The Bundelkhand Craton (BKC), one of the Archaean nuclei in the north central part of the Indian shield, has a lesser surface exposure compared to other cratons. Recent magnetotelluric (MT) study in the Central Ganga Basin (CGB) showed NNE-SSW extension of the cratonic block as a transverse ridge and delineated a shear zone within the buried section of the BKC. In the present study, we extend the MT profile to further south with 19 broadband MT sites in the exposed BKC to complement the lithospheric electrical resistivity architecture. Two-dimensional (2-D) geoelectric structure down to 100 km is obtained from inverse modelling of the distortion corrected MT impedance tensors together with the 31 sites in the CGB. The resulting geoelectric model reveals a flat and sharp resistivity contrast at 40–42 km depth, the electrical Moho (e-Moho), separating highly resistive Bundelkhand massif and moderately conductive upper mantle. The 2-D model also brings out two shear zones represented by near-vertical moderately conductive zones within the massif, indicating zones of amalgamation of different fragments of the pre-Bundelkhand craton. In contrast to other major cratons of the Indian shield, the present MT study has delineated a moderately conductive upper mantle beneath the BKC. In view of the estimated low mantle heat flow along with relatively flat topography, we infer metasomatism of the mantle lithosphere by percolation of fluids. We hypothesize that infiltration of fraction of water (H2O) in nominally anhydrous mantle minerals as hydrogen (H) bonded to structural oxygen (O) originated from the subducted oceanic slab has altered the mantle rheology and metasomatized the lithosphere.