Climate change mitigation technologies have been a focus in reducing atmospheric carbon levels for the past few years. One such mitigation technology is pyrolysis, where biomass feedstocks are combusted at elevated temperatures for varying durations to produce three main products: biochar, bio-oil, and biogas. While bio-oil and biogas are typically used to produce energy via further combustion, biochar can be used in several different applications. Furthermore, using forest harvest residues as a feedstock for biochar production helps use excess biomass from the forestry industry that was previously assumed unmarketable. In our study, we combined forest carbon analysis modelling with cradle-to-gate life cycle emissions to determine the greenhouse gas emissions of biochar produced from forest harvest residues. We examined three collection scenarios, spanning two harvesting methods in one forest management unit in northern Ontario, Canada. From our analysis, we observed immediate reductions (− 0.85 tCO2eq·tbiochar−1 in year 1) in CO2-equivalent emissions (CO2eq) when producing biochar from forest harvest residues that would have undergone controlled burning, without considering the end use of the biochar. For the forest harvest residues that would remain in-forest to decay over time, producing biochar would increase overall emissions by about 6 tCO2eq·tbiochar−1. Throughout the 100-year timeframe examined–in ascending order of cumulative emissions–scenario ranking was: full tree harvesting with slash pile burn < full tree harvesting with slash pile decay < cut-to-length/tree-length harvesting.Graphical