Freeze-thaw Conditions Research Articles

Experimental Study on Mechanical Characteristics of Stabilized Soil with Rice Husk Carbon and Calcium Lignosulfonate

In cold regions, the extensive distribution of silt exhibits limited applicability in engineering under freeze–thaw cycles. To address this issue, this study employed rice husk carbon and calcium lignosulfonate to stabilize silt from cold areas. The mechanical properties of the stabilized silt under freeze–thaw conditions were evaluated through unconfined compressive strength tests and triaxial shear tests. Additionally, scanning electron microscopy was utilized to analyze the mechanisms behind the stabilization. Ultimately, a damage model for rice husk carbon–calcium lignosulfonate stabilized silt was constructed based on the Weibull distribution function and Lemaitre’s principle of equivalent strain. The findings indicate that as the content of rice husk carbon and calcium lignosulfonate increases, the rate of improvement in the compressive strength of the stabilized silt progressively accelerates. With an increase in the number of freeze–thaw cycles, the deviatoric stress of the stabilized soil gradually diminishes; the decline in peak deviatoric stress becomes more gradual, while the reduction in cohesion intensifies. The decrease in the angle of internal friction is relatively minor. Microscopic examinations reveal that as the number of freeze–thaw cycles increases, the soil pores tend to enlarge and multiply. The established damage model for stabilized silt under freeze–thaw cycles and applied loads demonstrates a similar pattern between the experimental and theoretical curves under four different confining pressures, reflecting an initial rapid increase followed by a steady trend. Thus, it is evident that the damage model for stabilized silt under freeze–thaw conditions outperforms traditional constitutive models, offering a more accurate depiction of the experimental variations observed.

Development of New Method for Concrete Carbon Emission evaluation: The Anti-freezing durability-oriented Carbon Emission Indicator (CEI) System and its application in design of low carbon HPC with high durability

This research focuses on the development of the Anti-freezing Durability-Oriented Carbon Emission Indicator (CEI) system for assessing concrete's carbon footprint with an emphasis on durability, particularly in freeze-thaw conditions. This novel approach reduces the environmental impact of concrete by integrating durability metrics into carbon emission evaluations. The paper presents experimental findings on mix designs for high-strength, low-carbon concrete, which demonstrate improved freeze-thaw durability. And found out that concrete mixes using sulfate-resistant cement with GGBS outperform those with FA and OPC in terms of low-carbon performance, in the newly developed 19 mixes, concrete mix incorporating air-entraining agents with sulfate-resistant cement and 40% GGBS as a supplementary cementitious material, namely the HPC1-P•HSRF-S group, demonstrates a distinct low-carbon advantage across various indicators.Overall, the inclusion of fibers is shown to improve freeze-thaw durability, though with limited impact on compressive strength. The research underlines the importance of optimizing concrete mix designs for both environmental and durability considerations, presenting a significant step towards more sustainable construction practices.

A-057 Assessing Direct Renin Stability in EDTA Plasma Prior to Separation from Cells and Post-thaw

Abstract Background Renin is an enzyme secreted by the kidneys responsible for blood pressure regulation through the renin-angiotensin-aldosterone axis. Direct renin measurements are frequently used to investigate underlying causes of hypertension, including primary aldosteronism (PA), which is screened for using an aldosterone:renin ratio (ARR). Appropriate handling of renin samples in the preanalytical phase is critical, as cryoactivation of prorenin can occur when samples are refrigerated or cooled for extended periods of time, falsely elevating results. Manufacturer instructions for renin handling are often poorly defined and there is currently no consensus as to best handling practices. Two variables that frequently lead to renin sample rejections in our laboratory are time to centrifugation after collection and time kept at room temperature (RT). The objective of this study was to evaluate the stability of direct renin under ambient and freeze-thaw conditions in an effort to reduce test cancellations due to improper handling. Methods Plasma samples collected from five volunteers with consent in K2EDTA tubes were used for renin stability studies. Baseline renin samples were kept at RT for two hours after collection, centrifuged, measured, and subsequently frozen for post-thaw studies. To assess stability before separation from cells, samples kept at RT for two and four hours prior to centrifugation were assayed in triplicate for direct renin. For post-thaw stability studies, plasma samples were split into two aliquots each and frozen at -20⁰C for at least 24 hours, but no longer than 30 days. After removal from -20⁰C, one set of aliquots was thawed on the benchtop at RT and the second set was thawed in an RT water bath for up to one hour. Samples were centrifuged and assayed for direct renin in triplicate at baseline and six hours post-thaw. Direct renin was measured using the LIAISON XL chemiluminescent immunoassay (Diasorin). Bias was assessed after each treatment. The total allowable error (TEa) was ±2 pg/mL or ±20%. Results Measured renin concentrations ranged from 6.8-29.7 pg/mL. The percent bias in direct renin concentrations when comparing samples stored for two-hour and four-hour timepoints before centrifugation was 2.0% on average. Post-thaw studies comparing renin concentrations at the baseline and six-hour timepoints revealed an average percent bias of 13.1% and 12.2% for RT and water bath thawing methods, respectively. All samples tested were within the TEa. Conclusions Direct renin is stable in lavender K2EDTA tubes at RT for up to four hours, prior to centrifugation and separation from cells. Renin concentrations remained stable after storage at -20⁰C and thawing at RT for up to six hours, regardless of thawing method. By expanding direct renin stability criteria, we hope to reduce the number of cancellations due to preanalytical handling errors and prevent redundant phlebotomy for patients.

Effect of gelled phases on the relevance of double emulsion gels for probiotics encapsulation, rheological properties, and stability

This study aimed to develop a stable double emulsion gel (DEG) based on whey protein cold-set gelation of the external water phase and carnauba wax-based solidification of the oil phase as a potential delivery system for probiotics in high-protein food products. The effect of the gelation of different phases on the microstructure, gel properties, and stability of DEGs under storage and freezing–thawing conditions and the viability of L. plantarum loaded in the inner water phase of DEGs were evaluated. The oil phase crystallization allowed the formation of stable DEGs during storage, showing negligible changes in consistency index, G′, and particle size after 56 d of storage and under four freeze–thaw cycles. The gelation of both the oil and external water phases allowed a stronger gel network formation, with a six times lower creaming index than non-gelled double emulsions. All samples demonstrated that the encapsulation of L. plantarum into the inner water phase of the DEG is beneficial for the storage stability of probiotics.

Experimental investigation on the frost resistance of RCC layers with various interface treatments

This research investigates the influence of various interface treatment methods on the frost resistance performance of Roller Compacted Concrete (RCC) layers. Freeze-thaw cycle tests were conducted on RCC with interfaces treated using cement mortar, expansion agent mortar, and nano-SiO2 mortar. The study evaluated shear failure modes, shear strength, crack expansion, pore structure, and liquid uptake of the RCC interface after freeze-thaw cycles under different treatment methods. Results reveal that expansion agent mortar and nano-SiO2 mortar improve the shear strength of RCC after freeze-thaw cycles more effectively than cement mortar. The freeze-thaw cycles increase the width and expansion rate of cracks at the RCC interface during the shear process, while mortar treatments help delay crack development. Additionally, the pore volume at the RCC interface gradually increases, and the uniformity of pore distribution decreases under freeze-thaw cycles. During liquid uptake, mortar treatments slow down the upward migration of liquids by improving the pore structure at the interface. The liquid uptake of RCC exhibits a distinct linear relationship with its shear strength and pore structure. As liquid uptake time increases, water first fills larger pores before gradually entering smaller ones. Freeze-thaw cycles cause an increase in pore volume and enlargement, which leads to greater liquid uptake. Based on the damage mechanism of the RCC interface under freeze-thaw conditions, a model of shear strength degradation due to freeze-thaw cycles was established, aligning well with experimental results. Mechanism analysis indicates that nano-SiO2 and expansion agents enhance frost resistance by filling interface pores and cracks through reactions with certain compounds, thereby improving the microstructure.

Study of freeze-thaw deterioration of saturated and unsaturated hydraulic concrete based on measured strain

In actual concrete water projects, areas such as the back surface, above-water surface, and even areas where the water level fluctuates are in the unsaturated freeze-thaw state. The complexity of freeze-thaw tests of unsaturated hydraulic concrete has thus far prevented a sound understanding of the mechanisms at work in freeze-thaw deterioration of unsaturated hydraulic concrete. Given this situation, this study first compares three different unsaturated hydraulic concrete freeze-thaw test processes (polyurea seal, paraffin seal, and vacuum-bag seal) and then uses the vacuum-bag seal method to implement freeze-thaw tests of unsaturated hydraulic concrete. Afterward, three test schemes (unsaturated sealed freeze-thaw, water-freeze-thaw without air-entraining agent, and water-freeze-thaw with air-entraining agents) are conducted and the mechanisms of freeze-thaw deterioration of saturated and unsaturated hydraulic concrete are evaluated based on the measured temperature and strain of the concrete specimens. The results reveal a continuous and irreversible deterioration leading to the freeze-thaw damage of unsaturated sealed freeze-thaw specimens and water-freeze-thaw specimens with and without an air-entraining agent. After 200 freeze-thaw cycles, the cumulative residual strain of the aforementioned three test schemes reach 47 με, 616 με, and 273 με, respectively. The thermal expansion coefficient of concrete remains relatively constant with increasing freeze-thaw cycles. Water-freeze-thaw specimens without air-entraining agents have a greater thermal expansion coefficient than those with air-entraining agents, and unsaturated sealed freeze-thaw specimens have the smallest thermal expansion coefficient. The frost heave coefficient increases with increasing freeze-thaw cycles, and water-freeze-thaw specimens without air-entraining agents have greater frost heave coefficients than those with air-entraining agents.

Elucidating the evolution of pore structure, microstructural damage, and micromechanical response in cement pastes containing microencapsulated phase change materials under freeze-thaw conditions

As climate variability intensifies the frequency and severity of freeze-thaw cycles, the development of cementitious materials capable of withstanding these harsh conditions becomes increasingly crucial. This research focuses on the potential of Microencapsulated Phase Change Materials (MPCMs) to enhance the durability of Hardened Cement Paste (HCP) in the face of such challenges. Specifically, this paper evaluates the influence of MPCMs on evolution of pore microstructure, damage, and micromechanical response in HCP subjected to extended freeze-thaw cycles, utilizing Low-Temperature Differential Scanning Calorimetry (LTDSC), X-ray Tomography (XRT), and micro-indentation. LTDSC results indicate a lower ice-crystallization temperature and a significant reduction in ice formation in MPCM-integrated HCP. Micro-indentation experiments reveal that while the control HCP undergoes substantial decreases in indentation hardness (35 %) and Young's modulus (37 %) after 180 cycles, the MPCM samples show much lower losses (only 9 % loss in hardness and 7 % loss in Young's modulus for 20 % MPCM inclusion). XRT image analysis reveals that MPCMs mitigate pore enlargement, preserve a stable pore size distribution, and effectively reduce the risk of increased interconnected porosity in HCP when subjected to extended freeze-thaw cycles. Crack analysis demonstrates that control HCP samples exhibit significant crack propagation with increased freeze-thaw cycles, while samples with 10 % MPCM inclusion show only slight crack initiation, and those with 20 % MPCM inclusion maintained their structural integrity with virtually no crack progression after 180 freeze-thaw cycles. These findings underscore the potential of MPCMs to improve the durability of HCP against freeze-thaw damage, offering key insights for designing more robust materials.

Bank erosion under the impacts of fluvial erosion, frost heaving/freeze-thaw process of rivers in seasonal frozen regions

Bank erosion is a key feature of channel evolution in alluvial rivers, and will occur under the combined effect of hydraulic erosion and frost heave/freeze-thaw process of rivers in seasonal frozen regions. However, most research on bank erosion modeling has seldom considered the impact of the frost heave/freeze-thaw process. Therefore, the variation in the mechanical characteristics of riverbank soil under the freeze-thaw cycle was investigated firstly in the current research and then used in the modeling of bank erosion processes at typical sections of the Songhua River. Additionally, a sensitivity analysis of riverbank stability was conducted using orthogonal experiments. The results indicate that after 7 freeze-thaw cycles, the soil cohesion and internal friction angle of bank soil decreased by about 10%–47 % and 9%–19 %, respectively. Unlike lowland rivers, bank erosion of rivers in seasonal frozen regions is more likely to occur during the rising water period. The frost heaving/freeze-thaw process will make the bank stability safety coefficient Fs more quickly decrease to the unstable critical value. As compared with the case without considering the frost heaving/freeze-thaw process, the mass failure occurred in advance when the frost heaving/freeze-thaw process was considered, and the calculated bank erosion volume was increased by 11%–51 %, agreeing better with the measured value. The sensitivity ranking of the four influencing factors on riverbank stability under freezing-thawing conditions is as follows: river stage > groundwater level > cohesion > internal friction angle. The current study can provide a reference for research on bank erosion and channel evolution of rivers in seasonal frozen regions.

The potential of soil endemic microorganisms in ameliorating the physicochemical properties of soil subjected to a freeze-thaw cycle

Establishing soil biological crusts will result in the long-term restoration of ecosystems. Nonetheless, little research has been conducted to demonstrate the influence of soil endemic microorganisms on suppressing the adverse effects of freezing-thawing on soil properties. This current study evaluated the formation of biological crusts, the enhancement of physical and chemical characteristics of soil, and surface soil stability by inoculating native bacteria and cyanobacteria into the soil during a freezing-thawing cycle. The soil was collected from the Badranlou Region in North Khorasan Province, Northern Iran, and native bacteria and cyanobacteria were isolated, identified, chosen, and cultured. The native treatments of bacteria and cyanobacteria were then inoculated in individual bacteria, cyanobacteria, and combined inoculation of cyanobacteria and bacteria onto an experimental soil in six replications. After 60 days, they were subjected to freezing-thawing conditions to have maximum effect on the soil environment, and finally, the soil surface properties were statistically compared. The results of the significant effect (p<0.001) of inoculation treatments on the physical and chemical properties of the study soil revealed that the carbon, nitrogen, organic matter, phosphorus, potassium, and surface soil stability in bacterial treatment compared to the control treatment increased by 68, 39, 68, 17, 25, 99 %, respectively. While under cyanobacterial treatment, they rose by 83, 61, 83, 18, 73, and 172 %, respectively. The combination inoculation treatment of bacteria and cyanobacteria enhanced the study variables by 73, 66, 73, 25, 58, and 189 %, respectively. Compared to control plots, the soil bulk density in bacterial, cyanobacterial, and compound inoculation treatments was substantially reduced (p<0.001) by 9, 15, and 12 %, respectively. The soil stability, carbon, and organic matter were among the most essential properties of the soil, and they best showed the difference between the various treatments applied. It confirmed the region's potential restoration by inoculating native soil microorganisms.

Experimental study on the effect of freeze–thaw cycles to the cohesion and moisture content of geogrid reinforced silty clay

The freezing and thawing cycle is one of the primary causes of damage and instability to buildings in seasonal frost regions. During this process, the mechanical properties of soil are affected, leading to settlement, cracking, or deformation of infrastructure. Mitigating or reducing the occurrence of building frost damage in seasonal frost regions has become an important subject of study. Freeze–thaw (F–T) action will influence the distribution of moisture inside the reinforced soil and change the strength of thawing soil, which is closely related to the main influencing factors, such as initial moisture content, compaction degree, reinforced spacing, number of freeze–thaw cycles (FTC), freezing temperature, and effective vertical stress. Cohesion is an important index to determine the shear strength of clay, which is important to analyze the change in cohesion after F–T. Meanwhile, cohesion is closely related to soil moisture content. This study conducted orthogonal experiments on these primary influencing factors (6 factors at 5 levels) through FTC tests, triaxial tests, and moisture content tests to determine the undrained cohesion and moisture content of the clay after FTC, thereby establishing the influence of reinforcement on soil strength under freeze–thaw conditions. Based on the experimental results, SPSS software was used to fit the regression equations of undrained cohesion and moisture content expressed by the main influencing factors at different heights of the clay. Optimization options for the main influencing factors were obtained with Matlab software when the highest undrained cohesion values 6.8, 10.6, 8.9 kPa and lowest moisture content values 24.0%, 24.3%, 26.2% appeared in upper, middle and lower parts of the testing clay structure respectively, in conditions of − 15 °C freezing temperature and 5 times FTC. And determined the optimal combinations of moisture content, reinforcement spacing, compaction density, and vertical load at different heights. Decreasing reinforced spacing in silty clay was beneficial for liquid underwater seepage after F–T. The redistribution of internal moisture in the soil sample strengthened its undrained cohesion, thereby increasing the soil's shear strength. Comparing reinforcement conditions at different locations, it was found that when there were 3 layers of reinforcement with a spacing of 150 mm between them, this spacing was optimal. It played a significant role in improving the soil's shear strength and enhancing its bearing capacity. For reinforced clay itself, the order of the main factors influencing the undrained cohesion of soil after F–T, from high to low, was initial moisture content, reinforced spacing, and compaction degree.

Multi-scale damage characterisation of semi-flexible pavements under freeze-thaw cycles

This study aims to investigate the failure mechanism of semi-flexible pavements (SFP) under freeze-thaw conditions and to provide theoretical support for optimizing the material properties. By simulating the freeze-thaw damage process of SFP in actual service scenarios and combining various experimental methods, the strength characteristics and microstructural change rules of SFP in the freeze-thaw process are systematically analyzed. The study used freeze-thaw tests to simulate the real environment, combined with indirect tensile tests (IDT) and three-point bending tests to evaluate the mechanical properties of SFP. To further investigate the failure mechanism, scanning electron microscopy (SEM) was used to observe the interfacial changes between asphalt and early-strength sulphoaluminate cement (JGM301). Additionally, CT scanning was used to capture the structural changes of SFP during freeze-thaw cycles. The results showed that freeze-thaw cycles significantly and negatively affected the split tensile strength of SFP. SEM observations revealed that cracks appeared at the asphalt-cement interface (ITZ), the cement-SBS bond weakened, and the structure of the cement itself became loose. CT revealed structural changes such as cracking at the interface of the two-phase material, creation of new voids, and linkage of old voids during freeze-thawing of the SFP. In summary, the reduction in adhesion at the cement-asphalt interface and the frost swelling of JGM301 are the main reasons for the damage of SFP in freeze-thaw cycles. This study provides an important basis for an in-depth understanding of the freeze-thaw damage mechanism of SFP and optimization of its performance.

Frost Resistance Differences of Concrete in Frequent Natural Freeze–Thaw versus Standard Rapid Method

In order to find the anti-freezing durability differences between concrete in the frequent natural freeze–thaw conditions in the northwest of Sichuan Province, China, and concrete in the rapid freeze–thaw conditions of the standard rapid method, the typical temperature and humidity of the northwest of Sichuan Province were simulated. The results showed that the average number of freeze–thaw cycles in the northwest of this province can reach up to 150 per year. The relative dynamic modulus of C30 ordinary concrete, which is 100% pre-saturated, still remained above 90% after 450 cycles in simulated environments. However, during the rapid freeze–thaw test, even the C30 air-entrained concrete failed after 425 cycles. Compared to the saturation degree of concrete itself, the continuous replenishment of external moisture during freeze–thaw cycles is a key factor affecting the frost resistance of concrete. Rapid freeze–thaw reduces the number of the most probable pore sizes in ordinary concrete, and the pore size distribution curve tends to flatten. The reduction rate of the surface porosity of air-entrained concrete before and after rapid freeze–thaw is only about one third of that of ordinary concrete.

Experimental Study of Recycled Concrete under Freeze-Thaw Conditions.

Recycled concrete is a new and environmentally friendly material for future construction. When applying recycled concrete to cold and severe regions, it is necessary to consider the freeze-thaw resistance of recycled concrete. Using an indoor freeze-thaw cycle test system, the rapid freezing method was used to conduct rapid freeze-thaw tests on recycled concrete specimens under set freeze-thaw cycle conditions. Relevant parameters (such as compressive strength, quality loss rate, rebound value) were tested on recycled concrete specimens that completed the set number of freeze-thaw cycles. The influence of various factors (freeze-thaw cycle number, replacement rate of recycled aggregates) on the compressive strength, quality loss rate, and rebound value of recycled concrete was analyzed. The results indicate that with the increase of freeze-thaw cycles and recycled aggregate content, the workability, rebound value, and compressive strength of the specimens decrease, and the quality loss rate increases. The changes in workability of concrete are sharp, with a slump difference of 21 mm between concrete with 100% recycled coarse aggregate and concrete using natural coarse aggregate. The rebound value of the specimen shows a decreasing trend overall, but the rebound value varies for different measuring points on the same specimen. The attenuation of compressive strength is significant. When fully using recycled aggregates to prepare concrete, the compressive strength after 30 freeze-thaw cycles decreases by 49.42% compared to the compressive strength after 0 freeze-thaw cycles. The overall quality loss rate shows a decreasing trend, but the quality loss is not severe.

Measuring the Permeability and Compressive Strength of Concretes Containing Additives in Freeze–Thaw Conditions without Breaking the Sample

Measuring the Permeability and Compressive Strength of Concretes Containing Additives in Freeze–Thaw Conditions without Breaking the Sample

Frost deformation and microstructure evolution of porous rock under uniform and unidirectional freeze-thaw conditions

Frost deformation and microstructure evolution of porous rock under uniform and unidirectional freeze-thaw conditions

Influence in the mechanical properties and salt erosion resistance of recycled sand UHPC made from fly ash content

This study aims to explore the impact of fly ash (FA) as a partial replacement for cement on the durability of recycled sand (RS) ultra high performance concrete (UHPC). The effects of FA content on the mechanical properties, resistance to chloride salt freezing-thawing coupling, and resistance to sulfate dry-wet cycling coupling of F-RUHPC were investigated. The results showed that FA improved the mechanical properties of F-RUHPC, with a compressive strength of up to 120.8 MPa. It also resulted in higher tensile strength compared to the control group and demonstrated excellent resistance to chloride salt freezing-thawing and sulfate dry-wet cycling. Microscopic analysis revealed a low content of free chloride ions within F-RUHPC, all below 0.08 %. Additionally, the permeability coefficient of F-RUHPC with 10 % FA was found to be the lowest under chloride salt freezing-thawing conditions. Microstructural characterization demonstrated the dense structure of UHPC. The addition of 10 % FA was found to be beneficial in improving the mechanical properties and durability of F-RUHPC, providing a theoretical reference for the development of environmentally friendly UHPC.

Comparing Three Freeze-Thaw Schemes Using C-Band Radar Data in Southeastern New Hampshire, USA

Soil freeze-thaw (FT) cycles over agricultural lands are of great importance due to their vital role in controlling soil moisture distribution, nutrient availability, health of microbial communities, and water partitioning during flood events. Active microwave sensors such as C-band Sentinel-1 synthetic aperture radar (SAR) can serve as powerful tools to detect field-scale soil FT state. Using Sentinel-1 SAR observations, this study compares the performance of two FT detection approaches, a commonly used seasonal threshold approach (STA) and a computationally inexpensive general threshold approach (GTA) at an agricultural field in New Hampshire, US. It also explores the applicability of an interferometric coherence approach (ICA) for FT detection. STA and GTA achieved 85% and 78% accuracy, respectively, using VH polarization. We find a marginal degradation in the performance of STA (82%) and GTA (76%) when employing VV-polarized data. While there was approximately a 6 percentage point difference between STA’s and GTA‘s overall accuracy, we recommend GTA for FT detection using SAR images at sub-field-scale over extended regions because of its higher computational efficiency. Our analysis shows that interferometric coherence is not suitable for detecting FT transitions under mild and highly dynamic winter conditions. We hypothesize that the relatively mild winter conditions and therefore the subtle FT transitions are not able to significantly reduce the correlation between the phase values. Also, the ephemeral nature of snowpack in our study area, further compounded by frequent rainfall, could cause decorrelation of SAR images even in the absence of a FT transition. We conclude that despite Sentinel-1’s ~80% mapping accuracy at a mid-latitude site, understanding the cause of misclassification remains challenging, even when detailed ground data are readily available and employed in error attribution efforts.

Basalt Fibers versus Plant Fibers: The Effect of Fiber-Reinforced Red Clay on Shear Strength and Thermophysical Properties under Freeze–Thaw Conditions

Freeze–thaw cycling has a significant impact on the energy utilization and stability of roadbed fill. Given the good performance of basalt fiber (BF) and plant fiber (PF), a series of indoor tests are conducted on fiber-reinforced red clay (RC) specimens to analyze the shear strength, thermophysical, and microstructural changes and damage mechanisms of the RC under the freeze–thaw cycle–BF coupling, meanwhile, comparing the improvement effect of PF. The results indicate that the RC cohesion (c) first increases and then decreases with the increasing fiber content under BF improvement, reaching the maximum value at the content of 2%, and the change in the internal friction angle (φ) is relatively small. As the number of freeze–thaw cycles increases, cohesion (c) first decreases and then gradually stabilizes. The thermal conductivity increases with increasing moisture content, and the thermal effusivity increases and then decreases with increasing moisture content and fiber content. The heat storage capacity reaches the optimum level at a moisture content of 22.5% and a fiber content of 1%. Microanalysis reveals that at 2% fiber content, a fiber network structure is initially formed, and the gripping effect is optimal. The shear strength of PF-improved soil is higher than that of BF at a fiber content of 4–6%, and the thermal conductivity is better than that of BF. At the same fiber content, the heat storage and insulation capacity of BF-improved soil is significantly higher than that of PF.

Prediction of UCS and BTS under freeze-thaw conditions in the NW himalayan rock mass using petrographic analysis and laboratory testing

Repeated freeze-thaw (F&T) cycles substantially harm the durability of rocks, heightening the potential for landslides, rockslides, and avalanches. The current work investigates the effect of the F&T cycle on rock mass (biotite schist) samples. For this purpose, 32 rock samples were prepared and gathered from eight distinct locations in the northwest Himalayan region. For each sample, petrographical analysis and laboratory testing such as uniaxial compressive strength (UCS) and Brazilian tensile strength (BTS) are investigated at repeated (0th, 10th, 20th, and 30th) F&T cycles. Additionally, machine learning (ML) sequential models such as recurrent neural networks (RNN), gated recurrent units (GRU), and bi-directional long short-term memory (Bi-LSTM) are constructed to estimate the UCS and BTS under F&T conditions. Petrographical results show no change in the mineral indices, while there is a noticeable increase in aspect ratio but a significant decline in mean grain size with each successive 10th cycle, suggesting sample damage. The study also provides a comprehensive assessment of the ML models' performance, highlighting the Bi-LSTM model's superior accuracy among all models in terms of R2 (0.9850) and RMSLE (0.0100) during the TR stage and R2 (0.9020) and RMSLE (0.0170) during the TS stage for UCS prediction. Similarly, BTS prediction also shows superior precision, recording an R2 (0.7543) and RMSLE (0.0345) during TR and R2 (0.7404) and RMSLE (0.0213) during TS stages. The present study also explores the heatmap, line diagram, regression analysis, 2D kernel density plot, Taylor diagram, and DDR criterion for evaluating the model performance more clearly.

Compost-diatomite-based phytostabilization course under extreme environmental conditions in terms of high pollutant contents and low temperatures

The effects of changes in environmental temperatures on the immobilization or removal of cationic potentially toxic elements (PTE) in heavily polluted soils are often poorly understood, although both are widely studied in the context of phytostabilization. To address this issue, a novel compost-diatomite hybrid (CDH) amendment was developed and applied for assisted phytostabilization at two external temperature regimes. (Cd/Ni/Cu/Zn)-extremely polluted soils (unenriched and CDH-enriched) were cultivated with perennial ryegrass and native soil microbiome under greenhouse conditions and then transferred to freeze-thaw conditions (FTC). The decrease in metal potential toxicity in soils subjected to phytostabilization following both temperature treatments was characterized by a combination of sequential extraction and atomic absorption measurements. The soil microbiome was characterized by high-throughput sequencing. In a relative comparison, the greatest decrease in the content of all PTEs in CDH-enriched soil (compared to unenriched soil) appeared in FTC. Furthermore, under the influence of FTC, in the relative comparison between two CDH-enriched soils (exposed-, and not-exposed- to FTC) and two unenriched soils (exposed-, and not-exposed- to FTC), the content of all PTEs decreased more sharply in the CDH-enriched series than in the unenriched series. The largest redistribution into four sequentially extracted fractions in CDH-enriched soil was found for Zn. Based on the distribution pattern, Zn immobilization was greater in CDH-enriched soil in FTC. CDH increased species richness in the soil, while FTC stimulated the growth of Bacteroidia, Alphaproteobacteria, Theromomicrobia, and Gammaproteobacteria. The analysis of the functionalities of the microbiome indicated enhanced metal transportation and defense systems in samples exposed to FTC. The current research is crucial for understanding how extreme environmental conditions in both cases high pollutant levels and low temperatures affect the movement and transformation of PTEs in polluted soils during phytostabilization.