Coatings are essential for protecting steel structures from corrosion and mechanical stresses, especially under challenging environmental conditions. To this end, this study systematically examines the effects of temperature (20 °C to 50 °C), strain rate (6.67 × 10−4 s−1 to 1.67 × 10−2 s−1), and intermediate coat thickness (140 μm to 700 μm, the layer between the primer and topcoat) on the uniaxial tensile properties of heavy-duty coatings for steel structures. Experimental and theoretical analyses were conducted to quantitatively assess the influence of these factors on the mechanical properties of the coatings. A multifactor constitutive model was developed based on the Sherwood–Frost model by integrating material characteristics and fitting experimental data, incorporating response functions for temperature, strain rate, and intermediate coat thickness. The results reveal that increased temperature causes temperature-induced softening, while higher strain rates lead to strain rate-dependent strengthening of the coatings. In contrast, the effect of layer thickness on mechanical properties follows a non-monotonic trend, influenced by the structural and material characteristics of the coatings, with the most significant mechanical response occurring at 560 μm thickness. These findings suggest that optimal coating design must consider multiple factors to enhance mechanical performance. Additionally, the correlation coefficients (r) between the model predictions and experimental results are 0.97 or higher, indicating the model’s effectiveness in predicting and optimizing the mechanical performance of heavy-duty coatings under complex conditions.
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