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Published in last 50 years
Porphyrin dimer 1, which does not have an inside cavity and cannot interact with [60]fullerene (C60), becomes an excellent C60-acceptor with a large cavity in the presence of a Pd(II) complex.
A self-assembled fullerene receptor based on calix[5]arene has been developed. Silver cation complexation held together the two calix[5]arenes with bipyridine units providing a large enough cavity to take up C 60 or C 70. The formation of the supramolecular complex with C 60 or C 70 was established by using the electrospray mass spectrometry.