The Astrakhan gas-condensate deposit has high concentrations of hydrogen sulfide, the origin of which is of not only theoretical but practical importance, since it has a considerable effect on the reliability of forecasting the presence of high-sulfur gases, not only in the Caspian region but in other parts of the country. Two views have been expressed on the origin of the H/sub 2/S. According to one, it is a product of biogenic-abiogenic sulfate reduction by hydrocarbons. According to the second H/sub 2/S forms by two processes: abiogenic sulfate reduction by hydrocarbons and reaction of hydrocarbons with elemental sulfur, although it is considered that the first is more likely. The author presents an interesting case for the involvement of native sulfur, completely consumed far in the geologic past, in the formation of sour gases in the Astrakhan deposit. Disruption of the oil pools in the dome in the pre-Sakmarian period was accompanied by the formation of fairly extensive zones of sulfur mineralization, which were sufficient subsequently to produce gases with high H/sub 2/S concentrations, such as are now observed. In the later stages of the formation of the gas-condensate deposit, the migrating hydrocarbons dissolved the sulfur, which, because of the highmore » formation temperature, reacted with the hydrocarbon to give H/sub 2/S. The high temperatures and the carbonate reservoir rocks favored hydrocarbons reacting with the sulfur dissolved in the condensate phase, which gave H/sub 2/S and aromatic structures. H/sub 2/S is not being formed at the Astrakhan deposit at the present time because of the anomalously high formation pressures. 14 references.« less