Hydrogen fuel has gained global attention as a potential alternative to conventional fuels as it reduces greenhouse gas emissions and addresses energy sustainability challenges. In addition, biofuel (Azolla pinnata) is highly productive having limited negative impacts with an exemplary productivity rate. The energy-exergy analysis in CI engine's is an effective method for determining its efficiency and effectiveness. This paper highlights the effects of diesel, H2 enriched diesel, and H2 enriched B40 (60% diesel + 40% Algal Biodiesel) on the energetic and exergetic efficiency of a dual-fuel diesel engine with a rated speed and power of 1500 rpm and 3.5 kW respectively. The analysis was done at varying engine loads: low loads (25%), medium loads (50%), and high loads (75%), respectively. The energy and exergy for 40% hydrogen-enriched B40 increased by 8.77% and 23.85%, respectively, compared to neat diesel operation at higher loads. In addition, the irreversibility of 40% hydrogen-enriched B40 decreased by 13.82% at higher load conditions as compared to base diesel operation. The sustainability index of 40% hydrogen-enriched B40 was 1.38 compared to 1.28 of diesel, showing an improvement of 7.82%. The theoretical energy-exergy analyses showed an error less than 5% compared to BTE validating the results of the energy-exergy analyses performed theoretically.
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