Frying Oil Research Articles

Impact of multi-walled carbon nanotubes (MWCNTs) on hybrid biodiesel blends for cleaner combustion in CI engines

This study investigates the influence of multi-walled carbon nanotubes (MWCNTs) and hybrid biodiesel blends on the performance, combustion, and emission characteristics of a compression ignition engine. The hybrid biodiesel comprises waste frying oil methyl ester (WFOME), sesame oil methyl ester (SOME), and ultra-low sulfur diesel (ULSD) blended at 20 %:80 % by volume (B20). MWCNTs were added into B20 at 25 ppm and 50 ppm concentrations (B20-25MWCNT and B20-50MWCNT). Experimental analysis was conducted under varying engine loads and injection pressures, complemented by CFD simulations. Results demonstrate that the addition of MWCNTs significantly enhances B20 blend performance, with B20-50MWCNT exhibiting a 25 % increase in brake thermal efficiency and a 17 % reduction in brake specific fuel consumption compared to neat B20. Additionally, the incorporation of MWCNTs resulted in notable reductions in harmful emissions. NOx emissions for the B20 + 50MWCNT blend were reduced by up to 36 % compared to diesel and 43 % compared to B20. Smoke opacity and particulate emissions also showed significant decreases, highlighting the cleaner combustion facilitated by the presence of MWCNTs. The CFD simulations provided detailed insights into the combustion process, validating the experimental findings and elucidating the mechanisms behind the observed improvements. The enhanced fuel atomization, better fuel-air mixing, and catalytic properties of MWCNTs were identified as key factors contributing to the superior performance and reduced emissions.

Production and optimization of surfactin produced from locally isolated Bacillus halotolerans grown on agro-industrial wastes and its antimicrobial efficiency

IntroductionOptimal exploitation of the huge amounts of agro-industrial residuals that are produced annually, which endangers the ecosystem and ultimately contributes to climate change, is one of the solutions available to produce value-added compounds.Aim and objectivesThis study aimed at the economic production and optimization of surfactin. Therefore, the production was carried out by the microbial conversion of Potato Peel Waste (PPW) and Frying Oil Waste (FOW) utilizing locally isolated Bacillus halotolerans. Also, investigating its potential application as an antimicrobial agent towards some pathogenic strains.ResultsScreening the bacterial isolates for surfactin production revealed that the strain with the highest yield (49 g/100 g substrate) and efficient oil displacement activity was genetically identified as B. halotolerans. The production process was then optimized utilizing Central Composite Design (CCD) resulting in the amelioration of yield by 11.4% (from 49 to 55.3 g/100 g substrate) and surface tension (ST) by 8.3% (from 36 to 33 mN/m) with a constant level of the critical micelle concentration (CMC) at 125 mg/L. Moreover, the physiochemical characterization studies of the produced surfactin by FTIR, 1H NMR, and LC–MS/MS proved the existence of a cyclic lipopeptide (surfactin). The investigations further showed a strong emulsification affinity for soybean and motor oil (E24 = 50%), as well as the ability to maintain the emulsion stable over a wide pH (4–10) and temperature (10–100 °C) range. Interestingly, surfactin had a broad-spectrum range of inhibition activity against Bacillus subtilis, Staphylococcus aureus, Pseudomonas aeruginosa, klebsiella pneumonia, and Candida albicans.ConclusionSubsequently, the screening of the isolates and the utilized food-processing wastes along with the extraction technique resulted in a high yield of surfactin characterized by acceptable ST and CMC levels. However, optimization of the cultural conditions to improve the activity and productivity was achieved using Factor-At-A-Time (OFAT) and Central Composite Design (CCD). In contrast, surface activity recorded a maximum level of (33 mN/n) and productivity of 55.3 g/100 g substrate. The optimized surfactin had also the ability to maintain the stability of emulsions over a wide range of pH and temperature. Otherwise, the obtained results proved the promising efficiency of the surfactin against bacterial and fungal pathogens.

Green fuel production from waste fried sunflower oil using reusable mesoporous COP-KOH catalyst with a kinetic study

Declining fossil fuel reserves and fluctuating petroleum prices have prompted global research efforts to develop clean, renewable, and sustainable alternatives to traditional fossil fuels. In this study, a reusable and eco-friendly activation catalyst was designed by combining KOH with a polymer. A series of three polymer catalysts were synthesized, and their catalytic activities were compared with those of COP-KOH, COP-K3PO4 and COP-KF. It was found that the prepared COP-KOH catalyst showed the highest activity. The catalyst was characterized by FT-IR, which confirmed the presence of potassium support successfully coordinated on the COP. Additional analyses included N2 and BET, XPS, SEM, mapping, and basicity measurement by ICP analysis. The prepared catalysts a possessed mesoporous structure, high surface area of 4.2961 m2/g−1, pore volume of 2.2439 m2/g−1, and high basicity. Here, the activity and stability of the potassium modified mesoporous polymer COP-KOH catalyst in green fuel synthesis from waste fried sunflower oil was evaluated. The green fuel conversion rate of 96.42 % was achieved under optimal reaction conditions, with a molar ratio of 6:1 methanol to fried sunflower oil, a catalyst concentration of 85 wt%, a reaction temperature of 61 °C, and a reaction time of 4.5 h. A satisfactory yield of 92.1 % was obtained after use for four consecutive cycles without significant deactivation, and after the fourth cycle catalyst was reactivated with KOH. The characteristic differences in the FT-IR results of the fresh catalyst, used catalyst, and re-activated COP-KOH catalyst, indicated the mode of interaction between the catalyst and reactants. The kinetics of the transesterification reaction was also determined, and the activation energy was found to range from 20.9 to 23.4 kJ.mol−1. The properties of the green fuel were found to be in good agreement with the ASTM D6571-02 standard. The catalyst is recyclable, and using inexpensive feedstock makes the overall process more cost-effective and environmentally friendly.

Enhancing the quality of fried sunflower oil by oak hull ash as an efficient adsorbent

Enhancing the quality of fried sunflower oil by oak hull ash as an efficient adsorbent

Cellulose From Water Hyacinth As Acrylamide Adsorbent In Frying Oil

Cellulose From Water Hyacinth As Acrylamide Adsorbent In Frying Oil

The use of chitosan aerogels as an adsorbent for the regeneration of frying oil

One of the most commonly used food preparation methods is deep-fat frying. The improvement of the quality of used frying oil (UFO) is important because the reuse of frying oil could provide significant savings to the food industry. This study aimed to enhance the quality of used sunflower oil by using chitosan aerogels (CA), which can be considered as novel adsorbents with an increased surface area compared to chitosan powder. Aerogels are novel nanostructured materials with high porosity and large surface area. In this study, CA were produced by drying the 2% (w/v) chitosan gels using supercritical drying. In the study, 32 consecutive deep-fat frying were performed using potato slices in sunflower oil at 180 ± 5 °C. The effect of the adsorbent concentration (0.5, 1, and 2% (w/w)) and different adsorption temperatures (90, 135, and 180 °C) were studied by examining the UFO before and after the adsorption treatments. The physicochemical properties of the oil were analyzed by determining free fatty acid (FFA) content, total polar compounds (TPC), smoke point, p-anisidine value (p-AnV), and color (CIE L*, a*, b*). Moreover, the structural changes of aerogels after the adsorption process were investigated by Fourier Transform Infrared spectroscopy (FTIR) and Nuclear Magnetic Resonance (NMR). CA could reduce the % FFA values from 0.44% to 0.18% due to the ionic interaction between CA and FFA. In addition, TPC value and the smoke point increased after the treatments. The p-AnV was compensated with CA, indicating that secondary oxidation products were adsorbed. Moreover, CA caused a darker color after the adsorption treatments. Additionally, compared with magnesium silicate, the same concentrations of CA were found more effective in improving all the quality parameters of oil except for the L* values.

Exploring the multifarious blend ratios of waste fried edible oil biodiesel/diesel/low carbon methanol in an automotive engine: An approach towards fuel characterization, experimental, and multicriteria decision making method

AbstractA low‐cost, high‐performance alternative fuel to traditional fossil fuels is required due to rising energy demand, fossil fuel depletion, and rising prices. In this case, one of the green fuels could be synthesized using transesterification from waste‐fried edible oil (WFEO). The current study deals with neat diesel (D100) and waste‐fried edible oil biodiesel (B100) as the baseline fuels. By volume, a binary blend of 50% diesel and 50% WFEO biodiesel was prepared. The biodiesel/methanol/diesel mixture was considered a ternary blend under two different ternary ratios, such as B40M10D50 and B30M20D50, respectively. The fuel characterization and the rheological study were performed for all the fuel blends as per the ASTM standards. According to engine experimental results, the B30M20D50 blend has 25.42% higher brake thermal efficiency (BTE) than B100 but 3.4% lower than D100 at full load due to the higher methanol percentage. When compared with D100, adding 20% methanol to the ternary blend reduced brake‐specific fuel consumption (BSFC) by 33.34%. Both ternary blends increased NOx emissions by 27.38% and 22.97% compared to D100 but decreased them by 14.23% and 18.68% compared to B100. Both ternary blends produced 0.4 and 0.36 kg/kWh at lower loads, while the D100 and B100 produced 0.46 and 0.42 kg/kWh. Finally, the entropy‐weighted technique for order preference by similarity to the ideal solution (TOPSIS) multi‐criteria decision‐making method was used to determine the best blend for engine performance and emissions. The entropy‐weighted TOPSIS technique likewise found that a B30M20D50 ternary blend with 75% loading had the lowest emissions and best performance.

Biodiesel production and characteristics from waste frying oils: sources, challenges, and circular economic perspective.

Biodiesel serves as a viable alternative to traditional diesel due to its non-toxicity, biodegradability, and lower environmental footprint. Among the diverse edible and inedible feedstocks, waste frying oil emerges as a promising and affordable feedstock for biodiesel production. Commonly waste frying oils include those derived from palm, corn, sunflower, soybean, rapeseed, and canola. The primary challenge related to biodiesel production technologies is the high production cost, which poses a significant barrier to its widespread adoption. Thus, refining the production techniques is essential to enhance yield, reduce capital expenditure, and curtail raw material expenses. An examination of the research focusing on feedstock availability, production, hurdles, operational expenditures, and future potential is pivotal for identifying the most economically and technically viable solutions. This paper critically reviews such research by exploring feedstock availability, production techniques, challenges, and costs intrinsic to biodiesel synthesis. It also underscores the economic feasibility of biodiesel production, shedding light on the pivotal factors that influence profitability, especially when leveraging waste frying oils. Through an in-depth understanding of these considerations, optimal production and feedstock choices for biodiesel production can be identified. Addressing cost and production bottlenecks could potentially enhance the economic viability of waste frying oil-based biodiesel, thus fostering both environmental sustainability and more extensive adoption of biodiesel as an environmental-friendly fuel in the future.

Improving environmental indicators of the wheeled tractor diesel engine by using biofuels

The object of this study is the process of operation of a diesel engine in a wheeled tractor on methyl ether of spent frying sunflower oil. The task being solved is to improve the environmental performance of a diesel engine in a wheeled tractor during the operation of its diesel on such biodiesel fuel and its mixtures with mineral diesel fuel. The characteristics of the diesel D-243 were determined by the experimental method with the measurement of the toxicity of the waste gases during its operation on the methyl ether of the spent sunflower oil, mineral fuel, and their mixtures. A decrease in the content of soot in diesel exhaust gases and a slight increase in the types of nitrogen oxides was registered. The theoretical method using a mathematical model determined the indicators of a wheeled tractor during its movement with a trailer for the accepted driving cycle and the operation of its diesel on different fuels. To that end, the characteristics of a specific diesel engine were described by polynomial models. The adequacy of the mathematical model of the movement of a tractor with a trailer over a driving cycle was tested. By means of a mathematical model, the total road emissions of harmful substances of a diesel engine were calculated when the tractor is running with a trailer over the accepted driving cycle. Calculations were performed for two types of fuel: mineral diesel fuel and biodiesel fuel. Biofuel consumption increases by almost 10 % compared to diesel fuel. The total emissions of harmful substances are 1.1 times lower in a diesel engine running on biofuel than when using mineral fuel. The results could be used in the operation of technological transport in the industry and agriculture provided there is a sufficient volume of raw materials for the production of biofuel

Identification of key off-flavor compounds during storage of fried pepper (Zanthoxylum bungeanum Maxim.) oils by sensory-directed flavor analysis and partial least squares regression (PLSR)

Fried pepper oil (FPO) is a widely used flavoring oil in China, but it suffers from complex chemical reactions that give an unpleasant odor. The aim of this paper is to study the main causes of off-flavor in FPO, as well as identify key off-flavor compounds in FPO. Fifty-eight volatiles were identified using HS-SPME–GC–MS (headspace solid-phase microextraction–gas chromatography–mass spectrometry) during storage. Fifteen off-flavor compounds were initially targeted by odor activity values (OAVs) calculations and partial least squares regression (PLSR) analysis. Eventually, five key off-flavor compounds were identified by recombination experiments and omission test, which were hexanal, (E)-2-octenal, terpinyl acetate, α-terpineol, and hexanoic acid. The off-flavors could derive from the oxidative degradation of long-chain fatty acids and the acid-catalyzed rearrangement of terpenes. The results of the study provide a theoretical basis for the regulation of off-flavor in FPO and a practical guide for the industrial production of FPO.

Biodiesel Production over Banana Peel Biochar as a Sustainable Catalyst

Biodiesel from waste frying oil was produced via methanolysis using biochar-based catalysts prepared by carbonizing banana peels (350 °C and 400 °C) mixed with 20% (wt.) of alkali carbonates (Na, Li, or K). The catalysts exhibited a bi-functional character: acidic and basic. Raman spectroscopy confirmed the alkali’s role in char graphitization, influencing morphology and oxygen content. Oxygenated surface sites acted as acidic sites for free fatty acid esterification, while alkali sites facilitated triglyceride transesterification. The best catalyst obtained by carbonization at 350 °C, without alkali modifier, led to 97.5% FAME by processing a waste frying oil with 1.2 mg KOH/g oil acidity. Most of the studied catalysts yielded high-quality glycerin, allowing the significance of homogenous catalyzed processes to be discarded.

Concordance between In Vitro and In Vivo Relative Toxic Potencies of Diesel Exhaust Particles from Different Biodiesel Blends.

Diesel exhaust particles (DEPs) contribute to air pollution exposure-related adverse health impacts. Here, we examined in vitro, and in vivo toxicities of DEPs from a Caterpillar C11 heavy-duty diesel engine emissions using ultra-low-sulfur diesel (ULSD) and biodiesel blends (20% v/v) of canola (B20C), soy (B20S), or tallow-waste fry oil (B20T) in ULSD. The in vitro effects of DEPs (DEPULSD, DEPB20C, DEPB20S, and DEPB20T) in exposed mouse monocyte/macrophage cells (J774A.1) were examined by analyzing the cellular cytotoxicity endpoints (CTB, LDH, and ATP) and secreted proteins. The in vivo effects were assessed in BALB/c mice (n = 6/group) exposed to DEPs (250 µg), carbon black (CB), or saline via intratracheal instillation 24 h post-exposure. Bronchoalveolar lavage fluid (BALF) cell counts, cytokines, lung/heart mRNA, and plasma markers were examined. In vitro cytotoxic potencies (e.g., ATP) and secreted TNF-α were positively correlated (p < 0.05) with in vivo inflammatory potency (BALF cytokines, lung/heart mRNA, and plasma markers). Overall, DEPULSD and DEPB20C appeared to be more potent compared to DEPB20S and DEPB20T. These findings suggested that biodiesel blend-derived DEP potencies can be influenced by biodiesel sources, and inflammatory process- was one of the potential underlying toxicity mechanisms. These observations were consistent across in vitro and in vivo exposures, and this work adds value to the health risk analysis of cleaner fuel alternatives.

Repurpose of used frying sunflower oil as an ecofriendly plasticizer for polylactic acid

The development of competitive and sustainable additives for use in semicrystalline polymers is currently an area of growing interest in scientific and engineering areas. However, the feasibility of using waste oils as raw materials to produce effective plasticizers for these polymers has not yet been thoroughly investigated. In this work, the plasticization of polylactic acid (PLA), which is essential to improve its ductility, was studied using different contents of low molecular weight plasticizers: one synthesized from sunflower (Helianthus annuus) oil used in frying (USOP) and the bio-based commercial tributyrin (TB), selected as a control plasticizer. The experimental results revealed changes in the properties of pure PLA matrix that were explained considering the shape and chemical structure of the different plasticizers. Both compounds drastically decreased the glass transition temperature of PLA as well as the elastic modulus and tensile strength, although increase the elongation at break. The greatest plasticizing effect was obtained by adding 15 percent by weight of TB to the biodegradable matrix. However, the synthesized bio-based plasticizer exhibits a desirable low volatility, thus its thermal degradation occurs at higher temperatures in comparison with that of TB. Furthermore, the water vapor permeability of the PLA is not affected when USOP is used as plasticizer, which is a very interesting result for applications in which the material is in contact with food or humid environments.

Comparative Analysis of Performance and Emission Characteristics of Biodiesels from Animal Fats and Vegetable Oils as Fuel for Common Rail Engines

Currently, solving global environmental problems is recognized as an important task for humanity. In particular, automobile exhaust gases, which are pointed out as the main cause of environmental pollution, are increasing environmental pollutants and pollution problems, and exhaust gas regulations are being strengthened around the world. In particular, when an engine is idling while a car is stopped and not running, a lot of fine dust and toxic gases are emitted into the atmosphere due to the unnecessary fuel consumption of the engine. These idling emissions are making the Earth’s environmental pollution more serious and depleting limited oil resources. Biodiesel, which can replace diesel fuel, generally has similar physical properties to diesel fuel, so it is receiving a lot of attention as an eco-friendly alternative fuel. Biodiesel can be extracted from various substances of vegetable or animal origin and can also be extracted from waste resources discarded in nature. In this study, we used biodiesel blended fuel (B20) in a CRDI diesel engine to study the characteristics of gases emitted during combustion in the engine’s idling state. There were a total of four types of biodiesels used in the experiment. New Soybean Oil and New Lard Oil extracted from new resources and Waste Soybean Fried Oil and Waste Barbecue Lard Oil extracted from waste resources were used, and the gaseous substances emitted during combustion with pure diesel fuel and with the biodiesels were compared and analyzed. It was confirmed that all four B20 biodiesels had a reduction effect on PM, CO, and HC emissions, excluding NOx emissions, compared to pure diesel in terms of the emissions generated during combustion under no-load idling conditions. In particular, New Soybean Oil had the highest PM reduction rate of 20.3% compared to pure diesel, and Waste Soybean Fried Oil had the highest CO and HC reduction rates of 36.6% and 19.3%, respectively. However, NOx was confirmed to be highest in New Soybean Oil, and Waste Barbecue Lard Oil was the highest in fuel consumption.

Combinatorial effects of longan (Dimocarpus longan) peel extract and lecithin on stability of soybean oil and the oxidative stability of fried shrimp crackers during storage

Soybean oil contains relatively high polyunsaturated fatty acids (PUFAs) which present problems for storage, as they are not oxidatively stable. To solve this problem, the present study mixed a naturally hydrophilic antioxidant (longan peel extract, LP) with an amphiphilic compound (lecithin) to create a water-oil based interface with antioxidant properties and analyzed the effect on lipid oxidation. Pretreatments with LP, lecithin, and a combined mixture of LP and lecithin improved oxidative stability in refined soybean oil heated at 70 and 180 °C, by decreasing the resulting peroxide value (POV), conjugated dienes (CD) and thiobarbituric acid reactive substances (TBARS). Pretreatment with a combination of both LP and lecithin exhibited a synergistic effect in lowering TBARS and maintaining α-tocopherol, which is an endogenous antioxidant in soybean oil. The pretreatment helped to maintain PUFAs, which led to the prevention of POV, CD and TBARS formation in the oil. In deep-frying experiment, application of LP, lecithin, and a combined mixture of the two, improved the stability of the frying oil in addition to fried shrimp crackers that were cooked in the oil. Collectively, the results demonstrated the potential of LP, lecithin, and their combination in improving oxidative stability of vegetable oils under high-temperature conditions.

Factors influencing caterers' selection of cooking oils in Sekondi-Takoradi, Ghana

Background: Cooking oil is a plant or animal liquid fat used mostly in frying, baking, and other types of cooking methods. Oils are the basis for many recipes of caterers. There is a variety of cooking oils on the market, each with their specific benefits and nutritional value. This study explored factors that caterers consider when choosing cooking oils and how frequently they use them. Method: Forty-five hotels and restaurants were sampled from the Sekondi-Takoradi Metropolitan area: 30 hotels (3 four-star, 5 three-star, 22 two-star) and 15 restaurants. Self-administered questionnaires were used to gather data from 198 respondents. Descriptive statistics were used to analyze the data. Results: The study found out that caterers and clients mainly chose cooking oils based on nutritional value, quality, flavour/taste, and price. Respondents considered quality metrics on oil labels such as smoke point and fatty acid profiles, when selecting good frying oils to purchase. Conclusion: The accuracy of the cooking oil information obtained from advertisements is unclear. Further consumer education on interpreting and verifying claims made in commercial advertising may be beneficial. The research offers insights into the decision-making process and preferences caterers employ when selecting cooking oils and their typical frying frequencies.

Quality investigation of the most consumed refined seed oils after French fries’ domestic short-term deep-frying process

Deep-frying is an attractive food preparation method and has been in use for centuries. It is a very popular culinary practice worldwide and can be used both industrially and domestically. Deep-fried food has a unique sensorial property, such as flavor, aroma, and texture. However, the chemical quality of the frying oil can be affected by the high temperatures normally used in deep-frying. Complex series of reactions that occur in vegetable oils during deep-frying (hydrolytic and oxidative rancidity processes) they are related to several mechanisms, such as reactive species, chemical composition of the lipid, environment, and process, influencing the speed and nature of the oxidative process. This paper aimed to analyze the quality of the vegetable oils most consumed by the population (refined soybean and sunflower oils) used in domestic short-term deep-frying process, using a domestic-grade electric fryer and a conventional method. French fries were used because they are a convenient product, highly consumed in industrialized countries. Domestic events of short-term deep-frying were carried out for three days, with one-week intervals. After each frying events, the refined oils were analyzed. Methodology consists in bromatological analyses of quality research applying analyzes of acidity and peroxide, in which the free acidity content, compounds formed by hydrolytic rancidity, and hydroperoxides content, the first compounds formed in the oil´s oxidative rancidification process, were analyzed. These parameters will be fundamental in oils oxidative evaluating during frying. According to the results, fresh vegetable oils samples remained within regulatory limits. However, after short-term deep-frying, free fatty acids and hydroperoxides content increased in both domestic short-term deep-frying using both vegetable oils, exception of sunflower oil after last day of frying. Additionally, there was no significant difference in the fatty acids value increase comparing with both domestic frying techniques. However, there was significant difference in hydroperoxide value comparing the oils between deep-frying techniques. However, in general even the oils have shown great thermal quality, bromatological analyses demonstrated that must be taken careful when reusing oils for short-term deep-frying. Seeing that the electric fryer is effective in oil quality compared preservation comparing with conventional method, probably due to temperature control and better sealing efficiency.

Determination of some fuel properties of binary biodiesel and binary biodiesel – diesel blend fuels obtained from camelina oil and waste frying oils

In today's studies on liquid biofuels, it is observed that many of them focus on blends of single biodiesel with diesel. These studies have shown that biodiesel produced from different feedstocks exhibits similar properties to traditional diesel fuel in terms of fuel characteristics and engine performance, indicating the potential of biodiesel to replace diesel fuel. However, recent research has shown limited studies involving the blending of dual biodiesel with traditional diesel fuel.&#x0D; In this study, high oil content camelina plant, which has an important place in ensuring sustainability in human food production, in other words, it is not suitable for human food and has the potential to significantly increase our domestic biofuel production, and domestic waste frying oil, which significantly reduces the cost of biodiesel raw material production, were selected as biodiesel feedstock. Binary biodiesel fuels (D0C50WF50, D0C75WF25, and D0C25WF75) were obtained by mixing the biodiesel fuels produced from camelina and domestic waste frying oil by transesterification method in the ratio of 1:1 and 1:3 by volume. Binary biodiesel-diesel blend fuels were obtained by blending binary biodiesel fuels (D75C12.5WF12.5, D50C25WF25 and D25C37.5WF37.5) with conventional diesel fuel (diesel) after blending at 1:1 ratio by volume. As a result of the research, the physicochemical properties (density, kinematic viscosity, flash point, water content, calorific value, cold filter plugging point, cloud and pour point, copper strip corrosion) of the prepared binary biodiesel and binary biodiesel+diesel blend fuels were determined. The results of the analyses of the blend fuels were determined in accordance with the relevant biodiesel standards (EN 14214, ASTM D-6751) and the results were also compared with the reference fuel, diesel fuel.

Biodiesel production from waste frying oil by electrochemical method using stainless steel electrode

Biodiesel production from waste frying oil is important in terms of effectively utilizing waste and reducing production costs. It is important that the production method of biodiesel is environmentally friendly, economical, and sustainable. For this purpose, electrochemical transesterification process with stainless steel electrodes instead of rare metal electrodes was preferred in this study for biodiesel production. In this study, where SS304 class AISI 304 stainless steel was used as an electrode, biodiesel was produced from waste frying oil by electrochemical method. An electrolyte was prepared with 8:1 molar ratio of methanol, 2% by weight distilled water, 2% THF, 0.5% NaCl and waste frying oil. The conversion efficiency and fuel properties of biodiesel produced in the electrochemical process lasting 3 hours with a reaction voltage of 20 V were determined. The results were compared with biodiesel produced by conventional methods. According to the results, a conversion efficiency of 68% was achieved in the electrochemical process. Moreover, it has been determined that biodiesel properties are compatible with EN 14214.

Determination of Optimum Operating Parameters in a Non-Road Diesel Engine Fueled with 1-Heptanol/Biodiesel at Different Injection Pressures and Advances

It is important to reduce the negative environmental effects of non-road diesel engines, which are increasingly used in many facilities and machines, without loss of performance. Biodiesel is used as an alternative to fossil-based diesel fuels to eliminate these effects and ensure sustainability in energy. This study focused on the optimization of the operating parameters of a non-road diesel engine operating with a waste frying oil biodiesel mixture at 50% load. Pure biodiesel, 1-heptanol, different injection advances and pressures were determined as input parameters for optimization. The tests were designed according to Taguchi’s L16 orthogonal array. ANOVA analysis was performed to determine the importance of input parameters on engine performance and exhaust emissions. Optimization was made based on the highest brake thermal efficiency (BTE) in addition to the lowest values of brake-specific fuel consumption (BSFC), brake-specific hydrocarbon (BSHC), brake-specific nitrogen oxide (BSNOx) and smoke emissions. In the optimization carried out according to the response surface methodology (RSM), the optimum combinations to obtain the best engine characteristics were determined as 17.27% 1-heptanol, a 226-bar injection pressure, 27 CAD injection advance and B75. These optimization results were verified by engine experiments within the recommended error range.