Natural Gas Research Articles

Synthesis of long-chain polyester polymers and their properties as crude oil pour point depressant.

Using acrylic acid advanced ester and styrene as raw materials, the long-chain polyester polymer, polyacrylic acid advanced ester-styrene pour point depressant (P-PPD), was synthesized by molecular design, and its structure was characterized by infrared spectroscopy and nuclear magnetic resonance. In addition, this study experimentally investigated the effect of P-PPD on the phase equilibrium and induction time of natural gas hydrate inhibitors in deionized water (DW) and crude oil/water (O/W) systems, respectively. Polyvinylpyrrolidone (PVP) and mono ethylene glycol (EG) were selected as representatives of kinetic hydrate inhibitor (KHIs) and thermodynamic hydrate inhibitor (THIs), respectively. The results exhibit that P-PPD played a sight role in the phase equilibrium of hydrate, while the addition of P-PPD significantly prolonged the induction time of methane hydrate both in O/W + PVP, OW + EG and O/W + PVP + EG system, indicating that the addition of as-synthesized PPD has a synergistic inhibition effect on the nucleation ability of methane hydrate and can prevent hydrate from formatting during oil and gas transport process, and thus guarantee the flow assurance. The findings of this work will provide a data reference for the hybrid use of hydrate inhibitors and pour point depressants in oil and gas transport.

Rethinking Natural Gas Infrastructure: How Non‐Pipe Alternatives are Shaping Utility Planning

As greenhouse gas (GHG) emission reduction efforts accelerate, utility regulators nationwide are rethinking the role of natural gas in reducing GHG emissions over current levels. A key strategy emerging in several states is the mandatory consideration of non‐pipe alternatives (NPAs); solutions that avoid the need for new natural gas hook‐ups. California, Massachusetts, New York, and Colorado are leading the effort, and other states like Maryland, Hawaii, Oregon, Minnesota, and New Jersey are not far behind. Before gaining approval for traditional new pipeline investments as opposed to pipeline replacement, regulators are requiring utilities to thoroughly analyze the costs and benefits of NPAs. This is compelling natural gas utilities to rethink their business models and find the most effective ways to present NPAs to regulators and customers. With this enhanced scrutiny and regulatory mandates that are increasingly focusing on sustainability, natural gas distribution utilities are at a crossroads. The challenge lies in adapting to these expectations and innovating scalable investments that will meet regulatory demands while driving the transition to a cleaner energy future.

Industrial Symbiosis Practices: A Case Study of Türkiye and Denmark

The term "industrial symbiosis (IS)" refers to a cooperative strategy where industrial actors share services and exchange physical resources. This method improves resource efficiency and lessens the environmental effects of industrial operations within the network. It is a cooperative method in which businesses trade and reuse physical resources such as by-products, water, and energy, as well as share services such as waste management and infrastructure. It has several advantages, such as (i) lowering greenhouse gas emissions through energy, process, input, disposal, and transportation savings, as well as fuel substitution; (ii) cutting energy expenses; (iii) diverting waste from landfills; (iv) avoiding the use of virgin materials; (v) lowering transportation and logistics costs; (vi) lowering pollution to land, water, and air; (vii) lowering industrial water use; (viii) lowering hazardous waste; (ix) creating economic value from waste material; and (x) simplifying environmental legislation and regulation compliance. In Türkiye and Denmark, the number of industrial companies is rapidly increasing. These industries consume many resources (such as raw materials, water, electricity, natural gas, coal, etc.) and generate a large amount of solid, liquid, and gaseous waste. IS is gaining popularity as an approach for improving the sustainability of industrial systems. The efforts to develop IS have emerged as a critical issue over the last decade in these two European countries. The paper presents the current implementation of IS in Türkiye and Denmark’s process sectors, focusing on well-known IS practices.

Methane Emissions from Oil and Natural Gas Operations—30 Percent Reduction by 2030 Possible if Domestic and International Actions “Stay the Course”

When sworn into office in January 2021, the Biden–Harris Administration—through the National Climate Task Force—launched an ambitious, whole‐of‐government initiative to significantly double efforts and reduce methane emissions from the oil and natural gas sector, landfills, agriculture, and other lesser sources. These initiatives were documented in the U.S. Methane Emissions Reduction Action Plan, which proposed to use regulations, catalytic financial incentives, transparency and disclosure of actionable data, together with public and private partnerships, to identify and reduce methane emissions. President Biden's Build Back Better agenda was designed to accelerate, through investments, many of these domestic methane emissions reduction efforts.

Synbiotic Effects of Lacticaseibacillus paracasei K56 and Prebiotics on the Intestinal Microecology of Children with Obesity.

Lacticaseibacillus paracasei K56 (L. paracasei K56) is a probiotic with weight-loss effects. However, symbiosis research on the combined effects of Lacticaseibacillus paracasei K56 and prebiotics is lacking. Therefore, the aim of this study was to investigate the effects of L. paracasei K56, xylooligosaccharide (XOS), galactooligosaccharide (GOS), polyglucose (PG), and their synbiotic combinations (XOS + K56, GOS + K56, and PG + K56) on metabolism and gut composition in children with obesity, using an in vitro fermentation model. Fecal samples were collected from 14 children with obesity for in vitro fermentation, and the effects of the various treatments in gas production and short chain fatty acid synthesis (SCFAs) were assessed. Treatment with probiotics, prebiotics, and synbiotics regulated gut microbiota and metabolites in children with obesity. GOS and XOS had higher degradation rates than PG + K56 synbiotics in the gut microbiota of children with obesity. Moreover, treatment with XOS, GOS, and their synbiotic combinations, (XOS + K56) and (GOS + K56), significantly reduced the production of gas, propionic acid, and butyric acid compared with PG + K56 treatment. Treatments with GOS + K56 and XOS + K56 altered the composition of the gut microbiota, improved the abundance of Bifidobacteria and Lactobacilli, and reduced the abundance of Escherichia/Shigella. Overall, this study provides a theoretical foundation for the use of K56-based synbiotics.

Atmospheric propane (C3H8) column retrievals from ground-based FTIR observations in Xianghe, China

Abstract. Propane (C3H8) is an important trace gas in the atmosphere, as it is a proxy for oil and gas production and has a significant impact on atmospheric chemical reactions related to the hydroxyl radical and tropospheric ozone formation. In this study, solar direct absorption spectra near 2967 cm−1 recorded by a ground-based Fourier transform infrared spectrometer (FTIR) were applied to retrieve C3H8 total columns between June 2018 and July 2022 in Xianghe in north China. The systematic and random uncertainties of the C3H8 column retrieval are estimated to be 18.4 % and 18.1 %, respectively. The mean and standard deviation of the C3H8 columns derived from the FTIR spectra in Xianghe are 1.80 ± 0.81 (1σ) × 1015 molec. cm−2. Good correlations are found between C3H8 and other non-methane hydrocarbons, such as C2H6 (R=0.84) and C2H2 (R=0.79), as well as between C3H8 and CO (R=0.72). However, the correlation between C3H8 and CH4 is relatively weak (R=0.45). Moreover, the FTIR C3H8 measurements in Xianghe are also compared against MkIV measurements at several sites around the world. The new FTIR measurements in Xianghe provide us with insight into C3H8 column variations and the underlying processes in north China.

Enhancing offshore parcel delivery efficiency through vessel-unmanned aerial vehicle collaborative routing

Offshore oil and gas production is vital for global energy supply, but it faces logistical challenges due to the high costs and inefficiencies of traditional supply methods. This paper introduces the vessel-unmanned aerial vehicle (UAV) routing problem with multiple visits in a single flight (VURP-M), a novel logistical model that addresses aimed at enhancing the replenishment of offshore platforms with small, essential items. The VURP-M allows the UAV to perform multiple visits during a single flight, optimising the delivery process. To tackle the VURP-M, we propose two mixed-integer second-order cone programs that capture the problem's complexities. Given its NP-hard nature, we employ an adaptive large neighbourhood search (ALNS) method, featuring a segmented initialisation process and problem-specific operators guided by a rule-based mechanism to improve solution efficiency. The ALNS formulates an initial solution by solving a travelling salesman problem to create a giant tour, which is then used to group sequential targets into multiple UAV flights. The subsequent optimal resolution of a SOCP determines the take-off and landing points for each flight. Subsequently, the ALNS refines the initial solution through destroy and repair operators, enhancing the search for superior sequences and allocation schemes. The effectiveness of our approach is demonstrated through a real-world case study and numerical experiments on random instances featuring up to 100 platforms. The results offer implications of the collaborative vessel-UAV model for the offshore logistics industry.

CO2-free production of hydrogen via pyrolysis of natural gas: influence of non-methane hydrocarbons on product composition, methane conversion, hydrogen yield, and carbon capture

CO2-free production of hydrogen via pyrolysis of natural gas: influence of non-methane hydrocarbons on product composition, methane conversion, hydrogen yield, and carbon capture

Reforming Natural Gas for CO2 Pre-Combustion Capture in Trinary Cycle Power Plant

Today, most of the world’s electric energy is generated by burning hydrocarbon fuels, which causes significant emissions of harmful substances into the atmosphere by thermal power plants. In world practice, flue gas cleaning systems for removing nitrogen oxides, sulfur, and ash are successfully used at power facilities but reducing carbon dioxide emissions at thermal power plants is still difficult for technical and economic reasons. Thus, the introduction of carbon dioxide capture systems at modern power plants is accompanied by a decrease in net efficiency by 8–12%, which determines the high relevance of developing methods for increasing the energy efficiency of modern environmentally friendly power units. This paper presents the results of the development and study of the process flow charts of binary and trinary combined-cycle gas turbines with minimal emissions of harmful substances into the atmosphere. This research revealed that the net efficiency rate of a binary CCGT with integrated post-combustion technology capture is 39.10%; for a binary CCGT with integrated pre-combustion technology capture it is 40.26%; a trinary CCGT with integrated post-combustion technology capture is 40.35%; and for a trinary combined-cycle gas turbine with integrated pre-combustion technology capture it is 41.62%. The highest efficiency of a trinary CCGT with integrated pre-combustion technology capture is due to a reduction in the energy costs for carbon dioxide capture by 5.67 MW—compared to combined-cycle plants with integrated post-combustion technology capture—as well as an increase in the efficiency of the steam–water circuit of the combined-cycle plant by 3.09% relative to binary cycles.

Optimizing the Operation of an Electrolyzer with Hydrogen Storage Using Two Different Methods: A Trade-Off Between Simplicity and Precision in Minimizing Hydrogen Production Costs Using Day-Ahead Market Prices

The potential for hydrogen is high in industrial processes that are difficult to electrify. Many companies are asking themselves at what cost they can produce hydrogen using water electrolysis with hydrogen storage. This article presents a user-friendly and less computationally intensive method (called method 1 in the following) for determining the minimum of the levelized cost of hydrogen (LCOH) by optimizing the combination of electrolyzer size and hydrogen storage size and their operation, depending on electricity prices on the day-ahead market. Method 1 is validated by comparing it with a more accurate and complex method (called method 2 in the following). The methods are applied to the example of a medium-sized industrial company in the mechanical engineering sector with a total natural gas demand of 8 GWh per year. The optimized LCOH of the analyzed company in method 1 is 5.00 €/kg. This is only slightly higher than in method 2 (4.97 €/kg). The article shows that a very good estimate of the LCOH can be made with the user-friendly and less computationally intensive method 1. For further validation of the methods, they were applied to other companies and the results are presented below.

2D Nitrogen-Doped Graphene Materials for Noble Gas Separation.

Noble gases, notably xenon, play a pivotal role in diverse high-tech applications. However, manufacturing xenon is an inherently challenging task, due to its unique properties and trace abundance in the Earth's atmosphere. Consequently, there is a pressing need for the development of efficient methods for the separation of noble gases. Using mild fluorographene chemistry, nitrogen-doped graphene (GNs) materials are synthesized with abundant aromatic regions and extensive nitrogen doping within the vacancies and holes of the aromatic lattice. Due to the organized interlayer "nanochannels", nitrogen functional groups, and defects within the two-dimensional (2D)structures, GNs exhibits effective selectivity for Xe over Kr at low pressure. This enhanced selectivity is attributed to the stronger binding affinity of Xe to GN compared to Kr. The adsorption is governed by London dispersion forces, as revealed by theoretical calculations using symmetry-adapted perturbation theory (SAPT). Investigation of other GNs differing in nitrogen content, surface area, and pore sizes underscores the significance of nitrogen functional groups, defects, and interlayer nanochannels over thesurface area in achieving superior selectivity. This work offers a new perspective on the design and fabrication of functionalized graphene derivatives, exhibiting superior noble gas storage and separation activity exploitable in gas production technologies.

The Exergo-Economic and Environmental Evaluation of a Hybrid Solar–Natural Gas Power System in Kirkuk

The increasing environmental challenges posed by the widespread use of fossil fuels and the fluctuating nature of renewable energy have driven the need for more efficient and sustainable energy solutions. Current research is actively exploring hybrid energy systems as a means to address these issues. One such area of focus is the integration of Organic Rankine Cycles (ORCs) with gas and steam turbines, utilizing both natural gas (NG) and solar parabolic trough collectors (PTCs) as energy sources. This study examines the performance of a hybrid system implemented in Kirkuk, Iraq, a region known for its substantial solar radiation. Previous research has shown that hybrid systems can effectively enhance energy conversion efficiency and reduce environmental impacts, but there is still a need to assess the specific benefits of such systems in different geographical and operational contexts. The analysis reveals a thermal efficiency of 59.32% and an exergy efficiency of 57.28%. The exergoeconomic analysis highlights the optimal energy cost at USD 71.93/MWh when the compressor pressure ratio is set to 8 bar. The environmental assessment demonstrates a significant reduction in CO2/emissions, with a carbon footprint of 316.3 kg CO2/MWh at higher compressor pressure ratios. These results suggest that integrating solar energy with natural gas can substantially improve electricity generation while being both cost-effective and environmentally sustainable.

Digital twin for decision support system of industrial utility management

Manufacturing and industrial operations rely heavily on energy that is generated mostly from fossil fuels, such as coal, oil, and natural gas, which harm the environment and contribute to climate change. Thus, renewable energy is being integrated into industrial processes to lessen environmental effects and reduce fossil fuel usage. However, the renewable source performance process can be greatly affected by disturbances and constraints, such as ambient air temperature and relative humidity, minimum utility consumption, and the total energy required, making effective control difficult. This study proposes a digital twin built with machine learning regression techniques for load demand forecasting as a decision-support system for industrial utility management. From the results, the ensemble tree (ET) model produced the highest accuracy, based on validation and test dataset root mean squared error values of 23.164 and 27.558, respectively, and R2 values of 0.96 and 0.95, respectively. The digital twin and load demand forecasting approaches effectively created an efficient operating schedule for industrial utility management. The ET model had a total error of 23.86%, substantially lower than the average load demand's total error of 65.29%. Therefore, the ET model with weather conditions in four scenarios could be recommended to optimize energy utilization when creating the operating schedule.

Temperature effect of biogas production from a greenhouse biogas digester

Globally, energy challenges are increasing with population growth. Many countries solely depend on fossil fuels (oil, coal, natural gas, etc.) for energy generation for different processes. Fossil fuels fall under non-renewable energy sources, are polluters of the environment, and get depleted faster, thus making it challenging to sustain a continuous energy supply. Therefore, there is a need for alternative sources of energy to mitigate the hazards associated with the utilization of fossil fuels. The present study aims to monitor the performance of a three-meter cubic (3 m3) greenhouse biogas digester, focusing on the temperature effect in biodegrading cow dung materials for gas generation. The study was conducted under mesophilic temperature conditions, pH, and hydraulic retention time for 30 days. Results revealed that slurry temperatures of about 33.5 ℃ and ambient temperatures of about 35 ℃ resulted in a remarkable peak biogas yield of 0.3 m3 on the 23rd day of the month. After the optimum yield of the biogas, the performance declined and was ascribed to the non-supply of the new feedstock, and the environment in the reactor became acidic, hence hindering the biodegradation process. Ultimately, the total biogas yield obtained from the study was 2.58 m3, equivalent to 15.48 kWh of energy. This amount of bio-generated energy was twofold the average daily electricity consumption of middle-income South African households. It was demonstrated that temperature was a major factor influencing the performance of the assembled biogas digesters and, thus, should be closely monitored for appreciable biogas production. This study is envisaged to pave the way for the future affordable and environmentally friendly biogas production process.

Optimization of Maintenance Strategies in an Oil and Gas Production Facility to Minimize Maintenance Cost

Abstract: In this study, maintenance strategies in an oil and gas production facility were optimized to minimize maintenance costs. The centrifugal pump system in Port Harcourt Refinery was selected for this study because it significantly impacts on the productivity of the refining plant. The pump system’s failure mode effects and criticality analysis (FMECA) were examined, and an optimized maintenance task was developed for the system. The exponential reliability method was employed to analyse the pump’s failure data to determine the pump systems' failure rate and reliability while reliability centred maintenance (RCM) and linear programming (LP) model were employed to optimize the pump’s maintenance strategies and the pump’s maintenance labour force respectively. Broad-based results of the optimized maintenance strategies consisted of on-condition-directed (CD) maintenance, preventive maintenance (PreM), and Proactive maintenance (ProM) strategies to be carried out monthly. The optimized maintenance labour force result revealed that approximately three engineers and two technicians should be employed for the pump’s maintenance task with a minimum of N2, 585, 700 as cost of salaries for the labour force monthly as against the current maintenance labour force requiring fourteen engineers and thirteen technicians monthly. The results showed that the labour cost decreased from N180,000,000 per year to N31,028,400 per year (approximately 82.76% reduction) using the proposed optimized maintenance task compared to the current maintenance plan. Conclusion and recommendation were made that the maintenance optimization technique presented in this work should be adopted by the oil and gas processing and production companies in order to minimize maintenance cost.

Indicadores de rendimiento energético y ambiental en instalaciones petroleras de producción en Ecuador

The study evaluates the energy and environmental performance of Ecuador's upstream oil facilities between 2015 and 2020, focusing on major extraction blocks. By analyzing data on oil, gas, and water production, fossil fuel consumption, and electricity usage, key performance indicators were developed to assess efficiency and environmental impact. The findings revealed disparities in energy efficiency, with Block 43-ITT being the most efficient at 7.82 kWh per barrel, while Block 57-LB was the least efficient at 31.41 kWh per barrel. The study emphasizes that maturing oil fields require more energy and emit more greenhouse gases, underlining the necessity for sustainable energy practices. EP Petroecuador’s initiatives, such as substituting fuel and integrating renewable electricity, led to a reduction of approximately 540 kTons of CO2 emissions by replacing 163.32 million gallons of diesel with low-carbon fuels and renewable electricity. These findings serve as a baseline for optimizing energy use and reducing emissions, offering valuable insights for policymakers and industry leaders to adopt data-driven strategies that enhance energy efficiency and minimize environmental impact in Ecuador's oil sector.

Experimental Determination of a Mixture Composed of Camisea Natural Gas and CO2 Laminar Burning Velocity

The aim of this work is to provide new experimental data on laminar burning velocities for a new synthetic mixture composed of Camisea natural gas and CO2. It was found that the relevant published experimental background data are l imited to mixtures composed of methane and CO2; considering the fact that Camisea natural gas is widely used in Peru, this experimental research will serve as a supportive resource for further experimental and industrial implementations in this country, such as the design and modeling of new engines or industrial burners that are designed to be fueled by this mixture. An experimental setup for analyzing three types of flame geometry, which is feasible to implement for a wide range of conditions, was built in PUCP PI0735 laboratory and all the measurements were obtained for a range of mixtures (0%, 21.2%, 28.5%, 38.9%, 50% CO2) and ratios from around 0.55 to 0.95 at atmospheric conditions. The laminar burning velocities results obtained were analyzed in groups based on %CO2. In addition, the experimental margin error was determined by considering all the sources. The following conclusions were reached: (1) The laminar burning velocity decreases with the increase in CO2 percentage in the mixture due to the CO2 decreasing the flame temperature effect. (2) The flat flame type provided the highest value of burning velocity for each group of CO2 percentage in which it appears. (3) The highest obtained laminar burning velocity value was 22.64 ± 0.15 cm/s, for a flat flame with a ratio of 0.72 and 29.98% of CO2, while the lowest obtained value was 6.78 ± 0.15 cm/s for a conical trunk flame with a ratio of 0.59 and 49.83% of CO2. (4) The highest evaluated CO2 percentage was 50.97% for a conical trunk flame with a ratio of 0.69 and a burning velocity value of 11.04.

Gas Pathing: Improved Greenhouse Gas Emission Estimates of Liquefied Natural Gas Exports through Enhanced Supply Chain Resolution

Gas Pathing: Improved Greenhouse Gas Emission Estimates of Liquefied Natural Gas Exports through Enhanced Supply Chain Resolution

Delineation of the reservoir petrophysical parameters from well logs validated by the core samples case study Sitra field, Western Desert, Egypt.

In the northern section of the Western Desert, there are many extremely profitable petroleum and natural gas deposits in the Abu EL-Gharadig Basin. This study aims to highlight the hydrocarbon potential of Abu Roash F Formation, which stands for high organic content unconventional tight reservoirs, and Abu Roash G Formation which stands for conventional sand reservoirs, in Sitra field located in the central-western part of the Abu EL-Gharadig Basin. The research employed well-log data from four wells to ascertain petrophysical properties combined with core samples of two wells for a comprehensive examination and description of lithology. Initially, we commenced the execution of petrophysical analysis, encompassing log quality control procedures. Subsequently, we identified and revealed zones of interest and hydrocarbon indicators in both formations. Additionally, we ascertained the three most influential parameters, shale Volume, effective Porosity, and water saturation, which serve as defining factors for reservoir quality. Subsequently, an examination of the core samples, which encompassed lithologic description, lithofacies analysis, paleoenvironmental interpretation, petrographic analysis, and porosity assessment is conducted. For the sake of a more accurate interpretation, we conclude our research with cartographic maps created to evaluate the geographical distribution of hydrocarbon potential based on petrophysical characteristics, Distribution of the net-to-gross ratio among wells by correlating the litho-saturation models (rock models) for the four wells. The foregoing results declare that The Abu Roash F carbonate-rich rocks are a contender for unconventional tight oil reservoir potential with thin secondary porosity and high organic content, which normally requires a kind of hydraulic fracturing for prospective oil extraction, Furthermore, the upper section of Abu Roash G formation, particularly in well sitra8-03, has highly favorable conventional reservoir characteristics.

Interval Analysis of Volatile Solid (VS) and Biochemical Oxygen Demand (BOD) in Batch Anaerobic Fermentation of Selected Agrowaste

This study investigated the degradation of volatile solids (VS) and biochemical oxygen demand (BOD) during the anaerobic digestion of selected agro-waste, specifically cassava peels, maize husks, pig slurry, and the composite. The objective was to evaluate the biodegradability of these feedstocks, in line with their potential for biogas production. The Research was conducted at the National Centre for Energy Research and Development (NCERD) laboratory, University of Nigeria Nsukka (UNN). Batch reactors were used to conduct experiments over a period of 45 days. The digesters were operated under controlled conditions, and samples were analyzed at three (3) different points: 24 hours, peak of gas production (day 30), and at the end of the digestion (day 45). The results demonstrated that all the substrates exhibited a reduction in VS and BOD in the course of digestion. However, the most significant reduction in VS and BOD occurred around the peak of gas production. This entails that this period is critical for microbial activity and biogas yield. Corn husks had high initial VS and BOD values of 4.73±0.22 % and 92.80±3.26 mg/L respectively. However, that did not translate to higher biogas production compared with the composite that had initial values of 4.34±0.19 % and 88.00±5.50 mg/L respectively. By the end of the digestion, an average VS reduction of 65% and a BOD reduction of 70% were observed across all substrates, indicating a substantial degradation of organic material. Biogas production was better in the composite (72.580±4.53 %), an indication that higher VS and BOD do not automatically translate to higher gas yield. Thus, factors like multiple substrate interaction affect gas yield and process efficiency.