Atomic oxygen (AO), in the residual atmosphere of low-Earth-orbit space, may violently collide with spacecraft at a relative speed of up to 8 km/s and an impact energy of nearly 5 eV/atom. These collisions can lead to a series of physical and chemical reactions that may result in increased sputtering-erosion and corrosion of the exposed surface with performance degradation. This work examined the behavior of MoSi2, a commonly used coating, when exposed to AO using a ground-based space environment simulator. The erosion-corrosion kinetics and evolution of the microstructure and element distributions were analyzed. After MoSi2 was subjected to a total gas fluence of 9.72×1022 atoms/cm2 in 675 h, the erosion yield reached an exceptionally low value of 10-28 cm3/atom, indicative of its superior AO resistance, and XRD, SEM, XPS and EPMA were applied to analyze the phase transition of the coating surface: first it was released of adsorbed gas molecules and contaminants on the coating surface; then outside Mo and Si atoms were also sputtered, and the remaining Mo and Si atoms were gradually oxidized; finally, a continuous protective oxide film was generated which effectively resisting AO collisions. After AO impact, an ultrathin defensive granular oxide layer of MoO3 and SiO2 generated from the original smooth MoSi2 coating. Density functional theory calculations were conducted to clarify the thermodynamic and electronic structure mechanisms underlying the AO oxidation of the MoSi2 coating.
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