The galling mechanism of Tristelle 5183, an Fe-based hardfacing alloy, was investigated at elevated temperature. The test was performed using a bespoke galling rig. Adhesive transfer and galling were found to occur, as a result of shear at the adhesion boundary and the activation of an internal shear plane within one of the tribosurfaces. During deformation, carbides were observed to have fractured, as a result of the shear train they were exposed to and their lack of ductility. In the case of niobium carbides, their fracture resulted in the formation of voids, which were found to coalesce and led to cracking and adhesive transfer. A tribologically affected zone (TAZ) was found to form, which contained nanocrystalline austenite, as a result of the shear exerted within 30μm of the adhesion boundaries. The galling of Tristelle 5183 initiated from the formation of an adhesive boundary, followed by sub-surface shear in only one tribosurface, Following further sub-surface shear, an internal shear plane is activated. internal shear and shear at the adhesion boundary continues until fracture occur, resulting in adhesive transfer.