Interstellar Clouds Research Articles

Sequential Reactions of Acetylene with the Benzonitrile Radical Cation: New Insights into Structures and Rate Coefficients of the Covalent Ion Products.

Benzonitrile radical cations generated in ionizing environments such as solar nebulae and interstellar clouds can react with neutral molecules such as acetylene to form a variety of nitrogen-containing complex organics. Herein, we present results from mass-selected ion mobility experiments and coupled-cluster and DFT calculations for the sequential reactions of acetylene with the benzonitrile radical cation (C7NH5+•). The results reveal the formation of two covalently bonded adduct ions C9NH7+• and C11NH9+• with individual rate coefficients of 2.1(±0.4) × 10-11 cm3 s-1 and 1.1(±0.9) × 10-11 cm3 s-1, respectively measured at 334.5 K. The direct addition of acetylene onto the N atom of the benzonitrile cation results in the formation of a N-acetylene-benzonitrile+• radical cation with a calculated collision cross-section of 67.5 Å2 in perfect agreement with the measured cross-section of 67.5 Å2 of the C9NH7+• adduct. The measured collision cross-section of the second covalent adduct C11NH9+• (72.2 Å2) is also in excellent agreement with the calculated cross-section (71.2 Å2) of the lowest energy isomer of the C11NH9+• ion corresponding to the 2-phenylpyridine structure. The formation of the bicyclic 2-phenylpyridine radical cation is explained by the rapid conversion of the classical radical cation C11NH9+• into a distonic ion structure that can efficiently cyclize in an exothermic transformation to form the 2-phenylpyridine radical cation. This intriguing mechanism could explain the formation of N-containing complex organics in different regions of outer space. The current results are expected to have direct implications for the search for nitrogen-containing complex organics in space.

Review the formation and characteristics of black holes – examining the properties of Sgr A* centered at Milky Way

The black hole is one of the important celestial bodies in the universe, and understanding its properties is important to help us understand universe and our homeland Milky way. My aims are to explore the properties of center black hole on Milky Way, Sagittarius A (Sgr A*). I first review the properties of black hole in the literature, including the formation of black hole, classification, and observations of black holes. Then, I examine the properties of Sgr A*, exploring its mass-calculation based on observation and properties as supermassive black hole. Through this study, I find that Sgr A* can form from gravitational collapse of a massive cloud of gas and dust, properties and observations like accretion disk, gravitational influence, and gravitational waves it has as a supermassive black hole, and its mass can be calculated from star orbit. In summary, studying the properties of Sgr A* is crucial to understanding our galaxy, and the fundamental nature of the universe.

Collisions Between Dark Matter Confined High Velocity Clouds and Magnetized Galactic Disks: The Smith Cloud. II.

We present high-resolution simulations of high velocity clouds (HVCs) colliding with the outer part of the Galactic disk. All of the simulations include a 3 × 108 M ⊙ dark matter subhalo. Three simulations model a dark matter subhalo without a gaseous component, while eight simulations model a dark matter subhalo accompanied by a gaseous cloud of mass 2–8 × 106 M ⊙. Half of the simulations include the coherent component of the Galaxy's magnetic field. Each simulation spans ∼40 million years before the collision and ∼40 million years after the collision. The collisions between the gas cloud and disk splash gas into the halo, punch half-kiloparsec-size holes in the disk, and form long-lived, multi-kiloparsec-size shells. Each shell encloses a bubble of relatively cool gas. Holes and shells of these scales would be observable, and some have been observed in the past. We determine the fate of the HVC gas, temperature, composition, and ionization state of the bubble and shell gas, size and longevity of the holes, and effects of cloud density. Simulations show that the clouds do not survive the chaos of passage through the disk, but instead become part of the splash, bubble, and shell. Some dark matter clouds may appear to carry material with them long after the collision, but this material is shell gas that was captured by the dark matter subhalo. These results have ramifications for the Smith Cloud and other clouds hypothesized to have hit the Galactic disk.

Filamentary Molecular Cloud Formation via Collision-induced Magnetic Reconnection in a Cold Neutral Medium

We have investigated the possibility of molecular cloud formation via the collision-induced magnetic reconnection (CMR) mechanism of the cold neutral medium (CNM). Two atomic gas clouds with conditions typical of the CNM were set to collide at the interface of reverse magnetic fields. The cloud–cloud collision triggered magnetic reconnection and produced a giant 20 pc filamentary structure that was not seen in the control models without CMR. The cloud, with rich fiber-like substructures, developed a fully molecular spine at 5 Myr. Radiative transfer modeling of dust emission at far-infrared wavelengths showed that the middle part of the filament contained dense cores over a span of 5 pc. Some of the cores were actively forming stars and typically exhibited both connecting fibers in dust emission and high-velocity gas in CO line emission, indicative of active accretion through streamers. Supersonic turbulence was present in and around the CMR filament due to inflowing gas moving at supersonic velocities in the collision midplane. The shocked gas was condensed and transported to the main filament piece by piece by reconnected fields, making the filament and star formation a bottom-up process. Instead of forming a gravitationally bounded cloud that then fragments hierarchically (top-down) and forms stars, the CMR process creates dense gas pieces and magnetically transports them to the central axis to constitute the filament. Since no turbulence is manually driven, our results suggest that CMR is capable of self-generating turbulence. Finally, the resulting helical field should show field reversal on both sides of the filament from most viewing angles.

The Distance to Dobashi 6193—A Dark Cloud Shadowing the eROSITA Bubbles

We focus on a prominent gas cloud, Dobashi 6193, toward the western base of the northern eROSITA bubble (eRObub). It can potentially put a tight distance constraint on the eRObubs and clarify the emissions of the Loop I superbubble from the eRObubs. We found its distance to be 700 pc based on Gaia DR3 stellar extinction and parallax measurements, making it one of the most distant clouds shadowing the eRObubs well above the Galactic disk.

Rotational excitation of methyl mercaptan (CH3SH) in collisions with molecular hydrogen

Abstract This paper presents the calculation of rate coefficients for transitions between rotational levels of the A-type and E-type levels of methyl mercaptan (CH3SH) resulting from collisions with molecular hydrogen. Radiative transfer modeling requires both radiative and collisional rates to describe the rotational populations under the usual conditions in interstellar clouds where LTE conditions do not apply. To compute the intermolecular interaction between CH3SH and H2, the explicitly correlated CCSD(T)-F12a coupled-cluster method which utilized a correlation-consistent aug-cc-pVTZ basis was employed. The computed energies were fit to a functional form suitable for use in scattering calculations. Rate coefficients were calculated over the temperature range from 5 to 100 K for transitions between the 110 lowest CH3SH rotational levels (having energies less than 107 cm−1 (ca. 150 K) within both the A-type and E-type manifolds caused by collisions with para- and ortho-H2. The rate coefficients were obtained through time-independent quantum close coupling quantum scattering calculations utilizing the calculated PES.

Hydrodynamic shielding in radiative multicloud outflows within multiphase galactic winds

Abstract Stellar-driven galactic winds regulate the mass and energy content of star-forming galaxies. Emission- and absorption-line spectroscopy shows that these outflows are multiphase and comprised of dense gas clouds embedded in much hotter winds. Explaining the presence of cold gas in such environments is a challenging endeavour that requires numerical modelling. In this paper we report a set of 3D hydrodynamical simulations of supersonic winds interacting with radiative and adiabatic multicloud systems, in which clouds are placed along a stream and separated by different distances. As a complement to previous adiabatic, subsonic studies, we demonstrate that hydrodynamic shielding is also triggered in supersonic winds and operates differently in adiabatic and radiative regimes. We find that the condensation of warm, mixed gas in between clouds facilitates hydrodynamic shielding by replenishing dense gas along the stream, provided that its cooling length is shorter than the cloud radius. Small separation distances between clouds also favour hydrodynamic shielding by reducing drag forces and the extent of the mixing region around the clouds. In contrast, large separation distances promote mixing and dense gas destruction via dynamical instabilities. The transition between shielding and no-shielding scenarios across different cloud separation distances is smooth in radiative supersonic models, as opposed to their adiabatic counterparts for which clouds need to be in close proximity. Overall, hydrodynamic shielding and re-condensation are effective mechanisms for preserving cold gas in multiphase flows for several cloud-crushing times, and thus can help understand cold gas survival in galactic winds.

SDSS J102915.14+172927.9: Revisiting the chemical pattern

The small- to intermediate-mass ($ M<0.8 M_ most metal-poor stars that formed in the infancy of the Universe are still shining today in the sky. They are very rare, but their discovery and investigation brings new knowledge on the formation of the first stellar generations. SDSS J102915.14+172927.9 is one of the most metal-poor star known to date. Since no carbon can be detected in its spectrum, a careful upper limit is important, both to classify this star and to distinguish it from the carbon-enhanced stars that represent the majority at these metallicities. We undertook a new observational campaign to acquire high-resolution UVES spectra. The new spectra were combined with archival spectra in order to increase the signal-to-noise ratio. From the combined spectrum, we derived abundances for seven elements (Mg, Si, Ca, Ti, Fe, Ni, and a tentative Li) and five significant upper limits (C, Na, Al, Sr, and Ba). The star has a carbon abundance $ A(C)<4.68$ and therefore is not enhanced in carbon, at variance with the majority of the stars at this Fe regime, which typically show $ A(C)>6.0$. A feature compatible with the Li doublet at 670.7\,nm is tentatively detected. The upper limit on carbon implies $ Z<1.915 $, more than 20 times lower than the most iron-poor star known. Therefore, the gas cloud out of which the star was formed did not cool via atomic lines but probably through dust. Fragmentation of the primordial cloud is another possibility for the formation of a star with a metallicity this low.

H2 Fluorescent Emission from the Diffuse Interstellar Medium

Near-IR spectroscopy, which can now be performed at unprecedented sensitivity with the NIRSpec instrument on JWST, can offer a novel probe of diffuse clouds through the observation of H2 fluorescent emissions. Whereas previous observations of interstellar H2 fluorescent emissions were primarily confined to dense clouds lying close to a source of UV radiation, JWST opens the possibility of detecting such emissions from diffuse molecular clouds exposed to the average radiation field in the Galaxy. A simple analytic model is presented to predict the near-IR H2 fluorescent line intensities emitted by diffuse interstellar clouds with a Plummer density profile. It is applicable to sightlines where the column densities of H and H2 have been measured and the peak gas density can be estimated.

Modelling of long gamma-ray burst host galaxies at cosmic noon from damped Lyman-α absorption statistics

ABSTRACT We study the properties of long gamma-ray burst (GRB) host galaxies using a statistical modelling framework derived to model damped Lyman-$\alpha$ absorbers (DLAs) in quasar spectra at high redshift. The distribution of $N_{\rm H\, {\small I}}$ for GRB-DLAs is $\sim$10 times higher than what is found for quasar-DLAs at similar impact parameters. We interpret this as a temporal selection effect due to the short-lived GRB progenitor probing its host at the onset of a starburst where the interstellar medium may exhibit multiple overdense regions. Owing to the larger $N_{\rm H\, {\small I}}$, the dust extinction is larger with 29 per cent of GRB-DLAs exhibiting $A(V)\gt 1$ mag in agreement with the fraction of ‘dark bursts’. Despite the differences in $N_{\rm H\, {\small I}}$ distributions, we find that high-redshift $2 \lt z \lt 3$ quasar- and GRB-DLAs trace the luminosity function of star-forming host galaxies in the same way. We propose that their differences may arise from the fact that the galaxies are sampled at different times in their star formation histories, and that the absorption sightlines probe the galaxy haloes differently. Quasar-DLAs sample the full H i cross-section, whereas GRB-DLAs sample only regions hosting cold neutral medium. Previous studies have found that GRBs avoid high-metallicity galaxies ($\sim$0.5 $Z_{\odot }$). Since at these redshifts galaxies on average have lower metallicities, our sample is only weakly sensitive to such a threshold. Lastly, we find that the modest detection rate of cold gas (H$_2$ or C i) in GRB spectra can be explained mainly by a low volume filling factor of cold gas clouds and to a lesser degree by destruction from the GRB explosion itself.

The SDSS-V Local Volume Mapper (LVM): Scientific Motivation and Project Overview

We present the Sloan Digital Sky Survey V Local Volume Mapper (LVM). The LVM is an integral-field spectroscopic survey of the Milky Way, Magellanic Clouds, and a sample of local volume galaxies, connecting resolved parsec-scale individual sources of feedback to kiloparsec-scale ionized interstellar medium (ISM) properties. The 4 yr survey covers the southern Milky Way disk at spatial resolutions of 0.05–1 pc, the Magellanic Clouds at 10 pc resolution, and nearby large galaxies at larger scales totaling >4300 deg2 of sky and more than 55M spectra. It utilizes a new facility of alt–alt mounted siderostats feeding 16 cm refractive telescopes, lenslet-coupled fiber optics, and spectrographs covering 3600–9800 Å at R ∼ 4000. The ultra-wide-field integral-field unit has a diameter of 0.°5 with 1801 hexagonally packed fibers of 35.″3 apertures. The siderostats allow for a completely stationary fiber system, avoiding instability of the line-spread function seen in traditional fiber feeds. Scientifically, LVM resolves the regions where energy, momentum, and chemical elements are injected into the ISM at the scale of gas clouds, while simultaneously charting where energy is being dissipated (via cooling, shocks, turbulence, bulk flows, etc.) to global scales. This combined local and global view enables us to constrain physical processes regulating how stellar feedback operates and couples to galactic kinematics and disk-scale structures, such as the bar and spiral arms, as well as gas in- and outflows.

Intramolecular Vibrational Energy Redistribution in the Reaction H3+ + CO → H2 + HCO.

An ab initio direct molecular dynamics (MD) calculation at the RS2/aug-cc-pVQZ level, followed by vibration mapping, has been applied to the H3+ + CO → H2 + HCO+ reaction to elucidate the intramolecular vibrational energy redistribution (IVR) processes during the reaction. Direct MD calculations were carried out for 20 K (a typical temperature for interstellar dark clouds) and 330 K (a typical translational temperature for ions in a glow discharge). Under the Cs symmetry constraint, the approach of H3+ turned out to be the H-C stretching mode of the [H···CO]+ part, which invoked the C-O stretching and then the H-C-O bending modes. Under no symmetry constraint, a strong bending mode was first invoked, and the intensities of the subsequent H-C and C-O stretching modes were kept relatively small. The detailed analyses of the IVR during the reaction, in terms of vibration mixing, gave a clue to understanding experimentally observed anomalies in the bending modes, such as population inversion at some bending states. In the MD simulation at 20 K, less than two-thirds of the reaction energy was converted to the vibrational energy of the resultant HCO+ part and one-third to the translational and rotational energies of the leaving H2 molecule. These direct MD simulations, when combined with the experimental spectroscopy data, shed light on a clear understanding of the reaction mechanism, including the IVR during the reaction.

Local H i absorption towards the magellanic cloud foreground using ASKAP

ABSTRACT We present the largest Galactic neutral hydrogen H i absorption survey to date, utilizing the Australian SKA Pathfinder Telescope at an unprecedented spatial resolution of 30 arcsec. This survey, GASKAP-H i, unbiasedly targets 2714 continuum background sources over 250 square degrees in the direction of the Magellanic Clouds, a significant increase compared to a total of 373 sources observed by previous Galactic absorption surveys across the entire Milky Way. We aim to investigate the physical properties of cold (CNM) and warm (WNM) neutral atomic gas in the Milky Way foreground, characterized by two prominent filaments at high Galactic latitudes (between $-45^{\circ }$ and $-25^{\circ }$). We detected strong H i absorption along 462 lines of sight above the 3$\sigma$ threshold, achieving an absorption detection rate of 17 per cent. GASKAP-H i’s unprecedented angular resolution allows for simultaneous absorption and emission measurements to sample almost the same gas clouds along a line of sight. A joint Gaussian decomposition is then applied to absorption-emission spectra to provide direct estimates of H i optical depths, temperatures, and column densities for the CNM and WNM components. The thermal properties of CNM components are consistent with those previously observed along a wide range of Solar neighbourhood environments, indicating that cold H i properties are widely prevalent throughout the local interstellar medium. Across our region of interest, CNM accounts for $\sim$30 per cent of the total H i gas, with the CNM fraction increasing with column density towards the two filaments. Our analysis reveals an anticorrelation between CNM temperature and its optical depth, which implies that CNM with lower optical depth leads to a higher temperature.

Nearby Supernova and Cloud Crossing Effects on the Orbits of Small Bodies in the Solar System

Supernova (SN) blasts envelop many surrounding stellar systems, transferring kinetic energy to small bodies in the systems. Geologic evidence from 60Fe points to recent nearby SN activity within the past several Myr. Here, we model the transfer of energy and resulting orbital changes from these SN blasts to the Oort Cloud, the Kuiper Belt, and Saturn’s Phoebe ring. For the Oort Cloud, an impulse approximation shows that a 50 pc SN can eject approximately half of all objects less than 1 cm while altering the trajectories of larger ones, depending on their orbital parameters. For stars closest to SNe, objects up to ∼100 m can be ejected. Turning to the explored solar system, we find that SNe closer than 50 pc may affect Saturn’s Phoebe ring and can sweep away Kuiper Belt dust. It is also possible that the passage of the solar system through a dense interstellar cloud could have a similar effect; a numerical trajectory simulation shows that the location of the dust grains and the direction of the wind (from an SN or interstellar cloud) has a significant impact on whether or not the grains will become unbound from their orbit in the Kuiper Belt. Overall, nearby SNe sweep micron-sized dust from the solar system, though whether the grains are ultimately cast toward the Sun or altogether ejected depends on various factors. Evidence of SN-modified dust grain trajectories may be observed by New Horizons, though further modeling efforts are required.

Characterization of Monosubstituted Benzene Ices

Aromatic structures are fundamental for key biological molecules such as RNA and metabolites and the abundances of aromatic molecules on young planets are therefore of high interest. Recent detections of benzonitrile and other aromatic compounds in interstellar clouds and comets have revealed a rich aromatic astrochemistry. In the cold phases of star and planet formation, most of these aromatic molecules are likely to reside in icy grain mantles, where they could be observed through IR spectroscopy. We present laboratory IR spectra of benzene and four monosubstituted benzene molecules—toluene, phenol, benzonitrile, and benzaldehyde—to determine their IR ice absorbances in undiluted aromatic ices, and in mixtures with water and CO. We also characterize the aromatic ice desorption rates, and extract binding energies and respective pre-exponential factors using temperature-programmed desorption experiments. We use these to predict at which protostellar and protoplanetary disk temperatures these molecules sublimate into the gas phase. We find that benzene and monosubstituted benzene derivatives are low-volatility with binding energies in the 5220–8390 K (43–70 kJ mol−1) range, which suggests that most of the chemistry of benzene and of functionalized aromatic molecules is to be expected to occur in the ice phase during star and planet formation.

Massive star cluster formation

Two main mechanisms have classically been proposed for the formation of runaway stars. In the binary supernova scenario (BSS), a massive star in a binary explodes as a supernova, ejecting its companion. In the dynamical ejection scenario, a star is ejected during a strong dynamical encounter between multiple stars. We propose a third mechanism for the formation of runaway stars: the subcluster ejection scenario (SCES), where a subset of stars from an infalling subcluster is ejected out of the cluster via a tidal interaction with the contracting gravitational potential of the assembling cluster. We demonstrate the SCES in a star-by-star simulation of the formation of a young massive cluster from a 106 M⊙ gas cloud using the TORCH framework. This star cluster forms hierarchically through a sequence of subcluster mergers determined by the initial turbulent, spherical conditions of the gas. We find that these mergers drive the formation of runaway stars in our model. Late-forming subclusters fall into the central potential, where they are tidally disrupted, forming tidal tails of runaway stars that are distributed highly anisotropically. Runaways formed in the same SCES have similar ages, velocities, and ejection directions. Surveying observations, we identify several SCES candidate groups with anisotropic ejection directions. The SCES is capable of producing runaway binaries: two wide dynamical binaries in infalling subclusters were tightened through ejection. This allows for another velocity kick via subsequent via a subsequent BSS ejection. An SCES-BSS ejection is a possible avenue for the creation of hypervelocity stars unbound to the Galaxy. The SCES occurs when subcluster formation is resolved. We expect nonspherical initial gas distributions to increase the number of calculated runaway stars, bringing it closer to observed values. The observation of groups of runaway stars formed via the SCES can thus reveal the assembly history of their natal clusters.

Massive star cluster formation

The mode of star formation that results in the formation of globular clusters and young massive clusters is difficult to constrain through observations. We present models of massive star cluster formation using the TORCH framework, which uses the Astrophysical MUltipurpose Software Environment (AMUSE) to couple distinct multi-physics codes that handle star formation, stellar evolution and dynamics, radiative transfer, and magnetohydrodynamics. We upgraded TORCH by implementing the N-body code PETAR, thereby enabling TORCH to handle massive clusters forming from 106 M⊙ clouds with ≥105 individual stars. We present results from TORCH simulations of star clusters forming from 104, 105, and 106 M⊙ turbulent spherical gas clouds (named M4, M5, M6) of radius R = 11.7 pc. We find that star formation is highly efficient and becomes more so at a higher cloud mass and surface density. For M4, M5, and M6 with initial surface densities 2.325 × 101,2,3 M⊙ pc−2, after a free-fall time of tff = 6.7,2.1,0.67 Myr, we find that ∼30%, 40%, and 60% of the cloud mass has formed into stars, respectively. The end of simulation-integrated star formation efficiencies for M4, M5, and M6 are ϵ⋆ = M⋆/Mcloud = 36%, 65%, and 85%. Observations of nearby clusters similar in mass and size to M4 have instantaneous star formation efficiencies of ϵinst ≤ 30%, which is slightly lower than the integrated star formation efficiency of M4. The M5 and M6 models represent a different regime of cluster formation that is more appropriate for the conditions in starburst galaxies and gas-rich galaxies at high redshift, and that leads to a significantly higher efficiency of star formation. We argue that young massive clusters build up through short efficient bursts of star formation in regions that are sufficiently dense (Σ ≥ 102 M⊙ pc−2) and massive (Mcloud ≥ 105 M⊙). In such environments, stellar feedback from winds and radiation is not strong enough to counteract the gravity from gas and stars until a majority of the gas has formed into stars.

Balmer Decrement Anomalies in Galaxies at z ∼ 6 Found by JWST Observations: Density-bounded Nebulae or Excited H i Clouds?

We investigate the physical origins of the Balmer decrement anomalies in GS-NDG-9422 and RXCJ2248-ID galaxies at z ∼ 6 whose Hα/Hβ values are significantly smaller than 2.7, the latter of which also shows anomalous Hγ/Hβ and Hδ/Hβ values beyond the errors. Because the anomalous Balmer decrements are not reproduced under the Case B recombination, we explore the nebulae with optical depths smaller and larger than the Case B recombination by physical modeling. We find two cases quantitatively explaining the anomalies: (1) density-bounded nebulae that are opaque only up to around Lyγ–Ly8 transitions and (2) ionization-bounded nebulae partly/fully surrounded by optically thick excited H i clouds. The case of (1) produces more Hβ photons via Lyγ absorption in the nebulae, requiring fine tuning in optical depth values, while this case helps ionizing photon escape for cosmic reionization. The case of (2) needs the optically thick excited Hi clouds with N 2 ≃ 1012−1013 cm−2, where N 2 is the column density of the hydrogen atom with the principal quantum number of n = 2. Interestingly, the high N 2 values qualitatively agree with the recent claims for GS-NDG-9422 with the strong nebular continuum requiring a number of 2s-state electrons and for RXCJ2248-ID with the dense ionized regions likely coexisting with the optically thick clouds. While the physical origin of the optically thick excited H i clouds is unclear, these results may suggest gas clouds with excessive collisional excitation caused by an amount of accretion and supernovae in the high-z galaxies.

Reevaluation of the Cosmic-Ray Ionization Rate in Diffuse Clouds

All current estimates of the cosmic-ray (CR) ionization rate rely on assessments of the gas density along the probed sight lines. Until now, these have been based on observations of different tracers, with C2 being the most widely used in diffuse molecular clouds for this purpose. However, dust extinction maps have recently reached sufficient accuracy to give an independent measurement of the gas density on parsec scales. In addition, they allow us to identify the gas clumps along each sight line, thus localizing the regions where CR ionization is probed. We reevaluate H3+ observations, which are often considered as the most reliable method to measure the H2 ionization rate ζH2 in diffuse clouds. The peak density values derived from the extinction maps for 12 analyzed sight lines turn out to be, on average, an order of magnitude lower than the previous estimates and agree with the values obtained from revised analysis of C2 data. We use the extinction maps in combination with the 3d-pdr code to self-consistently compute the H3+ and H2 abundances in the identified clumps for different values of ζH2 . For each sight line, we obtain the optimum value by comparing the simulation results with observations. We show that ζH2 is systematically reduced with respect to the earlier estimates by a factor of ≈9 on average, to ≈6 × 10−17 s−1, primarily as a result of the density reduction. We emphasize that these results have profound consequences for all available measurements of the ionization rate.

The Densities in Diffuse and Translucent Molecular Clouds: Estimates from Observations of C2 and from Three-dimensional Extinction Maps

Newly computed collisional rate coefficients for the excitation of C2 in collisions with H2, presented recently by Najar & Kalugina, are significantly larger than the values adopted previously in models for the excitation of the C2 molecule, a widely used probe of the interstellar gas density. With these new rate coefficients, we have modeled the C2 rotational distributions inferred from visible and ultraviolet absorption observations of electronic transitions of C2 toward a collection of 46 nearby background sources. The inferred gas densities in the foreground interstellar clouds responsible for the observed C2 absorption are a factor 4–7 smaller than those inferred previously, a direct reflection of the larger collisional rate coefficients computed by Najar & Kalugina. These lower-density estimates are generally in good agreement with the peak densities inferred from 3D extinction maps for the relevant sight lines. In cases where H3+ absorption has also been observed and used to estimate the cosmic-ray ionization rate (CRIR), our estimates of the latter will also decrease accordingly because the H3+ abundance is a function of the ratio of the CRIR to the gas density.