The selective reduction of NO x over H-mordenite (H-m) was studied using CH 3OH as reducing agent. Results are compared with those obtained with other conventional reducing agents (ethylene and methane), with gas-phase reactions, and with other metal-exchanged mordenites (Cu-mordenite (Cu-m) and Co-mordenite (Co-m)). H-m was found to be an effective catalyst for the SCR of NO x with CH 3OH. When different reducing agents were compared over H-m, CH 3OH > C 2H 4 > CH 4 was the order according to the maximum NO conversion obtained using 1% of oxygen in the feed. Instead, if selectivity is considered, the order results CH 4 > CH 3OH > C 2H 4. In reaction experiments, two distinct zones defined by two maxima with NO to N 2 conversion are obtained at two different temperatures. A correlation exists between the said zones and the CO : CO 2 ratio. At low temperatures, CO prevails whereas at high temperatures CO 2 prevails. These results indicate that there exist different reaction intermediates. Evidence from reaction experiments, FTIR results, and transient experiments suggest that the reaction mechanism involves formaldehyde and dimethyl ether (DME) as intermediates in the 200–500°C temperature range. The surface interaction between CH 3OH (or its decomposition products) and NO is negligible if compared with NO 2, indicating that the oxidation of NO to NO 2 on acid sites is a fundamental path in this system. Different from other non-oxygenated reductants (methane and ethylene), a gas-phase NO x initiation effect on hydrocarbon combustion was not observed.
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