Gas Migration Channels Research Articles

Caprock Safety Evaluation Method in CCUS Based on Latin Hypercube Sampling: A case study of a block reservoir

Abstract CO2 geological sequestration is one of the essential means to achieve carbon neutrality goals. However, substantial CO2 sequestration in formations can lead to leakage issues, primarily through the caprock, involving caprock rupture, leakage along caprock fractures/faults, and capillary leakage. Therefore, establishing a method to assess the safety of the caprock during CO2 storage processes is crucial. Firstly, a numerical simulation model is constructed based on parameters from the target block to study the influences of reservoir property, development parameters, and caprock parameters on CO2 flooding, gas injection, and CO2 storage. Latin hypercube sampling is employed for scheme design and subsequent result analysis, applying Spearman’s method to analyze the controlling factors in each CO2 storage. Secondly, using continuous gas flooding as an example, the migration pattern of CO2 in the formation is investigated, and the influence of the formation pressure distribution on caprock safety is analyzed. Finally, considering the comprehensive impact of different parameters on caprock safety, a fuzzy comprehensive evaluation of caprock safety in the target block is conducted. The study indicates that caprock permeability is the most critical factor affecting safety operation across all storage stages, with respective highest positive correlation coefficients of 0.413, 0.356, and 0.221 in different stages. The migration of CO2 in the formation is primarily influenced by the distribution of injection wells and gas migration channels. The established quantitative evaluation standard for caprock safety in the target block calculates a suitability degree of 3.43, suggesting a relatively secure caprock in the block suitable for achieving long-term stable CO2 storage. This research provides theoretical support for the safety analysis of caprock in different stages of CO2 flooding and storage, offering a scientific basis for the safety operation of CCUS schemes.

Research on the Recognition and Characterization of Fractures in Coal Rock Based on CT Scanning

Abstract Coal rock fractures play a vital role as key channels for gas migration and storage in the exploration and development of coalbed methane. The characteristics of these fractures, such as porosity distribution, specific surface area, and connectivity, directly impact the adsorption, diffusion, and permeability behaviors of coal reservoirs. Therefore, a detailed analysis of coal rock fracture characteristics is vital in assessing the extractability of coalbed methane and during its exploration and development process. Currently, techniques like imaging logging, seismic detection, and micro-CT are employed for characterizing and studying fractures at various scales. Among these, high-resolution non-destructive CT scanning technology, by constructing three-dimensional data models of core samples, enables a quantitative analysis of fracture distribution features and size parameters. Traditional digital image processing methods, such as threshold segmentation and binary segmentation, though advantageous in computational speed, have limitations in the accuracy of fracture identification. With the advancement of artificial intelligence technology, deep learning-based image processing techniques have increasingly become significant tools for fracture detection due to their powerful feature extraction capabilities. This study conducted micrometer-level CT scanning experiments on coal rock samples, using CT image processing technology to construct a digitalized coal rock core model. Deep learning methods were applied for precise fracture identification, establishing an appropriate deep learning architecture and optimized parameters for coal rock fracture recognition. Furthermore, this paper provides a detailed quantitative characterization of the precisely identified fractures, offering robust technical support for the exploration and development of coalbed methane. The high-resolution non-destructive CT scanning technology and three-dimensional fracture network reconstruction method used in this study have been proven to be effective tools for investigating the micro-features of rocks, enabling the three-dimensional visualization and detailed characterization of rock microstructures.

Characteristics and Genesis of Carbonate Weathering Crust Reservoirs: A Case from the Ma5Member of Ordovician in Gaoqiao Area, Ordos Basin, China.

The hydrocarbon reserves in carbonate rocks account for about half of the global hydrocarbon reserves and are an important reservoir type. The Ordovician Majiagou Formation in the central Ordos Basin is a representative weathering crust reservoir. The Caledonian movement uplifted the stratum as a whole, and subsequently, 120 million years of exposed weathering, denudation, and leaching created this unique karst paleomorphology. Dolomite reservoirs have developed dissolved pores and microfractures, which are the best reserved spaces for natural gas and good hydrocarbon migration channels. This paper takes the Ma5Member (hereinafter referred to as Ma51+2) carbonate reservoir in Gaoqiao Gas Field as the research target, based on the core, thin section, cathodoluminescence, logging data, etc., and systematically study the effect of karstification on the reservoir and the genesis of the dolomite reservoir. The results show that the depositional period of the Ordovician Majiagou strata is a regression cycle and the depositional environment is a limited evaporative tidal flat. The reservoir lithology of Ma51+2 is mainly gypsiferous dolomite and micrite dolomite. The reservoir space types consist of intergranular pores, gypsum mold pore, intragranular dissolution pores, intercrystalline pores, and microfractures. The porosity has values from 0.3 to 11.2% (mostly less than 5.0%) with an average of 3.3%, and the permeability ranges from 0.003 to 13.2 mD (mostly less than 1 mD) with an average of 0.36 mD. Karstification is divided into three periods, including syngenetic karst, eogenetic karst, and burial karst. The sedimentary microfacies determine the material basis of the reservoir, and multistage karstification finally modifies the physical properties. By deeply exploring the formation mechanism and influencing factors of the carbonate reservoir in the Ordovician Majiagou Formation, it provides an important theoretical basis and practical guidance for oil and gas exploration and development. At the same time, it also has important reference value for understanding and predicting the development law and distribution characteristics of carbonate reservoirs under similar geological background.

Gas migration at the granite–bentonite interface under semirigid boundary conditions in the context of high‐level radioactive waste disposal

AbstractThe corrosion of waste canisters in the deep geological disposal facilities (GDFs) for high‐level radioactive waste (HLRW) can generate gas, which escapes from the engineered barrier system through the interfaces between the bentonite buffer blocks and the host rock and those between the bentonite blocks. In this study, a series of water infiltration and gas breakthrough experiments were conducted on granite and on granite–bentonite specimens with smooth and grooved interfaces. On this basis, this study presents new insights and a quantitative assessment of the impact of the interface between clay and host rock on gas transport. As the results show, the water permeability values from water infiltration tests on granite and granite–bentonite samples (10−19–10−20 m2) are found to be slightly higher than that of bentonite. The gas permeability of the mock‐up samples with smooth interfaces is one order of magnitude larger than that of the mock‐up with grooved interfaces. The gas results of breakthrough pressures for the granite and the granite–bentonite mock‐up samples are significantly lower than that of bentonite. The results highlight the potential existence of preferential gas migration channels between the rock and bentonite buffer that require further considerations in safety assessment.

Analysis and Characterization of Micro–Nano Pores in Coal Reservoirs of Different Coal Ranks

Coalbed methane represents a promising source of clean and efficient unconventional energy. The intricate network of micro–nano pores within coal serves as the primary adsorption space for gas, contributing to the complexity of gas migration channels. In this study, based on the box-counting method, three coal samples representing low, medium, and high ranks were subjected to high-precision micro-CT scanning and nano-CT scanning to generate three-dimensional (3D) pore network models using Avizo visualization software. This facilitated the accurate and quantitative characterization of the micro–nano pore structures within coal reservoirs. The results indicated that the face rate distribution range of each sample was large, indicating relatively strong heterogeneity in each sample. The volume fractal dimension of each sample, determined through micro–nano-CT scanning, was around 2.5, while the surface fractal dimension exhibited oscillatory characteristics with moderate uniformity. The pore equivalent radius and throat equivalent radius distributions were unimodal across all the samples, with the micro-CT scanning revealing a concentration primarily within the range of 100–400 μm for the pore equivalent radius and within 200 μm for the throat equivalent radius. Conversely, the nano-CT scanning exhibited concentrations primarily within the range of 500–2500 nm for the pore equivalent radius and within 2000 nm for the throat equivalent radius. The analysis of the 3D reconstruction structures indicated that the middle-rank coal exhibited more developed large–medium pores compared with the low-rank and high-rank coal, while the low-rank and high-rank coal exhibited relatively more micro–small pores. Furthermore, the low-rank coal exhibited the fewest number of pores but the largest average pore equivalent radius and throat radius. Additionally, the middle–high-rank coal exhibited a relatively larger number of pores. Despite the complex topological structures observed in each sample, a significant proportion indicated a coordination number of 0–20, indicating excellent connectivity within the coal samples. This study is conducive to the optimization of coalbed methane surface development blocks and the formulation of reasonable development plans.

Effects of Coal Thickness on the Fractal Dimension of Gas Migration Channels: Laboratory and Field Study of a Gassy Coal Mine

Effects of Coal Thickness on the Fractal Dimension of Gas Migration Channels: Laboratory and Field Study of a Gassy Coal Mine

Research on productivity of stimulated natural gas hydrate reservoir

Natural gas hydrate (NGH) is a prospective clean energy. Conventional development method of the NGH reservoir by pressure drop in vertical well faces the problems of limited stimulated reservoir volume, low production efficiency, and low conductivity. At present, pressure drop production in various well types and stimulation treatments such as hydraulic fracturing in fracable NGH reservoirs have become the focus. The effects of pressure drop production in vertical well, horizontal well, radial wells, and hydraulic fracturing in vertical and horizontal wells in NGH reservoirs were simulated with HydrateResSim. We simulated the productivity of NGH reservoir for 1000 days with several types of development mode. The productivity is highest in horizontal well staged fracturing (5 stages), followed by pressure drop production in horizontal well, fractured vertical well (single fracture), and radial well (16 holes). The worst effect is obtained through production by pressure drop in single vertical well. The optimal effects were obtained with the fracture spacing of 58 m, the fracture half-length of 100 m and the conductivity of 30 μm2 cm. The horizontal well multi-cluster fracturing significantly enlarges the stimulated area and provides channels for gas migration and enhances productivity.

Analysis of the filling patterns and reservoir development models of the Ordovician paleokarst reservoirs in the tahe oilfield

The characteristics of Ordovician paleokarst reservoirs in the Tahe Oilfield are complex. Many prediction studies on the distribution of karst fractures and caves have been carried out, but the filling types and distribution characteristics of caves have been less studied and are thus less understood. First, the development characteristics of the early paleohydrological landforms in the early Hercynian are considered, the paleokarst landforms are restored, the characteristics of the paleohydrological network are clarified, and the lateral distribution of the surface and groundwater systems is illustrated. Additionally, based on a qualitative analysis of core thin section photographs, conventional logging curves, full-bore formation microresistivity scanning, imaging, logging and other characteristics, the existing filling types are divided into four classes: vertical flow filling, river transport filling, cave collapse and hydrothermal transformation. Moreover, reservoir facies division standards for the different filling types are established. Different filling types are constrained in the context of paleogeomorphology and paleohydrology to further study the filling effects and the corresponding controlling factors. As research progresses, five common joint control modes are proposed: joint control of sinkholes and underground rivers, joint control of ancient landforms and underground rivers, joint control of multilayer caves and ancient landforms, control due to collapse and fracture, and joint control of early collapse and late hydrothermal transformation. Based on the model, the relevant mechanisms and the concentrated areas of development are analyzed in depth. The distribution map of the plane filling type is obtained by combining the development model with the identification of the filling type. The relationships between oil and gas production and the reservoir filling degree and between oil and gas migration channels are analyzed by the classification and statistics of different filling types laterally, and the relationships between oil and gas production and the reservoir filling degree and between oil and gas migration channels are analyzed. Hydrothermal action has the strongest ability to transform reservoirs, mainly due to hydrothermal dissolution and fault zones transporting oil and gas; the yield of caves filled with sinkholes is relatively low, which is related to the good reservoir space retained by oil and gas filling and the migration channels provided by fault zones. The yield of the underground river filling type is lower than that of the water-falling cave filling type, mainly because the underground river filling type is located in the karst slope and lower part of the basin. The water energy in the karst slope is relatively strong, and the interior of the cave is filled with medium-fine sandstone. In the lower part of the karst zone, the water energy becomes weak; both of these conditions lead to further filling of the cave reservoir space and a lack of migration channels. The collapse filling type has the strongest impact on the reservoir because this discussion is mainly about late collapse, which causes the cave to collapse, and the internal filling is severe; even if a fault zone acts as a migration channel, oil and gas production is relatively low.

Gas migration channels and efficient gas extraction levels of soft–hard alternate coal seam composite roof

Gas migration channels and efficient gas extraction levels of soft–hard alternate coal seam composite roof

Dynamic effects of rough elements in fractures on coal permeability during different stages of methane extraction

Fractures in coal seams are channels for gas migration, and their geometric characteristics can affect permeability, thereby affecting the effectiveness of coalbed methane (CBM) extraction and carbon dioxide sequestration. The surface of natural fractures is rough and composed of minerals with complex shapes. At present, research on rough fracture is mainly focused on surface characteristics, with less attention given to the dynamic effects of rough structure in fractures on coal permeability considering effective stress and matrix adsorption expansion during different stages of methane extraction. In this work, we construct the complex geometric structure in the fracture surface into simplified rough elements. First, a physical model of fracture rough elements was constructed by using the analytical geometry method; meanwhile, the roughness applicable to this model was proposed, and the characterization of roughness degree of different-shaped rough elements was unified. Subsequently, a definition and an approach for selecting and computing effective fracture aperture were proposed. By taking into account the competition between effective stress and matrix adsorption expansion, the change of effective fracture aperture related to pore pressure was determined. Additionally, a novel permeability evolution model was formulated according to the cubic law and compared with the numerical simulation of other researchers for verification. The variation patterns of permeability, gas pressure and fracture aperture under diverse characteristic fracture roughness elements during CBM extraction were obtained by utilizing the proposed model. The findings indicate that the fractures with smaller roughness, higher stagger degree and gentler inclination angle of rough elements are more favorable for CBM extraction. This has inspired a new understanding of the mechanism of CO2-enhanced coal bed methane recovery (CO2-ECBM) technology in deep coal seams with regard to fracture rough element characteristics, which offers valuable theoretical support for the practical implementation of this technology.

Accumulation conditions and patterns of natural gas hydrate in the Muli permafrost area, northeastern margin of the Qinghai‒Tibet Plateau, NW China

Abstract The Muli permafrost area is the only midlatitude permafrost area where natural gas hydrates (NGHs) have been drilled. Although a series of achievements has been made in studies on NGH accumulation conditions in the permafrost area, related studies on gas hydrate stability zones, gas sources and groundwater are still controversial and need further work. Based on geophysical, geological and geochemical data, this paper systematically elaborates the main NGH accumulation conditions in the Muli area in terms of the pressure‒temperature stability conditions, fault structure, gas composition, gas source, reservoir characteristics, groundwater distribution and topographic characteristics. The results show that the thicknesses of the NGH stability zone range from 491.0 to 962.7 m. The fault structure can provide a pathway for hydrocarbon gas migration from deep to NGH stability zones, in which thrust faults can prevent the upwards migration of gas by sealing it below the hanging wall block. Rock fractures in the NGH stability zone can not only be gas migration channels, but also serve as a reservoir space for NGH accumulation. The hydrocarbon gas of NGHs shows multiple origins and is mainly composed of oil-associated gas. The formation of frost mounds related to the overpressured gas ejection caused by NGH decomposition may imply the existence of NGHs. Synthetically, similarities and differences in NGH accumulation conditions between the Muli permafrost area and other high-latitude permafrost areas are proposed, and the ‘regression’ NGH accumulation pattern in the Muli area is constructed. The study results can enrich theoretical knowledge of terrestrial NGH accumulation, and provide scientific guidance for NGH exploration in midlatitude permafrost areas.

Complex genesis of multiperiod fractures in the Middle Triassic Leikoupo Formation in the Pengzhou gas field, western Sichuan Basin, China

The cumulative expression of multistage deformation is complex multiperiod fractures, which are commonly seen in tectonic zones. The Middle Triassic Leikoupo Formation in the western Sichuan Basin Depression, China, is a typical marine carbonate reservoir with natural fractures caused mainly by tectonic movements. According to outcrops, drill cores, image logging, and fluid inclusions, the fracture characteristics, types of natural fractures, and interactions of fractures are determined. In total, 419 natural fractures in 493.2 m of cores from 7 wells are investigated, which are mainly shear and tensile fractures with a small number of weathering generated fractures. Meanwhile, the results of the stable isotope analysis of δ13C and δ18O, as well as the flow fluid inclusion data, reveal four tectonic periods of fractures with different occurrences. Based on the history of regional tectonic evolution, indicating one period of weathering fractures ascribable to stratal uplift and three periods of structural fractures related to the sequential tectonic movements of the Longmenshan fault belt. By analyzing the interaction relationships of fractures, three types of fracture interaction relationships are observed: cutting, restraining, and overlapping. The four stages fractures are chronologically assigned to (1) the early Indosinian N–S trending compression, (2) the late Indosinian NW-SE compression, (3) the middle Yanshanian NE-SE compression, and (4) the early Himalayan E-W compression. The influence of natural fractures on gas migration and well production in marine carbonates is discussed, and indicates that tectonic fractures could provide seepage channels for gas migration and accumulation from near or distant hydrocarbon source rocks into the Middle Triassic Leikoupo Formation. This study utilizes a pragmatic approach for understanding the fracture genesis mechanism in oil and gas field with multiperiod fractures.

Effects of Volcanic Activity on Organic Matter Enrichment in the Sediments and its Implications for Oil and Gas Exploration and Development

Volcanic activity is an important geological phenomenon in the evolution and development of the earth and brings rich resources to benefit human society, such as geothermal resources, valuable minerals, petroleum, and natural gas, although volcanic eruptions cause serious threats to the ecological environment of our planet. The co-development of oil and gas and volcanic activity in the same basin is a common phenomenon globally. Volcanic activity can bring abundant nutrients into the basins, conducive to the development of algae and other microorganisms in the water body. After the death of organisms, their remaining settles down to the water bottom and accumulate in the sediments. Meanwhile, reducing gases, releasing along with the volcano eruption, including H2S, CO2, etc., result in anoxia in the water body, benefiting the preservation of organic matter at the bottom and brings a large amount of material basis for the generation of oil and gas. Additionally, volcanic activity and hydrothermal fluids are rich in acid substances, will dissolve part of the minerals in the formation, generates a large number of migration channels for oil and gas migration. Some volcanic rocks are rich in pores, making them natural tanks for oil and gas storage. However, volcanic activity also has destructive effects on oil and gas accumulation. High hydrothermal/volcanic input can dilute primary productivity or reduce the abundance of organic matter due to high deposition rates, while excessive volcanic activity or hydrothermal fluid input can introduce large amounts of sulfate into the water, causing strong bacterial sulfate reduction (BSR). The high consumption of organic matter can hamper the organic matter enrichment. Therefore, how to define appropriate volcanic activity conducive to organic carbon preservation, and to establish the relationship model between volcanic activity and organic matter enrichment, are key scientific issues.

Understanding the role of sequence stratigraphy and diagenesis on the temporal and spatial distribution of carbonate reservoir quality: A conceptual modeling approach

Karst caves formed by meteoric water leaching are important oil/gas storage spaces in carbonate reservoirs. However, carbonate reservoirs are transformed by atmospheric freshwater due to long-term cumulative effects that take place over millions of years, and laboratory physical simulations are therefore difficult to conduct. The mechanism by which meteoric water leaching transforms the carbonate sequence stratigraphy is therefore unclear, which has hindered the exploration and development of oil/gas resources. In this study, a large set of geological test data was utilized to develop a solute transport numerical simulation model based on multi-phase flow and multi-component reaction. This was then applied to construct a conceptual model of a grade III sequence stratigraphy for a reservoir in the Yingshan Formation in the central Tarim Basin, China. The multi-stage leaching process of meteoric water during the periodic exposure of the sequence stratigraphy was simulated to explore the effects of the diagenetic transformation of meteoric water on sequence stratigraphy and the associated physical responses. Results revealed that the composition of carbonate rocks affects the degree of reservoir development under the sequence boundary. Calcite dissolution plays a strong role in meteoric water leaching. Carbonate strata with a high calcite content forms secondary pores relatively easily and dolomite can be preserved. Under open geological conditions, the transformation of reservoirs by meteoric water in different periods has the characteristics of continuity, indirectness, superposition, and heterogeneity. In addition to the mineral dissolution caused by the unsaturated solution of the underlying strata, the transformation was also affected by the superposition and indirect influence of the migration and infiltration of the overlying strata fluid. Under heterogeneous conditions, meteoric water preferentially flowed along the dominant channels, which could improve reservoir performance locally, and may form oil and gas migration channels or large karst caves. This investigation of the control of meteoric water during reservoir development provides a theoretical basis for the genetic mechanism by which a high-quality reservoir can develop under the carbonate sequence boundary.

Feasibility investigation of enhanced coalbed methane recovery by steam injection

Heat injection is an effective technique to enhance unconventional oil and gas recovery. As an excellent heat transfer medium, steam has a great potential for coalbed methane (CBM) recovery enhancement. To investigate the feasibility of enhanced CBM recovery by steam injection, infrared thermal imaging (ITI) and thermocouples were employed to study the heating efficiency of steam on three ranks of coal, and nuclear magnetic resonance (NMR) was applied to analyze water transport within the coal after steam treatment. The results showed that the internal temperature of the coal samples reached about 80 °C in 17 min of steam treatment and thermal cracking of coal were induced, hence steam injection could facilitate gas desorption and provide more channels for gas migration. NMR test results indicated that steam preferentially condensed in coal micropores due to the capillary condensation effect, hence steam might have the potential to displace methane. The T2 spectra of the coals after steam treatment exhibited only the first two peaks without the third peak, indicating that steam injection might not cause the water blocking effect. The outcomes of this study are expected to provide valuable insights into the field application of steam injection to enhance CBM production.

Опасные газонасыщенные объекты на акваториях Мирового океана: Восточно-Сибирское море

For the first time, the researchers performed the interpretation of the upper part of the common depth point (CDP) seismic sections in the northwestern part of the East Siberian Sea (ESS) along the 44 lines of JSC MAGE in the amount of 8200 km. They revealed 129 anomalous objects in near-bottom sediments, potentially associated with gas accumulations and channels of its subvertical migration. The average distance between these objects along the lines was 63.6 km — 5.2—6.2 times less than in the Chukchi, Laptev and Bering seas. The authors substantiate that the ESS is characterized by a significantly smaller number of gas migration channels — active faults reaching the near-bottom sediments, compared to the seas mentioned above. This is consistent with the lower neotectonic activity of the ESS and the absence of significant seismic events. In the study area, the researchers revealed a large number of depressions in the bottom relief, which are associated with the furrows of ice gouging during the transgressions-regressions of the sea and at the present stage. Significant errors in the GEBCO bathymetry database were also revealed.

Study of diffusion coefficients and molecular adsorption laws for the slit-hole coal model under the thermal-gas-liuid coupling effect with hot nitrogen injection

To solve the serious filtering problems of fracturing fluid during active hydraulic fracturing of coalbed methane, which blocks gas migration channels with residual fracturing fluid and results in a rapid decline in coalbed methane production, several preliminary experiment of thermal nitrogen injection was carried out. To explain the process and mechanism of thermal nitrogen injection at the nanoscale, an adsorption and diffusion model was established to study the adsorption and diffusion of methane, water and fracturing fluid during thermal nitrogen injection. The results showed that the self-diffusion coefficient of methane was increased by 23%, 45% and 32%, the self-diffusion coefficient of water molecule was increased by 108%, 185% and 138%, the self-diffusion coefficient of fracturing fluid molecule was increased by 169%, 275% and 181%, and the total number of atoms in the slit hole was decreased by 15%, 25% and 37%, respectively, when hot nitrogen was injected at 2, 4 and 6 Mpa, respectively. This shows that the numbers of methane, water and fracturing fluid molecules in the slit hole were significantly decreased by the thermal and displacement effects of hot nitrogen injection. The self-diffusion coefficient was significantly improved, and the effects of plug removal was remarkable.

Effects of Coal Thickness on the Formation and Evolution of Gas Migration Channels: Laboratory and Field Study of a Gassy Mine

Effects of Coal Thickness on the Formation and Evolution of Gas Migration Channels: Laboratory and Field Study of a Gassy Mine

Quantitative Characterization and Determination of the Main Factors That Control Fracture Development in the Lower Paleozoic Shale in Southeastern Chongqing, China

The Longmaxi and Niutitang Formations are typical shale reservoirs in southeastern Chongqing. Since the Paleozoic, southeastern Chongqing has experienced multistage tectonic movement and diagenesis, resulting in the formation of a large number of natural fractures. In shale reservoirs, fractures not only provide seepage channels for oil and gas migration but also play an important role in the oil and gas reservoir space. Natural fractures provide a flow path from source rock to reservoir during oil filling and connect hydraulic fractures, matrix pores, and boreholes during production. Therefore, identifying the main factors that control the development of natural fractures in the Longmaxi and Niutitang Formations in southeastern Chongqing has a guiding significance for the efficient development of shale reservoirs in this area. By considering the Longmaxi and Niutitang Formation shales as case studies, using field outcrops, drilling cores, and other data, and conducting X-ray diffraction (XRD) analysis as well as total organic carbon (TOC) measurements, the quantitative parameter characteristics and main factors that control the development of natural fractures in reservoir shales were examined in detail. The results obtained showed that there are three types of fractures in the lower Paleozoic shale in southeastern Chongqing, which are structural, diagenetic, and abnormal high-pressure fractures. Among them, the fractures in the Longmaxi Formation shale, which are relatively abundant, predominantly consist of low-angle and high-angle inclined fractures, while the Niutitang Formation predominantly consists of high-angle fractures. Additionally, the investigation of fracture size and fracture density, as well as correlation analyses, showed that the fractures of the Lower Paleozoic shale are predominantly micro fractures that play a key role in improving reservoir seepage. It was also noted that the development of fractures is affected by several factors, including tectonic stress, mineral composition, organic carbon content, and rock thickness. The degree of fracture development was found to be positively correlated with brittle mineral and quartz contents, and high organic matter contents also significantly favored the formation micro fractures.

Soil Degassing From the Xianshuihe–Xiaojiang Fault System at the Eastern Boundary of the Chuan–Dian Rhombic Block, Southwest China

The Chuan–Dian region, situated in the middle part of the north-south seismic zone of mainland China in a highly deformed area of the eastern margin of the Tibetan Plateau, is one of the principal areas for monitoring earthquake activities in China. In this study, the geochemical characteristics of soil degassing (of CH4, H2, CO2, Rn, and Hg) and, the relationship between degassing and fault activity, were investigated in the Xianshuihe–Xiaojiang fault system (XXFS) at the eastern boundary of the Chuan–Dian rhombic block. The mean soil-gas concentrations of CH4, H2, CO2, Rn, and Hg in the XXFS were 8.1 ppm, 9.9 ppm, 0.5%, 15.1 kBq/m3 and 12.9 ng/m3, respectively. The δ13CCO2 and δ13CCH4 values of the hot-spring gases varied from −11.9‰ to −3.7‰ and −62.5‰ to 17‰, respectively. The He-C isotopic ratios indicate that the carbon in the northern and middle parts of the XXFS may have originated from deep fluids, whereas the carbon in the southern part of the XXFS is of organic origin. The high concentrations of soil gas were distributed near the faults, indicating that the faults could act as channels for gas migration. The distributions of the high soil-gas concentrations in the XXFS coincide with the highest stress and maximum strain rates, indicating that the fault activity enhanced permeability and increased the emission rates of the gases. The results of this study will be helpful for degassing in active fault zones and earthquake monitoring.