Frequency Dependence Of Permittivity Research Articles

Interpretation of dielectric spectroscopy measurements of ferroelectric nematic liquid crystals

The magnitude of the relative permittivity of the ferroelectric nematic phase (NF) has been the subject of lively scientific discussion since the phase was recently discovered. Dielectric spectroscopy measurements (DSMs) give a huge value of relative permittivity, which depends on the cell thickness, but this is argued to result from a misinterpretation of the DSM results. We have conducted DSM using a set of cells differing in thickness of the NF layer, type of electrodes, and presence/absence of nanoscale-thick surface polymer layers. To model the DSM results, cells are presented by an equivalent electric circuit that includes a capacitor due to the NF layer with frequency dependent complex relative permittivity, capacitors due to surface layers, and a resistor describing the limited conductivity of electrodes. DSM results for different cells with the same liquid crystal in the NF phase are semiquantitatively reproduced by the same set of physical parameters if a huge relative permittivity of the NF, which is even orders of magnitude larger than the measured apparent values, is assumed. We show that the capacitance of surface layers should also be considered in cells with no polymer alignment layer on the electrodes. Published by the American Physical Society 2024

Effects of the material properties of the microstructured gap on the electromechanical behavior of a capacitive micro-devices

This paper presents a novel capacitive microelectromechanical system comprising an array of elastomeric micro-pillars, which has been developed through the introduction of a coupled set of three nonlinear equations. The results have demonstrated that the new model utilizing polydimethylsiloxane is effective in reducing the actuation voltage, although this efficiency is reduced when the temperature is decreased. Moreover, the impact of frequency-dependent permittivity and its relaxation time on the vibrations of the moving electrode has been examined. The provided model and procedure can be utilized to analyze the effects of other materials on the system’s performance and to enhance its sensitivity.

Tuning Dielectric Properties with Nanofiller Dimensionality in Polymer Nanocomposites.

Polymer nanocomposites hold great potential as dielectrics for energy storage devices and flexible electronics. The structural architecture of the nanofillers is expected to play a crucial role in the fundamental mechanisms governing the electrical breakdown and dielectric properties of the nanocomposites. However, the effect of nanofiller structure and dimensionality on these properties has not been studied thoroughly to date. This study explores the critical relationship between nanofiller dimensionality and dielectric properties in polymer nanocomposites. We fabricated polyvinylidene fluoride (PVDF) nanocomposites by incorporating a range of carbon-based nanofillers separately, including zero-dimensional (0D) carbon black (CB), one-dimensional (1D) multiwalled carbon nanotubes (MWCNT), 1D single-walled carbon nanotubes (SWCNT), two-dimensional (2D) reduced graphene oxide (rGO), and three-dimensional (3D) graphite. The frequency-dependent (1 kHz to 1 MHz) dielectric permittivity (k) of the nanocomposites at the same concentration of nanofillers demonstrated a hierarchical order, with MWCNT showing the highest permittivity (∼400%), succeeded by rGO (∼360%), CB (∼290%), SWCNT (∼230%), and graphite (∼70%), respectively. The temperature-dependent (50-150 °C) dielectric spectroscopy revealed high k with increasing temperature due to the enhanced dipole movement. However, their dielectric breakdown strength and energy densities were not correlated to k and exhibited the following order: SWCNT > MWCNT > CB > rGO > graphite. As the electrical breakdown depends upon the nanocomposites' mechanical strength, we correlated the mechanical properties with the nanofiller dimensionality, and Young's modulus followed the 1D ≈ 2D > 0D > 3D order. These findings will provide fundamental insights into designing tunable, conducive nanofiller-based nanocomposites in next-generation flexible electronics and capacitive energy storage devices.

Graphene-based metamaterial ultrawideband absorber with enhanced terahertz performance

In this paper, we present a graphene-based metamaterial ultrawideband absorber operating in the terahertz regime. The absorber is composed of two patterned and continuous graphene layers, a bottom gold layer, and a SiO2 substrate that separates the continuous graphene layer from the gold layer. The absorption spectrum is enhanced by integrating a graphene resonator with water, which has frequency-dependent permittivity. The water is encapsulated in polytetrafluoroethylene (PTFE) in the form of a circular ring sandwiched between the two graphene layers. Simulation results show that the absorber attains a 90 % absorption bandwidth of about 14.55 THz. The proposed absorber is polarization-insensitive under normal incidence. For TE polarization, the absorption level remains stable for incident angles θ from 0° to 55° across the entire frequency band (14.55 THz), except for the 5–8 THz range. For TM polarization, the absorption level remains stable for θ ranging from 0° to 60° over the entire bandwidth. Additionally, the absorption level is consistent for both TM and TE polarizations across the entire bandwidth for incident angles φ from 0° to 90°.

Finding the best frequency dependent performance of 3d transition metals (Co, Ni, and Mn) substituted nano magnetite for miniaturizing device applications

Ferrite samples with enhanced magneto-dielectric properties are more essential in electromagnetic applications. Therefore, a parent composition of Fe3O4 has been modified by substituting 3d transition metal elements (Co, Ni, Mn) at a single Fe atom using the co-precipitation synthesis method. The structural properties of the synthesized Fe3O4, NiFe2O4, CoFe2O4, and MnFe2O4 samples have been evaluated from the X-ray diffraction patterns. The surface morphology and microstructures of the studied samples were studied by field emission scanning electron microscopy and the average grain size of all the studied samples varied from 60.11 to 106.03 nm. The magneto-dielectric properties were analyzed by frequency dependent permeability (μ) and permittivity (ε) measurements for the range of 100 Hz to 100 MHz. The conduction process for the synthesized ferrites has been noticed from the ac conductivity (σac). The localized relaxation mechanism for the studied ferrites has been observed from the variation of imaginary portion of the electric modulus (M") and the impedance (Z"). Moreover, the mismatch (Z/ηο) between the impedance of the antenna substrates (Z) made of the studied samples and air (ηο) has been evaluated from the permeability and permittivity. Finally, NiFe2O4 has been derived as a suitable ferrite for miniaturizing devices over a frequency range of 10 kHz-6.5 MHz.

Electrical transport characteristics of rare earth ions (Er³⁺, Sm³⁺) exchanged cobalt-manganese ferrite using impedance spectroscopy

This study presents findings on the AC impedance characteristics of rare earth-doped Co0.5Mn0.5RExFe2-xO4 ferrites (where RE = Er and Sm, and 0.0 ≤ x ≤ 0.1), synthesized utilizing the citrate auto-combustion process. Employing impedance spectroscopy at frequencies ranging from (100 −1 MHz) and temperatures between 30°C and 120°C, we distinguished the impact of grains (Gs) and grain boundaries (GBs) in these compositions. The Jonscher power law was applied to characterize the AC conductivity results. The dielectric constant έ and dielectric loss ε” decline as the frequency rises and reach a stable state at higher frequencies, indicating the characteristic dielectric dispersion. This phenomenon manifests the Maxwell-Wagner polarization, as described by Koop's hypothesis. The modified Debye formula provides a good match for the frequency-dependent dielectric permittivity fluctuation. The Cole-Cole plots revealed a single semicircle for the unaltered sample and lower Er³⁺ concentrations (up to x=0.02), but two semicircles appeared at higher Er³⁺ concentrations and in the Sm³⁺ doped samples. The G and GB resistances increased with higher concentrations of Er³⁺/ Sm³⁺ but showed a decrease at x=0.1 in Sm³⁺-doped samples. The data examination designates that the resistive and capacitive possessions are predominantly affected by G and GB processes. A relaxation phenomenon in the existing samples is shown by the frequency-dependent of the imaginary portion of impedance (Z"). Remarkably, the relaxation time (τz) showed linear temperature dependence. Additionally, studies of the electrical modulus (M’ and M”) highlighted non-Debye sort dielectric relaxation in all compositions, with peaks in the imaginary modulus indicating a shift in charge carrier mobility from long-range toward short-range. The investigation focused on the non-Debye relaxation, which was analyzed by determining the stretching exponential parameter (β). This factor was obtained by fitting the modified Kohlrausch-Williams-Watts (KWW) formula to the graph of the imaginary electric modulus. The substitution of Fe3+ by Er3+ and Sm3+ ions substantially enhanced the dielectric properties, particularly Co-Mn-Sm ferrite series, suggesting their potential use in high-frequency devices.

Microwave dielectric properties of normal, fibroelastotic, and malignant human lung tissue

Technological development of microwave treatment and detection techniques for lung cancer requires accurate and comprehensive knowledge of the microwave dielectric properties of human lung tissue. We characterize the dielectric properties of room temperature human lung tissue from 0.5 to 10 GHz for three lung tissue groups: normal, fibroelastotic, and malignant. We fit a two-pole Debye model to the measured frequency-dependent complex permittivity and calculate the median Debye parameters for the three groups. We find that malignant lung tissue is approximately 10% higher in relative permittivity and conductivity compared to normal lung tissue; this trend matches previously reported normal versus malignant data for other biological tissues. There is little contrast between benign lung tissue with fibroelastosis and malignant lung tissue. We extrapolate our data from room temperature to 37 °C using a temperature-dependence model for animal lung tissue and use the Maxwell-Garnett dielectric mixing model to predict the dielectric properties of inflation-dynamic human lung tissue; both approximations correspond with previously reported dielectric data of bovine and porcine lung tissue.

Dielectric relaxation spectroscopy of hybrid insulating nanofluids in time, distribution, and frequency domain

Improving the dielectric properties of insulating liquids belongs to the modern motivation to optimize the operation of high-voltage devices. Hybrid nanofluids can provide the mentioned improvement, and thus, it is necessary to reveal their hidden potential. This study investigates hybrid nanofluids with different concentrations of magnetite and fullerene nanoparticles, a separate fullerene and magnetic nanofluid, and a base carrier fluid based on gas-to-liquid technology. The investigated samples are subjected to dielectric relaxation spectroscopy analysis at three applied electric field intensities in the time, distribution, and frequency domain. The lack of information about the studied parameters of the mentioned nanofluids is another reason for our experimental measurements. A significant dispersion of the charging current characteristics of nanofluids with magnetic nanoparticles is observed. At lower electric field intensities, the increasing fullerene concentration of the hybrid nanofluids reduces the charging currents up to a charging time of 200 s. Magnetic nanofluid shows the highest values of conductivity currents. Experiments show that the suspension of fullerene in the base oil causes a higher charging current and a more pronounced relaxation response than pure base oil. Significant relaxation information in the low-frequency band is detected from the distribution spectra. At higher electric field intensities in the low-frequency spectrum, the relaxation peaks decrease when the concentration of fullerene in hybrid nanofluids increases. The distribution area shows the effect of higher polarizability of magnetite nanoparticles. Compared to lower electric field intensities, at the value of 333.3 kV/m, several polarization processes are captured in the entire frequency spectrum. The frequency-dependent complex permittivity confirms the findings from the time and distribution domains. Comparing the distribution domain with the frequency domain shows higher sensitivity and accuracy in capturing relaxation processes in the distribution domain.

Tunable Magnetic and Dielectric Properties of BaMg0.4Al0.4Fe11.2O19 and SiO2 Composites for High-Frequency Applications

This study focuses on the synthesis and characterization of Mg and Al co-doped M-type Barium hexaferrite (BaMg0.4Al0.4Fe11.2O19) powder via the sol-gel method. Structural analysis using X-ray diffraction (XRD) and Fourier transformation infrared spectroscopy (FTIR) confirmed the single-phase structure of the synthesized powder. Morphological properties were examined through field emission scanning electron microscopy (FESEM), revealing hexagonal particle morphology with an average size of approximately 60 nm for BaMg0.4Al0.4Fe11.2O19. To fabricate composites, commercially purchased SiO2 was used to prepare the composites of (1–x) BaMg0.4Al0.4Fe11.2O19+ (x) SiO2 {where x = 0.0, 0.1, 0.3, 0.5 and 0.7). The composites were prepared using the mixing method followed by microwave sintered at 1000 °C/90 min. FESEM and energy-dispersive X-ray spectroscopy (EDS) were employed to analyze the morphology and elemental composition of the composites. The composites ‘ frequency-dependent complex permittivity was measured over 300 kHz to 3 GHz. Magnetic hysteresis (M-H) loops were used to analyze the magnetic properties of composite samples. A reduction in magnetic saturation was observed with increasing SiO2 concentration, while there was a slight increase in coercivity for the composite samples compared to pure hexaferrite. Coercivity remained relatively unchanged with varying SiO2 concentrations in the composites. A possible relation between the magnetic and dielectric properties and the microstructure of the sintered composites with the composition variation was investigated.

Frequency-Dependent Dielectric Permittivity and Water Permeability in Ordered Mesoporous Silica-Grafted Fluorinated Polyimides.

Polymers with a low dielectric constant (Dk) are promising materials for high-speed communication networks, which demand exceptional thermal stability, ultralow Dk and dissipation factor, and minimum moisture absorption. In this paper, we prepared a series of novel low-Dk polyimide films containing an MCM-41-type amino-functionalized mesoporous silica (AMS) via in situ polymerization and subsequent thermal imidization and investigated their morphologies, thermal properties, frequency-dependent dielectric behaviors, and water permeabilities. Incorporating 6 wt.% AMS reduced the Dk at 1 MHz from 2.91 of the pristine fluorinated polyimide (FPI) to 2.67 of the AMS-grafted FPI (FPI-g-AMS), attributed to the free volume and low polarizability of fluorine moieties in the backbone and the incorporation of air voids within the mesoporous AMS particles. The FPI-g-AMS films presented a stable dissipation factor across a wide frequency range. Introducing a silane coupling agent increased the hydrophobicity of AMS surfaces, which inhibited the approaching of the water molecules, avoiding the hydrolysis of Si-O-Si bonds of the AMS pore walls. The increased tortuosity caused by the AMS particles also reduced water permeability. All the FPI-g-AMS films displayed excellent thermooxidative/thermomechanical stability, including a high 5% weight loss temperature (>531 °C), char residue at 800 °C (>51%), and glass transition temperature (>300 °C).

Comments on the dielectric spectroscopy results on a new series of fluorinated hydrogen-bonded liquid crystals

Recently, a work entitled “Synthesis, thermal, dielectric and electro-optic properties of new series of fluorinated hydrogen-bonded liquid crystals” is published by M. Derbali et al., in J Mol Liq, 367 (2022) 120510. Authors reported SmA and SmC mesophases in the synthesised liquid crystalline materials. However, dielectric data reported here are erroneous when tested even from some fundamental aspects. Inadvertent omissions by the authors in presenting and explaining the dielectric results in terms of frequency dependent permittivity and loss are discussed here so that appropriate precautions may be taken by the readers to avoid such fundamental gross mistakes. Some problems related to other studies are also discussed in brief.

Ferroelectric and antiferroelectric chiral multilactate liquid crystalline materials with negative dielectric anisotropy

In this work, the mesomorphic, electro-optic and dielectric properties have been discussed in the light of molecular structure-property correlations of two chiral multilactate liquid crystalline materials possessing the orthogonal paraelectric Smectic A* phase, tilted ferroelectric Smectic C* phase and the tilted antiferroelectric Smectic CA* phase, over a substantially broad temperature range. Interestingly, a reasonably rare re-entrant Smectic C* phase (SmCre*) has also been identified in one of the investigated materials. These materials differ in their linkage groups (keto or ether) and an additional chiral unit in the terminal chain. The phase transition temperatures and transition enthalpies were determined from Polarizing Optical Microscopy and Differential Scanning Calorimetry (DSC) measurements. The compounds exhibit negative dielectric anisotropy (Δε) throughout the mesomorphic range (maximum −18 and −4 in SmA* for both the compounds) and moderately high values of spontaneous polarization (∼153 nC/cm2 in SmCre* phase). The temperature dependence of the response time (τ), bulk viscosity (η) and the activation energies (Ea) throughout the mesomorphic phase have been determined from the spontaneous polarization measurements. To emphasize the structure-property correlations in more detail, dielectric spectroscopy measurement has also been performed to measure the dielectric strength, dielectric loss, frequency dependent permittivities, relaxation time and relaxation frequencies. The clear evidence of the relatively rare SmCre* phase has also been confirmed from the temperature and frequency dependence of the dielectric permittivity. These results shed important light on the emergence of these materials as a smart alternative for their application in multicomponent mixtures targeted for advanced electro-optic and photonic devices.

Crystal structure and dielectric properties of Ln2Ti2SiO9 (Ln = Pr and Nd)

Low loss and high dielectric constant materials are essentially desired for wide varieties of applications in electronics and communication technology. Herein the structure and dielectric properties of two titanosilicates, Ln2Ti2SiO9, for Ln = Pr3+ and Nd3+ are reported. Both materials are isostructural and have layered structure with layers of [LnTi2SiO9]3- and Ln3+ ions. Electrical properties of both have been analyzed by using the temperature and frequency dependent permittivity, loss, conductivity and modulus data. At room temperature, appreciable relative permittivity (35 for Nd2Ti2SiO9 and 22 for Pr2Ti2SiO9 over the frequency range of 100 Hz to 5 MHz) and low dielectric loss (like 0.007–0.03 at 100 Hz and 10−4-10−3 at 1 MHz). Analysis of dc-conductivity data of both compounds indicate that the conduction in both materials is due to the correlated barrier hopping (CBH) of polarons. The relaxation peak of modulus spectra indicates more non-Debye like relaxation in Pr2Ti2SiO9 than that in Nd2Ti2SiO9, and that is possibly due to increased correlation in the dynamics of hopping polarons in Pr2Ti2SiO9.

Surface plasmon induced quantum interference at meta-material interface

In this work we investigate quantum interference in a four-level atom coupled to a negative index meta-material (NIMM) anisotropic plasmonic environment that supports both TE and TM polarized surface plasmons (SP). The analysis confirms the creation of the anisotropic environment and two dipoles can interfere with each other even if they are orthogonal by sharing such SP modes. The NIMM/plasmonic environment provides more options to control SP interaction with emitters and their spontaneous emission decays and spectrum. The spectrum depends critically on structure parameters, mode frequency, frequency dependent electric permittivity and magnetic permeability, and the location of the atom etc. We observe orders of magnitudes enhancement in the plasmonic-modified decays and spectrum compared to free space case.

Permittivity analysis of weathered concrete in a bridge based on open-ended probe and impedance measurements

Pathologies like corrosion of rebars or alkali aggregate reactions in a reinforced concrete (RC) bridge are usually accompanied by the existence of aqueous pore solutions with a high concentration of ions. The distribution of aqueous solutions in the concrete is inhomogeneous and depends on the RC’s location in the bridge and complex climate factors. Frequency-dependent complex permittivity is sensitive to aqueous pore solutions because the high conductivity caused by charge carriers can result in a large imaginary part of the permittivity, much higher than that caused by water. In this study, we used a non-destructive open-ended probe to measure the complex permittivity of the RC in a bridge’s pillar with different levels of pathologies. By measuring the impedance of core samples with various controlled water volumetric fractions in the laboratory, the water effect on the evolution of the loss tangent (the ratio between the imaginary part of the permittivity and the real part) can be calibrated. Comparing the loss tangent in the bridge with that of the core samples treated by water, we can map the areas with a high density of aqueous pore solution and cracks, and estimate the unhealthy area with partial damage in the pillar by an effective and non-destructive diagnosis.

Split-ring resonator with interdigital Split electrodes as detector for liquid and ion chromatography

The analysis of food and drugs as well as the monitoring of chemical processes and bioreactors by high-performance liquid chromatography and ion chromatography requires universal, cost-effective, and sensitive detectors. Therefore, this work presents a split-ring resonator that detects changes in the electrical and dielectric properties of the eluate from liquid chromatography or ion chromatography by monitoring the amplitude of the transmitted signal using an envelope detector. The used split-ring resonator consists of a simple printed circuit board featuring two microstrip lines. One is formed to a ring with interdigital split electrodes. The interdigital split electrodes forming the sensitive area significantly enhance the sensitivity to changes in relative permittivity, dielectric losses and electrical conductivity of the eluate In addition, the split-ring resonator is a small, inexpensive and easy-to-use detector that uses several dielectric parameters simultaneously for the measurement. Furthermore, the split-ring resonator measures these parameters at a significantly lower frequency than optical detectors and therefore measures different changes in frequency-dependent permittivity. For demonstrating feasibility of a split-ring resonator as a detector for high-performance liquid chromatography and ion chromatography, various anion and cation standards, basic and acidic amino acids, sugars, as well as sugar alcohols were separated and detected. A conductivity detector for ion chromatography and a refractive index detector for high-performance liquid chromatography were used as reference detectors.

A New Method for Calculating the Hamaker Constant Based on the Hansen Solubility Parameters for Non-Polar Liquids

A simple relationship between the Hamaker constant and the Hansen solubility parameters for non-polar liquids is derived by combining a Hamaker constant/surface tension relationship derived by Israelachvili and a Hansen solubility parameters/surface tension relationship derived by Abbott. With this relationship, one can easily estimate the Hamaker constant of non-polar liquids on the basis of the database of the Hansen solubility parameters. This is an entirely new method for calculating the Hamaker constant without recourse to data on the frequency-dependent dielectric permittivity of those substances (which are required for the rigorous Lifshitz theory) and laborious numerical calculations.

Study of permeability and permittivity of [formula omitted]-Fe[formula omitted]O[formula omitted] using computer simulation method

This study proposes a computational method to directly obtain the frequency-dependent permeability and permittivity of materials from computer simulation data. The method combines first-principles calculations, Green’s function formalism, and magnetic moment dynamics simulations. Using α-Fe2O3 as an example, we demonstrate the validation process of the computational approach. By calculating the time correlation functions of electric and magnetic dipole moments and applying linear response theory, we successfully obtained the frequency-dependent permeability and permittivity of α-Fe2O3 at 300 K. The calculated results agree well with experimental values, proving the efficacy of the proposed computational method. This study provides a reliable computational pathway to predict electromagnetic parameters of materials using computer simulations.

Time-domain modeling of interband transitions in plasmonic systems

Efficient modeling of dispersive materials via time-domain simulations of the Maxwell equations relies on the technique of auxiliary differential equations. In this approach, a material’s frequency-dependent permittivity is represented via a sum of rational functions, e.g., Lorentz poles, and the associated free parameters are determined by fitting to experimental data. In the present work, we present a modified approach for plasmonic materials that requires considerably fewer fit parameters than traditional approaches. Specifically, we consider the underlying microscopic theory and, in the frequency domain, separate the hydrodynamic contributions of the quasi-free electrons in partially filled bands from the interband transitions. As an illustration, we apply our approach to gold and demonstrate how to treat the interband transitions within the effective model via connecting to the underlying electronic band structure, thereby assigning physical meaning to the remaining fit parameters. Finally, we show how to utilize this approach within the technique of auxiliary differential equations. Our approach can be extended to other plasmonic materials and leads to efficient time-domain simulations of plasmonic structures for frequency ranges where interband transitions have to be considered.

Health assessment of converter transformer pressboard insulation based on FDS and digital image processing

The stable operation of the converter transformer is an essential task for power system operation reliability and security. Nowadays, Frequency domain spectroscopy (FDS) technology is prominently utilized for assessing oil-impregnated pressboard insulation. The present study examines the effect of the pressboard insulation material as a function of frequency and elevated temperature. The experimental analysis on oil-impregnated pressboard insulation is carried out at temperatures from 30 °C to 130 °C with an incremental rise of 20 °C intervals with frequency variation from 1 Hz to 10 MHz. The frequency-dependent permittivity, conductivity and loss tangent angle studies also confirm the deterioration of oil-impregnated pressboard insulation. The surface morphological changes inside the pressboard insulation are recorded with the help of scanning electron microscopy (SEM). The synergistic effect generated on pressboard insulation is examined by fiber width changeand image processing approach by randomly selecting the average of three local areas of SEM image. A canny operator is selected to extract the exact boundaries of images and more change is recorded in the edge detection count after 90 °C.The porosity and pore size distribution can be increased with elevated temperatures. A single-phase, 315 MVA valve side star winding with 60 discs of single-phase converter transformers model is developed in MATLAB Simulink. An impulse of 100 kV, 1.2/50μsec is applied across the star winding to identify the pressboard insulation degradation derived from FDS data with the help of mathematical morphology and wavelet transform technique. The energy of the wavelet coefficient on the neutral current capture during the impulse test adds a significant contribution to analyzing pressboard insulation degradation. The results presented are in good agreement with the published work.