previously by the authors to determine the probability of breakage for selected single glass lite geometries with fully fixed edges under uniform lateral loads. The paper presents comparisons between results of analyses of lites with fixed edges with analyses of lites with simply supported edges. The comparisons indicate that not all single glass lite geometries benefit from fully fixing edges, but the benefits of doing so appear to increase as lite aspect ratio (AR) increases. The comparisons bracket benefits that can accrue from the partial fixity provided by structural silicone supports. The actual degree of fixity provided by structural silicone can only be determined experimentally, which lies outside the scope of this paper.

Influence of flange geometric configuration and bolt stress on joint integrity during assembly using FEA

The aim of this study is to develop a procedure suitable to determine the maximum bolt pre-stress required for the proper gasket seating in bolted flange connections. The proposed method is valid for all the flange types and assumes that the gasket leakage must be limited so as to not affect the flange joint integrity. A 3D finite element model is used in which elastic–plastic behaviour of the flange material, non-linear gasket material behaviour and non-linear flange–gasket contact are assumed. The final goal of the developed work is to update, using a more realistic perspective, the recommendations given by ASME PCC-1 Appendix-O for bolt pre-stress values when applied to standard dimensional ASME flanges. Additionally, in this work, the effect of the straight portion length of the flange hub at its welded connection with the connected pipe and the fillet radius at the hub-flange transition on the stresses and strains distribution are also addressed.

Flat gaskets provide effective static sealing at low and high temperatures

Trelleborg Sealing Solutions has developed a range of flat gasket materials for effective static sealing in applications that involve low and high temperatures.

Moisture ingress in commercial steel drums: Water content determination, diffusion modelling and predicted permeation rates

AbstractCommercial steel drums underpin the global economy, playing a pivotal role in the storage and transportation of critical materials. Transported and stored materials, such as food, chemical and nuclear waste, can be sensitive to ambient conditions, particularly moisture that can enhance negative effects such as corrosion and material degradation. Although international standards and regulations are in place for the qualification of steel drums, there are no current testing requirements, established limits or boundaries for the permeation of moisture into the drums during transportation or storage. This work aims to provide insights into the moisture ingress over time into properly sealed steel drums and provides estimated moisture ingress rates over time through extrapolation. Water vapour transmission rate (WVTR) measurements through the gasket material at 10–40°C were 0.11–2.1 g/m2/day resulting in a permeation activation energy of 30.2 kJ/mol. Water sorption measurements and Karl Fischer titration (KFT) on ethylene propylene diene monomer (EPDM) gasket material revealed a decrease in equilibrium moisture saturation with increasing temperature. KFT measurements also revealed the presence of moisture within the adhesive and drum wall after exposure to ambient conditions. KFT and Fourier transform infrared spectroscopy (FTIR) show that moisture will desorb from the EPDM and drum wall after exposure to desiccating conditions, although a minimal amount of moisture will remain present. When sealed to the manufacturer's recommendations, the steel drums are effective in minimizing moisture ingress. In sealed empty drums, moisture ingress rates for 19‐L drums were 0.4–1.5 mg/day at 25°C 15% relative humidity (RH) and increased to 7.1–8.8 mg/day at 40°C 90% RH, and moisture ingress rates for 210‐L drums were 2.5 and 3.5 mg/day at field deployment conditions of 15.5°C 51.5% RH and 23°C 40% RH, respectively.

A systematic study of the effect of graphene oxide and reduced graphene oxide on the thermal degradation behavior of acrylonitrile-butadiene rubber in air and nitrogen media

Thermal degradation of acrylonitrile-butadiene rubber (NBR)-graphene oxide (GO)/reduced graphene Oxide (G) composites (NBR-GO/G) was studied in air O2(g) and nitrogen N2(g) media at ∼800°C, using Thermal Gravimetric Analysis (TGA/DTG). The char yield of the composites was high the in N2(g) medium. This was associated with lower weight loss (%) and higher maximum degradation temperatures, Tmax(°C). Doyle simple kinetic approach was used for the first time to estimate the degradation kinetics of the NBR-GO/G composites and large amounts of activation energy Ea (KJ/mol) was observed, particularly for the NBR-GO composites. In O2(g) medium, severe degradation of NBR occurred irrespective of the GO/G-filler content. This suggested that insignificant char yield was produced to protect the scission of the NBR backbone, as decomposition of the main chain seemed to have been accelerated by the high oxygenated moieties (C–O–C, –O–C=O and O–H) decorating GO/G-sheets. For instance, NBR showed ∼89, ∼21 and ∼86 % weight residue, Wr (%) than G0.1, G0.5 and G1 respectively and ∼154, ∼350, ∼92 % higher than the respective GO0.1, GO0.5 and GO1 samples. Although, NBR-G recorded higher Wr(%) than NBR-GO, NBR-GO generally slowed the degradation of NBR than NBR-G composites, possibly due to the presence of high concentration of interactions (NBR—Sx—GO—S—NBR and NBR—O—Hσ+—N σ−—C—NBR) which raised the Ea (KJ/mol) barrier for decomposition. The high thermal stability and compression set (%) properties of NBR-GO/G composites obtained as compared to pure NBR indicated that solution processing techniques used in this current work was very effective than those compounded with melt mixing methods or with GO/G-functionalized nanoparticles. Therefore, this present study provides insights on tailoring rubber-graphene based materials for thermally harsh and high pressure applications such as; oil/gas drilling hose, oil/gas seals, gasket and tire tread materials.