Gas-fired Boiler Research Articles

Impact of Hydrogen Blending Policies on the Energy Efficiency, Environmental and Economics parameters of Residential Gas Boilers

Abstract At present, gas-fired boilers are among the most common systems for heating residential buildings. The potential integration of hydrogen into the gas network is being considered as a viable option for decarbonising heating systems. This study investigates the impact of hydrogen injection into the network, focusing on how it affects boiler performance by analysing energy and environmental parameters with different hydrogen fractions. Specifically, the study examines the technical, economic and environmental consequences of using hydrogen-enriched natural gas (H2NG) blends in gas-fired boilers. Primary energy consumption and emissions were evaluated using H2NG blends with hydrogen fractions ranging from 0% to 25% by volume. In addition, the study evaluates the influence of the blend on the system operating costs and the LCOH (levelized cost of heat) in relation to the LCOH2 (levelized cost of hydrogen). An analysis was carried out to determine the effect of hydrogen on emissions to facilitate the calculation of the Carbon Abatement Cost (CAC) of using the blend. The results show that the incorporation of H2NG blends further reduces the EPnr, with a 30% hydrogen blend achieving a 12.05% reduction. CO2 emissions also decrease proportionally with increasing hydrogen content. Economically, LCOH increases with increasing hydrogen content, with a 30% blend increasing boiler costs by 4.93%. In conclusion, the integration of hydrogen into heating systems can significantly reduce both non-renewable energy consumption and CO2 emissions but requires an increase in costs for fuel purchase due to the different energy vector.

Optimization of reversible heat pumps utilizing waste heat from electric power plants

Abstract Current global climate targets aim to decarbonize all energy sectors. In the power generation sector, the increasing presence of Renewable Energy Sources (RES) has changed the role of Combined Cycle Gas Turbine (CCGT) power plants. They are becoming systems that need to provide more flexibility to the grid through ancillary and balancing services or reserve capacity. At the same time, urgent action is needed to significantly reduce the carbon intensity of the heating sector, a major contributor to greenhouse gas emissions. Using the low-exergy waste heat from water-cooled CCGT condensers as a thermal source for vapor compression heat pumps serves two purposes. Firstly, it improves the economic viability of CCGT plants, which is crucial for ensuring the security of the electricity supply. Secondly, the heat produced provides a low-carbon alternative to conventional gas-fired boilers or less efficient air-source heat pumps. This study evaluates the potential for recovering thermal energy from seawater cooling at the condenser of the 794 MWel CCGT plant in Vado Ligure operated by Tirreno Power. A high-temperature heat pump using R600 as the working fluid is proposed. Seawater is an advantageous heat source, and integration into the power plant site allows the heat pump to be operated at a lower cost than the retail price of electricity. To assess economic and environmental performance, the case study focuses on the new Vado Ligure sports hall. This involves sizing the heat pump and analysing its impact, managing both heating and cooling demand using the same reverse cycle heat pumps.

Effects of sub-atmospheric pressure on appearance and pollutant formation of inverse diffusion flame within a confined space

Gas-fired boilers operating at high-altitude regions often suffer from inadequate output, decreased thermal efficiency, and excessive NOx emissions. The effect of sub-atmospheric pressure on flame appearance and pollutant formation is the main reason for those problems, and thus needs to be clarified particularly under furnace combustion conditions with a fixed excess air coefficient. Inverse diffusion is a widely employed fuel–air configuration in burners of gas-fired boilers, and therefore the flame appearance, CO generation, and NO generation were experimentally investigated in this paper by adopting a low-pressure quartz tube reactor. Results show that the flame is elongated from reducing pressure under fuel-lean conditions, mainly due to the reduced oxygen mass concentration and the elevated jet velocity. Under fuel-rich combustion conditions, however, the flame is shorted at sub-atmospheric pressure from the suppressed soot formation. The reduced pressure leads to an increase in the global strain rate, making the flame more prone to uplift. With decreasing pressure, the increased air–fuel mixing and flame length facilitate the gas burnout, thus decreasing CO generation. The sub-atmospheric pressure could evidently reduce the NO generation under fuel-rich conditions, but slightly increase it under fuel-lean conditions. Under fuel-lean conditions, the NO major pathways (prompt, thermal, NNH, and N2O) are promoted which leads to an increase in NO generation with decreasing pressure. Under fuel-rich conditions, however, NO formation is suppressed from the decreased rate of reaction N2+CH↔HCN+N.

Analysis of the Impact of Funding Policies for the Energy Refurbishment of Buildings Using Dynamic Simulations

Dynamic simulations can accurately estimate the thermal demands for space heating and cooling in buildings, as well as the energy and economic performance of specific energy refurbishment actions. This study aims to evaluate the energy and economic savings resulting from the adoption of particular energy measures applied to a cluster of residential condominium buildings, also considering some possible Italian funding policies. To this scope, dynamic simulation models of several buildings with different features in terms of geometry, shape, and thermo-physical properties are considered. The selected buildings are representative of the most common buildings in the city of Naples, Southern Italy. Two scenarios regarding the possible penetration of the refurbishment actions are considered: the “25% scenario”, where 25% of buildings in the Naples municipality adopt the selected measures, and the “100% scenario”, where all buildings adopt such energy refurbishment actions. The results of the simulations, reported over different time periods, compare the economic, energy, and environmental benefits of the specific energy measures. This study evaluates the replacement of conventional natural gas-fired boilers with natural gas-fired condensing boilers, as well as the use of thermal insulation on the external walls of the buildings. The primary energy demand for space heating decreased by 28% when the proposed energy measures were implemented in all buildings of the Naples municipality.

A generic stochastic network-based formulation for production optimization of district heating systems

AbstractDistrict heating (DH) systems are an important component in the EU strategy to reach the emission goals, since they allow an efficient supply of heat while using the advantages of sector coupling between different energy carriers such as power, heat, gas and biomass. Most DH systems use several different types of units to produce heat for hundreds or thousands of households (e.g. natural gas-fired boilers, electric boilers, biomass-fired units, waste heat from industry, solar thermal units). Furthermore, combined heat and power units units are often included to use the synergy effects of excess heat from electricity production. To address the challenge of providing optimization tools for a vast variety of different system configurations, we propose a generic mixed-integer linear programming formulation for the operational production optimization in DH systems. The model is based on a network structure that can represent different system setups while the underlying model formulation stays the same. Therefore, the model can be used for most DH systems although they might use different combinations of technologies in different system layouts. The mathematical formulation is based on stochastic programming to account for the uncertainty of energy prices and production from non-dispatchable units such as waste heat and solar heat. Furthermore, the model is easily adaptable to different application cases in DH systems such as operational planning, bidding to electricity markets and long-term evaluation. We present results from three real cases in Denmark with different requirements.

Field deployable laser sensor for calibration-free and real-time measurement of NOx from stationary sources

Nitrogen oxides (NOx) are common pollutants emitted from stationary sources, such as industrial boilers and power plants, with significant adverse impacts on the environment and biosphere. The abatement of NOx from anthropic industrial processes requires reliable and sensitive monitoring systems. To address this challenge, we report a sensitive, robust, and compact quantum cascade laser (QCL)-based sensor to measure NO and NO2 emissions from industrial exhausts. This sensor uses two quantum cascade lasers, which take advantage of the intense absorption spectra of NO at 1929 cm−1 and NO2 at 1599 cm−1. A high-temperature multipass cell is designed to withstand harsh environments, which increases the light path length. The NOx concentrations are directly determined from the wavelength modulation spectroscopic model without the need for calibration. We conducted several laboratory experiments to evaluate the sensor's performance, with a focus on accuracy, sensitivity and selectivity. In the end, we showcased the field deployment of our sensor by continuously measuring NOx concentrations in a 2.8-MW gas-fired industrial boiler.

Comprehensive pollutant emission prediction models from hydrogen-enriched methane combustion in a gas-fired boiler based on box-behnken design method

Hydrogen-enriched methane (HEM) combustion is an effective method for reducing the consumption of carbonaceous fuels. However, high adiabatic flame temperature of H2 can cause large NO emissions. To reduce the NO and CO2 emissions from HEM combustion, the Box-Behnken design (BBD) method combining response surface experimental design, analysis of variance, and multi-nonlinear regression models was adopted. The effects of the H2 doping ratio (XH2), preheated air temperature (Tair), excess air coefficient of burners arranged at the bottom (Ex,b), and their interactions on the NO, N2O, and CO2 emissions of a gas-fired boiler were investigated. According to the BBD method, the NO, N2O, and CO2 emissions prediction models with R2 exceeding 0.98 were proposed, respectively. The results showed that the increase of Tair had a positive effect on reducing NO emissions, as the NO exhausted from HEM combustion is mainly thermal NO. Compared with Tair and Ex,b, XH2 was the most significant factor affecting N2O and CO2 emissions, indicating that an increase in XH2 can significantly reduce greenhouse gas emissions. Additionally, the formation and consumption of N2O emissions presented a competitive mechanism at XH2 increased from 0 to 0.8, and CO2 emissions reduced with the increase of XH2, Tair, and Ex,b. Furthermore, a comprehensive emission prediction model with NO, N2O, and CO2 emissions was proposed. With the target of minimizing total NO, N2O and CO2 emissions, three groups of combinations for XH2, Tair, and Ex,b were obtained from the equal weight, entropy weight method, and criteria importance through the inter-criteria correlation method as 1:1:1, 24:9:17, and 21:11:18. The results showed that for minimize emissions, there is not much difference in the results calculated based on the optimal boundary conditions under different weights. For various reduction targets for nitrogen, carbon, and greenhouse gases, three groups of optimal combinations of XH2, Tair, and Ex,b were obtained and their accuracies were verified based on numerical calculations with relative errors below 6%. The proposed comprehensive pollutant emission prediction models are conducive to calculating the pollutant emissions of HEM combustion and guiding the investigation of prediction models considering other operating conditions.

Numerical Simulation and Field Experimental Study of Combustion Characteristics of Hydrogen-Enriched Natural Gas

For the safe and efficient utilization of hydrogen-enriched natural gas combustion in industrial gas-fired boilers, the present study adopted a combination of numerical simulation and field tests to investigate its adaptability. Firstly, the combustion characteristics of hydrogen-enriched natural gas with different hydrogen blending ratios and equivalence ratios were evaluated by using the Chemkin Pro platform. Secondly, a field experimental study was carried out based on the WNS2-1.25-Q gas-fired boiler to investigate the boiler’s thermal efficiency, heat loss, and pollutant emissions after hydrogen addition. The results show that at the same equivalence ratio, with the hydrogen blending ratio increasing from 0% to 25%, the laminar flame propagation speed of the fuel increases, the extinction strain rate rises, and the combustion limit expands. The laminar flame propagation speed of premixed methane/air gas reaches the maximum value when the equivalence ratio is 1.0, and the combustion intensity of the flame is the highest at this time. In the field tests, as the hydrogen blending ratio increases from 0% to nearly 10% with the increasing excess air ratio, the boiler’s thermal efficiency decreases as well as the NOx emission. This indicates that there exists a tradeoff between the boiler thermal efficiency and NOx emission in practice.

Retrofitting Natural Gas–Fired Boiler for Hydrogen Combustion: Operational Performance and NOx Emissions

Abstract The effects of hydrogen fraction (HF: volumetric fraction of H2 in the fuel mixture of CH4 + H2) from 0% to 100% by volume, on the thermal and environmental performance of a 207-MW industrial water tube boiler, are investigated numerically at a fixed excess air factor, λ = 1.15. This study aims to determine the hardware modifications required for boilers to be retrofitted for pure hydrogen operation and investigates how NOx emissions are affected by hydrogen enrichment. The results showed insignificant increases in maximum combustion temperature with increasing the HF, though the distributions of temperature profiles are distinct. In reference to the basic methane combustion, H2 flames resulted in a positive temperature rise in the vicinity of the burner. Increasing the HF from 0% to 2% resulted in higher average thermal NOx emissions at the boiler exit section from 37 up to 1284 ppm, then it decreased to 1136 ppm at HF = 30%, and later it leveled up to 1474 ppm at HF = 100%. The spots for higher differences in NO formation compared to the reference case are shifted downstream at higher HFs. The effect of hydrogen enrichment on CO2 and H2O as radiation sources, as well as the volumetric absorption radiation of the furnace wall and the heat flux at furnace surfaces, has all been presented in relation to the effect of hydrogen addition on boiler performance.

Design and Performance Assessment of District Heating Systems in Latvian Region

The energy consumed by buildings for air conditioning accounts for a large percentage of global energy consumption. To promote efficiency and sustainability, the scientific community is making great efforts to develop renewable technologies. A well-known but unfortunately underestimated solution is the development of centralized heating and cooling systems that consistently reduce energy consumption.The work proposes a comparison between three heating configurations covering the demand of a settlement in the Latvian region: 1) centralized district heating (DH) system; 2) 5th generation district heating & cooling (5GDHC) system and 3) individual home heating (HH) systems. Thermal and electrical loads are evaluated by transient simulations of a residential area with 80 buildings for the Riga climate and compared with the same settlement in a Mediterranean region (Milan, IT). The energy plants are based on different technologies: combined heat and power (CHP) plants, gas-fired boilers, and domestic heat pumps.The analysis includes the option of power exchange with the national grid. A transient numerical model has been developed for each solution. Every component is modelled according to performance maps provided by the manufacturers, allowing an accurate simulation in both design and off-design operating conditions. The study includes energy, economic and environmental aspects.The result of the simulation highlights the large difference between the two locations, not only in terms of annual load, but also in terms of load distribution. On an annual basis, the Latvian residential complex requires almost twice as much energy as the Italian one. The thermal losses in the district systems are 4.21% in Milan solution and 5.65% in Riga. The district heating system coupled with heat pump represents the best layout in terms of primary energy consumption in both locations, with energy savings of 50% compared to other solutions. The use of 5GDHC is a good compromise that could increase the use of renewable energy. The adoption of cogeneration plant is a good choice in case of centralized district system that allows the installation of high efficiency genset. On the contrary, for small application as residential, the installation of cogeneration system results expensive and the conversion efficiency does not justify the installation.

Energy performance analysis of solar assisted gas-fired boiler heating system for floating roof oil tank

An innovative solar assisted gas-fired boiler heating system for floating roof oil tank is proposed to achieve the low carbonization of the conventional crude oil heating method. However, the dynamic energy transport performance of the proposed heating system affected by the key engineering parameters (crude oil capacity load, mass flow rate of heat transfer fluid (HTF), crude oil initial temperature) is unclear, which hinders the engineering application of this technology. In this regard, a simulation platform for solar assisted gas-fired boiler heating system for floating roof oil tank is established, and the above mentioned engineering parameters are investigated. The results show that under the condition of combined heating of evacuated tube solar collector (ETSC), phase change heat storage tank (PCHT), and auxiliary heat source (AHS), the system can achieve stable operation by means of controllers. With the increase of crude oil capacity load, the time for the crude oil to reach its design temperature is delayed, and up to 84.21% time lag is recorded. Apart from the contribution of AHS, the maximum annual heat supply of 43.37% is provided by PCHT and ETSC, presenting good energy-saving potential. Increasing HTF mass flow rate and crude oil initial temperature is a good strategy to reduce the output of AHS, in which the annual heat supply proportion of AHS decreases by 2.25% and 2.05%, respectively. The operating stability of proposed system is enhanced under the condition of higher HTF mass flow rate, compared to the 3.5 kg/s HTF mass flow rate, the safe reserve time increases by 31.44% for 7 kg/s and 34.24% for 14 kg/s HTF mass flow rate, respectively.

Thermodynamic and emission characteristics of a hydrogen-enriched natural gas-fired boiler integrated with external flue gas recirculation and waste heat recovery

Hydrogen-enriched natural gas (HENG) is a low-carbon fuel and its utilization in combustion devices has been under extensive discussion recently as it is a promising way to reduce the CO2 emission during combustion. The applicability of HENG in the existing natural gas-fired combustion equipment in terms of its efficiency and emissions attracts increasing attention, especially for industrial and domestic small-scale boilers. In this study, the thermal efficiency and pollutant emissions of a 4.2 MWth HENG-fired boiler integrated with external flue gas recirculation (FGR) were respectively evaluated based on the thermodynamic and heat transfer models and the Chemical Reaction Network model. Results suggested that NOx emission rose by ∼19% as the hydrogen volumetric fraction in the fuel increased from 0 to 0.4 at a constant excess air ratio and FGR rate. To suppress the NOx rise, the FGR rate was tuned higher while the system thermal efficiency decreased subsequently. To further improve the overall system thermal efficiency, a cascade flue gas waste heat recovery strategy including sensible heat recovery using an external economizer and latent heat recovery using dual-spray heat exchangers was proposed. The thermodynamic analysis demonstrated that the external economizer improved the overall system thermal efficiency by 0.4% - 0.7% and the dual-spray heat exchangers promoted the overall system thermal efficiency by over 5%. Thus, a comprehensive performance optimization strategy was developed for HENG-fired boilers in terms of their overall system thermal efficiency promotion, NOx emission control, and CO2 emission reduction.

Design and Performance Comparison of District Heating Systems in Milan and Riga

Abstract The work proposes a comparison between three heating configurations covering the demand of a new settlement: 1) centralized district heating system (DHC); 2) 5th generation district heating & cooling system (5GDHC) and 3) individual home heating and cooling (HHC) systems. Thermal and electrical loads are evaluated by transient simulations of a residential area with 80 buildings. The energy plants are based on different technologies: combined heat and power plants, gas-fired boilers, and domestic heat pumps. A transient numerical model has been developed for each solution. Every component is modelled according to performance maps provided by the manufacturers, allowing an accurate simulation in both design and off-design operating conditions. On an annual basis, the Latvian residential complex requires almost twice as much energy as the Milan one. The thermal losses in the district systems are 4.21 % in the Milan solution and 5.65 % in Riga. The district heating system coupled with a heat pump represents the best layout in terms of primary energy consumption in both locations, with energy savings of 50 % compared to other solutions. The use of 5GDHC is a good compromise that could increase the use of renewable energy. The adoption of a cogeneration plant is a good choice in the case of a centralized district system that allows the installation of high-efficiency genset. On the contrary, for small applications such as residential, the cogeneration results are expensive, and the conversion efficiency does not justify the installation.

Cost details from front-end engineering design of piperazine with the advanced stripper

This Front-End Engineering Design (FEED) was funded by the U.S. Department of Energy (DOE) to estimate the cost to capture and compress 90 % of the CO2 from an existing natural gas combined cycle (NGCC) in Denver City, Texas, USA. The FEED used the PZAS (Piperazine with the Advanced Stripper) 2 G amine scrubbing technology developed and modeled by The University of Texas at Austin. This FEED is unique in providing more public cost details than other FEEDs funded by DOE. The primary objective of the FEED was to provide a comprehensive estimate for the total installed cost of the capture plant. The estimated capital cost of NGCC at the Mustang Station is $727 million for a capacity of 460 MW and 1.6 million tonnes CO2/yr. This includes a contingency of $104.6 million and a contractor's profit of $60.1 million. The total direct field cost is $384.1 million. With an optimistic fuel value of $3/MMBtu, the estimated cost of capture varies from $85/t at 4 % IRR/85 % load to $170/t at 10 % IRR/52 % load. Air cooling is technically feasible but expensive. The air cooling systems for the water wash and pump-around intercooling account for 23.4 % of the direct cost. The gas-fired boilers represent only 4 % of the direct costs, but steam extraction would reduce energy cost, free up cooling water, and reduce the direct costs of processing additional flue gas and CO2 from the boilers. The absorbers represent 9.6 % of the direct cost in this FEED with no direct contact cooler and only 7.6 m of packing. The solvent cross exchangers are less expensive than expected (2.5 % of direct costs). Doubling the number of these exchangers could reduce the heat duty from 3.0 to 2.5 GJ/t CO2.

Problems of operating heating boilers of increased environmental efficiency

Purpose. Ensuring reliable operation of heating heat-generating devices with recirculation and exhaust gas heat recovery. Methodology. The normative methods of thermal calculation for surface heat exchange devices and the software according to the requirements of regulatory methods for this type of equipment for processing the results of our own experimental studies on heat exchange during deep cooling of combustion products of gas-consuming boilers were used. Findings. Calculation studies on the thermal operation modes during the heating period under the conditions of recirculation and heat recovery of flue gases of gas-fired water-heating boiler plants not equipped with air heaters were carried out. The main characteristics were determined of the thermal and humidity operation state for the air-supply ducts of these installations under the conditions of recirculation of flue gases’ part into the blown air. Regularities of temperature and dew point changes in the mixture of admixed gases and air under the conditions of using traditional heat recovery technologies and without them in different boiler modes and with different parts of recirculated gases were established. Problems of ensuring the operability and reliability of such boiler plants are highlighted. It is shown that these problems are related to condensate formation on the internal surfaces of air ducts and their freezing in some operating modes during in the cold period of the heating season. It is also shown that an effective solution to existing problems can be the use of air heaters in heat recovery systems to preheat the blown air before its mixing with recirculation gases. Originality. For the first time, the thermal and humidity operation modes of the air-supply ducts of heating boiler plants with increased environmental efficiency, which is ensured by boiler exhaust gases recirculation into the blown air, have been investigated. Practical value. The obtained research results will be used in the design of systems of recirculation and heat recovery of heat-generating devices’ exhaust gases to improve their environmental and thermal efficiency.

Assessment of Commercially Available Hydrogen Supply Chains for Gas-Fired Boilers

Hydrogen energy is a clean and efficient secondary energy source, and hydrogen derived from renewable sources is regarded as the key to achieving a low-carbon clean energy supply. Currently, the hydrogen energy supply chain is still in its development stage and requires a comprehensive comparative analysis of various hydrogen production technologies as well as storage and transportation methods to ensure the optimal application route for hydrogen energy. In this study, GaBi 10 software is used to conduct a comparative and evaluative analysis of the potential environmental impact associated with hydrogen energy application. The life cycle assessment encompasses all stages of the hydrogen supply chain, including production, transportation and utilization. The results indicate that hydrogen production from wind power has the lowest global warming potential (GWP), acidification potential (AP), eutrophication potential (EP) and photochemical ozone creation potential (POCP). Due to the high energy consumption of the liquefaction process, liquid hydrogen transportation is currently associated with the largest carbon emissions among all modes of hydrogen transport. However, if renewable energy sources are utilized to power hydrogen liquefaction, significant reductions in carbon emissions can be achieved. An evaluation of the carbon footprint associated with the completed hydrogen supply chain indicates that hydrogen produced from renewable sources is cost-effective for use in gas-fired boilers from an environmental perspective.

Numerical study on oxy-fuel combustion characteristics of industrial furnace firing coking dry gas

One of the most promising methods for clean utilization of hydrocarbon fuels and CO2 capture is oxy-fuel combustion. However, report on oxy-fuel burning of industrial gas is still limited. In the study, numerical simulation was conducted to explore the oxy-fuel combustion performance of a coking dry gas fired industrial furnace. A modified weighted sum gray gas (WSGG) model with a four-gray body and fourth-degree temperature polynomial was proposed for both air and oxy-fuel combustion with the introduction of the fourth graybody. The impacts of oxygen content, excess oxygen ratio, oxygen purity, and dehydration efficiency on combustion and heat transfer were mainly investigated. The maximum furnace temperature increases significantly, and the high temperature region inside the furnace shrinks and moves downward as the oxygen content rises. The H2O content increases from ∼20% to ∼37%, and the CO2 content decreases from ∼77% to ∼60%. The furnace temperature is up to 1835 K under air conditions, while the furnace temperature is reduced by 195 K under oxy-fuel condition of 21% O2 content. The composition of flue gas barely changes as the excess oxygen ratio increases from 1.02 to 1.20. Although the CO2 enrichment in flue gas and the improvement of oxy-fuel combustion performance benefit from an increase in oxygen purity, the combustion performance further advances little when it is raised to over 98%. Additionally, when dehydration efficiency grows, radiant heat transfer decreases and the flue gas temperature at the furnace outlet rises. The content of O2 and N2 has little relationship with dehydration efficiency. This study aids in understanding the actual oxy-fuel combustion process of an industrial gas-fired boiler and offers a possible theoretical basis for clean burning of petrochemical combustible gas and carbon capture.

Effect of hydrogen-enriched natural gas on flue gas waste heat recovery potential and condensing heat exchanger performance

Hydrogen-enriched natural gas (HENG) is one of the significant ways to store, transport, and utilize hydrogen energy. This paper presents the characteristics of HENG and flue gas, energy saving, carbon reduction, and condensate recovery potential of flue gas waste heat. Based on the theoretical and experimental study of the existing flue gas condensing heat exchanger (FGCHE) added at the rail of gas-fired boiler, the performance of the FGCHE under different hydrogen blending ratios is studied. The results show that augmenting the hydrogen blending ratio decreases the volume heating value of HENG, and CO2 content of flue gas. Meanwhile, the mass heating value of the HENG, the water vapor content, and dew point temperature of flue gas increase as the hydrogen blending ratio increases. The flue gas waste heat recovery utilization ratio and energy-saving efficiency of the FGCHE can be promoted. Moreover, the heat transfer capacity of the FGCHE using HENG is enhanced, while the flue gas flow pressure drop is reduced. Compared with the FGCHE used in pure natural gas systems, the all-hydrogen system increases the flue gas waste heat recovery amount by 62.4–120.4 %, reduces the flue gas flow pressure drop by 33.9 %, and reduces the carbon emission by 100 %.

Enabling residential heating decarbonization through hydronic low-temperature thermal distribution using forced-air assistive devices

Space heating represents approximately one-tenth of the United States’ energy use and has a breadth of potential for emission reduction. An element of space heating, hydronic heat distribution methods, use water supply temperatures up to 82.2 °C (180 °F). However, this operating temperature can be incompatible with high-efficiency heat generation systems, which typically provide heating temperatures of up to 60 °C (140 °F). In this work, a low-cost retrofit solution is developed using experimentally validated computational tools by incorporating an airflow distributor that preferentially directs the airflow from a fan to enhance heat transfer over the finned-tube heat exchanger found in conventional baseboards. The same heat output of traditional baseboard heat distribution systems operating at higher water supply temperatures (71.1 – 82.2 °C) can also be achieved at lower temperatures (≤ 60 °C). Specifically, results indicate that the technology can produce more than a 46.7% improvement in the heat transfer output at temperatures as low as 60 °C (140 °F), effectively matching the same output range achieved by 71.1 – 82.2 °C (160–180 °F) water supply temperatures. An important benefit of this solution is that it utilizes the existing infrastructure as opposed to requiring the replacement of the entire distribution system. Additionally, this technology enables existing building infrastructure to be coupled with newer, high-efficiency heating systems such as condensing boilers, solar-thermal systems, and geothermal/air-to-water heat pumps that may produce lower water supply temperatures (60 °C). A geospatially resolved techno-economic and environmental analysis is completed and presented to further understand the equivalent carbon footprint of enabling higher efficiency heat generation systems with the improved efficiency heat distribution system disclosed. Using 2021 grid-average emission factors, an emission reduction of up to a 67.5% decrease (2658 kgCO2/yr) for a single-family home, depending on state and climate region, could be realized by replacing a traditional natural gas-fired boiler with an air-to-water heat pump coupled to the same high-temperature heat distribution system along with the low-cost retrofit solution. A complete CO2 emission reduction of 6688 kgCO2/yr, depending on state and climate region, could be realized if all electricity is further renewably sourced. Thus, this study provides a possible pathway towards enabling the reduction of operational emissions in space heating.

A simplified mechanism of hydrogen addition to methane combustion for the pollutant emission characteristics of a gas-fired boiler

The reaction mechanism of hydrogen-enriched methane (HEM) combustion is significant in the combustion process. In this study, four widely used reaction mechanisms for methane combustion are simplified to investigate the pollutant emission characteristics of a gas-fired boiler used for HEM combustion. The laminar burn velocity (LBV) and ignition delay time (IDT) of the four detailed and four simplified mechanisms are compared, and the simplified San Diego mechanism is identified as the optimal mechanism using relative error and population standard deviation analysis. The temperatures and key components of the simplified San Diego mechanism are also compared with those of the detailed San Diego mechanism under various XH2. Based on the simplified San Diego mechanism, a chemical reactor network model for gas-fired boilers is further established to investigate the pollutant emissions of HEM combustion, in which the hydrogen doping ratio XH2 ranged from 0 to 80% and the inlet air and fuel temperature Tin ranged from 300 K to 600 K. Results showed that at Tin = 300 K with XH2 ranging from 0 to 80%, the mole fraction of NO increase by 1.94 times because of the increase in peak flame temperature; moreover, the mole fractions of N2O, CO, and CO2 decrease by approximately 25%, 50%, and 52%, respectively. With XH2 ranging from 0 to 40% and Tin ≥ 500 K, the mole fraction of NO decreases because the reduction reaction of NO + H = N + OH is promoted, whereas when XH2 is further increased to 80%, the increased H promotes the increase in NO again. CO emissions decreased as XH2 increased from 0 to 80%, whereas they increased by approximately 1.3 times as Tin increased from 300 K to 600 K because of the CO2 decomposition. N2O emissions decreased by more than 25% as XH2 increased from 0 to 80%. Additionally, CO2 emissions decrease by 52% with an increase in XH2 and by only 5% with an increase in Tin, indicating that XH2 has a larger impact on CO2 emissions. The proposed optimal HEM combustion mechanism is conducive to improving the efficiency of numerical calculations.