Mantle Garnet Research Articles

A rapid transition from subduction to Barrovian metamorphism: geochronology of mafic–ultramafic relicts of oceanic crust in the Central Alps, Switzerland

Relicts of subducted oceanic lithosphere provide key information for the tectonic reconstructions of convergent margins. In the Central Alps, such relicts occur as isolated mafic–ultramafic lenses within the migmatites of the southern Adula nappe and Cima-Lunga unit. Analysis of the major-, minor-, and accessory minerals of these ophiolitic relicts, combined with zircon and rutile U–Pb ages and zircon oxygen isotopes, allows the reconstruction of different stages of their complex evolution. The mafic–ultramafic suite in Valle di Moleno consists of chlorite-harzburgites associated with metarodingites and retrogressed eclogites. Relic omphacite and kyanite in retrogressed eclogites provide evidence for subduction-related metamorphism. Increasing XPrp in the garnet mantle towards the rim documents heating during high-pressure metamorphism up to 800–850 °C. Polyphase inclusions and chemical zoning in garnet suggest fluid-assisted melting during high-pressure metamorphism dated at 31.0 ± 0.9 Ma. In Val Cama, chlorite-harzburgites, metarodingites and calcsilicate-metasediments occur. Detrital zircon ages in the metasediment suggest a Mesozoic deposition. The metarodingite-metaperidotite-metasediment association and the low δ18O signatures of zircon (δ18O 3.0–3.7‰), inherited from seafloor metasomatism of the protoliths, show that the rocks are derived from former altered oceanic crust. Amphibolite facies metamorphism related to the Central Alps Barrovian evolution in Val Cama occurred at 28.8 ± 1.5 Ma. The combined data from Moleno and Cama indicate a rapid transition (~ 2 Ma) from subduction to collisional metamorphism with corresponding exhumation rates of 3–6 cm/year. Fast exhumation tectonics may have been favored by slab break-off or slab extraction. U–Pb dating of rutile from both localities yields ages of ~ 20 Ma, suggesting that these rocks remained at amphibolite-facies conditions for about 10 Ma and underwent a second fast exhumation of 3 cm/year associated with vertical movements along the Insubric line.

Transition from oceanic subduction to continental collision: Insights from volcanogenic-sedimentary rocks of the Tannuola terrane (northern Central Asian Orogenic Belt)

Magmatism associated with oceanic subduction plays a dominant role in crustal growth during the Earth’s evolution. The Tannuola terrane, situated in the northern Central Asian Orogenic Belt (CAOB), is a key area to understanding oceanic subduction and initial collision processes in the northern CAOB. In order to investigate the switch from subduction to collision settings, detailed field mapping, zircon SHRIMP U-Pb geochronological and whole-rock geochemical studies of volcanogenic-sedimentary rocks from the Tannuola terrane were carried out. Zircon U-Pb ages indicate multi-stage volcanism lasted at least 30 Ma from ∼540 to ∼510 Ma, that can be divided into three events: the late Ediacaran (before ∼540 Ma), the early Cambrian (∼520 Ma) and the middle Cambrian (∼510 Ma). These ages are interpreted to the initial, main and final stages of oceanic subduction during the late Proterozoic – early Paleozoic. During the late Ediacaran, tholeiitic basalts with high εNd(t) values (from +7.4 to +8.5) were emplaced. Likely forming by the 10 %–30 % partial melting of spinel – garnet mantle source during slab subduction. During the early Cambrian, transitional from tholeiitic to calc-alkaline basaltic rocks with εNd(t) value (+5.6) and coeval intermediate–felsic volcanic rocks with similar εNd(t) values (+5.9 and +6.5) formed. The early Cambrian basaltic rocks are interpreted to be derived by 10 %–30 % partial melting of a depleted mantle source metasomatized by slab-derived fluids released from the subducting oceanic slab. The middle Cambrian calc-alkaline basaltic rocks with εNd(t) value of +6.2 might be emplaced as a result of low (5 %–10 %) degree partial melting of a metasomatized mantle followed by fractional crystallization of clinopyroxene and plagioclase. Associated intermediate-felsic volcanic rocks with εNd(t) values from +6.0 to +6.8 were formed through fractionation of the juvenile Neoproterozoic sources. The middle Cambrian volcanism is interpreted to be triggered by the slab break-off during the transition to a collisional setting.

Ultrahigh-Pressure Metamorphism and P-T-t Paths for the Eclogites from the Central Areas of Sulu Orogen, Eastern China

Eclogites from the Guanshan and Yangkou areas of the Sulu orogen consist of garnet, omphacite, phengite, amphibole, quartz/coesite, rutile, and ilmenite. Garnet exhibits weak compositional zoning where Xgr decreases from the core to the mantle and then increases towards the rim, coupled with an increase in Xpy from the core to the mantle and then decrease towards the rim. Phase equilibria modelling with pseudosections calculated using THERMOCALC in the NCKFMASHTO system for the Guanshan and Yangkou eclogites records two stages of metamorphism: (I) prograde associated with quick subduction (Stage-I) and (II) retrograde associated with quick exhumation (Stage-II). Stage-I is recorded in the core-mantle zoning of garnet and Si content in phengite in the Guanshan and Yangkou eclogites with a mineral assemblage of Grt-Omp-Amp-Phg-Qtz-Rt ± Lws, and the P-T conditions are constrained at 22–26 kbar and 600–615 °C in Guanshan, while 24–26 kbar and 595–600 °C in Yangkou. The peak P-T conditions (Pmax = 33 kbar; T = 685 °C) of Guanshan eclogites are revealed by the maximum Si content in phengite and the minimum Xgr in the garnet mantle with the mineral assemblage of Grt-Omp-Phg-Coe-Rt ± Lws. The value of Pmax suggests that the subduction depth of the Guanshan eclogites exceeds 110 km. Stage-II is recorded in the mantle-rim zoning of garnet, and its P-T conditions are estimated to be 12–15 kbar and 780–820 °C for the Guanshan eclogites reflected by the assemblage of Grt-Omp-Amp-Pl-LL-Qtz-Rt ± ilm, and 13–14 kbar and 770–790 °C for the Yangkou eclogites by the assemblage of Grt-Omp-Amp-Pl-LL-Qtz-Rt. The two stages of metamorphism in the study areas are overall consistent with the regional metamorphic events, from ultra-high-pressure eclogite facies, through high pressure eclogite facies, to amphibole eclogite facies, with the ages of 245, 227 and 195 Ma, respectively.

High-pressure/ultrahigh-temperature mafic and felsic granulites associated with magnetite deposits from the Jiaobei terrane, Jiao-Liao-Ji Belt, North China Craton

Garnet-bearing mafic and felsic granulites associated with magnetite deposits that have undergone high-pressure (HP) and ultrahigh-temperature (UHT) metamorphism occur in the Yangjiazhai area of the Jiaobei terrane within the Jiao-Liao-Ji Belt, North China Craton. In mafic granulite, the early prograde assemblage (M1) is preserved as inclusions in the core of garnet. Matrix minerals and the garnet mantle define the peak metamorphic assemblage (M2). Near-isothermal decompression (M3) is recorded by the garnet rim and symplectitic minerals. The final cooling process is defined by the late growth of amphibole (M4). Abundant magnetite occurring in some mafic granulite samples may be inherited from the protolith. The felsic granulite records the peak metamorphic stage (M2) defined by the matrix minerals and the garnet mantle, and the retrograde stage defined by the symplectite and the garnet rim (M3). P-T estimations using pseudosection techniques and two-feldspar thermometry yield ∼8–9.8 kbar/710–828 °C for the prograde stage M1, ∼14.5–15 kbar/1040–1073 °C for the peak P-T stage M2, 9.1–10 kbar/965–1015 °C for the post-peak stage M3 and 6.6–9.4 kbar/820–853 °C for the cooling stage M4 as recorded by the mafic granulite. P-T conditions of ∼14–16.5 kbar/985–1077 °C for the peak P-T stage M2 and ∼7.8–9 kbar/889–902 °C for the post-peak stage M3 were derived from the felsic granulite. Thus a clockwise trajectory can be defined by constraining peak-metamorphic high-pressure/ultrahigh-temperature (HP-UHT) conditions. Zircon U-Pb dating and REE characteristics show a contrasting information. Oscillatory zoned zircon domains yield an age of ∼2150 Ma with a steep HREE characteristic, which is interpreted to indicate a magmatic origin of the mafic granulite. The peak HP-UHT stage obtained from metamorphic zircon domains in felsic and mafic granulites is constrained by an age of ∼1950–1900 Ma, which possibly corresponds to a collisional event shortly after subduction. The decompression occurred at ∼1880 Ma following the subsequent cooling at ∼1820 Ma indicating a rapid exhumation of the HP-UHT granulite followed by slow cooling.

P-T path from garnet zoning in pelitic schist from NE Sardinia, Italy: Further constraints on the metamorphic and tectonic evolution of the north Sardinia Variscan belt

Mylonitic micaschists in the south-eastern sector of the Posada-Asinara Shear Zone in the Axial Zone of the Sardinia Variscan chain were investigated for the reconstruction of their metamorphic evolution and P-T history. Micaschists underwent polyphase ductile deformation consisting of an old D1 deformation (~345–340 Ma) associated to shearing and folding and to a penetrative S1 axial plane foliation. The S1 foliation is progressively transposed by the D2 phase, which is associated with upright up to NE verging folds and dextral shear zones. Micaschists are characterized by abundant centimetric garnet crystals with strong compositional zoning. The garnet porphyroblasts (~15 vol%) are associated with plagioclase, quartz, biotite, staurolite, white mica, chloritoid and retrograde chlorite. Garnet presents an internal foliation identified by the isoorientation of quartz inclusions sometimes arranged into a sigmoidal pattern suggesting rotation of the garnet during growth, discordant respect to the external S2 foliation. The S2 foliation is identified by the preferred orientation of micas and chlorite and by the alternance between quartzo-feldspathic and micaceous layers. The garnet core contains several small inclusions of quartz, rutile, apatite, and minor monazite and zircon. Additional inclusions, observed in the garnet domain around the core are ilmenite, chloritoid, staurolite and white mica. EMPA analyses reveal an even more complex chemical zoning consisting of garnet core, garnet mantle, and rim. The compositional isopleths that match the composition of the garnet core intersect with isopleths for the highest Si contents in K-white mica at about T 430–490 °C, P 1.3–1.4 GPa. Garnet rim isopleths and isopleths for the lowest Si contents in K-white mica indicate P-T conditions close to 560–630 °C/0.6–1.1 GPa. The resulting P-T path is clockwise, subdivided into two separate stages. The first stage is a prograde segment suggested by the garnet core to mantle compositional variation whereas the second reflects garnet rim growth during exhumation. • Garnet crystals up to 1 cm are characterized by core, mantle, rim, and outer rim • Clockwise P-T path shows a prograde segment up to pressure peak (1.7GPa) • High – pressure conditions pre-date Barrovian metamorphism in Sardinia

“Hot” subduction initiation and the origin of the Yarlung-Tsangbo ophiolites, southern Tibet: New insights from ultrahigh temperature metamorphic soles

Metamorphic soles within ophiolite mélanges record key information on subduction initiation and evolution of paleo-oceans. Mafic granulite and amphibolite occur in metamorphic soles within the Saga and Bairang ophiolitic mélanges of the Yarlung Tsangbo suture zone, southern Tibet. In fresh mafic granulite, the early prograde assemblage (M1) is preserved as inclusions in the core of garnet. Minerals in matrix and garnet mantle define the peak metamorphic assemblage (M2). Near-isothermal decompression (M3) is recorded by the garnet rim and a symplectic corona. The mineral assemblage of the fresh amphibolite only records one major stage. Many samples were overprinted by strong metasomatism at sub-greenschist-facies conditions (M4). According to geochemical fingerprints, the soles originate from a mid-ocean-ridge environment with strong affinities to the non-metamorphic oceanic crust of the Yarlung Tsangbo ophiolites. P-T calculations of the granulites by pseudosection techniques, Zr-in-rutile and REE-based thermobarometry show ∼690-760°C/9.5-12.5 kbar for the prograde (M1) stage, 900-970°C/14-16 kbar for the peak (M2) stage followed by 902-983°C/9.5-12.6 kbar for the retrograde (M3) stage. From the amphibolite P-T conditions of <700-880°C/7-12.5 kbar were derived. This results in a clockwise trajectory with peak-high pressure to ultrahigh-temperature conditions characterizing a “hot” subduction environment. U-Pb dating of magmatic zircon yields ∼133-127 Ma as protolith ages of the soles, almost coeval with the igneous ages of the unmetamorphosed oceanic crust. U/Pb ages of metamorphic zircon show a similar range within uncertainties (∼131-119 Ma) indicating that initiation of subduction subsequently followed the protolith crystallisation. The metamorphic soles were subducted to a depth of 50 km triggering partial melting in the mantle wedge by dehydration reactions and formation of supra-subduction-zone magma. The mantle wedge became cooler and more buoyant when the subduction zone matured, which caused exhumation of the metamorphic soles and surrounding mantle rocks as well as cooling. A new model for a “hot” subduction initiation close to a mid-ocean ridge near the Asian margin is proposed based on the data from this study and previous studies. The relict mid-ocean-ridge basalts after subduction initiation and the subsequent supra-subduction-zone basalts formed the YTSZ ophiolites during ∼130-120 Ma.

Effects of Oxygen Fugacity on Hydroxyl Incorporation in Garnet at 1–3 GPa and 800–1000°C and Implications for Water Storage in the Mantle

AbstractGarnet, an important mineral component in Earth's interior, usually contains minor water as structural OH, but experimental data on OH incorporation in the mineral as a function of chemical and thermodynamic parameters remain rare. In particular, the role of oxygen fugacity (fO2) that is variable in the Earth has not been well assessed. We examine the effects of fO2 on the incorporation of OH at 1–3 GPa and 800–1000°C, by H‐annealing gem‐quality spessartine‐rich, grossular‐rich, and pyrope‐rich garnets. For each type of annealed garnet, the OH peak positions and spectral shapes are the same, suggesting the same OH incorporation mechanism(s). Under identical conditions, spessartine‐rich and grossular‐rich garnets are rich in OH, with solubility orders of magnitudes greater than for pyrope‐rich garnets. Over the studied conditions, the solubility of OH increases with pressure and temperature but decreases with fO2. The negative correlation of fO2 and OH solubility is probably due to the Fe3+ to Fe2+ reduction at more reduced conditions and the coupled OH incorporation in the structure. The effects of fO2 on OH solubility are more significant in Fe‐rich garnets. The ascertained small OH solubility in peridotite garnets, together with comparisons with relevant studies, suggest that mantle garnet is unlikely to be a major water carrier. In combination with literature‐reported positive correlation of fO2 and OH solubility in olivine, the partition coefficient of OH between garnet and olivine in the upper mantle is expected to be redox‐dependent.

Metamorphic evolution and Petrogenesis of garnet–corundum silica–undersaturated metapelitic granulites: A new case study from the Mianlüe Tectonic Zone of South Qinling, Central China

Newly identified garnet–corundum silica-undersaturated pelitic granulites in the Mianlüe Tectonic Zone of the South Qinling belt, central China, preserve a distinct mineral assemblage of garnet + corundum + biotite + plagioclase ± kyanite + sillimanite + staurolite and are therefore useful for deciphering the metamorphic evolution of the zone. Most of the garnet porphyroblasts preserve prominent major- and trace-element zoning, which provides evidence for two stages of garnet growth, under subsolidus conditions and then fluid-absent conditions, during prograde metamorphism. The distinctive yttrium annuli in garnet grains are most likely the result of the breakdown of xenotime. Four stages in the pressure–temperature (P–T) evolution of the granulites are inferred from the results of P–T pseudosection analysis together with petrographic observations. The first stage records the early prograde evolution, comprising isobaric heating at ~7 kbar from 580 to ~700 °C, and the later-stage prograde evolution with increasing pressure and temperature to the peak-pressure stage. The second stage is marked by the maximum XGrs in the garnet mantle, indicating the peak conditions in the high-P–high-T granulite facies of 830 °C at ~11.7 kbar. The third stage is characterized by a continued increase in pyrope in the garnet rim, suggesting decompression with slight heating from the peak pressure to reach the peak temperature at ~9.4 kbar and ~850 °C. The late retrograde cooling stage is represented by further decompression after the peak temperature, accompanied by the growth of staurolite. 7–13 mol% melt was produced during prograde metamorphism via the reaction sill + bi + pl → g + crn + melt. Although later melt loss reduced the bulk-rock Si and Al, the low-Si and high-Al–Fe bulk compositions of restite were inherited mainly from the protolith, which comprised high-Fe sediments (bauxites) derived from weathering of adjacent mafic rock. U–Pb dating of metamorphic zircon rims yielded two age clusters: ~227 Ma represents the timing close to peak-pressure conditions, and 222–217 Ma represents the timing of post-Tmax cooling to the solidus. Monazite U–Pb ages of 212–206 Ma are interpreted as the timing of further retrograde cooling under the solidus. The geochronological data and clockwise P–T paths indicate the garnet–corundum pelitic granulites record a complete metamorphic P–T–t history, including crustal thickening during continental collision/subduction and subsequent exhumation and cooling during the early Mesozoic. Combined with recent high-precision early Neoproterozoic data, we proposed that the MTZ was formed as a result of Grenvillian oceanic plate subduction and the assembly of Rodinia during the early Neoproterozoic and that it also records processes related to continental collision/subduction during the early Mesozoic.

Origin of Antecrysts in Igneous Rocks from the Salavat Range (NW Iran): an Explanation for the Geochemical Signature of Potassic Alkaline Rocks

AbstractAbundant silica-undersaturated potassic lavas are found in the centre of the Turkish–Iranian plateau (NW Iran) as flows, pillows and dykes. They display abundant zoned clinopyroxene macrocrysts and xenoliths of igneous cumulates. We determined four types of zoned crystals (Type-I, -II, -III and -IV) on the basis of their composition and zoning patterns. Use of in situ compositional data, together with whole-rock major and trace elements and the isotopic signatures of the host lavas provided evidence for the derivation of the different types of zoned clinopyroxenes from at least two contrasting parental melts. Our findings are consistent with an origin of the ultrapotassic and sodic alkaline melts from the deep-seated compaction pockets inferred from our previous studies of the alkaline magmatism throughout the Turkish–Iranian plateau. The ultrapotassic melt, which accumulated at the top of the compaction pockets, eventually ponded close to the spinel–garnet mantle transition and generated colourless antecrysts (Type-I and Type-II) and clinopyroxenite cumulates. When the compaction pocket impinged on the continental lithosphere, interstitial melts segregated and flowed inside dykes where grass green antecrysts (Type-III) and zoned phenocrysts (Type-IVa) crystallized from a melt having a geochemical signature of sodic alkaline melt. Later, at the crustal level, melt crystallization processes produced Type-IVb zoned phenocrysts. Our results are at odds with the paradigm of potassic magmas in NW Iran being derived strictly from a single mantle source.

Subcratonic and tectonic evolution of pyroxenite and eclogite with lamellar inclusions in garnet, Western Gneiss Region, Norway

Abstract Oriented lamellar inclusions of pyroxene and rutile in mantle garnet often serve as evidence for majoritic and titaniferous precursor garnets, respectively. We investigated ten new such microstructure-bearing samples from six orogenic peridotite bodies in SW Norway, which originated in the E Greenland mantle lithosphere, petrologically and thermobarometrically. All pyroxenite (nine) and eclogite (one) samples have large (mainly porphyroclastic) garnet containing silicate and oxide inclusions with shape-preferred orientation relationship. These inclusions vary—dependent on their size—systematically in shape (acicular to subprismatic), width (∼50 μm to submicron size), spacing (several 100 to ∼10 μm) and phase (pyroxene to Ti-oxide ± pyroxene). Smaller inclusions can fill the space between larger inclusions, which support the idea of consecutive generations. The larger, early formed lamellae occur least frequent and are most poorly preserved. A younger generation of other inclusions decorates healed cracks cutting across cores but not rims of garnet. These inclusions comprise oxides, silicates, carbonates (aragonite, calcite, magnesite) and fluid components (N2, CO2, H2O). The older, homogeneously distributed inclusions comply texturally and stoichiometrically with an origin by exsolution from excess Si- and Ti-bearing garnet. Their microstructural systematic variation demonstrates a similar early evolution of pyroxenite and eclogite. The younger inclusions in planar structures are ascribed to a metasomatic environment that affected the subcratonic lithosphere. The microstructure-bearing garnets equilibrated at ∼3.7 GPa (840 °C) and ∼3.0 GPa (710 °C), at a cratonic geotherm related to 37–38 mW m−2 surface heat flow. Some associated porphyroclastic grains of Mg-rich pyroxene have exsolution lamellae of Ca-rich pyroxene and vice versa that indicate a preceding cooling event. Projected isobaric cooling paths intersect isopleths for excess Si in garnet at ∼1550 °C, if an internally consistent thermodynamic data set in the system Na2O–CaO–MgO–Al2O3–SiO2 (NCMAS) is applied (or ∼1600 °C if using CMAS). This temperature may confine the crystallisation of the unexsolved garnets at 100–120 km depths of the E Greenland subcratonic lithosphere. Tectonism is indicated in coastal and hinterland samples by porphyroclastic orthopyroxene with Al2O3 concentrations showing W-shaped profiles. Cores of associated large (&amp;gt;200 μm) recrystallised grains have low Al2O3 contents (0.18–0.23 wt.%). Both characteristics typify relatively short intracrystalline Al diffusion lengths and a prograde metamorphism into the diamond stability field. We assign this event to subduction during the Scandian orogeny. Porphyroclastic orthopyroxene in other samples shows U-shaped Al2O3 concentration profiles paired with long Al diffusion lengths (several 100 μm) that exceed the radius of recrystallised grains. Their cores contain high Al2O3 contents (0.65–1.16 wt.%), consistent with a diffusional overprint that obliterated prograde and peak metamorphic records. Unlike Al2O3, the CaO content in porphyroclastic orthopyroxene cores is uniform suggesting that early exhumation was subparallel to Ca isopleths in pressure–temperature space. The depth of sample origin implies that rock bodies of Scandian ultra-high pressure metamorphism occur in nearly the entire area betweenNordfjord and Storfjord and from the coast towards ∼100 km in the hinterland, i.e. in a region much larger than anticipated from crustal eclogite.

Massive Fluid Influx beneath the Colorado Plateau (USA) Related to Slab Removal and Diatreme Emplacement: Evidence from Oxygen Isotope Zoning in Eclogite Xenoliths

Abstract The Colorado Plateau has undergone as much as 1·8 km of uplift over the past 80 Myr, but never underwent the pervasive deformation common in the neighboring tectonic provinces of the western USA. To understand the source, timing and distribution of mantle hydration, and its role in plateau uplift, garnets from four eclogite xenoliths of the Moses Rock diatreme (Navajo Volcanic Field, Utah, USA) were analyzed in situ for δ18O by secondary ion mass spectrometry. These garnets have the largest reported intra-crystalline oxygen isotope zoning to date in mantle-derived xenoliths with core-to-rim variations of as much as 3 ‰. All samples have core δ18O values greater than that of the pristine mantle (∼5·3 ‰, mantle garnet as derived from mantle zircon in earlier work) consistent with an altered upper oceanic crust protolith. Oxygen isotope ratios decrease from core to rim, recording interaction with a low-δ18O fluid at high temperature, probably derived from serpentinite in the foundering Farallon slab. All zoned samples converge at a δ18O value of ∼6 ‰, regardless of core composition, suggesting that fluid infiltration was widely distributed. Constraints on the timing of this fluid influx, relative to diatreme emplacement, can be gained from diffusion modeling of major element zoning in garnet. Modeling using best estimates of peak metamorphic conditions (620 °C, 3·7 GPa) yields durations of &amp;lt;200 kyr, suggesting that fluid influx and diatreme emplacement were temporally linked. These eclogite xenoliths from the Colorado Plateau record extensive fluid influx, pointing to complex hydration–dehydration processes related to flat-slab subduction and foundering of the Farallon plate. Extensive hydration of the lithospheric mantle during this fluid influx may have contributed to buoyancy-driven uplift of the Colorado Plateau and melt-free emplacement of Navajo Volcanic Field diatremes.

Micro‐Raman study of crichtonite group minerals enclosed into mantle garnet

AbstractWe report the first comprehensive micro‐Raman study of crichtonite group minerals (CGM) as inclusions in pyropic garnet grains from peridotite and pyroxenite mantle xenoliths of the Yakutian kimberlites as well as in garnet xenocrysts from the Aldan shield lamprophyres (Russia). The CGM form (i) morphologically oriented needles, lamellae, and short prisms and (ii) optically unoriented subhedral to euhedral grains, either single or intergrown with other minerals. We considered common mantle‐derived CGM species (like loveringite, lindsleyite, and their analogues), with Ca, Ba, or Sr dominating in the dodecahedral A site and Zr or Fe in the octahedral B site. The Raman bands at the region of 600–830 cm−1 are indicative of CGM and their crystal‐chemical distinction, although the intensity and shape of the bands appear to be dependent on laser beam power and wavelength. The factor‐group analysis based on the loveringite crystal structure showed the octahedral and tetrahedral cation groups with 18f and 6c Wyckoff positions, namely, dominantly TiO6 and to a lower extent CrO6, MgO4, and FeO4 groups, to be the major contributors to the Raman spectral features. The ionic groups with dodecahedral (M0) and octahedral (M1) coordination are inactive for Raman scattering while active in infrared absorption. A number of observed Raman modes in the CGM spectra are several times lower than that predicted by the factor group analysis. The noticed broadening of modes in the CGM Raman spectra may result from a combining of bands at the narrow frequency shift regions. Solid solution behavior, luminescence, and partial metamictization of the CGM may exert additional influence on the Raman band shape. The Raman spectral features showed CGM to be accurately identified and distinguished from other Ti‐, Fe‐, Cr‐, and Zr‐containing oxides (e.g., ilmenite or those of spinel and magnetoplumbite groups) occurring as accessory mantle minerals.

Clinopyroxene and Garnet Mantle Cargo in Kimberlites as Probes of Dharwar Craton Architecture and Geotherms, with Implications for Post-1·1 Ga Lithosphere Thinning Events Beneath Southern India

AbstractThe Wajrakarur Kimberlite Field (WKF) on the Eastern Dharwar Craton in southern India hosts several occurrences of Mesoproterozoic kimberlites, lamproites and ultramafic lamprophyres, for which mantle-derived xenoliths are rare and only poorly preserved. The general paucity of mantle cargo has hampered the investigation of the nature and evolution of the continental lithospheric mantle (CLM) beneath cratonic southern India. We present a comprehensive study of the major and trace element compositions of clinopyroxene and garnet xenocrysts recovered from heavy mineral concentrates for three c.1·1 Ga old WKF kimberlite pipes (P7, P9, P10), with the goal to improve our understanding of the cratonic mantle architecture and its evolution beneath southern India. The pressure-temperature conditions recorded by peridotitic clinopyroxene xenocrysts, estimated using single-pyroxene thermobarometry, suggest a relatively moderate cratonic mantle geotherm of 40 mW/m2 at 1·1 Ga. Reconstruction of the vertical distribution of clinopyroxene and garnet xenocrysts, combined with some rare mantle xenoliths data, reveals a compositionally layered CLM structure. Two main lithological horizons are identified and denoted as layer A (∼80–145 km depth) and layer B (∼160–190 km depth). Layer A is dominated by depleted lherzolite with subordinate amounts of pyroxenite, whereas layer B comprises mainly refertilised and Ti-metasomatized peridotite. Harzburgite occurs as a minor lithology in both layers. Eclogite stringers occur within the lower portion of layer A and at the bottom of layer B near the lithosphere–asthenosphere boundary at 1·1 Ga. Refertilisation of layer B is marked by garnet compositions with enrichment in Ca, Ti, Fe, Zr and LREE, although Y is depleted compared to garnet in layer A. Garnet trace element systematics such as Zr/Hf and Ti/Eu indicate that both kimberlitic and carbonatitic melts have interacted with and compositionally overprinted layer B. Progressive changes in the REE systematics of garnet grains with depth record an upward percolation of a continuously evolving metasomatic agent. The intervening zone between layers A and B at ∼145–160 km depth is characterized by a general paucity of garnet. This ‘garnet-paucity’ zone and an overlying type II clinopyroxene-bearing zone (∼115–145 km) appear to be rich in hydrous mineral assemblages of the MARID- or PIC kind. The composite horizon between ∼115–160 km depth may represent the product of intensive melt/rock interaction by which former garnet was largely reacted out and new metasomatic phases such as type II clinopyroxene and phlogopite plus amphibole were introduced. By analogy with better-studied cratons, this ‘metasomatic horizon’ may be a petrological manifestation of a former mid-lithospheric discontinuity at 1·1 Ga. Importantly, the depth interval of the present-day lithosphere–asthenosphere boundary beneath Peninsular India as detected in seismic surveys coincides with this heavily overprinted metasomatic horizon, which suggests that post-1·1 Ga delamination of cratonic mantle lithosphere progressed all the way to mid-lithospheric depth. This finding implies that strongly overprinted metasomatic layers, such as the ‘garnet-paucity’ zone beneath the Dharwar craton, present structural zones of weakness that aid lithosphere detachment and foundering in response to plate tectonic stresses.

Identification of growth mechanisms in metamorphic garnet by high-resolution trace element mapping with LA-ICP-TOFMS

Garnet is one of the most robust and ubiquitous minerals that record element zoning during crustal metamorphism. In addition to major elements, zoning in trace elements can provide a wealth of information to document the changing conditions of garnet growth and modification. However, mapping trace elements at low concentrations, over large areas and with high resolution has remained a major challenge. We present a comprehensive investigation of the TE distribution in garnet from three Alpine samples that underwent a complex evolution at different metamorphic conditions. The TE distribution in garnet grains is mapped in 2D in thin section with a novel approach using laser ablation inductively coupled plasma time of flight mass spectrometry (LA-ICP-TOFMS) to achieve a lateral resolution of 5 µm and limits of detection for the heavy rare earth elements (REE) down to 0.2 µg/g. Comparison with major element zoning measured by electron probe microanalysis and trace elements measured by conventional LA-ICPMS spot analysis testifies to the accuracy of the measurements. Garnet in an amphibolite-facies metapelite from Campolungo, Central Alps, that recorded metamorphism to 600 °C preserves Y + REE trace element zoning that closely matches that of Ca. In this sample, there is no notable diffusive modification for trace elements. Y + REE zoning is dominated by Rayleigh fractionation in the core and by the sporadic breakdown of accessory phases producing annuli in the rim of the garnet. A granulite-facies garnet from Malenco, Eastern Central Alps, formed during subsolidus heating, followed by peritectic melting reactions up to temperatures of 800–850 °C. Major and trace element zoning are decoupled indicating diffusional resetting of major elements, whereas trace elements still largely document the growth history. Enrichment of trace elements in the garnet mantle may be related to the consumption of biotite (V, Cr) and the dissolution of zircon (Zr) and monazite (Y + REE) in the melt. Diffusion of Y + HREE at the core–mantle boundary occurred over a length scale of ~ 200 µm. Garnet in an eclogite from the Sesia Zone, Western Alps (P ~ 2 GPa, T ~ 600 °C), displays pronounced fluid-related veinlets, visible in FeO, MgO and MnO, which cross-cut the primary growth zoning. Surprisingly, complex Y + REE and Cr zoning is not affected by the veinlets, indicating that they did not form by a crack-seal mechanism but are rather related to a selective replacement process. The trace element maps provide a detailed insight into the growth and modification of garnet and thus allow assessment of equilibrium versus disequilibrium processes, and assist in determination of P–T conditions, garnet dating, diffusion modelling as well as documenting fluid-induced modifications.

Late paleozoic to early mesozoic paleo-tethys tectonic evolution of central NE Tibetan Plateau: Insights from the Zhiduo mafic-ultramafic complex

Recent research has identified abundant Early Permian to Late Triassic ultramafic-mafic rocks along the west Jinsha to Garzê-Litang suture, central NE Tibetan Plateau. However, the petrogenesis and tectonic setting of these rocks are hotly debated. This paper presents a combination of zircon UPb ages, major and trace element concentrations, and SrNd isotopic data for mafic rocks from the Zhiduo Complex in the west Jinsha suture. Three geochemical subgroups are recognized among these rocks; metagabbros showing arc-type affinity (Group 1; 286–268 Ma); isotropic gabbros with an oceanic-island basalt-like signature (Group 2; 252 ± 2 Ma); and pillow/massive basalts (Group 3; ca. 235 Ma) having back-arc basin basalt affinity. Group 1 rocks exhibit moderate-high MgO (5.98–8.07 wt%) and Al2O3 (13.75–17.40 wt%) contents and are characterized by subduction-type trace element patterns and high initial 87Sr/86Sr ratios (0.71155–0.71261) and low εNd(t) values (−7.0 to −6.0), indicating that they originated from a spinel lithospheric mantle metasomatized by slab-derived fluids. Group 2 rocks have high contents of TiO2 (2.28–4.96 wt%), total Fe2O3 (11.67–14.80 wt%), Nb (18.3–22.8 ppm), and Ta (1.52–1.81 ppm) and more radiogenic Nd isotopes [εNd(t) = +0.3 to +0.9]. These data show that they were derived from a spinel + garnet mantle source enriched by plume-type components. Group 3 rocks possess high MgO (7.29–9.29 wt%), Cr (427–488 ppm), and Ni (215–238 ppm) contents but low Nb (5.00–5.60 ppm) and Ta (0.36–0.84 ppm), coupled with low Sr (initial 87Sr/86Sr = 0.70523–0.70567) and high Nd isotopes [εNd(t) = +3.1 to +3.5]. These values suggest that they were sourced from a garnet + spinel mantle affected by slight plume contamination. Combined with previous structural and geochemical studies, the ultramafic-mafic rocks of the Zhiduo Complex and arc magmatic rocks from nearby regions indicate an integrated Early Permian to Late Triassic oceanic basin–arc–back-arc system developed in the central NE Tibetan Plateau. Thus, the west Jinsha to Garzê-Litang represents a mature Paleo-Tethys Ocean rather than small back-arc basins. Southward subduction and associated back-arc spreading led to the genesis of widespread late Paleozoic to early Mesozoic magmatic rocks in the hinterland and along the northern margin of the North Qiangtang Block.

Granulites record the tectonic evolution from collisional thickening to extensional thinning of the Tongbai orogen in central China

AbstractA combined study of petrology and geochemistry was carried out for granulites from the Tongbai orogen in central China. The results reveal the tectonic evolution from collisional thickening to extensional thinning of the lithosphere at the convergent plate boundary. Petrographic observations, zircon U–Pb dating, and pseudosection calculations indicate that the granulites underwent four metamorphic stages, which are categorized into two cycles. The first cycle occurred at 490–450 Ma and involves high‐P (HP) metamorphism (M1) at 785–815°C and 10–14 kbar followed by decompressional heating to 840–880°C and 8–9 kbar for medium‐pressure granulite facies metamorphism (M2), defining a clockwise P–T path. The high pressure is indicated by the occurrence of inclusions of rutile+kyanite+K‐feldspar in the garnet mantle. The second cycle occurred at c. 440 Ma and shows an anticlockwise P–T path with continuous heating to ultrahigh‐temperature (UHT) metamorphism (M3) at 890–980°C and 9–11 kbar, followed by decompressional cooling to 740–880°C and 7–9 kbar (M4) till 405 Ma. The HP metamorphism is synchronous with the ultrahigh‐pressure eclogite facies metamorphism in the Qinling orogen, indicating its relevance to the continental collision in the Cambrian. The UHT metamorphism took place at reduced pressures, indicating thinning of the collision‐thickened orogenic lithosphere. Therefore, the Tongbai orogen was initially thickened by the collisional orogeny and then thinned, possibly as a result of foundering of the orogenic root. Such tectonic evolution may be common in collisional orogens where compression during continental collision switched to extension during continental rifting.

P–T–t Path of Garnetites in South Altyn Tagh, West China: A Complete Record of the Ultradeep Subduction and Exhumation of Continental Crust

AbstractWe report here a detailed investigation of mineral chemistry, phase modelling and geochronology for garnetites from the Bashiwake ultrahigh pressure (UHP) terrane, South Altyn Tagh, West China. Three generations of mineral assemblages including two stages of melting were identified. The first generation is represented by the zoning with decreasing grossular and increasing pyrope and multiphase inclusions in garnet core. It records an early‐stage prograde evolution from amphibolite facies to eclogite facies (1.7–2.5 GPa/710–850 °C) where the first stage of melting occurs. The second generation is characterized by the zoning in garnet mantle with increasing grossular and nearly constant pyrope, defining a later‐stage prograde evolution to UHP peak with the minimum condition of 6.5–7.0 GPa/990 °C. The pressure is consistent with that constrained from the pigeonite exsolution particularly along (401) planes in clinopyroxene. The third generation includes the presence of perthite, plagioclase along with amphibole, suggesting the decompression from eclogite facies to HP–ultrahigh‐temperature (UHT) granulite facies (~3.3–1.2 GPa/960–1020 °C) coupled with the second stage of melting. It is for the first time to get two metamorphic ages about 500 Ma and 486 Ma using in situ SIMS zircon dating which represent the prograde eclogite facies and decompressional granulite facies stages, suggesting the rocks staying at mantle depths for ~14 million years. The garnetites have recorded a complete metamorphic P–T–t history of continental ultradeep subduction to mantle depths of ~200 km or more followed by diapiring exhumation to the crust bottom.

Calculation of effective bulk composition and its application in metamorphic phase equilibria modeling

变质相平衡模拟是变质岩领域近几十年最重要的进展之一，它已经成为确定变质作用P-T-t轨迹和探索变质演化过程的有力工具。变质岩的矿物组合不但与其形成的温度（T）和压力（P）条件有关，而且受控于岩石的全岩成分（X）。但是变质岩通常是不均匀的并且往往保留两期以上的矿物组合，因此计算不同成分域或不同变质演化期次的有效全岩成分是模拟P-T视剖面图的核心问题之一。在中-低温变质岩中，石榴石变斑晶的生长会不断地将其核部成分冻结而不参与后续变质反应，这导致根据实测全岩成分计算的P-T视剖面图无法有效地模拟石榴石幔部或边部生长阶段的变质演化过程。瑞利分馏法和球体积法利用电子探针实测的石榴石成分环带可以模拟计算石榴石各个生长阶段所对应的有效全岩成分，本文推荐使用这两个方法来处理石榴石变斑晶的分馏效应问题。相比较而言，石榴石在高温变质岩中通常无法保留生长阶段的成分环带特征，这是因为石榴石成分在高温条件下会发生扩散再平衡，并同时与多数基质矿物达到热力学平衡，这时一般不需要考虑石榴石的分馏效应。但是高温变质岩通常会发生部分熔融并伴随熔体的迁移，进而改变岩石的有效全岩成分。因此，通过P-T视剖面图模拟熔体迁移前后的变质演化过程需要使用相平衡法计算迁移的熔体成分以及熔体迁移前后岩石的有效全岩成分。此外，后成合晶与反应边是变质岩中最常见的退变质反应结构，但是后成合晶或反应边中的矿物之间并未达到热力学平衡。这种情况需要结合岩相学观察和矿物成分，利用最小二乘法确定后成合晶或反应边中发生的平衡反应方程式，进而获取变质反应发生时的有效全岩成分并通过计算P-T视剖面图来估算退变质的温压条件。除此之外，岩石体系中三价铁（Fe₂O₃）和H₂O含量的估算一直以来都是相平衡模拟研究中的难点，本文推荐使用P/T-X（Fe³⁺/Fe^tot，MH₂O）视剖面图来确定这两个组分的含量，这是因为P/T-X图可以估算各个变质演化阶段或特定矿物组合的Fe₂O₃或H₂O含量。;Phase equilibria modeling is one of the most important advances in metamorphic petrology in recent decades,which has become a useful tool for determining the P-T-t paths and understanding the metamorphic evolution. The metamorphic mineral assemblages are not only determined by pressure (P) and temperature (T), but also controlled by the bulk-rock compositions (X). However, the metamorphic rocks are commonly heterogeneous and preserve two or more mineral assemblages. Thus, to perform P-T pseudosections, it is critical to calculate the effective bulk compositions of different compositional domains and/or mineral assemblages. In low-medium temperature metamorphic rocks,the growth of garnet porphyroblasts will continuously isolate the garnet core from the matrix. Thus, the P-T pseudosection calculated using the analyzed bulk-rock composition may not represent the metamorphic evolution related to the growth of garnet mantle or rim. Using the measured garnet zoning profiles, both Rayleigh fractionation and ball volume methods can be applied to calculate the effective bulk composition corresponding to each stage of garnet growth. Therefore, it is recommended to treat the garnet fractionation through these two methods. By contrast, garnet does not commonly show growth compositional zoning profile in high-temperature metamorphic rocks, because the garnet composition will suffer volume diffusion and re-equilibrated at high temperature conditions. This will lead to the thermodynamic equilibrium between garnet and matrix minerals. In this case, it is unnecessary to consider the garnet fractionation. However, high-temperature metamorphic rocks usually undergo partial melting and melt migration, which in turn changes the bulk-rock compositions. Therefore, to model the metamorphic evolutions before and/or after melt migration through the P-T pseudosection requires the phase equilibria method to calculate the migrated melt compositions and the effective bulk compositions before and/or after the melt migration. The symplectites and corona are the most common retrograde microstructures in metamorphic rocks, but the thermodynamic equilibrium has not been reached between the minerals in symplectites and corona. In this case, we suggest determining the equilibrium reaction equation that occurs in the symplectites and corona through the least square method combined with the petrographic observation and mineral compositions. Thus, the bulk composition of the reactants or products represents the effective bulk composition when the equilibrium reaction occurs. In addition,the estimation of ferric iron (Fe₂O₃) and H₂O content in bulk-rock composition is always critical to the phase equilibria modeling. It is suggested to apply the P/T-X (Fe³⁺/Fe^tot, MH₂O) pseudosections to determine the content of these two components. Because the P/T-X pseudosections are robust to estimate the Fe₂O₃ or H₂O content for any metamorphic evolution stage or mineral assemblage.

Multistage Metamorphic Evolution of Retrograded Eclogites from the Songshugou Complex, Qinling Orogenic Belt, China

Abstract The Qinling Orogenic Belt is one of the major collisional orogens in eastern Asia and marks the boundary between the North China Craton and South China Craton. The Songshugou complex is the largest basic to ultrabasic body to be found in the North Qinling Belt, and was emplaced as a lens-shaped body at the southern margin of the Qinling Group. A detailed petrological investigation of garnet amphibolite, augen amphibolite and well-foliated amphibolite together with garnet zoning patterns of major and trace elements, inclusions in garnet, and thermodynamic modelling indicate a multistage metamorphic history. Garnets clearly show characteristics of discontinuous growth, as they display optically light-colored snowball-textured cores surrounded by a darker mantle with few inclusions as well as chemically a sudden increase in grossular and decrease in almandine components. A partly resorbed rim is not recognized optically but mineral inclusions and a discontinuous chemical composition of garnet are proof of this third garnet growth stage. Rare earth element distribution patterns of garnet also show clear evidence for discontinuous growth and allow us to identify the reactions responsible for garnet growth. Garnet core compositions as well as amphibole inclusions allow us to constrain a P–T window where this rock equilibrated in a first stage. Calculated pseudosections and the application of the garnet–amphibole thermometer indicate an upper amphibolite- to lower granulite-facies metamorphic episode at 630–740 °C and 0·7–0·9 GPa. The presence of relict omphacite as well as a discontinuously grown garnet mantle with rutile inclusions clearly places the peak metamorphic stage in the eclogite facies. Garnet (XGrs, XAlm, XPrp) and omphacite isopleths (XMg, XNa) constrain this event at 1·7–2·1 GPa and 570–650 °C. Consistent temperatures of 500–650 °C were also determined by clinopyroxene–garnet geothermobarometry for this event. Growth of an outermost rim as well as different stages of garnet breakdown to plagioclase + amphibole coronae and the nearly complete replacement of former omphacite by a variety of symplectites point to an intricate retrograde P–T path. In more strongly retrograded samples plagioclase + amphibole ± quartz pseudomorphs entirely replace former garnet grains. Certain coronae around garnets and symplectites also contain prehnite and pumpellyite, which formed during a late retrograde stage or during a different event at very low P–T conditions (250–350 °C). Based on the detailed petrological study, we favour a multistage metamorphic history of the Songshugou metabasic rocks. The age of the eclogite-facies metamorphic event must be related to the deep subduction of the Songshugou complex during the early Paleozoic, although the age of garnet core growth remains enigmatic. The development of garnet cores indicates an upper amphibolite-facies regional metamorphic overprint succeeded by an eclogite-facies event around 500 Ma and subsequent retrogression seen in replacement of garnet and formation of symplectite. The latest imprint evidenced by prehnite and pumpellyite may be the result of fluid infiltration during the fading orogenic phase or represents a low-temperature overprint by a later process, probably related to the uplift of the North Qinling terrane at around 420 Ma.

Nixonite, Na2Ti6O13, a new mineral from a metasomatized mantle garnet pyroxenite from the western Rae Craton, Darby kimberlite field, Canada

Abstract Nixonite (IMA 2018-133), ideally Na2Ti6O13, is a new mineral found within a heavily metasomatized pyroxenite xenolith from the Darby kimberlite field, beneath the west-central Rae Craton, Canada. It occurs as microcrystalline aggregates, 15 to 40 μm in length. Nixonite is isostructural with jeppeite, K2Ti6O13, with a structure consisting of edge- and corner-shared titanium-centered octahedra that enclose alkali-metal ions. The Mohs hardness is estimated to be between 5 and 6 by comparison to jeppeite, and the calculated density is 3.51(1) g/cm3. Electron microprobe wavelength-dispersive spectroscopic analysis (average of 6 points) yielded: Na2O 6.87, K2O 5.67, CaO 0.57, TiO2 84.99, V2O3 0.31, Cr2O3 0.04, MnO 0.01, Fe2O3 0.26, SrO 0.07, total 98.79 wt%. The empirical formula, based on 13 O atoms, is: (Na1.24K0.67Ca0.06)Σ1.97(Ti5.96V0.023Fe0.018)Σ6.00O13 with minor amounts of Cr and Mn. Nixonite is monoclinic, space group C2/m, with unit-cell parameters a = 15.3632(26) Å, b = 3.7782(7) Å, c = 9.1266(15) Å, β = 99.35(15)°, and V = 522.72(1) Å3, Z = 2. Based on the average of seven integrated multi-grain diffraction images, the strongest diffraction lines are [dobs in Å (I in %) (hkl)]: 3.02 (100) (310), 3.66 (75) (110), 7.57 (73) (200), 6.31 (68) (201), 2.96 (63) (311), 2.96 (63) (203), and 2.71 (62) (402). The five main Raman peaks of nixonite, in order of decreasing intensity, are at 863, 280, 664, 135, and 113 cm–1. Nixonite is named after Peter H. Nixon, a renowned scientist in the field of kimberlites and mantle xenoliths. Nixonite occurs within a pyroxenite xenolith in a kimberlite, in association with rutile, priderite, perovskite, freudenbergite, and ilmenite. This complex Na-K-Ti-rich metasomatic mineral assemblage may have been produced by a fractionated Na-rich kimberlitic melt that infiltrated a mantle-derived garnet pyroxenite and reacted with rutile during kimberlite crystallization.