Front Side Research Articles

Unveiling the origin of metal contact failures in TOPCon solar cells through accelerated damp-heat testing

Tunnel oxide passivated contact (TOPCon) solar cells are expected to dominate the global photovoltaic market in the coming decade thanks to rapid advancements in power conversion efficiency (PCE). However, there are concerns about the reliability of TOPCon modules, particularly in hot and humid conditions. The current module-level fundamental analysis strategies for TOPCon solar cells provide too slow feedback for rapid process development. This study explores the degradation of metal contacts in TOPCon solar cells under accelerated testing conditions of 85 °C and 85 % relative humidity (DH85). The degradation was induced by two commonly used sodium-related salts, sodium bicarbonate (NaHCO3) and sodium chloride (NaCl), in the testing of the solar cells. When applied to the front side, NaHCO3 caused a ∼5%relPCE reduction after 100-h DH85 exposure, while NaCl leads to a more significant ∼92%relPCE reduction. The primary cause of degradation is a considerable increase in series resistance (Rs), likely due to electrochemical reactions within the Ag/Al paste. When the salts are applied to the rear of the TOPCon solar cell, the degradation becomes more complex. NaHCO3 increases recombination and results in a deterioration of the contact, resulting in a ∼16%relPCE reduction after 100-h DH85 testing. Conversely, NaCl primarily causes a decline in open-circuit voltage (Voc) and a ∼4%relPCE loss. This manuscript primarily investigates degradation mechanisms related on the rear side, with a focus on significant oxidation occurring at the interface between Ag and Si. These findings highlight the susceptibility of TOPCon solar cells to contact corrosion, emphasizing the electrochemical reactivity of metallisation as a potential risk for long-term TOPCon module operation. This study provides crucial insights into TOPCon cell degradation mechanisms, which are essential for optimising performance and enhancing the long-term reliability of TOPCon modules.

Effects of die top system and trenches on large thin die mechanical robustness

Abstract Power MOSFET dies in the automotive industry are becoming larger (> 5 x 5 mm) and thinner (< 50 µm) to meet high-performance and lifetime requirements. Ensuring the mechanical robustness of these large ultrathin chips is crucial for reliable electronic devices and high-throughput packaging processes. The high aspect ratio and advanced chip designs incorporating trench technology present significant challenges in semiconductor assembly, packaging, and testing. This paper introduces an experimental front-end strategy aimed at strengthening the front side of large ultrathin dies using various die-top systems. Industry-equivalent 50 µm thick dummy power MOSFET dies were fabricated to evaluate the efficacy of different chip designs and materials, such as polyimide, in mitigating fracture risks. Fabrication-induced stresses and warpage in the device layers were measured using a thin-film stress measurement tool. Additionally, the frontside strength of the ultrathin dies was assessed using the three-point bending method, with the resulting data analyzed via two-parameter Weibull distribution plots. Results demonstrated that the deposition of 5 µm polyimide (PI) on the nitride die topside significantly increased die strength from 339 MPa to 760 MPa, with 5 µm PI proving more effective for die strengthening than 10 µm. The interaction between the metal-trench layer and the die was found to be critical to the robustness of ultrathin dies, influenced by the pattern and layout of the trenches. Die-top metallization designs, such as meandering patterns, showed promising improvements in die strength compared to standard designs. A proposed chip layout aims to maximize polyimide coverage for clip-bonded products on the die topside, leveraging its strengthening effect. The study also demonstrated that dummy reference chips can facilitate rapid and straightforward evaluation of extensive design experiments to identify robust chip designs.

Exploring the reaction mechanistic pathway for the sensing of G-Series nerve agent with Kemp's triacid derivative: A computational study

Kemp's triacid derivative have been reported as a candidate for sensing of nerve agents employing the photoinduced electron transfer (PET) processes. The sensor probe molecules were prepared with primary alcohol in very close proximity to a tertiary amine to acylate the alcohol with rapid intramolecular N-alkylation to produce quaternary ammonium salt. The reaction pathways for the formation of quaternary ammonium salt and isomethyl propyl phosphonate remain unexplored. In this report, the mechanistic pathways of G-series nerve agents sarin and its simulant diethylcholorophosphate (DCP) with Kemp's triacid derivatives has been explored computationally. The calculations performed with B3LYP-D3/6-311+G(d,p) level of theory in DCM solvent revealed that the reaction proceeds via intermolecular and intramolecular SN2 pathways. The probe molecule is sterically hindered, therefore, the frontside and backside SN2 reaction pathways have been examined. The computed results suggest that the first intermolecular SN2 reaction of Kemp's triacid derivatives (I &II) with sarin for the backside attack is energetically favored compared to the frontside attack and the following intramolecular SN2 reaction is a barrierless process. The calculations performed with simulant diethylcholorophosphate (DCP) and Kemp's triacid derivatives (I &II) show that the reactions are energetically more facile compared to the nerve agent sarin molecule. The Distortion-Interaction model and ΔNBOSteric analysis showed that the back side is energetically favored over the front side attack in such SN2 reactions. The designed Kemp's triacid derivative (II) with phosphorus center for sensing sarin and (DCP) suggests that the size of the hetero centers are important to facilitate the reaction in the probe molecule.

Direct visualization of viscous dissipation and wetting ridge geometry on lubricant-infused surfaces

Drops are exceptionally mobile on lubricant-infused surfaces, yet they exhibit fundamentally different dynamics than on traditional superhydrophobic surfaces due to the formation of a wetting ridge around the drop. Despite the importance of the wetting ridge in controlling drop motion, it is unclear how it dissipates energy and changes shape during motion. Here, we use lattice Boltzmann simulations and confocal microscopy to image how the wetting ridge evolves with speed, and construct heatmaps to visualize where energy is dissipated on flat and rough lubricated surfaces. As speed increases, the wetting ridge height decreases according to a power law, and an asymmetry develops between the front and rear sides. Most of the dissipation in the lubricant ( >75%) occurs directly in front and behind the drop. The geometry of the underlying solid surface hardly affects the dissipation mechanism, implying that future designs should focus on optimizing the surface geometry to maximize lubricant retention.

Fresnel Diffraction Model for Laser Dazzling Spots of Complementary Metal Oxide Semiconductor Cameras.

Laser dazzling on complementary metal oxide semiconductor (CMOS) image sensors is an effective method in optoelectronic countermeasures. However, previous research mainly focused on the laser dazzling under far fields, with limited studies on situations that the far-field conditions were not satisfied. In this paper, we established a Fresnel diffraction model of laser dazzling on a CMOS by combining experiments and simulations. We calculated that the laser power density and the area of saturated pixels on the detector exhibit a linear relationship with a slope of 0.64 in a log-log plot. In the experiment, we found that the back side illumination (BSI-CMOS) matched the simulations, with an error margin of 3%, while the front side illumination (FSI-CMOS) slightly mismatched the simulations, with an error margin of 14%. We also found that the full-screen saturation threshold for the BSI-CMOS was 25% higher than the FSI-CMOS. Our work demonstrates the applicability of the Fresnel diffraction model for BSI-CMOS, which provides a valuable reference for studying laser dazzling.

A novel dual-band defected ground structure wearable microstrip patch antenna for breast tumor detection in biomedical applications

This paper presents a dual-band, low-profile wearable antenna for detecting breast tumors in biomedical applications. The antenna is designed on the FR4 substrate with an optimized dimension of 32 × 27.5 × 0.61 mm3. The compact rectangular patch is miniaturized by cutting the rectangular slots on the front side. The partial ground structure is used for moving the resonance frequency in the ISM band region and for giving the tripping result of the return loss. A breast phantom is created between the transmitter and receiver for detecting the tumor in the phantom model. The different sizes and positions of the tumor in the breast phantom provide different values of the return loss. The final optimized design of the antenna is operated at 2.43 GHz and 3.32 GHz with −35 and −24 return losses respectively. It has been observed from the simulated and measured results that the antenna has a negligible difference between the reflected coefficient, radiation pattern and gain. Afterward, the antenna is also checked for biocompatibility, which represents its good performance. The on-body analysis of the antenna represents a minor variation in the results. The Specific Absorption Ratio (SAR) value of the antenna is in the acceptable range as defined for the wearable device. It is a promising compact wearable antenna that can be used in biomedical applications.

Bilateral Production Shield Enabling Highly Efficient Perovskite Photovoltaics.

Enhancing the intrinsic stability of perovskite and through encapsulation to isolate water, oxygen, and UV-induced decomposition are currently common and most effective strategies in perovskite solar cells. Here, the atomic layer deposition process is employed to deposit a nanoscale (≈100nm), uniform, and dense Al2O3 film on the front side of perovskite devices, effectively isolating them from the erosion caused by water and oxygen in the humid air. Simultaneously, nanoscale (≈100nm) TiO2 films are also deposited on the glass surface to efficiently filter out the ultraviolet (UV) light in the light source, which induces degradation in perovskite. Ultimately, throughthe collaborative effects of both aspects, the stability of the devices is significantly improved under conditions of humid air and illumination. As a result, after storing the devices in ambient air for 1000h, the efficiency only declines to 95%, and even after 662h of UV exposure, the efficiency remains at 88%, far surpassing the performance of comparison devices. These results strongly indicate that the adopted Al2O3 and TiO2 thin films play a significant role in enhancing the stability of perovskite solar cells, demonstrating substantial potential for widespread industrial applications.

Experimental measurements of gamma-photon production and estimation of electron/positron production on the PETAL laser facility

This article reports the first measurements of high-energy photons produced with the high-intensity PETawatt Aquitaine Laser (PETAL) laser. The experiments were performed during the commissioning of the laser. The laser had an energy of about 400 J, an intensity of 8 × 1018 W·cm−2, and a pulse duration of 660 fs (FWHM). It was shot at a 2 mm-thick solid tungsten target. The high-energy photons were produced mainly from the bremsstrahlung process for relativistic electrons accelerated inside a plasma generated on the front side of the target. This paper reports measurements of electrons, protons and photons. Hot electrons up to ≈35 MeV with a few-MeV temperature were recorded by a spectrometer, called SESAME (Spectre ÉlectronS Angulaire Moyenne Énergie). K- and L-shells were clearly detected by a photon spectrometer called SPECTIX (Spectromètre Petal à Cristal en TransmIssion pour le rayonnnement X). High-energy photons were diagnosed by CRACC-X (Cassette de RAdiographie Centre Chambre-rayonnement X), a bremsstrahlung cannon. Bremsstrahlung cannon analysis is strongly dependent on the hypothesis adopted for the spectral shape. Different shapes can exhibit similar reproductions of the experimental data. To eliminate dependence on the shape hypothesis and to facilitate analysis of the data, simulations of the interaction were performed. To model the mechanisms involved, a simulation chain including hydrodynamic, particle-in-cell, and Monte Carlo simulations was used. The simulations model the preplasma generated at the front of the target by the PETAL laser prepulse, the acceleration of electrons inside the plasma, the generation of MeV-range photons from these electrons, and the response of the detector impacted by the energetic photon beam. All this work enabled reproduction of the experimental data. The high-energy photons produced have a large emission angle and an exponential distribution shape. In addition to the analysis of the photon spectra, positron production was also investigated. Indeed, if high-energy photons are generated inside the solid target, some positron/electron pairs may be produced by the Bethe–Heitler process. Therefore, the positron production achievable within the PETAL laser facility was quantified. To conclude the study, the possibility of creating electron/positron pairs through the linear Breit–Wheeler process with PETAL was investigated.

Instability monitoring of molten pool in pure copper laser welding based on a multi-scale cascade model and spatial optical signals

During laser welding of pure copper, instabilities such as violent molten pool oscillation, large spatters, and melt ejection severely damage weld quality, which are caused by copper’s high reflectivity on commonly used infrared laser. The seriously unstable molten pool and keyhole and complicated laser-material interactions result in complex process signal emission waveforms, adding to the difficulties in process stability monitoring tasks. In this work, to break down different contents in the complex signals and deeply analyzing signal-process relation, combinative spatial optical sensor system was designed, and time-frequency signal analysis in multi-scale windows was performed. It was found that the infrared radiation at the front and end side of molten pool indicates the oscillation behavior of liquid metal surface, and the signal fluctuation patterns of visible radiation from different height of metal vapor varied when meeting severe instability like melt ejections. Signal features were extracted based on the understanding of process mechanism and signal behaviors. A cascade model combining Artificial Neural Network (ANN) and Support Vector Machine (SVM) was introduced to predict weld seam quality, where the ANN model focused on short-time stability status perception and the SVM model was used to decide macroscopic seam formation defects based on combining outputs of the ANN model in a long-term sampling window. Application results showed that the recognition accuracy of pit was 100 % and the accuracy of uneven toe reached 86.3 %. The multi-source signals of unstable molten pool recognized by the cascade model were summarized. The evolution process of copper molten pool ejection was revealed.

Synthesis, characterization and photoelectrochemical performance of Bi2Fe4O9 thin films

Mullite-type Bi2Fe4O9 has been little explored in thin film form as a photoanode for photoelectrochemical water splitting. In this study, Bi2Fe4O9 thin films have been prepared using the sol-gel technique from a simple precursor solution based on the corresponding metal salts, acetic acid, and polyvinyl alcohol. The films were deposited by dip-coating onto fluorine-doped tin oxide substrates and dried at 350 °C, repeating the dipping-drying cycle six times, and finally sintered at 600 °C. The films were characterized by GIXRD, revealing the formation of the material in its orthorhombic phase. Raman spectroscopy showed the Ag and B1g vibrational modes, validating the formation of the bismuth iron oxide. UV–Vis transmittance measurements revealed that the material exhibits two optical transitions: a direct band gap of 2.86 eV and an indirect band gap of 1.98 eV. FESEM micrographs and AFM images showed a uniform nanostructured surface morphology. The photoelectrochemical properties of the Bi2Fe4O9 films were studied using cyclic voltammetry and chronoamperometry with front side illumination, demonstrating the stability of the material in aqueous media and the generation of photocurrent in the presence of H2O2. Furthermore, results from intensity-modulated photocurrent spectroscopy (IMPS) revealed that the photocurrent is limited by both bulk and surface recombination and a short hole diffusion length.

Fabrication of PSCs with light absorption chips utilizing double-metal-cladding waveguide technology

Metal nanoparticles or periodic metal nanostructures exhibit localized surface plasmon resonance (LSPR) effects, widely employed in photovoltaic devices to enhance the light absorption. In this study, we used a double-metal-cladding waveguide (DMCW) structure to fabricate hexagonal metal nanostructures on the front side of the indium tin oxide (ITO) glass, positioned away from the incident light direction. We then prepared perovskite solar cells under various reaction conditions. The analysis results indicate that the metal nanostructure chip excites near-field coupling, generating strong localized fields, and enhances the light absorption through the LSPR effect. The perovskite solar cells (PSCs) with the chip structures exhibited a significant increase in short-circuit current density (JSC) and fill factor (FF), accompanied by a decrease in dark current, indicating improved photovoltaic characteristics of the cells. Altering the evaporative deposition time of the silver film and the concentration of the reaction solution led to a 12.79% increase in the power conversion efficiency (PCE) of the PSCs.

Effects of position layout and length gradient of two side ducts of on methane/air explosion in a tube

ABSTRACT In order to examine how two side ducts affect the dynamic behavior of a gas explosion in a tube, two side ducts were added to a tube containing a mixture of 9.5% methane and air. An experiment was conducted to release the explosion pressure and study how the position and length gradient of the side ducts influence the explosion’s overpressure and the speed at which the flame spreads. Based on the data, it was found that the most effective pressure release occurred at a length of 0.2 m for the front side duct and 0.1 m for the end side duct. Additionally, the greatest explosive overpressure recorded was 2.54 kPa. A double driving effect was created between the two side ducts when they were put in the front and middle and the middle and end locations. This increased the flame propagated speed. The greatest acceleration effect on the flame front occurred at 0.2 m of side duct length. When the two side ducts were placed at the front and end of the tube, the length gradient did not have any impact on flame propagation. Instead, it was predominantly the length of the front side duct that controlled flame propagation. The pressure relief effect was more pronounced when the two side ducts had a downward gradient; however, it was affected by the length of the end side duct. A relationship equation was established between the lengths of the two side ducts (d 1 and d 2), positioned at the front and end locations, and the maximum flame velocity (Vmax). The analysis results of the impact of different positioning layouts and length gradients of two side ducts on flame propagation and pressure release within the tube were instrumental in ensuring the safety of personnel, equipment, and environment during energy utilization processes.

Photocatalytic oxidation of n-decane in a NETmix photoreactor: Insights into the reactor geometry and illumination mechanism

This study focuses on the gas-phase photocatalytic degradation of n-decane using a NETmix photoreactor illuminated by UVA light-emitting diodes. The photoreactor is a static mixer composed of a network of cylindrical chambers interconnected by prismatic channels imprinted in a stainless-steel slab sealed with a borosilicate glass slab (reactor window with 55.7 cm2 of illuminated area). Photocatalytic performance was evaluated as a function of the flow rate (0.67 to 15 L min−1), corresponding to Reynolds number (Re) from 54 to 1209, using NETmix plates with 1 mm (92.3 cm2) and 3 mm depth (165.4 cm2), under back-side (BSI) and front-side (FSI) illumination mechanisms. The TiO2-P25 loading over the borosilicate slab (25–100 mg; BSI optimal: 75 mg) and stainless-steel slabs (100–400 mg; FSI-1/FSI-3 optimal: 200/400 mg) was optimized. Within system constraints, higher Re corresponds to increased reaction rate, apparent quantum yield, and reactivity, with decreased degradation efficiency, due to a reduction in the residence time, regardless of the reactor geometry and illumination. Moreover, operating at the same Re, the NETmix plate with 3 mm depth achieves reaction rates 2.2-/1.9-fold higher than 1 mm, considering FSI/BSI mechanisms. The results were consistent with applied experimental conditions and ray tracing simulations, indicating superior kinetic performance with higher catalyst superficial area. Ray tracing was coupled with Computational Fluid Dynamics (CFD) simulations to evaluate n-decane single-pass oxidation. A 94 % n-decane maximum experimental conversion was attained for a Re of 54, representing an error of ∼ 6.6 % compared to CFD simulation. In these conditions, only 1 % of n-decane was not mineralized, being identified aldehydes, alkanes, carboxylic acids, and ketones as the main reaction by-products. The influence of relative humidity (2 %-40 %) and n-decane inlet concentration (15–114 ppm) were also investigated.

Investigation of Cu Corrosion Defects Induced by Humidity Imbalance in the Cu Damascene Process of Semiconductors

As integrated circuit design rules shrink in semiconductor, Copper (Cu) has been employed as the back end of line (BEOL) interconnect metal to enhance device performance through reduced resistivity and resistive-capacitive delay.[1] However, Cu metal lines are prone to degradation caused by Cu oxidation-induced defects, including extrusions and voids, owing to their inherent properties.[2] Consequently, it becomes essential to regulate the oxidation rate during the chip fabrication process, particularly when the Cu metal line is exposed during the Damascene process. This control is crucial for ensuring long-term reliability and achieving a higher yield.[3]From the learning of earlier technological nodes, we are aware to and already precisely controlling both process queue time and wafer surface humidity. We must exercise control over the queue time, addressing both inter-process intervals and in-process queuing. [4] This underscores the importance of managing queue time and maintaining low environmental humidity to mitigate wafer surface defects when the FOUP (Front Opening Unified Pod) is opened at the EFEM (Equipment Front End Module).[5] Those humidity and queue times related Cu corrosion defects have been mitigated by N2 purge in FOUP and reducing the wafer quantity. However, dividing the lot, typically consisting of 25 wafers, by half or less to reduce queue times leads to an imbalance in low humidity due to N2 purging. This occurs when the FOUP is opened in EFEM.This paper examines Cu corrosion under low humidity conditions in a FOUP with a small quantity of wafers, specifically examining the influence of queue time during N2 purging in the EFEM. Through simulation of the interaction between the inlet air entering the EFEM and the purged N2 gas, a vulnerable area is identified where copper oxidation takes place. In addition, we propose an arrangement to mitigate high humidity, supported by experiments conducted under real equipment conditions.Fig. 1 shows Cu corrosion defects after ILD etching at around 20% RH in the FOUP. This defect is only observed in the lower slot of the FOUP on the N2 purged load port. Figure 2 illustrates a chart depicting the humidity inside the FOUP under various conditions. The humid region within the FOUP when opened on the N2 purged load port without wafers. (Fig.2a) While the extent of the humid area is contingent upon the flow rate of the N2 purge and the intake of air through the Fan Filter Unit (FFU), the vortex of the inlet air from the cleanroom (<42% RH) is notably observed at the bottom and front side of the FOUP. Therefore, wafers stored in the lower slot of the FOUP face an increased risk of Cu corrosions when subjected to elevated humidity levels during processes like ILD etching and subsequent cleaning. Specifically, an extended queue time amplifies the probability of Cu defects occurring in this high-humidity slot compared to slots with lower humidity. We observed an unintended increase to 28.2% RH in specific configurations when reducing the quantity of wafers to minimize queue time. (Fig. 2b)Hence, we propose an arrangement for wafers that maintains low humidity with small quantity. When placing 12 wafers in the FOUP, an arrangement with equal spacing from the first slot to the 25th slot ensures uniform N2 flow, thereby reducing the highest humidity from 28.2% RH to 14.0% RH by half. (Fig.3a) Alternatively, positioning all wafers on the upper section is another method. (Fig.3b) Therefore, by halving the quantity of wafers and reducing the process wait time by half, and applying the optimal wafer arrangement that maintains low humidity balance even with a small number of wafers, we confirmed the absence of Cu corrosion.

Qualification Methodology for the Double Side Printed Substrate for Hybrid Microcircuits Application

Hybrid Microcircuits (HMCs) are always preferred over discrete versions due to small size, less weight, better performance and high reliability for space applications. Double side printed substrates realized using Thick film screen printing and Printed Through Hole (PTH) processes are being used in HMCs in order to achieve further miniaturization. This article details the newly developed innovative Thick film process technology involving drilling of holes and filling the through hole with gold conductive paste to connect the front and rear side of conductor patterns on an alumina substrate. The biggest challenge in the realization of double side printed substrates is creating multiple via holes and filling them with conductor paste. In addition, the limited ability to achieve substrate integration and uniformity pose additional challenges that require optimization of process parameters. A comprehensive test plan created to qualify this innovative method in terms of quality and reliability suitable for the aerospace industry is also presented.

The Role of Luminescent Coupling in Monolithic Perovskite/Silicon Tandem Solar Cells.

Luminescent coupling (LC) is a key phenomenon in monolithic tandem solar cells. This study presents a nondestructive technique to quantitatively evaluate the LC effect, addressing a gap in the existing predictions made by optical modeling. The method involves measuring the ratio of photons emitted from the high bandgap top cell that escape through the rear, contributing additional current to the bottom cell, and to those escaping from the front side of top cell. The findings indicate that in the analyzed monolithic perovskite/silicon tandem solar cells, more than 85% of the emitted photons escaping from the perovskite top cell are used to generate additional current in the bottom cell. This process notably reduces the mismatch in the generated current between each subcell, particularly when the current is limited by the low bandgap subcell. The presented method is applicable to a variety of monolithic tandem structures, providing vital information for subcell characterization, providing vital information for predicting energy output and optimization for outdoor applications.

A Split Square-shaped Metamaterial Loaded Microstrip Patch Antenna for 5G Communication

This paper describes a split square-shaped metamaterial (MTM) design which was applied for the performance enhancement of a rectangular-shaped microstrip patch antenna (MPA). A proposed split square-shaped MTM-based microstrip patch antenna resonates at two frequencies, 18.57 GHz and 25.24 GHz. In both cases, the bandwidths were obtained at 2 GHz and 6.72 GHz respectively. The proposed antenna was designed on FR-4 substrate material, with the dimensions of 20×20 mm2. For the performance investigation, the MTM was placed first at the front side of the antenna and subsequently placed at the back side of the antenna. It was found that the antenna showed better performance when the MTM was placed at the back side of the antenna instead of the front side. The wide bandwidth, high directivity and enhanced gain have made the antenna a potential one for the 5G communication.

A wideband bianisotropic FSS absorber with angular stable and polarization-insensitive properties

This paper introduces a bi-anisotropic frequency selective surface (BFSS) that provides absorption from one illuminating side, and partial reflections (PR) from the other illuminating side, along with non-zero in-band (IB) and out-of-band (OB) transmissions. When an x-polarized or y-polarized wave is incident on the front side of the BFSS, over 90% of the incident waves are absorbed in the frequency band of 13.1–13.6 GHz. Similarly, when the back side of the BFSS is excited with an x-polarized or y-polarized incident wave, almost 85% of the incident wave is reflected (PR) in the frequency band of 13.1–13.6 GHz. Moreover, due to the absence of a complete ground plane, in-band (IB) and out-of-band (OB) transmissions are achieved in the frequency bands of 13.1–13.6 and 11.1 GHz to 12.3 GHz, respectively. The proposed structure behaves the same against the oblique incident angle up to 60°. Besides, the BFSS response remains consistent against any arbitrary oriented linearly polarized wave or circularly polarized incident wave. The proposed BFSS with simultaneous absorption, PR, IB transmission, OB transmission, polarization insensitivity, and angular stability is a vital candidate for various microwave applications.

First report of Alternaria alternata causing leaf spot on Polygonatum kingianum in China.

Polygonatum kingianum is a Chinese herbal medicine that belongs to the genus Polygonatum of the family Liliaceae. In June 2023, Polygonatum kingianum Coll. et Hemsl. in nurseries in Qujing, Yunnan Province, China, showed irregular brown spots on the leaves, whole leaf necrosis, and plant death in serious cases, with an incidence of 10-20% (Fig. S1). To identify the pathogens of P. kingianum, six diseased samples were collected from nurseries with 0.6 acre. These diseased sample leaves were soaked in 0.1% HgCl2 for 1 min and 75% ethanol for 2 min and then rinsed thrice with sterile water. Treated leaves were cut into small pieces (5×5 mm) and cultured on potato dextrose agar (PDA) for five days at 28°C. Total thirteen fungal strains were isolated from PDA medium. The nuclear ribosomal internal transcribed spacer of ribosomal DNA (ITS rDNA) region of these 13 strains was amplified by polymerase chain reaction (PCR) using universal primers ITSI/ITS4 (White et al. 1990). Sequencing and BLAST of the ITS region on NCBI showed that 11 out of 13 fungal strains belonged to the genus Alternaria, with an identity ≥99%. We selected one of the Alternaria strains, HJ-A1, for further study. The HJ-A1 colony appeared grayish brown white-to-gray with a flocculent texture on the front side and a dark gray underside on the PDA medium (Fig. S1). The conidiophores appeared brown, either single or branched, and produced numerous short conidial chains. The conidia were obclavate to obpyriform or ellipsoid in shape and contained 1-4 transverse septa and 0-2 oblique septa. The conidial diameter was 27.30µm in length and 12.27µm in width. (Fig. S1). To further determine the species of HJA1, the genomic DNA of HJ-A1 was extracted using the Lysis Buffer for PCR (AG, Hunan, China). Four Alternaria genomic DNA regions including the ITS, translation elongation factor 1-α gene (TEF1-α), glyceraldehyde-3-phosphate dehydrogenase (GAPDH), and Alternaria major allergen gene (Alt a1) were amplified by PCR using the primers as previously reported (Woudenberg et al. 2013, Hong et al. 2005). Sequence analysis revealed that the ITS (484bp) of HJ-A1 (NCBI No. PP082633), TEF1-α (267bp) of HJ-A1 (NCBI No. PP419893), GAPDH (582bp) of HJ-A1 (NCBI No. PP419892), and Alt a1 (522bp) of HJ-A1 (NCBI No. PP228046) shared the highest identity with A. alternata respectively (99≥%). A maximum likelihood phylogenetic tree was constructed with the combined sequence data sets of ITS, GAPDH, TEF, and Alt a1 using MEGA 7. The results showed that HJ-A1 strain clustered with A. alternate (Fig. S2). The pathogenicity of HJ-A1 was tested according to Koch's postulates by inoculating HJ-A1 conidia suspension (2×105 conidia/mL) into leaves of 1-year-old P. kingianum, with sterile water as a control. Each treatment group included 3 plants with 3 replicates. The tested plants were planted in a phytotron at 28℃ and 90% humidity. Three days after inoculation, symptoms similar to those under natural conditions were observed in the HJ-A1-inoculated plants, whereas no symptoms were observed in the control plants (Fig. S1). The same fungal strains were re-isolated from inoculated leaves and identified by morphologically and sequence of ITS. Previous studies showed that Alternaria alternata funji cause many plant diseases, such as fig fruit rot (Latinović N et al. 2014)，daylily leaf spot (Huang D et al. 2022), fruit blight on sesame (Cheng H et al. 2021)，leaf spot of Cynanchum atratum Bunge (Sun H et al. 2021) and so on. To our knowledge, this is the first report of A. alternata causing P. kingianum leaf spot in China. The discovery of this pathogen will help to guide the protection and control of P. kingianum disease.

TCAD simulation of germanium-based heterostructure solar cell employing molybdenum oxide as a hole-selective layer

Molybdenum Oxide (MoO x ) has been used as a hole-extraction film for photovoltaic (PV) applications; however, its interaction with Germanium (Ge)-based solar cells is less understood. For the first time, this paper aims to physically model the Ge solar cell that incorporates MoO x for hole transportation at the front side of the PV device facing the sunlight. However, the charge transportation process within the PV device is influenced by several design parameters that need optimization. A higher work function of MoO x increases the barrier height against minority carriers of electrons which is beneficial for extricating holes at the front interface of MoO x /Ge. A progressive reduction in the recombination of charge carriers has been observed by including a passivation layer of amorphous silicon (i-a-Si:H). Similarly, inserting a passivation and back surface field (BSF) stack of i-a-Si:H strengthens the electric field and likewise reduces the recombination at the rear side of the device. An enhanced doping concentration of BSF assists in the favorable alignment of energy bands for improved charge transportation within the solar cell as the rear passivation maintains the field strength for accelerated movement of charge carriers. However, optimizing the thickness of the front-passivation film is challenging due to the parasitic absorption of light at larger thicknesses. A comparative study with the reference device revealed that the proposed device exhibited a step-increase in the conversion efficiency (η) from 4.23% to 13.10%, with a higher J sc of 46.4 mA cm−2, V oc of 383 mV, and FF of 74%. The proposed study is anticipated to meet the research gap in the physical device modelling of Ge-based solar cells employing high work function MoO x as a carrier-selective layer that could be conducive to the development of highly efficient multijunction solar cells.