GaInP Top Cell Research Articles

Radiative recombination of carriers in the GaxIn1−xP/GaAs double-junction tandem solar cells

Radiative recombination of carriers in two kinds of GaxIn1−xP/GaAs double-junction tandem solar cell structures was investigated by using room-temperature electroluminescence (EL) and photoluminescence (PL) techniques. Efficient radiative recombination was observed simultaneously in the top and the bottom subcells in both the samples. By studying the behavior of EL and PL spectra, the radiative recombination intensity ΦEL was demonstrated to be reliant on the material-dependent radiative recombination coefficient, base layer doping concentration and thickness. Furthermore, dependence of ΦEL on substrate misorientation in both the subcells was also evidenced, which was explained in terms of the growth-induced variations in microstructure for the GaInP top cell and in potential barrier profile across the p–n junction for the GaAs bottom cell. Based on these observations, the radiative recombination in the two base layers of the subcells was demonstrated to be the major carrier loss mechanism in the GaxIn1−xP/GaAs double-junction tandem photovoltaic devices and should be suppressed.

Demonstration of Photon Coupling in Dual Multiple-Quantum-Well Solar Cells

Multiple-quantum-well (MQW) top cells can enhance the performance of multi-junction solar cells since the absorption edge of top and middle subcells can be tuned with the MQWs to maximize the efficiency. The radiative dominance of MQW top cells can enhance photon coupling, which can potentially reduce the spectral sensitivity of the device and, thus, raise the energy harvest. We present experimental results on photon coupling in dual-junction cells with GaInP top cells containing GaInAsP quantum wells along with theoretical calculation based on a detailed balance model. It is observed that at high concentration, approximately 50% of the dark current of an MQW top cell is transferred to the photocurrent of the cell in the bottom, which is much higher than any previously reported values.

Influence of GaInP ordering on the electronic quality of concentrator solar cells

The ordering phenomenon produces a reduction in the band gap of the GaInP material. Though a drawback for many optoelectronic applications, ordering can be used as an additional degree of material and device engineering freedom. The performance of the record efficiency GaInP/GaAs/Ge multijunction solar cells depends on the quality and design of the GaInP top cell, which can be affected also by ordering. The tradeoff existing between band gap and minority carrier properties, and the possibility of creating a back surface field (BSF) structure based on an order–disorder GaInP heterostructure makes the study of the ordering appealing for solar cell applications. In this work, the ordering dependency with the growth conditions and substrate orientation is studied. The results obtained are presented to enrich and extend the data available in the literature. Then the properties of order–disorder GaInP heterostructures are assessed by using them as BSF in GaInP concentrator solar cells. The external quantum efficiency (EQE) shows a good behavior of these BSF layers, but unexpectedly poor electronic quality in the active layers. Although the exact origin of this problem remains to be known, it is attributed to traps introduced by the ordered/disordered domains matrix or growth native defects. EQE measurements with bias light show a recovery of the minority carrier properties, presumably due to the saturation of the traps.

Effects of 0.28–2.80 MeV proton irradiation on GaInP/GaAs/Ge triple-junction solar cells for space use

GaInP/GaAs/Ge triple-junction solar cells were irradiated with 0.28, 0.62 and 2.80MeV protons with fluences ranging from 1×1010cm−2 to 1×1013cm−2. Their performance degradation is analyzed using current–voltage characteristics and spectral response measurements. The degradation rates of the short circuit current, open circuit voltage, and maximum power output increase with fluence, but decrease with increasing proton energy. It was also observed that the spectral response of the GaAs middle cell degrades more significantly than that of the GaInP top cell.