The hydrogen recirculation ejector, known for its low cost and simple structure, has garnered widespread attention in PEM fuel cell applications. As a fluid-driven passive component, the fluid dynamics inside the ejector play a pivotal role in determining its entrainment performance. This study explores the impact of the primary flow temperature on phase change characteristics based on the Euler-Lagrange model. Results indicate that at a primary flow temperature of −40 °C, the mass flow rate of droplets at the outlet reaches 285.2 mg/s, representing a condensation efficiency of 24.1%. Concurrently, condensation elevates the outlet temperature by 31.2 °C, resulting in an 8.8% reduction in the entrainment ratio. The mass flow rate of droplets decreases significantly as the primary flow temperature increases. As the temperature rises to 60 °C, homogeneous droplets vanish entirely. Simultaneously, foreign heterogeneous droplets evaporate by 42.0%, attributed to the negative subcooling degree at the diffuser and outlet pipe. This study emphasizes the significance of controlling the primary flow temperature for the hydrogen recirculation ejector.