Gas Hydrate Stability Research Articles

Varying free-gas zone (FGZ) and bottom-simulating reflection (BSR) response across a deep graben off Trujillo, central Peru

The complexity of marine gas hydrate systems at the Peruvian convergent margin has been linked to the post-Miocene history of vertical tectonics and subduction erosion that affected the forearc. Here, multichannel seismic data and published findings reveal that such a complexity has been further extended by the occurrence of the pre-Miocene deep Morsa Norte Graben (MNG) off Trujillo (8°–9° S) in the Central Peru margin. At water depths of 650–750 m in the upper slope, directly above the MNG depocentre (which has a 4–6 km overburden thickness), continuous bottom-simulating reflections (BSRs) and concentrated sub-BSR high-amplitude reflections are confined beneath a layered basin with a low–moderate near-seafloor heat flow (7–33 mW m −2 ). A deeper BSR modelled with a thermogenic gas composition is associated with the enhanced reflections. At a water depth of 900 m, sub-BSR reflections become less frequent in an area with a layered sediment cover defined by a moderate near-seafloor heat flow (15–33 mW m −2 ). At a water depth of 1200 m, where the MNG is relatively thick (3–4 km overburden thickness), faults connect patchy BSRs with a moderate–high near-seafloor heat flow (52–110 mW m −2 ). There, sub-BSR enhanced reflections are scarce. Immediately above the top of the gas hydrate stability zone (GHSZ), the near-seafloor heat flow reaches 81 mW m −2 . Modelling suggests a water depth-dependent transport of heat towards the seafloor with respect to the top of the GHSZ, implying that the closer the seafloor is to the top of the GHSZ, the lower the advection of heat, and vice versa. Recent seafloor-related depositional and structural features amplify such relations in agreement with near-seafloor heat-flow variability. However, towards the area outside the extent of the MNG (<3 km overburden thickness), continuous BSRs are not linked either to a deeper BSR or to sub-BSR enhanced reflections. The continuity of one of these BSRs is deflected upwards beneath a slump, suggesting an incomplete thermal re-equilibration of the GHSZ. Therefore, we conclude that the BSR responds to: (1) the confinement and thickening of the free-gas zone (FGZ) above the MNG depocentre due to the sealing effect of recent sedimentation close to the top of the GHSZ; (2) the seepage of gas-rich fluids from a thinned FGZ above the relatively thick MNG, due to the enabling effect of faults cutting the GHSZ far from the top of the GHSZ; (3) the undisturbed state of the FGZ outside the extent of the MNG; and (4) the disequilibrium state of the base of the GHSZ due to the unloading of sediments in an unstable slope environment prone to failure.

Shallow subsurface fluid dynamics in the Malvinas Basin (SW Atlantic): A geoacoustic analysis

Using a database consisting of sub-bottom profiles, 2D and 3D seismic data, a series of seep structures and acoustic anomalies associated with a plumbing system in the subsurface of the southern part of the Malvinas Basin off the Argentine coast are presented. The seep morphologies consist of mounds, pockmarks, and a carbonate mound, derived from hydrocarbons migrating from the Early Cretaceous Springhill and Lower Inoceramus formations through extensional faults and overthrusts of the Malvinas Fold-Thrust Belt and accumulating in the gas hydrate stability zone. This configuration is widely observed in the anticlines of the Malvinas Fold-Thrust Belt, which are characterized by a vertical structure highlighting a Bottom Simulating Reflector (BSR) overlain by a blanked-out zone at the seabed, interpreted as a gas hydrate stability zone. The plumbing system is influenced by active transtensional tectonics, as shown by two sets of extensional faults concentrated over some anticlines. These faults lead to displacements that, in many cases, reach the seabed. One nuance of the influence of tectonic activity on fluid escape is most evident in the Malvinas anticline, where all the pockmarks and the carbonate mound are concentrated. In the western part of the Malvinas anticline, five pockmarks are observed in an area characterized by a shallow BSR. In contrast, in the eastern part of the Malvinas Basin, one pockmark and one carbonate mound are derived from a series of extensional faults. The presented data, as well as a comparison between the western and eastern parts of the Malvinas anticline, indicate that the anticlines are the main cause of seepage in this area, as they allow the accumulation of migrating fluids. Likewise, the seepage morphologies outside the anticlines are much less pronounced, as can be observed in the mounds that overlie the bottom vents.

Phase Stability of CH4 and CO2 Hydrates under Confinement Predicted by Machine Learning.

Understanding the phase stability of gas hydrates under confinement is fundamental to the geological stability evolutions of gas hydrate systems on Earth. Herein, the phase stability of CH4 and CO2 hydrates under confinement is predicted by machine learning. Three machine learning models, including support vector machine, random forest, and gradient boosting decision tree, are constructed to predict the phase stability of CH4 and CO2 hydrates under confinement. Our machine learning results show that the prediction accuracy of the support vector machine model is highest, yet the prediction accuracy of the random forest model is lowest among those machine learning models in determining the phase stability of confined gas hydrates. Based on their performance in predicting the phase stability of confined gas hydrates, the support vector machine model with a training set fraction of 0.7 is finally chosen to deal with the unknown phase stability of confined gas hydrates. Importantly, the average accuracy of the support vector machine model can reach more than 90% in predicting the unknown phase stability of both CH4 and CO2 hydrates. The trained machine learning models can help us to quickly and accurately determine the phase stability of CH4 and CO2 hydrates under confinement in future applications.

Shoaling of the gas hydrate stability zone inferred from 3D seismic data of the Cauvery basin

Shoaling of the gas hydrate stability zone inferred from 3D seismic data of the Cauvery basin

Effect of particle size, water saturation, inorganic salt and methane on the phase equilibrium of CO2 hydrates in sediments

Understanding the thermal stability of gas hydrate in complex marine geological environment is of importance to hydrate-based carbon sequestration. In this work, the factors affecting the equilibrium of CO2 hydrate in ocean sediments, including quartz sands, inorganic salts and gas impurities were quantitatively measured in a temperature range from 273 to 283 K and a phase equilibrium model of hydrate was established. To reveal the distribution in pore structure, the micro-morphologies of hydrate-bearing sediments were measured by cryo-SEM. Results showed that reduction of initial water saturation, addition of NaCl and CH4 were found to have inhibitory effect on CO2 hydrate equilibrium. Initial water saturation reduced the equilibrium temperature by the capillary pressure, but only 0.3–0.7 K temperature depression was observed as the water saturation reduced to 5 %. About 5.7 K in the average temperature depression was found by the addition of 10 wt% NaCl and 24 mol% CH4. NaCl and CH4 influenced the hydrate equilibrium by changing the water activity and chemical potential of hydrate water lattice. SEM images showed that the hydrate formed in pores of quartz sand had porous surface and coated the sand particles like a layer of cells which are 5–20 μm in diameter, suggesting the hydrate layer exists between the liquid and gas phase. Based on the van der Waals-Platteeuw model, a hydrate equilibrium model was developed. The model provided a good prediction of the hydrate equilibrium in the presence of quartz sand, NaCl and CH4 with an averaged deviation of ±4.2 %, which had the potential to be applicated in more complexed ocean sedimentary environment.

Gas hydrate stability for CO2-methane gas mixes in the Pegasus Basin, New Zealand: A geological control for potential gas production using methane-CO2 exchange in hydrates

Gas hydrate is an ice-like form of water containing gas, in nature mostly methane (CH4), which requires moderate pressures and low temperatures. The replacement of CH4 by CO2, which also forms a hydrate, could allow CH4 production from hydrate while sequestering CO2. A number of recent studies have focused on theoretical background, experimental simulations, and engineering approaches related to CH4-CO2 exchange in hydrates. We here investigate a key geologic constraint for possible CH4-CO2 exchange in sub-seafloor reservoirs, hydrate stability. We analyze seismic data and gas hydrate system models from the Pegasus Basin east of New Zealand, a region with evidence for abundant gas hydrates. Pressure-temperature conditions beneath the seafloor need to be within the stability fields for both CH4 hydrate and hydrate from the resulting gas mix after CO2 injection. Based on experimental and theoretical studies, we consider 64% a benchmark for maximum achievable CH4 replacement by CO2, resulting in a mix of 64% CO2 – 36% CH4, in hydrate. Down to a water depth of 1087 m, hydrate from this gas mix is stable within the entire CH4 hydrate stability field. A gap develops in deeper water with the base of gas hydrate stability (BGHS) for CH4 being deeper than for the 64% CO2 – 36% CH4 mix. In nature, most mechanisms for CH4 hydrate formation favor high saturation near the BGHS. For an evaluation of possible CH4-CO2 exchange, it is therefore important to investigate mixed-gas hydrate stability near the CH4-BGHS and to identify CH4 hydrates closer to the seafloor.

Gas hydrate technological applications: From energy recovery to carbon capture and storage

Hydrates are crystalline structures that trap small gas molecules inside hydrogen-bonded water cages. These structures form at high pressure and low temperature. In recent years, there has been a growing interest in gas hydrates for technological applications, specifically in energy recovery, as well as carbon dioxide capture and storage. In the CO2/CH4 exchange using gas hydrates, researchers have reported a large amount of natural gas trapped in the form of gas hydrates under the ocean seafloor and permafrost regions. This large amount of natural gas trapped inside hydrate cages in oceanic and permafrost deposits has driven interest in the energy sector to investigate the possibility of safely harvesting gas hydrates as one of energy resources. However, there are still unanswered fundamental questions including the mechanism of natural gas recovery from gas hydrates. Another gas hydrate-based technology that has a growing interest is the use of gas hydrates for separation including carbon dioxide capture and storage. Carbon dioxide molecules have been shown to be preferentially trapped in the hydrate phase, demonstrating the possibility of the usage for carbon capture technology. Similarly, there are still underlying concerns of these applications, such as thermodynamics and stability of gas hydrates in porous materials, and the crystallization kinetics and mechanism of hydrate formation. This paper provides an overview of laboratory investigations conducted to understand the mechanism and evaluate the feasibility of energy recovery as well as discussion on recent advances in laboratory investigations on gas hydrate-based technology.

A new thermodynamic model for predicting the 3-D phase equilibrium surface of gas hydrates considering the effect of salt concentration

An accurate understanding of the thermodynamic stability of gas hydrates in salt-bearing systems is of great significance for predicting the extent of hydrate accumulation and determining the hydrate decomposition domain. Therefore, this study proposes a thermodynamic model for predicting the temperature–pressure-salt concentration three-dimensional phase-equilibrium surface. The model considered the interaction of the electrolyte in a mixed salt solution system and non-spherical shaped hydrate crystal cavity. The modified van der Waals-Platteeuw (vdW-P) model and Benedict-Webb-Rubin-Starling (BWRS) equation of state were used to describe the hydrate phase. The Pitzer-Debye-Hückel equation and nonelectrolyte non random two liquid non random factor (N-NRTL-NRF) activity coefficient model were used to describe the fluid phase. The prediction results of the model agreed with the experimental data, and the absolute average relative deviation in temperature (AARD-T) under pure water conditions was only 0.08, and the AARD-T under electrolyte conditions did not exceed 0.15, which proved the accuracy and reliability of the model. The calculation results showed that when the mole fraction of chloride salt was greater than 0.02 and the pressure was higher than 20 MPa, chemical factors caused the p-T curves to translate. When the pressure was low, the temperature gradient along the direction of the salt concentration changed drastically, and the p-T curves no longer had translation characteristics. In comparison, under the same mole fraction, AlCl3 had a stronger inhibitory effect on the CH4 hydrate than the other chloride salts. The lnp-X-1/T three-dimensional surface of the CH4 hydrate exhibited good Clausius-Clapeyron linear behavior locally, and the surface had certain nonlinear characteristics. The degree of nonlinearity of the lnp-X-1/T three-dimensional surfaces of different types of chloride salts was different. A better inhibitory effect of the chloride salt electrolyte on the CH4 hydrate was associated with stronger nonlinearity between 1/T and lnp.

MASS-WASTING INDUCED SHIFTS OF THE BASE OF THE GAS HYDRATE STABILITY ZONE: EXAMPLES FROM THE OFFSHORE NIGER DELTA BASIN, NIGERIA

Mass-wasting episodes lead to significant changes in the pressure and temperature regimes within shallow marine sediments and induce variations in the thickness of the gas hydrate stability zone. These variations are marked by vertical migrations of bottom-simulating reflections that typically mark the base of the hydrate zone. Using exploration seismic data from the Offshore Niger Delta, this study presents two examples involving the vertical migration of the base of the gas hydrate stability zones induced by mass-wasting events. The first is related to a slope failure surface along the forelimb of an active thrust-cored anticline with considerable bathymetric relief. Sediment removal has induced both a decrease in overburden pressure and an incursion of cooler temperature flux in strata in the anticline and led to a migration of the base of the gas hydrate stability zone to deeper levels. The second case is related to a recent erosional event that has led to sediment removal along a seafloor channel course. Evidence of ongoing migration of the base of the gas hydrate stability zone to deeper levels is provided by the lateral termination of a BSR along channel wall, its absence beneath the channel bottom and its apparent downward bend close to the channel fringes. Apart from unroofing hydrate systems and releasing free gas into the ocean and possibly the atmosphere, mass-wasting events on the seafloor, represent significant drivers influencing the formation of gas hydrates in shallow subsea sediments and the thickness and depths of the gas hydrate stability zone.

Numerical study on decomposition characteristics of natural gas hydrate based on molecular dynamics method

The molecular dynamics method is used to investigate decomposition characteristics of natural gas hydrate under different pressure and salinity. In this paper, the influence of pressure variation on the stability of natural gas hydrate under high pressure is studied from the molecular point of view based on the seabed pressure in Shenhu sea area. At the same time, taking the real marine conditions in the South China Sea as a reference, the effect of the synergistic effect of various salt ions on the decomposition of natural gas hydrate under the effect of salinity is studied. Its decomposition behavior is discussed by analyzing the parameters such as cell conformation, radial distribution function, mean square displacement and self-diffusion coefficient. The results show that pressure and salinity influence the decomposition of natural gas hydrate through modifying stable its conditions, from solid state to gas-liquid state. And the reduction of pressure accelerates the decomposition of natural gas hydrate under high pressure, while the increase of salinity promotes the decomposition of natural gas hydrate under the condition of high salinity.

Impact of gas arising from gas hydrate decomposition on the effective permeability of bottom sediments of the Arctic shelf: a laboratory simulation

Relevance. The necessity to investigate the mechanism of gas (methane) flow occurring during decomposition of gas hydrate formations within the layers of bottom sediments. This process is evident through substantial releases of methane bubbles in extensive shallow regions of the Russian Arctic shelf and has the potential to alter the equilibrium of atmospheric methane, a critical greenhouse gas. Aim. To quantitatively investigate, within the context of gas transport in bottom sediments, the impact of free and bound gas within the pores on the nonlinearity of filtration flows. Methods. The model samples with filtration properties similar to those of the bottom rocks of the East Siberian Arctic shelf. During the experiments, a specific amount of gas was injected into the saturated model sample, followed by the measurement of its effective permeability during a slow decrease in pore pressure gradient. The obtained curve was interpreted within the framework of the threshold gradient model. Results. The experiments yielded curves showing the dependency of the threshold gradient magnitude on gas saturation for several samples. It was found that the threshold gradient linearly increases with the growth in gas fraction within the pore space. Already at a gas fraction of approximately 0.02, this value in the experiments reached 0.01 MPa/m, corresponding to the hydrostatic pressure gradient in water. This suggests that even areas with relatively low gas saturation may be impermeable to convective fluid flow. This possibility should be considered when creating models for bubble gas transporting through the rock layers of bottom sediments. Furthermore, the existence of gas-saturated zones with threshold gradients can significantly impact the vertical profile of pore pressure and lead to a reassessment of the depth of gas hydrate stability zones.

Evaluation of Thermal and Mechanical Properties of Foamed Phosphogypsum-Based Cementitious Materials for Well Cementing in Hydrate Reservoirs

As detrimental byproduct waste generated during the production of fertilizers, phosphogypsum can be harmlessly treated by producing phosphogypsum-based cementitious materials (PGCs) for offshore well cementing in hydrate reservoirs. To be specific, the excellent mechanical properties of PGCs significantly promote wellbore stability. And the preeminent temperature control performance of PGCs helps to control undesirable gas channeling, increasing the formation stability of natural gas hydrate (NGH) reservoirs. Notably, to further enhance temperature control performance, foaming agents are added to PGCs to increase porosity, which however reduces the compressive strength and increases the risk of wellbore instability. Therefore, the synergetic effect between temperature control performance and mechanical properties should be quantitatively evaluated to enhance the overall performance of foamed PGCs for well cementing in NGH reservoirs. But so far, most existing studies of foamed PGCs are limited to experimental work and ignore the synergetic effect. Motivated by this, we combine experimental work with theoretical work to investigate the correlations between the porosity, temperature control performance, and mechanical properties of foamed PGCs. Specifically, the thermal conductivity and compressive strength of foamed PGCs are accurately determined through experimental measurements, then theoretical models are proposed to make up for the non-repeatability of experiments. The results show that, when the porosity increases from 6% to 70%, the 7 d and 28 d compressive strengths of foamed PGCs respectively decrease from 21.3 MPa to 0.9 MPa and from 23.5 MPa to 1.0 MPa, and the thermal conductivity decreases from 0.33 W·m−1·K−1 to 0.12 W·m−1·K−1. Additionally, an overall performance index evaluation system is established, advancing the application of foamed PGCs for well cementing in NGH reservoirs and promoting the recycling of phosphogypsum.

Formation and phase equilibria of gas hydrates confined in hydrophobic nanoparticles

The promotion of gas hydrate formation is of fundamental importance to facilitate its great potential applications in, for example, gas separation, transportation and energy storage. The employment of Dry Water (DW), which is a powdery Pickering system composed of macro water droplets surrounded by stabilising hydrophobic nanoparticles, is considered an effective method for enhancing hydrate formation. The promotion mechanism underlying this observation, however, has yet to be well understood. In this work, the effect of DW on both formation kinetics and thermodynamic stability of gas hydrates was investigated using a micro differential scanning calorimetry (µDSC) in CH4 and CO2 hydrate systems, using two different hydrophobic nanoparticles. Distinctly shorter induction times and higher conversion ratios were observed for DW compared to bulk water. The DW system stabilised by more hydrophobic nanoparticles showed benefits in accelerating nucleation, while the other system, which consisted of smaller DW droplets, led to a superior enhancement of hydrate growth. Besides the effect on formation kinetics, it was also noted that DW influenced the µDSC hydrate dissociation peak characteristics, including melting points and melting peak shapes. This phenomenon suggested that the centre- and surface-droplet hydrates in DW may have different structures, due to the “hydrophobic effect” of the nanoparticles structuring the near-surface water, so exhibiting melting points corresponding to bulk hydrate or to a more structured surface hydrate (with raised melting point), respectively. To support this “hydrophobic effect” hypothesis, a series of hydrate and ice formation experiments were conducted in porous media having different hydrophobicity, the results of which demonstrated that hydrates adjoining confined hydrophobized surfaces, in other systems similar to DW, also displayed higher melting temperatures.

Dynamic accumulation of a high-grade gas hydrate system: insights from the trial production gas hydrate reservoir in the Shenhu area, northern South China Sea

The ultimate enrichment level and quantity of gas hydrate resources are influenced by the dynamic process of accumulation and preservation. High-resolution 3-D seismic data, logging while drilling (LWD), pressured coring, and in situ testing were used to characterize the dynamic accumulation and preservation of the trial production high-grade gas hydrate reservoir (HGGHR) in the Shenhu area. Through seismic variance analysis and ant-tracking, we found that newly identified mud diapir-associated faults with three development stages controlled the migration and accumulation of gas hydrate and shifted the base of the gas hydrate stability zone (BGHSZ), resulting in dynamic accumulation and dissociation of gas hydrates. The recognized double bottom simulating reflectors (BSRs) were concluded to have been formed due to the shift of the BGHSZ caused by the variational equilibrium conditions. The interval between the double BSRs was inferred to be a disequilibrium zone where gas recycling occurred, contributing to the coexistence of gas hydrates and free gas and the dynamic formation of the HGGHR. Multiple gliding faults formed within the GHSZ in the late period have altered the HGGHR and control the present thickness and distribution of the gas hydrates and free gas in the hanging wall and footwall. Under the influence of geothermal fluids and the fault system associated with the mud diapir, the HGGHR experienced dynamic accumulation with three stages, including early accumulation, medium-term adjustment, and late alteration and preservation. We conclude that four factors affected the formation, distribution, and occurrence of the HGGHR: the geothermal fluids accompanying the deep mud diapir below the reservoir, the dual supply of thermogenic gas and biogenic gas, the recycling of hydrate gas beneath the BGHSZ, and the post-gas hydrate faults developed within the GHSZ. A geological model illustrating the dynamic formation of the trial production HGGHR was proposed, providing a reference for future exploration of HGGHRs with a great production potential in deepwater settings.

Slow Dynamics of Hydrate Systems Revealed by a Double BSR

AbstractDetermining how gas hydrate distribution evolved along continental margins in the past is essential to understanding its evolution in the future. Moreover, hydrate decomposition has been linked to several catastrophic events, including some of the largest submarine landslides on Earth and the massive release of greenhouse gases into the ocean. Offshore Romania, the presence of a second bottom‐simulating reflector (BSR) provides an opportunity to gain valuable insights into hydrate dynamics since the Last Glacial Period (LGP). We conducted transient modeling of hydrate thermodynamic stability by merging in‐situ observations with indirect assessments of sea‐bottom temperature, thermal conductivity, salinity, sedimentation rate, and sea‐level variations. We reveal a strong correlation between the BSRs and the base of the Gas Hydrate Stability Zone (GHSZ) during both the present and LGP periods. The gradual evolution of the GHSZ over the past 34 ka presented here supports a conceptual model that excludes catastrophic environmental scenarios.

Seep carbonate clumped isotopes revealing ocean warming-induced gas hydrate dissociation

The dissociation of marine methane hydrates due to the increased ocean temperature may be widespread in the context of global warming. However, direct evidence for this phenomenon is limited. Here, we reported the carbon and oxygen isotopes, mineralogy, elements, and clumped isotopes (Δ47) of coring seep carbonates (MIS5e) to explore the influence of temperature changes on gas hydrate stability. The extremely low δ13C and high δ18O values of bulk carbonates (average, −48.1‰ and 4.4‰, respectively) indicated the authigenic carbonates formed from the anaerobic oxidation of methane and gas hydrate dissociation. An anaerobic environmental condition with intense methane seepages was confirmed by the dominant aragonite, Mo enrichment (MoEF averaged as 312), and positive Ce anomalies (averaged as −0.03). The Δ47 values ranged from 0.714 to 0.745, indicating a higher bottom-water temperature (averaged at 7.5 °C) during MIS5e compared with the current seafloor temperature (5.4 °C). This study provides direct evidence for the dissociation of gas hydrate triggered by ocean warming, presenting new insights into potential temperature-induced gas hydrate instability due to global climate warming.

Study on the Mechanism of Natural Gas Hydrate Decomposition and Seabed Seepage Triggered by Mass Transport Deposits

Previous studies indicate that mass transport deposits are related to the dynamic accumulation of natural gas hydrates and gas leakage. This research aims to elucidate the causal mechanism of seabed seepage in the western region of the southeastern Qiongdongnan Basin through the application of seismic interpretation and attribute fusion techniques. The mass transport deposits, bottom simulating reflector, submarine mounds, and other phenomena were identified through seismic interpretation techniques. Faults and fractures were identified by utilizing variance attribute analysis. Gas chimneys were identified using instantaneous frequency attribute analysis. Free gas and paleo-seepage points were identified using sweetness attributes, enabling the analysis of fluid seepage pathways and the establishment of a seepage evolution model. Research has shown that in areas where the mass transport deposits develop thicker layers, there is a greater uplift of the bottom boundary of the gas hydrate stability zone, which can significantly alter the seafloor topography. Conversely, the opposite is true. The research indicates that the upward migration of the gas hydrate stability zone, induced by the mass transport deposits in the study area, can result in the rapid decomposition of gas hydrates. The gas generated from the decomposition of gas hydrates is identified as the principal factor responsible for inducing seabed seepage. Moderate- and low-speed natural gas seepage can create spiny seamounts and domed seamounts, respectively.

Methane seeps on the U.S. Atlantic margin: An updated inventory and interpretative framework

Since the discovery of >570 methane flares on the northern U.S. Atlantic margin between Cape Hatteras and Georges Bank in the last decade, the acquisition of thousands of kilometers of additional water column imaging data has provided greater coverage at water depths between the outer continental shelf and the lower continental slope. The additional high-resolution data reveal >1400 gas flares, but the removal of probable duplicates from the combined database of new flares and those recognized in 2014 yields ∼1139 unique sites. Most of these sites occur in clusters of 5 or more seeps, leaving about 275 unique locations (including 47 clusters) for seepage along the margin. As a function of depth, seep distribution is heavily skewed toward the upper continental slope at water depths shallower than 400 m on the southern New England margin and ∼ 550 m in the Mid-Atlantic Bight, with additional seeps clustered at ∼1100 m and just deeper than ∼1400 m in both sectors. Despite little ongoing tectonic deformation or active faulting on this passive margin, a variety of processes driven from below the seafloor (e.g., migration of fluids along faults or through permeable strata, seepage above diapirs or other pre-existing structures) and from above (e.g., erosion, sapping, unroofing) contribute to the development of seeps in different settings along the margin. In addition, the prevalence of seeps on promontories overlooking shelf-breaking canyons may be directly related to the three-dimensional nature of the hydrate stability zone in these locations. As a function of depth, the parts of the slope at the contemporary landward limit of gas hydrate stability are devoid of seeps, and the upper slope zones with the most concentrated seepage were not within the gas hydrate stability zone even during the Last Glacial Maximum. Thus, if the large number of upper slope seeps is at least partially sourced in gas hydrate degradation, the gas emitted at these seeps must have migrated there from greater depths on the continental slope.

Thermodynamic phase equilibria study of Hythane (methane + hydrogen) gas hydrates for enhanced energy storage applications

Hydrogen blending with natural gas has become an effective technique for incorporating the characteristics of natural gas and facilitating the storage and transportation of hydrogen gas. The transportation of hydrogen and natural gas (methane) blend, also referred to as Hythane, presents numerous challenges, advantages, and disadvantages that differ based on the technology employed. The current research showcased a thorough examination of the thermodynamics involved in studying the three phase equilibrium analysis of gas hydrate technology for storing Hythane gas mixtures. Three different Hythane compositions varying in hydrogen percentage were selected, and the isochoric gas hydrate phase equilibria study was performed. The experimental results of phase equilibria and thermodynamic modelling using CPA EOS in software were compared. A similar study was also conducted in the presence of a 5.56 mol % THF solution to understand the reduction in the pressure requirement for the phase equilibria. Results from the mixed Hythane+THF gas hydrate findings suggested stable gas hydrate formation at much lower pressure requirements, increasing the credibility of storing Hythane mixtures in gas hydrates at moderate conditions. The gas compositions for each experiment were analyzed using gas chromatography to evaluate the presence of the desired gas in the hydrate phase. Heat exchange during the gas hydrate dissociation was analyzed using a high pressure differential scanning calorimeter (DSC). The change in the heat release temperature also indicates the stability of the gas hydrate, and with increasing hydrogen gas in the blend, the gas hydrate stability decreased. The Clausius-Clapeyron equation was employed to compute the heat of gas hydrate dissociation, and a comparison was made with the heat of dissociation obtained from the DSC study. The experimental investigations on Hythane gas hydrates were performed to find the hydrogen storage inside the gas hydrate phase and compare it with the previous studies of pure hydrogen hydrates. To demonstrate the Hythane gas transportation, Hythane gas hydrate pellets were formed, followed by their storage in a controlled environment to observeany changes in pressure and temperature. The Hythane gas hydrate pellets demonstrated exceptional stability of Hythane gas presenting an intriguing prospect for utilizing gas hydrate technology in Hythane gas transportation.

INFLUENCE OF PLEISTOCENE GLACIATION ON PETROLEUM SYSTEMS AND GAS HYDRATE STABILITY IN THE OLGA BASIN REGION, BARENTS SEA

This study presents the results of a 2D numerical basin and petroleum systems model of the Olga Basin in the NW Barents Sea offshore northern Norway, a frontier exploration area in which there are abundant seafloor oil and gas seepages. The effects of Pleistocene ice sheet advances on rock properties and subsurface fluid migration in this area, and on seafloor hydrocarbon seepage, are not well understood. The 2D numerical model takes account of recurrent ice advances and retreats, together with related erosional and temperature effects, and investigates the influence of these parameters on fluid migration. Model results show that Pleistocene glaciations reduced the temperature in the sedimentary succession in the Olga Basin by up to 20 °C, for example in the uppermost Cretaceous and Jurassic sediments which underlie the seafloor down to a depth of 0.5 to 1 km. The decrease in temperature was in general predominantly related to the intensity of glacial erosion, which was set in this study to a depth of 600 m based on previous studies. Hydrocarbon fluids expelled from potential thermogenic source rocks of Carboniferous to Triassic ages on the SW margin of the Olga Basin migrated to the seafloor through permeable carrier beds. However, fluid migration to the surface in the NE of the study area took place along fault conduits. In a closed fault model scenario, only 0.3 Mt of hydrocarbons are modelled to have migrated along the 0.5 km wide model section; in a second scenario with partially open faults, about 22 Mt of hydrocarbons, representing about 11% of the total hydrocarbons generated by potential thermogenic source rocks in the study area, were lost to the surface during the Pleistocene. The potential for microbial methane generation in the Olga Basin was limited both during the Pleistocene and at the present day due to the significant reduction in temperature during glacial episodes, and due to the intense glacial‐related erosion of the Mesozoic to Cenozoic stratigraphy. During glacial stages, the gas hydrate stability zone beneath the ice sheet is modelled to have extended to a depth of up to 900 m for a pure methane composition, and to a depth of up to 1100 m for a possible thermogenic‐sourced mixed gas composition of 90% methane, 7% propane and 3% ethane. Gas hydrates with this mixed composition are modelled to have been stable in the Olga Basin during the last three glacial advances and into the present. These modelling results provide an insight into the key factors controlling the migration and surface leakage of hydrocarbon fluids in the Olga Basin region, and into the effects of glaciations on rock properties in a glaciated basin.