We provide a simple model of vector dark matter (DM) which can realize the recently proposed freeze-out mechanism with catalyzed annihilation. In our setup, a vector DM field Xμ and a catalyst field Cμ is unified by an SU(2)D gauge symmetry. These gauge fields acquire their masses via spontaneously symmetry breaking triggered by a doublet and a real triplet scalar fields. The catalyst particle is automatically lighter than the DM since it only acquires mass from the vacuum expectation value of the doublet scalar. We also introduce a dimension-5 operator to generate a kinetic mixing term between Cμ and the U(1)Y gauge field Bμ. This mixing term is naturally small due to a suppression with a high UV completion scale, and thus it allows the catalyst to decay after the DM freeze-out. We derive the annihilation cross sections of processes X* + X → 2C and 3C → X* + X and solve the Boltzmann equations for both the DM and the catalyst. We develop the analytical approximate solutions of the equations and find them matching the numerical solutions well. Constraints from relic abundance and indirect detection of DM are considered. We find that the DM with a mass mX ≳ 4.5 TeV survives in the case of a long-living catalyst. On the other hand, if the catalyst decays during the catalyzed annihilation era, then the bound can be released. We also discuss two paradigms which can maintain the kinetic equilibrium of DM until the DM freeze-out. In both cases, the freeze-out temperature of DM is an order of magnitude higher than the original model.
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