Gallons Of Biodiesel Research Articles

Organic waste derived biodiesel supply chain network: Deterministic multi-period planning model

In this study, a multi-period model of an organic waste-to-biodiesel phased supply chain network is developed to strategically consider variations in the biodiesel demand and the organic waste usage over a long-term planning interval. The proposed model can facilitate planning to determine the biorefinery location and the amount of biodiesel to produce, transport, or utilize to reduce the total cost of the organic waste-to-biodiesel supply chain network design while meeting the biodiesel demand during each period of the planning interval. The features and capabilities of the model are validated by application of a future organic waste-to-biodiesel supply chain network design in South Korea. The optimization results illustrate that the average total annual cost of the organic waste of biodiesel based on the multi-period model will be $US 4.2 billion per year during the period 2020–2030. The minimum selling prices for the optimal network design were determined ranged from $US 3.154–3.156/gallon of biodiesel containing 3% butanol derived from organic waste combined with diesel. A small portion (4.9–6.6%) of the total biodiesel demand was produced from organic waste because of low organic waste availability in the existing anaerobic digestion facilities, leading to increasing the outsourcing costs of butanol. The proposed approach will facilitate the strategic development of a sustainable supply chain network for organic waste recycling for material and energy valorization.

Economic perspective of ethanol and biodiesel coproduction from industrial hemp

In this study, the economics of producing biofuels from an industrial hemp (Cannabis sativa) genotype – 19m96136 was investigated. A lignocellulosic biofuel plant, hourly consuming 85 metric tons of hemp biomass was modeled in SuperPro Designer®. The integrated bioenergy plant produced hemp biodiesel and bioethanol from lipids and carbohydrates, respectively. The structural composition of the industrial hemp plant was analyzed in a previous study. The data obtained was used to simulate feedstock composition in SuperPro Designer®.The simulation results indicated that Hemp containing 2% lipids can yield up to 3.95 million gallons of biodiesel annually. On improving biomass lipid content to 5 and 10%, biodiesel production increased to 9.88 and 19.91 million gallons, respectively. The breakeven unit production cost of hemp biodiesel with 2, 5, and 10% lipid containing hemp was $18.49, $7.87, and $4.13/gallon, respectively. The biodiesel unit production cost when utilizing 10% lipid-containing hemp was comparable to soybean biodiesel at $4.13/gallon. Furthermore, sensitivity analysis revealed the possibility of a 7.80% reduction in unit production cost upon a 10% reduction in hemp feedstock cost. Furthermore, industrial hemp was capable of producing between 307.80 and 325.82 gallons of total biofuels per hectare of agricultural land than soybean.

Production of Biofuel Crops in Florida: Peanut

This document explores the production of peanuts (Arachis hypogaea) in Florida and their potential as a biofuel crop. Peanuts thrive in the sandy, infertile soils of the southeastern United States, particularly in Florida, where they cover approximately 170,000 acres annually. With a high oil content of 45-52%, peanuts can produce over 150 gallons of biodiesel per acre, making them a promising biofuel source. The crop's biology, production practices, potential yields, challenges, and environmental considerations are discussed. Peanuts' adaptability, established production practices, and the potential for breeding disease-resistant, low-input varieties position them as a competitive candidate in the biofuels market. This document was first time published in January 2008.

Waste cooking oil logistics and environmental assessment for biodiesel production in Cali

The present article analyzes different strategies for collecting Waste Cooking Oil (WCO) to produce biodiesel in Santiago de Cali. The quantitative and qualitative analysis of the models found in the literature highlighted the main characteristics for developing a WCO collection model considering the local parameters. Initial results showed that there is not enough WCO to satisfy the demand. However, an improved scenario is proposed following a supply point’s densification strategy. The improved scenario not only fulfills the plant’s installed capacity but also achieved WCO collection cost of 695.5 COP per gallon. 304 gallons of biodiesel could be produced with the collected WCO achieving a potential reduction of 230.81 kg of CO2 if this biodiesel is used to replace the same amount of diesel in the market, due to the difference between the CO2 emissions factor of diesel [kg CO2/diesel gal] and biodiesel [kg CO2/biodiesel gal].

The prevention of saltwater algal pond contamination using the electron transport chain disruptor, rotenone

Rotenone is a classic inhibitor of Complex I of the electron transport chain which is common to all life. Algae are known to be rotenone-insensitive because in addition to Complex I they have alternative pathways for the oxidation of NADH2. It is this differential sensitivity to rotenone that can be exploited to reduce many types of predators while not affecting biodiesel-producing algae. A universal tool like rotenone is needed to reduce predation in open ponds as predation is well known to limit cultivation to a few weeks in the warmer months. In this study, we tested the effect of rotenone on the mortality and reproduction of two marine algae strains, Nannochloropsis oculata and Tetraselmis suecica, and two marine rotifer strains, Brachionus manjavacas and Brachionus rotundiformis. The LC50s for the two rotifers ranged from 0.18 to 0.35μM while N. oculata was unaffected to at least 7.6μM. Rotifer reproduction was reduced at rotenone concentrations lower than those that caused mortality. Rotenone applications to produce 1 million gallons of biodiesel in one year are estimated to cost $1684. This provides algae farmers an important and inexpensive tool to manage grazing predators in algae mass cultures and avoid pond crashes.

The Use of the Schizonticidal Agent Quinine Sulfate to Prevent Pond Crashes for Algal-Biofuel Production.

Algal biofuels are investigated as a promising alternative to petroleum fuel sources to satisfy transportation demand. Despite the high growth rate of algae, predation by rotifers, ciliates, golden algae, and other predators will cause an algae in open ponds to crash. In this study, Chlorella kessleri was used as a model alga and the freshwater rotifer, Brachionus calyciflorus, as a model predator. The goal of this study was to test the selective toxicity of the chemical, quinine sulfate (QS), on both the alga and the rotifer in order to fully inhibit the rotifer while minimizing its impact on algal growth. The QS LC50 for B. calyciflorus was 17 µM while C. kessleri growth was not inhibited at concentrations <25 µM. In co-culture, complete inhibition of rotifers was observed when the QS concentration was 7.7 µM, while algal growth was not affected. QS applications to produce 1 million gallons of biodiesel in one year are estimated to be $0.04/gallon or ~1% of Bioenergy Technologies Office’s (BETO) projected cost of $5/gge (gallon gasoline equivalent). This provides algae farmers an important tool to manage grazing predators in algae mass cultures and avoid pond crashes.

Truck versus pipeline transportation cost analysis of wastewater sludge

Domestic and industrial sludge generated at wastewater treatment facilities is considered a potential biomass source for producing biodiesel. However, transportation of large amounts of sludge from wastewater treatment facilities to a biorefinery is expensive. The objective of this paper is to identify the proper transportation mode to use as a function of the volume shipped and transportation distances. Currently, sludge is mainly shipped by truck and pipeline. We estimated that the fixed and variable cost components of pipeline transportation for a volume such as 480m3/day and a distance of 100miles are $0.116/m3 and $0.089/m3/mile, respectively. We estimated the biomass (sludge) transportation cost per gallon of biodiesel, and observed the changes in these costs as a function of distance traveled and volume shipped. The outcomes of this study have the potential to help biofuel plants make better biomass transportation decisions, and consequently reduce the price of biodiesel significantly.

Improvement of Biodiesel Product Yield during Simple Consecutive-Competitive Reactions

Biodiesel is a renewable fuel that can be made from vegetable oil and waste restaurant greases by catalysed transesterification reactions. Over 5 billion gallons of biodiesel was produced in 2010. The European Union and United States are seeing the sigmoidal portion of the growth curve in biodiesel production. Economic analysis such as profitability and annualized worth (AW) of a biodiesel plant in Taiwan is presented. With the revenue from glycerine byproduct recovery and with lower raw material costs, biodiesel may be profitable especially during days of higher gasoline prices. Multiple reactions of the consecutive-competive type may be used to model the methonolysis of trigylcerides. The reaction rate constant ratios and residence time in the reactor are important parameters in determining higher selectivity of FAME, fatty acid methyl ester product yield over glycerol by-product production. Illustrations of higher FAME yield, higher glycerol yield and cross-over from FAME to glycerol are shown for some values of reaction rate constant ratios and reaction scheme from triglycerides to diglycerides, monoglycerides and glycerol along with formation of FAME in each step by addition of methanol and catalyst is shown. Product distribution curves are presented in Figures 2-5 for different values or reaction rate constant ratios.

Economic feasibility of algal biodiesel under alternative public policies

The motivation for this research was to determine the influence of public policies on economic feasibility of producing algal biodiesel in a system that produced all its energy needs internally. To achieve this, a steady-state mass balance/unit operation system was modeled first. Open raceway technology was assumed for the production of algal feedstock, and the residual biomass after oil extraction was assumed fermented to produce ethanol for the transesterification process. The project assumed the production of 50 million gallons of biodiesel per year and using about 14% of the diesel output to supplement internal energy requirements. It sold the remainder biodiesel and ethanol as pure biofuels to maximize the rents from the renewable fuel standards quota system. Assuming a peak daily yield of 500 kg algal biomass (dry basis)/ha, the results show that production of algal biodiesel under the foregoing constraints is only economically feasible with direct and indirect public policy intervention. For example, the renewable fuel standards' tracking RIN (Renewable fuel Identification Number) system provides a treasury-neutral value for biofuel producers as does the reinstatement of the renewable fuel tax credit. Additionally, the capital costs of an integrated system are such that some form of capital cost grant from the government would support the economic feasibility of the algal biodiesel production.

Transesterification of Triglyceride to Fatty Acid Alkyl Esters (Biodiesel): Comparison of Utility Requirements and Capital Costs between Reaction Separation and Catalytic Distillation Configurations

The efficacy of catalytic distillation (CD) and the economic merits that it would bring into the biodiesel production process is studied. Process flow sheets depicting conventional and CD technology are modeled in Aspen Plus, and detailed operating conditions and equipment designs are provided for each process. The feedstock considered is soybean oil, and the transesterification reaction for the triglyceride is considered for biodiesel production. After optimal design of both process flow sheets to produce 10 million gallons of biodiesel per year, adhering to ASTM purity standards, a detailed cost analysis is carried out using the Aspen economic analyzer tool to predict capital, operating, and utility costs and to calculate the cost of production per gallon of biodiesel. Results depict CD to be a promising candidate to replicate the conversion and product purity of conventional biodiesel processes while having significant savings in capital (41.42% cheaper than the conventional process) and utility (18.12% less than the conventional process) costs, thereby making it a very competitive alternative. The total operating costs and price of production per gallon of biodiesel are only meagerly cheaper for a CD process because the most significant factor to the biodiesel production process is the raw material cost. For both processes, the price of production per gallon of biodiesel after accounting for revenue generated from glycerol product is predicted to be around 1.7 dollars/gallon. The Aspen model is flexible to accommodate higher flow rates for scale-up of operations, add or remove stages of operation into the biodiesel process, modify feedstock and stream prices, and predict associated capital and production costs.

Enhanced characteristics of genetically modified switchgrass (Panicum virgatum L.) for high biofuel production

BackgroundLignocellulosic biomass is one of the most promising renewable and clean energy resources to reduce greenhouse gas emissions and dependence on fossil fuels. However, the resistance to accessibility of sugars embedded in plant cell walls (so-called recalcitrance) is a major barrier to economically viable cellulosic ethanol production. A recent report from the US National Academy of Sciences indicated that, “absent technological breakthroughs”, it was unlikely that the US would meet the congressionally mandated renewable fuel standard of 35 billion gallons of ethanol-equivalent biofuels plus 1 billion gallons of biodiesel by 2022. We here describe the properties of switchgrass (Panicum virgatum) biomass that has been genetically engineered to increase the cellulosic ethanol yield by more than 2-fold.ResultsWe have increased the cellulosic ethanol yield from switchgrass by 2.6-fold through overexpression of the transcription factor PvMYB4. This strategy reduces carbon deposition into lignin and phenolic fermentation inhibitors while maintaining the availability of potentially fermentable soluble sugars and pectic polysaccharides. Detailed biomass characterization analyses revealed that the levels and nature of phenolic acids embedded in the cell-wall, the lignin content and polymer size, lignin internal linkage levels, linkages between lignin and xylans/pectins, and levels of wall-bound fucose are all altered in PvMYB4-OX lines. Genetically engineered PvMYB4-OX switchgrass therefore provides a novel system for further understanding cell wall recalcitrance.ConclusionsOur results have demonstrated that overexpression of PvMYB4, a general transcriptional repressor of the phenylpropanoid/lignin biosynthesis pathway, can lead to very high yield ethanol production through dramatic reduction of recalcitrance. MYB4-OX switchgrass is an excellent model system for understanding recalcitrance, and provides new germplasm for developing switchgrass cultivars as biomass feedstocks for biofuel production.

Wastewater use in algae production for generation of renewable resources: a review and preliminary results

Microalgae feedstock production can be integrated with wastewater and industrial sources of carbon dioxide. This study reviews the literature on algae grown on wastewater and includes a preliminary analysis of algal production based on anaerobic digestion sludge centrate from the Howard F. Curren Advanced Wastewater Treatment Plant (HFC AWTP) in Tampa, Florida and secondary effluent from the City of Lakeland wastewater treatment facilities in Lakeland, Florida. It was demonstrated that a mixed culture of wild algae species could successfully be grown on wastewater nutrients and potentially scaled to commercial production. Algae have demonstrated the ability to naturally colonize low-nutrient effluent water in a wetland treatment system utilized by the City of Lakeland. The results from these experiments show that the algae grown in high strength wastewater from the HFC AWTP are light-limited when cultivated indoor since more than 50% of the outdoor illumination is attenuated in the greenhouse.An analysis was performed to determine the mass of algae that can be supported by the wastewater nutrients (mainly nitrogen and phosphorous) available from the two Florida cities. The study was guided by the growth and productivity data obtained for algal growth in the photobioreactors in operation at the University of South Florida. In the analysis, nutrients and light are assumed to be limited, while CO2 is abundantly available. There is some limitation on land, especially since the HFC AWTP is located at the Port of Tampa. The temperature range in Tampa is assumed to be suitable for algal growth year round. Assuming that the numerous technical challenges to achieving commercial-scale algal production can be met, the results presented suggest that an excess of 71 metric tons per hectare per year of algal biomass can be produced. Two energy production options were considered; liquid biofuels from feedstock with high lipid content, and biogas generation from anaerobic digestion of algae biomass. The total potential oil volume was determined to be approximately 337,500 gallons per year, which may result in the annual production of 270,000 gallons of biodiesel when 80% conversion efficiency is assumed. This production level would be able to sustain approximately 450 cars per year on average. Potential biogas production was estimated to be above 415,000 kg/yr, the equivalent of powering close to 500 homes for a year.

A comparative study of solvent-assisted pretreatment of biodiesel derived crude glycerol on growth and 1,3-propanediol production from Citrobacter freundii

The rapidly growing biodiesel industry has created a scenario, where it is both important and challenging to deal with the enormous amount of crude glycerol generated as an inherent by-product. With every 100 gallons of biodiesel produced, 5-10 gallons of the crude glycerol is left behind containing several impurities which makes its disposal difficult. The objective of the present investigation was to evaluate the impact of biodiesel-derived crude glycerol upon microbial growth and production of 1,3-propanediol by Citrobacter freundii. Five different grades of crude glycerol (obtained from biodiesel preparation using jatropha, soybean, sunflower, rice bran and linseed oils) were used. Crude glycerol caused significant inhibition of microbial growth and subsequently 1,3-propanediol production as compared to pure glycerol. Therefore, a process was developed for the treatment of crude glycerol using solvents before fermentation wherein four different non-polar solvents were examined yielding different grades of pretreated glycerol. Subsequently, the potential toxic effects of pretreated glycerol on the growth and 1,3-propanediol production by C. freundii was evaluated. In case of petroleum ether-treated crude glycerol obtained from jatropha & linseed and hexane-treated crude glycerol obtained from rice bran, the yields obtained were comparable to the pure glycerol. Similarly, soybean-derived glycerol gave comparable results after treatment with either hexane or petroleum ether.

A Greener Solution for Darker Side of Biodiesel: Utilization of Crude Glycerol in 1,3-Propanediol Production

In contrast to the debate on nuclear power and genetically altered food, the public doesn't yet view the manufacturing strategies of biodiesel as a noteworthy hazard. For every 100 gallons of biodiesel produced, 5–10 gallons of the less glamorous crude glycerol are left behind with a sparking debate about the best uses of this waste. This impure form of glycerol must either be disposed off or sold off to market for a minimal amount due to the free fatty acids, water, methanol, and salt content. At present, most of it is simply incinerated. Well that doesn't make biodiesel a clean alternative energy anymore. The utilization of a crude glycerol to produce value–added products provides areas of opportunity where it would be possible to capitalize on the surplus of waste glycerol. In this context, glycerol which promises to be a good substrate for microbial production of 1,3-propanediol, changes the perception of glycerol as being an industrial waste. The present work necessitates to evaluate the possibility of capitalizing on the surplus glycerol by converting it into 1,3-propanediol. In this respect, more then 200 bacterial strains were screened out, to identify their ability to convert glycerol to 1,3-propanediol anaerobically. One of the potent strain which produces 1,3-propanediol was identified as Citrobacter freundii. Various raw and pretreated glycerol types were obtained from biodiesel production processes, used as a substrate to produce 1,3-propanediol in batch fermentation. Production and growth inhibition of C. freundii using different grades of glycerol were evaluated. In order to optimize the production, parametric optimization was carried out to fetch out the best parametric combination. Further, the process was scaled up to 30 L fermentor in which the final yield of 1,3-propanediol reached to maximum of 28.0g/l under anaerobic condition.

A Green Process for Producing Biodiesel from Feather Meal

This paper describes a new and environmentally friendly process for developing biodiesel from commercial feather meal, a waste product of the poultry industry. Currently, feather meal is used as an animal feed, given its high protein content, and also as a fertilizer because of its high nitrogen content. In this work, we have extracted fat from the feather meal in boiling water (70 degrees C) and then transesterified the fat into biodiesel using KOH and methanol; 7-11% biodiesel (on a dry basis) is produced in this process. ASTM analysis of the prepared feather meal biodiesel confirmed that the biodiesel is of good quality and comparable to other biodiesels made from other common feedstocks. Given the amount of feather meal produced by the poultry industry, it is estimated that this process can create 150-200 million gallons of biodiesel in the United States and 593.2 million gallons worldwide.

Spent Coffee Grounds as a Versatile Source of Green Energy

The production of energy from renewable and waste materials is an attractive alternative to the conventional agricultural feed stocks such as corn and soybean. This paper describes an approach to extract oil from spent coffee grounds and to further transesterify the processed oil to convert it into biodiesel. This process yields 10-15% oil depending on the coffee species (Arabica or Robusta). The biodiesel derived from the coffee grounds (100% conversion of oil to biodiesel) was found to be stable for more than 1 month under ambient conditions. It is projected that 340 million gallons of biodiesel can be produced from the waste coffee grounds around the world. The coffee grounds after oil extraction are ideal materials for garden fertilizer, feedstock for ethanol, and as fuel pellets.

Food vs Biofuel

Food vs Biofuel

Economic Parameters for Corn Ethanol and Biodiesel Production

This article presents current investment and operating costs of ethanol and biodiesel plants for alternative prices of feedstock. The price of these two fuels is estimated for alternative prices of crude oil with the existing renewable fuels policy. The excise tax credit, currently $0.51 per gallon of ethanol and $1.00 per gallon of biodiesel, is a major contributor to the fuel price and profitability of these industries. The analysis demonstrates how the crude oil price, feedstock price, and excise tax credits interact to impact profitability of these industries.

Brief Report: Hazardous Materials Release Resulting From Home Production of Biodiesel—Colorado, May 2006

On May 7, 2006, a hazardous materials (HazMat) release occurred in a residential area of Colorado when a homeowner who was processing a tank of homemade biodiesel fuel forgot to turn off the tank's heating element and left for the weekend. The heating element overheated and caused a fire that burned the surrounding shed and equipment. The shed had contained >600 gallons of biodiesel and recycled restaurant cooking oil, smaller amounts of glycerin and sodium hydroxide, and 1-gallon containers of sulfuric and phosphoric acid; a mixture of these ingredients seeped into the ground during the fire. A certified HazMat team and the local fire department responded. Investigators found seven 55-gallon barrels of methanol and other hazardous materials outside the shed. No injuries or evacuations occurred. To prevent potential injuries, biodiesel should be purchased from a licensed commercial source.

CHARACTERIZATION OF CRUDE GLYCEROL FROM BIODIESEL PRODUCTION FROM MULTIPLE FEEDSTOCKS

Glycerol is the principal by-product of biodiesel production. For each gallon of biodiesel produced, approximately0.3 kg of crude glycerol accompanies. Such crude glycerol possesses very low value because of the impurities contained. Asthe demand and production of biodiesel grow exponentially, the utilization of the glycerol becomes an urgent topic. Themake-up of crude glycerol varies depending on the parent feedstock and the biodiesel production process. Before the crudeglycerol could be considered for possible value-added utilizations, it is necessary to characterize it on its physical, chemical,and nutritional properties. This article reports the characterization of crude glycerol obtained from different seed oilfeedstocks of mustard, rapeseed, canola, crambe, soybean, and waste cooking oils. Batch processes of biodiesel productionwere used as the means of crude glycerol preparation using unrefined vegetable oils, methanol, and sodium methylate as thecatalyst. After separation from biodiesel, the crude glycerol from each of the oils was analyzed using ASTM and other standardtest methods. Elemental impurities, nutritional value, and other chemical properties were tested.