Gas Production Behavior Research Articles

Effect of Isotropic and Anisotropic Permeability on Gas Production Behavior of Site NGHP-01-10D in Krishna-Godavari Basin

This study reports an investigation into both isotropic and anisotropic permeability effects on gas production behavior during depressurization-induced natural gas hydrate dissociation at site NGHP-01-10D in the Krishna-Godavari basin. Numerical simulations were performed on a reservoir-scale model incorporating a single vertical well, examining different scenarios of permeability ratios (rrz). The investigation assessed gas and water production rates, cumulative production volumes, the gas-to-water ratio, and the spatial distribution of reservoir parameters throughout a production duration of 3 years. The findings indicate that permeability anisotropy has a substantial impact on hydrate dissociation and gas recovery. For rrz > 1, horizontal pressure propagation was promoted and gas production increased. For example, at t = 1100 days, the total gas production improved from 7.88 × 105 ST m3 for rrz = 1 to 55.9 × 105 ST m3 for rrz = 10. For rrz < 1, vertical pressure propagation resulted in higher water production with concomitantly lower rates of gas production rates. Spatial distribution analysis revealed that higher rrz values led to more extensive radial propagation of pressure drop, temperature decrease, gas saturation increase, and hydrate dissociation. The study concludes that higher horizontal permeability enhances depressurization effects, resulting in higher gas production rates and more favorable gas-to-water ratios.

Effect of salinity on anaerobic fermentation gas production behaviors of the thermal pretreated fruit waste

Effect of salinity on anaerobic fermentation gas production behaviors of the thermal pretreated fruit waste

A device for real-time detection of gas generated from commercial lithium-ion cell

Abstract Lithium-ion batteries generate a large amount of flammable and toxic gases under abuse conditions. Research on the detection methods of gas generation from batteries is of great significance for understanding the reaction mechanism of batteries under abuse conditions, assessing the impact of gas generation on the health of occupants, and developing safer battery products. However, there is a lack of research reports on the real-time gas production behavior of commercial batteries. In this paper, a device for real-time detecting the gas component of the cylindrical lithium-ion cell is designed. Combined with a gas mass spectrometer can implement the real-time detection of the gas component of the lithium-ion cell. The device is used to explore the gas generation characteristics of lithium-ion cells in the overcharged state, and the influence of the material system and the degree of aging on the results are analyzed, verifying the feasibility of the device.

Numerical Simulation of Vertical Well Depressurization-Assisted In Situ Heating Mining in a Class 1-Type Hydrate Reservoir

In situ electric heating is an important method used to increase production capacity during the extraction of natural gas hydrates. This work numerically evaluated the sensitivity of different heating parameters on gas production behavior with a vertical well depressurization in the Shenhu Sea area hydrate reservoir, the production pressure difference of 4 MPa, and continuous depressurization for 1080 days. The results showed that the in situ electric heating method can effectively enhance production capability by promoting hydrate dissociation and eliminating secondary hydrates. Compared with scenarios without heating, implementing whole wellbore heating (100 W/m) increases cumulative gas production (Vg) by 118.56%. When intermittent heating is applied to the local wellbore (15 m) located in the three-phase layer (with an interval of 30 days) and stops heating in advance at 480 days, there is no significant difference in Vg compared to the whole wellbore heating case, and the cumulative heat input is only 4.76%. We recommend considering intermittent heating of the local wellbore and stopping heating in advance during vertical well depressurization as this approach significantly reduces heating energy consumption while simultaneously improving production capacity.

Numerical Simulation of Gas Production Behavior Using Radial Lateral Well and Horizontal Snake Well Depressurization Mining of Hydrate Reservoir in the Shenhu Sea Area of the South China Sea

Improving the production capacity of natural gas hydrates (NGHs) is crucial for their commercial development. Based on the data of the first on-site testing production of NGHs in the Shenhu Sea area, numerical methods were used to analyze the production behavior of radial lateral well (RLW) and horizontal snake well (HSW) with different completion lengths when they deployed at different layers of the Class-1 type hydrate reservoir (with a fixed pressure difference of 6 MPa and continuous production for 360 days). The results indicate that compared with the single vertical well production, RLW and HSW can effectively increase production capacity by enlarging drainage area and the productivity is directly proportional to the total completion length. The RLW and HSW deployed at the three-phase layer (TPL) have optimal mining performance within a 360-day production period. Different to the previous research findings, during a short-term production period of 360 days, regardless of the deployment layer, the overall production capacity of HSW is better than RLW’s. The total gas production of HSW-2 circles well type is about four times that of a single vertical well, reaching 1.554 × 107 ST m3. Moreover, the HSW-1 lateral well type stands out with an average Qg of 3.63 × 104 ST m3/d and a specific production index J of 16.93; it has the highest J-index among all well types, which means the best mining efficiency. It is recommended to choose the HSW-1 circle well type, if the coiled tubing drilling technique is used for on-site testing production of NGHs in the future. The research results provide insights into the potential applications of RLW and HSW in this sea area.

Taking Advantage of Potential Coincidence Region: Insights into Gas Production Behavior in Advanced Self-Activated Hydrazine-Assisted Alkaline Seawater Electrolysis.

Water electrolysis assisted by hydrazine has emerged as a prospective energy conversion method for achieving efficient hydrogen generation. Due to the potential coincidence region (PCR) between the hydrogen evolution reaction (HER) and the electro-oxidation of hydrazine, the hydrazine oxidation reaction (HzOR) offers distinct advantages in terms of strategy amalgamation, device architecture, and the broadening of application horizons. Herein, we report a bifunctional electrocatalyst of interfacial heterogeneous Fe2P/Co2P microspheres supported on Ni foam (FeCoP/NF). Benefiting from the strong interfacial coupling effect between Fe2P and Co2P and the three-dimensional microsphere structure, FeCoP/NF exhibits outstanding bifunctional electrocatalytic performance, achieving 10 mA cm-2 with low overpotentials of 10 and 203 mV for HER and HzOR, respectively. Utilizing FeCoP/NF for both electrodes in HzOR-assisted water electrolysis results in significantly reduced potentials of 820 mV for 1 A cm-2 in contrast to the electro-oxidation of alternative chemical substrates. The presence of a potential coincidence region makes the application of self-activated seawater electrolysis realistic. The gas production behavior at different current densities in this interesting hydrogen production system is discussed, and some rules that are distinguished from conventional water electrolysis are summarized. Furthermore, a new self-powered hydrogen production system with a direct hydrazine fuel cell, rechargeable Zn-hydrazine battery, and hydrazine-assisted seawater electrolysis is proposed, emphasizing the distinct benefits of HzOR and its potential role in electrochemical energy conversion technologies powered by renewable sources.

Numerical Simulation of Gas Production Behavior Using Stepwise Depressurization with a Vertical Well in the Shenhu Sea Area Hydrate Reservoir of the South China Sea

Numerical Simulation of Gas Production Behavior Using Stepwise Depressurization with a Vertical Well in the Shenhu Sea Area Hydrate Reservoir of the South China Sea

Study on the effect of low-temperature cycling on the thermal and gas production behaviors of Ni0.8Co0.1Al0.1/graphite lithium-ion batteries

With their high energy density and long cycle life, lithium-ion batteries (LIBs) are currently the most promising electrochemical energy storage system for electric vehicles. However, their safety and cycling performance can be significantly compromised in low-temperature environments due to lithium plating and other factors. Therefore, it is essential to study the safety of aging batteries. In this study, we focused on a commercially available high-specific-energy Ni0.8Co0.1Al0.1 cathode system battery and simulated the aging of the battery by long-term cycling at 0 ℃. This study compares and analyzes the samples on the basis of the previous ones in terms of heat production power, thermal runaway (TR) characteristics and gas production characteristics. It reveals the influence of low-temperature aging on the comprehensive performance of lithium batteries in a more comprehensive way. The results show that the charging pattern of all three characteristics is related to the aging degree of the battery. In terms of the thermal characteristics, the relative change in specific heat capacity of the aged battery is only between 0.32 % and 1.08 % compared to that of a fresh battery, so the effect of ageing on the specific heat capacity of the battery is negligible. The average heat generation power of batteries with different state of health (SOH) is not monotonically increasing with the decrease of SOH, the threshold of dramatic increase is SOH = 80 %. In terms of TR characteristics, the onset temperature of exothermic reactions (TOER) of aged batteries is significantly lower than that of fresh batteries. With the decrease of SOH, TOER also decreases gradually. Compared with batteries with different SOHs, the more seriously aged the battery safety valve opens earlier, and the TR occurs earlier. In terms of the TR gas production characteristics, the more severely aged the battery, the earlier the safety valve opens compared to a fresh battery. The most gas is produced when SOH = 70 %, which increases the risk of catastrophic damage.

Adsorption–desorption characteristics of coal-bearing shale gas under three-dimensional stress state studied by low field nuclear magnetic resonance spectrum experiments

The micro-scale gas adsorption–desorption characteristics determine the macro-scale gas transport and production behavior. To reveal the three-dimensional stress state-induced gas adsorption–desorption characteristics in coal-bearing shale reservoirs from a micro-scale perspective, the coal-bearing shale samples from the Dongbaowei Coal Mine in the Shuangyashan Basin were chosen as the research subject. Isothermal adsorption–desorption experiments under three-dimensional stress state were conducted using the low field nuclear magnetic resonance (L-NMR) T2 spectrum method to simulate the in-situ coal-bearing shale gas adsorption–desorption process. The average effective stress was used as the equivalent stress indicator for coal-bearing shale, and the integral of nuclear magnetic resonance T2 spectrum amplitude was employed as the gas characterization indicator for coal-bearing shale. A quantitative analysis was performed to examine the relationship between gas adsorption in coal-bearing shale and the average effective stress. And a quantitative analysis was performed to examine the relationship between the macroscopic and microscopic gas quantities of coal-bearing shale. Experimental findings: (1) The adsorption–desorption process of coal-bearing shale gas follows the L-F function model and the D-A-d function model respectively with respect to the amount of gas and the average effective stress. (2) There is a logarithmic relationship between the macroscopic and microscopic gas quantities of coal-bearing shale during the adsorption–desorption process. This quantitatively characterizes the differences in the curves, which may be related to the elastic–plastic deformation, damage and fracture of the micropores in coal-bearing shale, as well as the hysteresis of gas desorption and the stress field of the gas occurrence state.

On the Influence of Fine Particle Migration and Deposition on Gas Hydrate Production: Insights from the First Trial Production in the South China Sea

Summary As a promising alternative energy source with vast reserves, the primary challenge in exploiting natural gas hydrates (NGHs) lies in achieving long-term safety and efficiency. Several production tests conducted globally have demonstrated that the production of solid particles is one of the main factors contributing to this issue. However, most studies on assessing NGH production capacity have overlooked this phenomenon and its impact on production performance, potentially compromising the accuracy of simulation results. Therefore, this study aims to quantitatively analyze the impact of fine particle migration and deposition on gas production by numerically examining the first NGH production test conducted in the Shenhu area of the South China Sea (SCS). Through comparison of simulation results with the reconstructed gas production curve, the model was calibrated and enabled an explanation of unique gas production performance during field testing. It is found that the deposition of solid particles reduced the gas production rate by nearly an order of magnitude during the initial stage of exploitation. Long-term simulation results indicate that only the three-phase layer (TPL) remains partially unobstructed and serves as the primary source of gas production in later stages. Sensitivity analysis reveals that both depressurization and particle control strategies exert significant effects on particle migration, which in turn affects gas production. Specifically, the increase in depressurization amplitude does not necessarily lead to improved gas production behavior beyond a certain threshold (approximately 6 MPa). This study illustrates the inherent trade-off between preventing particle production and increasing gas production, highlighting the need for a safe and efficient production scheme that strikes a balance between these two objectives. Based on the current study, it is preliminarily recommended to maintain a depressurization amplitude of approximately 6 MPa with a maximum depressurization rate of 3 MPa/d and ensure a fine particle filtration ratio of no less than 95%.

Influence of depressurization mode on natural gas hydrate production characteristics: One-dimensional experimental study

The latest research suggests that using depressurization methods and their enhancements could be the most effective way to produce natural gas hydrates efficiently in marine areas. Therefore, it's crucial to investigate the gas production behavior and the changes in temperature and pressure within natural gas hydrate reservoirs under different depressurization methods. In this paper, the self-developed one-dimensional natural gas hydrate production simulation test system was utilized to conduct one-dimensional depressurization production tests during two depressurization modes of significant depressurization and slow depressurization. The findings indicated that the minimum temperature increment-depressurization rate curves in significant depressurization tests exhibited irregular patterns, primarily due to the frequency and intensity of hydrate reformation, while the smaller the depressurization rate, the larger the minimum temperature increment and the smaller the maximum dissociation rate under slow depressurization. In addition, when maintaining a fixed hydrate saturation level, the peak gas production rate showed a decline with decreasing depressurization rate. However, the exact correlation between the peak gas production rate and the depressurization rate remained uncertain due to the unpredictable nature of the “armoring” effect.

Numerical simulation of gas production behavior of class Ⅰ, class Ⅱ and class Ⅲ hydrate reservoirs for different well locations

The exploitation of natural gas hydrate, an unconventional natural gas, has drawn attention on a global scale due to increasing imbalance between energy supply and demand. Horizontal wells are considered to have a better production performance, while vertical wells have been mostly employed in previous field tests and laboratory research. Therefore, based on the representative properties of three kinds of hydrate reservoirs, a hydrate decomposition model is built to study the gas generation behaviors of various hydrate reservoirs with different horizontal well-spacing strategies in this work. The results show that for Class I hydrate reservoirs, placing the production well near the free gas layer can improve gas generation by 47%, and GWR (gas-water ratio) to 346.0 and maintain higher temperature in hydrate reservoir than that with placing the well in the hydrate reservoir. For Class Ⅱ hydrate reservoirs, placing the producing well away from the free water layer can cut down water production by 92%, while gas production could be also elevated, causing GWR increasing to 175.8. In Class Ⅲ reservoirs, the reduction of 30% in water production, and increment in GWR from 81.5 to 118.0 can be achieved by placing the well on the top of the hydrate layer, rather than that on the bottom. In addition, the presence of free gas layer, free water layer can promote the pressure-drop interface spread, provide sensible heat, and then accelerate hydrate decomposition further.

Suppression of thermal runaway induced by thermal abuse in large-capacity lithium-ion batteries with water mist

Thermal runaway (TR), as the most critical safety problem of lithium-ion batteries (LIBs), may cause considerable accident consequences, especially for large capacity LIBs, TR hazards should be multiplied. Therefore, effective TR mitigation strategies are needed. Water mist (WM), being widely considered as a clean and efficient fire suppression method, is employed for TR control in this work. TR evolution of the multi-cell large capacity LIBs induced by thermal abuse has been clearly demonstrated for the first time, the disaster characteristics of the LIB before TR are dominated by the successive gas production behaviors of the internal cells, but the battery ultimately triggers the TR as a whole. More than that, the critical signal is identified based on the battery disaster development and is successfully used for TR suppression. Then the reason for TR being suppressed is revealed by elucidating the overall and instantaneous cooling effects of the WM on LIBs. Moreover, it is found that the disaster of large capacity LIBs develops quickly, and 15 s is sufficient to make TR uncontrollable. Even so, the WM still exhibits excellent cooling ability, taking away over 65 % of the battery heat accumulation. The results provide the first comprehensive analysis of TR evolution and clarify the ability of WM in TR suppression of multi-cell LIBs.

Experimental study of gas production and flame behavior induced by the thermal runaway of 280 Ah lithium iron phosphate battery

With the popularization and application of lithium-ion batteries in the field of energy storage, safety issue has attracted more attention. Thermal runaway is the main cause of lithium-ion battery accidents. A major trend in battery development is to increase the capacity of individual batteries, and large-capacity batteries tend to cause more serious damage when thermal runaway occurs. The paper studied the gas production and flame behavior of the 280 Ah large capacity lithium iron phosphate battery under different SOC and analyzed the surface temperature, voltage, and mass loss of the battery during the process of thermal runaway comprehensively. The thermal runaway of the battery was caused by external heating. The results show that the thermal runaway process can be divided into four stages, and there is a clear thermal runaway internal spreading phenomenon. TR temperature is almost the same under the ignition and the gas condition and is greatly affected by the state of charge. The hazards for the gas scenario are presented as toxicity, asphyxiation and combustion risk, and the flame scenario is presented as the thermal hazard. The work could provide a reference for the process safety design and reduce the fire risk.

Unsaturated water flow-induced the structure variation of gas hydrate reservoir and its effect on fluid migration and gas production

Multi-phase (gas, saturated water, and unsaturated water) seepage is bound to exist in natural gas hydrates (NGHs) production process. The effect of water flow, especially for unsaturated water flow, on the permeability variation of hydrate reservoir and gas production behavior do not appear well understood. In this study, the unsaturated water flow in hydrate-bearing sediment and hydrate-free sediment is simulated by controlling water flow velocity. The hydrate phase distribution was monitored using visualization magnetic resonance imaging system. The variation of temperature, pressure, and gas production rate during the unsaturated water flow were analyzed. The results show that the changing trend of the pressure difference presented the three stages for the hydrate-free sediment. In contrast, the pressure difference followed a five-stage change for the hydrate-bearing sediment in the unsaturated water flow process due to the hydrate dissolution. The hydrate dissolution caused an increase in permeability (maximum of log10(Kr) was 0.5) and formed the obvious unsaturated water flow channel. Moreover, the higher water flow velocity, which increased the chemical potential difference between hydrate phase and water phase, accelerated the MH dissolution, and further induced the faster increase rate of permeability and gas production. Surprisingly, when the unsaturated water flow velocity was improved to 15 mL/min from 0.5 mL/min, the gas production rate increased by 35 times. Furthermore, the average gas production rate was mainly determined by the unsaturated water flow velocity, it was changing in a linear fashion with the increasing water flow velocity. The findings could provide new knowledge on the strategy design on NGHs production with high efficiency.

Improved temperature distribution upon varying gas producing channel in gas hydrate reservoir: Insights from the Joule-Thomson effect

The gas production from marine gas hydrate has always been plagued by low productivity; the complex geological environment poses a significant obstacle to its commercialization. Horizontal wells are thus getting increasing attention due to their advantages in facilitating pressure propagation. Here a pre-embedded dual horizontal well was used to probe its effects in the local temperature distribution and gas production behavior. By doubling the number of boreholes, the flow channels of gas were increased enlarging the decomposition zone. Specifically, this was found to raise the reservoir temperature from −1 °C in a single well to approximately 0 °C. The temperature decline was more moderate due to a weakened Joule-Thomson effect. Consequently, almost 90% of the cumulative gas yield was produced before the lowest temperature occurred, compared to ∼30% in the single vertical well case. This indicates that the gas production from a dual well case was proceeding at a relatively higher temperature, potentially benefitting an enhanced gas production efficiency. An enlarged depressurization region was thus suggested in the field test for a controlled temperature decline to make more use of the sensible heat of the reservoir.

Research on Natural Gas Production Behavior Using Stepwise Depressurization with a Horizontal Well

Research on Natural Gas Production Behavior Using Stepwise Depressurization with a Horizontal Well

Numerical Simulation of Optimized Step-Wise Depressurization for Enhanced Natural Gas Hydrate Production in the Nankai Trough of Japan

The utilization of natural gas hydrates as an alternative energy source has garnered significant attention due to their proven potential. Despite the successful offshore natural gas hydrate production tests, commercial exploitation has not been achieved. This study aims to enhance the understanding of gas production behavior through simulations from a single vertical well in the Nankai Trough and assess the effectiveness of the step-wise depressurization method for gas production using TOUGH + HYDRATE. The simulation results showed that the effective permeability for the water phase decreased as the hydrates were decomposed, and the invasion of the pore water from the underburden eliminated this effect. Compared with the direct depressurization method, the step-wise depressurization method significantly increased the cumulative gas production by more than 10% and mitigated the rapid generation of gas and water production during the moment of depressurization. The results also indicated that the depressurization gradient was more sensitive to the cumulative gas production than the maintenance time of depressurization. In view of the gas and water production characteristics coupled with the challenges in carrying out the step-wise depressurization method, it is suggested that a depressurization gradient of 1 MPa and a maintenance time of 1 day should be employed.

Temperature response mechanism of methane hydrate decomposition coupled with icing and melting under variational thermodynamic conditions

High-efficient decomposition is the precondition of commercial production of methane hydrates. Under variational thermodynamic conditions, icing and melting may occur during hydrate decomposition, inducing complex heat and mass transfer. In this study, hydrates formed under temperature gradient of 0.012, 0.020 and 0.026 °C/mm in a 2 L reactor, decomposed by long depressurization to 1.0 MPa at constant exhaust rate from 0.11 to 1.07 ln/min. Temperature of hydrate-bearing area was in a specific relationship called thermodynamic non-equilibrium effect with pressure, controlled by hydrate decomposition. When pressure reached around 2.1–2.3 MPa, instant icing caused rapid temperature rise, and accelerated hydrate decomposition generating pressure rise of 2.36 MPa at most coordinated by limited exhaust rate. Isothermy stage occurred in double phase transition system with hydrate decomposition and ice melting, temperature slightly raised after most hydrates had decomposed. Temperature gradient only worked on non-hydrate/ice area because the temperature response of hydrate decomposition couple with icing and melting is first dominated by thermodynamics and then affected by heat and mass transfer. The control effect of ice melting in thermodynamic is stronger than hydrate decomposition. These results are significant for systematic analysis among gas production, hydrate decomposition, temperature gradient and ice behavior of actual hydrate exploitation.

Enhanced Gas Production from Class II Gas Hydrate Reservoirs by the Multistage Fractured Horizontal Well

In the two test productions that have been conducted in the hydrate reservoir test development zone in the South China Sea, the gas production capacity of single wells is low and the exploitation difficulty with the cost is too high for commercial demand economically. The low permeability of the hydrate-bearing layer (HBL) acts as the major barrier for pressure propagation during depressurization. Hydraulic fracturing by the combined depressurization is considered a promising hydrate production enhancement technology that can effectively improve the seepage state in the reservoir. In this study, to evaluate the effectiveness of the development methods association with fracturing, we established an idealized Class II hydrate reservoir and studied it using a multi-stage fractured horizontal well to assist in depressurization extraction. In order to evaluate the production enhancement effect of this method, we compared the gas production results of four methods, including single vertical well, vertical fractured well, horizontal well, and multistage fractured horizontal well through numerical simulation. In order to investigate the influence of key fracture parameters on the production enhancement effect, a sensitivity analysis of the production effect of Class II hydrate reservoirs with different fracture spacing, number of fractures, fracture conductivity, and fracture length was conducted, and the results were analyzed in terms of gas production and water production behavior curves as well as physical field evolution over time. The simulation results show that the multi-stage fractured horizontal wells have the best production increase in the comparison of well types. In the analysis of fracture parameters, it can be found that the selection of proper fracture spacing and dimensionless fracture conductivity can lead to a significant increase in gas production.