We report on the first characterization of the frequency transfer performance of the GPS precise point positioning with carrier-phase integer ambiguity resolution (PPP-AR) implemented by the Natural Resources Canada (NRCan) online service CSRS-PPP. We show that continuous PPP-AR links of multiple days can be formed by carefully fixing the day boundary phase discontinuity. The stability of the links can reach and (Allan deviation) at 1 d and 7 d averaging times, respectively, and mid to low 10−17 at 20 d–30 d. We compared the atomic fountain primary frequency standards (PFS) between NRC in Ottawa, Canada and PTB in Braunschweig, Germany for 135 d via GPS PPP-AR and precise point positioning links. The NRC and PTB PFS agree within a few parts in 1016, which is well below the combined systematic uncertainty. It is expected that with uncertainty at 10−17, the PPP-AR links will become a powerful tool for remote comparisons of atomic optical clocks, essential for the future redefinition of the SI second.