Free Quantum Research Articles

Relative entropy and curved spacetimes

Given any half-sided modular inclusion of standard subspaces, we show that the entropy function associated with the decreasing one-parameter family of translated standard subspaces is convex for any given (not necessarily smooth) vector in the underlying Hilbert space. In second quantisation, this infers the convexity of the vacuum relative entropy with respect to the translation parameter of the modular tunnel of von Neumann algebras. This result allows us to study the QNEC inequality for coherent states in a free Quantum Field Theory on a stationary curved spacetime, given a KMS state. To this end, we define wedge regions and appropriate (deformed) subregions. Examples are given by the Schwarzschild spacetime and null translated subregions with respect to the time translation Killing flow. More generally, we define wedge and strip regions on a globally hyperbolic spacetime, so to have non trivial modular inclusions of von Neumann algebras, and make our analysis in this context.

A Mathematical Analysis of Casimir Interactions I: The Scalar Field

Starting from the construction of the free quantum scalar field of mass mge 0, we give mathematically precise and rigorous versions of three different approaches to computing the Casimir forces between compact obstacles. We then prove that they are equivalent.

Zooming in on heavy fermions in Kondo lattice models

Resolving the heavy fermion band in the conduction electron momentum resolved spectral function of the Kondo lattice model is challenging since, in the weak coupling limit, its spectral weight is exponentially small. In this article we consider a composite fermion operator, consisting of a conduction electron dressed by spin fluctuations that shares the same quantum numbers as the electron operator. Using approximation free auxiliary field quantum Monte Carlo simulations we show that for the SU(2) spin-symmetric model on the square lattice at half filling, the composite fermion acts as a magnifying glass for the heavy fermion band. In comparison to the conduction electron residue that scales as $e^{-W/J_k}$ with $W$ the bandwidth and $J_k$ the Kondo coupling, the residue of the composite fermion tracks $J_k$. This result holds down to $J_k/W = 0.05$, and confirms the point of view that magnetic ordering, present below $J_k/W = 0.18$, does not destroy the heavy quasiparticle. We furthermore investigate the spectral function of the composite fermion in the ground state and at finite temperatures, for SU($N$) generalizations of the Kondo lattice model, as well as for ferromagnetic Kondo couplings, and compare our results to analytical calculations in the limit of high temperatures, large-$N$, large-$S$, and large $J_k$. Based on these calculations, we conjecture that the composite fermion operator provides a unique tool to study the destruction of the heavy fermion quasiparticle in Kondo breakdown transitions. The relation of our results to scanning tunneling spectroscopy and photoemission experiments is discussed.

Calculation of the creation and annihilation operators of a free particle in the light cone coordinate formalism

This work didactically presents the mathematical procedures required for the construction of the creation and annihilation operators for a free quantum particle considering the coordinates of the light cone. For that, the relationships between the aforementioned coordinates and the coordinates (ct, x, y, z) are listed, in addition to the use of the Klein-Gordon-Fock equation in the formalism of the light cone coordinates. Finally, the temporal evolution operator and the quantum operators of creation and annihilation of the integral type of motion are obtained.

Electron Pulse Compression with Optical Beat Note.

Compressing electron pulses is important in many applications of electron beam systems. In this study, we propose to use optical beat notes to compress electron pulses. The beat frequency is chosen to match the initial electron pulse duration, which enables the compression of electron pulses with a wide range of durations. This functionality extends the optical control of electron beams, which is important in compact electron beam systems such as dielectric laser accelerators. We also find that the dominant frequency of the electron charge density changes continuously along its drift trajectory, which may open up new opportunities in coherent interaction between free electrons and quantum or classical systems.

Odd entanglement entropy and logarithmic negativity for thermofield double states

We investigate the time evolution of odd entanglement entropy (OEE) and logarithmic negativity (LN) for the thermofield double (TFD) states in free scalar quantum field theories using the covariance matrix approach. To have mixed states, we choose non-complementary subsystems, either adjacent or disjoint intervals on each side of the TFD. We find that the time evolution pattern of OEE is a linear growth followed by saturation. On a circular lattice, for longer times the finite size effect demonstrates itself as oscillatory behavior. In the limit of vanishing mass, for a subsystem containing a single degree of freedom on each side of the TFD, we analytically find the effect of zero-mode on the time evolution of OEE which leads to logarithmic growth in the intermediate times. Moreover, for adjacent intervals we find that the LN is zero for times t < β/2 (half of the inverse temperature) and after that, it begins to grow linearly. For disjoint intervals at fixed temperature, the vanishing of LN is observed for times t < d/2 (half of the distance between intervals). We also find a similar delay to see linear growth of ∆S = SOEE− SEE. All these results show that the dynamics of these measures are consistent with the quasi-particle picture, of course apart from the logarithmic growth.

An introductory review on resource theories of generalized nonclassical light

Quantum resource theory is perhaps the most revolutionary framework that quantum physics has ever experienced. It plays vigorous roles in unifying the quantification methods of a requisite quantum effect as wells as in identifying protocols that optimize its usefulness in a given application in areas ranging from quantum information to computation. Moreover, the resource theories have transmuted radical quantum phenomena like coherence, nonclassicality and entanglement from being just intriguing to being helpful in executing realistic thoughts. A general quantum resource theoretical framework relies on the method of categorization of all possible quantum states into two sets, namely, the free set and the resource set. Associated with the set of free states there is a number of free quantum operations emerging from the natural constraints attributed to the corresponding physical system. Then, the task of quantum resource theory is to discover possible aspects arising from the restricted set of operations as resources. Along with the rapid growth of various resource theories corresponding to standard harmonic oscillator quantum optical states, significant advancement has been expedited along the same direction for generalized quantum optical states. Generalized quantum optical framework strives to bring in several prosperous contemporary ideas including nonlinearity, -symmetric non-Hermitian theories, q-deformed bosonic systems, etc., to accomplish similar but elevated objectives of the standard quantum optics and information theories. In this article, we review the developments of nonclassical resource theories of different generalized quantum optical states and their usefulness in the context of quantum information theories.

Theoretical study of the adsorption of BMSF-BENZ drug for osteoporosis disease treatment on Al-doped carbon nanotubes (Al-CNT) as a drug delivery vehicle

The adsorption energy of the BMSF-BENZ adsorbed complexes was investigated to understand the non-local dispersion interactions, with many other chemical parameters related to this subject like HOMO and LUMO, energy gap, and the time needed for the BMSF-BENZ to be desorbed from the nanotube (recovery time). Our study reveals that Al-CNT is a promising adsorbent for this drug as Eads of BMSF-BENZ/Al-CNT complexes are -22.09, -38.68, -12.89, -31.01, -27.31, -21.90, and -21.42 kcal/mol in the gas phase on the active atoms of the BMSF BENZ (Br, N8, N9, N58, O35, O41, and S), respectively. In addition, the spontaneous and favorable interaction between the BMSF BENZ and all nanoparticles was confirmed by investigating Gibbs free energy and quantum theory of atoms in molecule analysis (QTAIM) so that it can be used as an electrochemical sensor or biosensor. Furthermore, to more visualize the nature of intermolecular bonding and the strength of interaction between the BMSF-BENZ drug molecule and the nanotube, QTAIM has been widely studied in the case of drug delivery purposes. Al-CNT (4,0) can be extended as a drug delivery system and the work function type sensor.

Superconducting Fluctuations in Overdoped Bi2Sr2CaCu2O8+δ

Fluctuating superconductivity - vestigial Cooper pairing in the resistive state of a material - is usually associated with low dimensionality, strong disorder or low carrier density. Here, we report single particle spectroscopic, thermodynamic and magnetic evidence for persistent superconducting fluctuations in heavily hole-doped cuprate superconductor Bi$_2$Sr$_2$CaCu$_2$O$_{8+\delta}$ ($T_c$ = 66~K) despite the high carrier density. With a sign-problem free quantum Monte Carlo calculation, we show how a partially flat band at ($\pi$,0) can help enhance superconducting phase fluctuations. Finally, we discuss the implications of an anisotropic band structure on the phase-coherence-limited superconductivity in overdoped cuprates and other superconductors.

On the experiment-friendly formulation of quantum backflow

In its standard formulation, quantum backflow is a classically impossible phenomenon in which a free quantum particle in a positive-momentum state exhibits a negative probability current. Recently, Miller et al. [Quantum 5, 379 (2021)] have put forward a new, "experiment-friendly" formulation of quantum backflow that aims at extending the notion of quantum backflow to situations in which the particle's state may have both positive and negative momenta. Here, we investigate how the experiment-friendly formulation of quantum backflow compares to the standard one when applied to a free particle in a positive-momentum state. We show that the two formulations are not always compatible. We further identify a parametric regime in which the two formulations appear to be in qualitative agreement with one another.

Complete Logarithmic Sobolev inequality via Ricci curvature bounded below II

We study the “geometric Ricci curvature lower bound”, introduced previously by Junge, Li and LaRacuente, for a variety of examples including group von Neumann algebras, free orthogonal quantum groups [Formula: see text], [Formula: see text]-deformed Gaussian algebras and quantum tori. In particular, we show that Laplace operator on [Formula: see text] admits a factorization through the Laplace–Beltrami operator on the classical orthogonal group, which establishes the first connection between these two operators. Based on a non-negative curvature condition, we obtain the completely bounded version of the modified log-Sobolev inequalities for the corresponding quantum Markov semigroups on the examples mentioned above. We also prove that the “geometric Ricci curvature lower bound” is stable under tensor products and amalgamated free products. As an application, we obtain a sharp Ricci curvature lower bound for word-length semigroups on free group factors.

Quantum Particle on Dual Weight Lattice in Weyl Alcove

Families of discrete quantum models that describe a free non-relativistic quantum particle propagating on rescaled and shifted dual weight lattices inside closures of Weyl alcoves are developed. The boundary conditions of the presented discrete quantum billiards are enforced by precisely positioned Dirichlet and Neumann walls on the borders of the Weyl alcoves. The amplitudes of the particle’s propagation to neighbouring positions are determined by a complex-valued dual-weight hopping function of finite support. The discrete dual-weight Hamiltonians are obtained as the sum of specifically constructed dual-weight hopping operators. By utilising the generalised dual-weight Fourier–Weyl transforms, the solutions of the time-independent Schrödinger equation together with the eigenenergies of the quantum systems are exactly resolved. The matrix Hamiltonians, stationary states and eigenenergies of the discrete models are exemplified for the rank two cases C2 and G2.

Taming the Sign Problem in Auxiliary-Field Quantum Monte Carlo Using Accurate Wave Functions.

We explore different ways of incorporating accurate trial wave functions into free projection auxiliary-field quantum Monte Carlo (fp-AFQMC). States employed include coupled-cluster singles and doubles, multi-Slater, and symmetry-projected mean-field wave functions. We adapt a recently proposed fast multi-Slater local energy evaluation algorithm for fp-AFQMC, making the use of long expansions from selected configuration interaction methods feasible. We demonstrate how these wave functions serve to mitigate the sign problem and accelerate convergence in quantum chemical problems, allowing the application of fp-AFQMC to systems of substantial sizes. Our calculations on the widely studied model Cu2O22+ system show that many previously reported isomerization energies differ substantially from the near-exact fp-AFQMC value.

Wave-particle duality and the zitterbewegung

In previous work, the Hamilton-Jacobi equation has been associated with the metrics of general relativity and shown to be a generalized Dirac equation for quantum mechanics. This lends itself to a natural definition of wave-particle duality in quantum mechanics. This theory is now further developed to show that a free spinless quantum particle moving with velocity v obeys the standard wave equation of electro-magnetism. We also discuss the implications for the zitterbewegung problem and its relationship to isotropy. Moreover, it is also shown that for the theory to be consistent, the momentum defined by the Hamilton-.!acobi function presupposes the existence of a universal parameter internal to the system. In the case of particles with mass this invariant can be defined by dX = dt/m(t) where t has the units of time and m = m(t) has the units of mass.

Substituted Stilbene-based D-π-A and A-π-A type oxime esters as photoinitiators for LED photopolymerization

Three novel oxime esters based on the π-conjugated trans-stilbene group were designed and synthesized as photoinitiators (PIs) for light-emitting diode (LED) photopolymerization. Three substituents (thioether, sulfoxide, and sulfone) with different electron pushing and withdrawing abilities were introduced into the chromophore to constitute D-π-A (OXE-S) and A-π-A (OXE-SO, OXE-SO2) type structures of PIs to rationalize their relevant effects on free radical photoinitiation ability. Structure-activity relationship, electronic properties, and photodissociation mechanism were investigated using steady-state photolysis, density functional theory (DFT) calculations, and real-time 1H NMR. The compounds show good absorption under exposure to LED irradiation wavelength (i.e., 365–405 nm). The polarity of solvent influences the photoreactivity of this series of oxime esters. The photolysis rates and free radical generation quantum yields for the three PIs increase from polar to nonpolar solvent. For D-π-A type OXE-S, the photolysis rate increases 70 times from acetonitrile to toluene. The three PIs can efficiently initiate the polymerization of acrylate monomer under exposure to LED irradiation at 365–405 nm. The excellent absorption and efficient photoinitiation properties of the PIs demonstrate their great potential in photocuring applications.

Bosonic entanglement renormalization circuits from wavelet theory

Entanglement renormalization is a unitary real-space renormalization scheme. The corresponding quantum circuits or tensor networks are known as MERA, and they are particularly well-suited to describing quantum systems at criticality. In this work we show how to construct Gaussian bosonic quantum circuits that implement entanglement renormalization for ground states of arbitrary free bosonic chains. The construction is based on wavelet theory, and the dispersion relation of the Hamiltonian is translated into a filter design problem. We give a general algorithm that approximately solves this design problem and provide an approximation theory that relates the properties of the filters to the accuracy of the corresponding quantum circuits. Finally, we explain how the continuum limit (a free bosonic quantum field) emerges naturally from the wavelet construction.

Modeling and Simulation for Performance Evaluation of Optical Quantum Channels in Quantum key Distribution Systems

In this research work, a simulator with time-domain visualizers and configurable parameters using a continuous time simulation approach with Matlab R2019a is presented for modeling and investigating the performance of optical fiber and free-space quantum channels as a part of a generic quantum key distribution system simulator. The modeled optical fiber quantum channel is characterized with a maximum allowable distance of 150 km with 0.2 dB/km at =1550nm. While, at =900nm and =830nm the attenuation values are 2 dB/km and 3 dB/km respectively. The modeled free space quantum channel is characterized at 0.1 dB/km at =860 nm with maximum allowable distance of 150 km also. The simulator was investigated in terms of the execution of the BB84 protocol based on polarizing encoding with consideration of the optical fiber and free-space quantum channel imperfections and losses by estimating the quantum bit error rate and final secure key. This work shows a general repeatable modeling process for significant performance evaluation. The most remarkable result that emerged from the simulated data generated and detected is that the modeling process provides guidance for optical quantum channels design and characterization for other quantum key distribution protocols.

Strict deformations of quantum field theory in de Sitter spacetime

We propose a new deformed Rieffel product for functions in de Sitter spacetimes and study the resulting deformation of quantum field theory in de Sitter using warped convolutions. This deformation is obtained by embedding de Sitter in a higher-dimensional Minkowski spacetime, deforming there using the action of translations and subsequently projecting back to de Sitter. We determine the two-point function of a deformed free scalar quantum field, which differs from the undeformed one, in contrast to the results in deformed Minkowski spacetime where they coincide. Nevertheless, we show that in the limit where the de Sitter spacetime becomes flat, we recover the well-known non-commutative Minkowski spacetime.

Strong 1-boundedness of unimodular orthogonal free quantum groups

Recently, Brannan and Vergnioux showed that the orthogonal free quantum group factors [Formula: see text] have Jung’s strong [Formula: see text]-boundedness property, and hence are not isomorphic to free group factors. We prove an analogous result for the other unimodular case, where the parameter matrix is the standard symplectic matrix in [Formula: see text] dimensions [Formula: see text]. We compute free derivatives of the defining relations by introducing self-adjoint generators through a decomposition of the fundamental representation in terms of Pauli matrices, resulting in [Formula: see text]-boundedness of these generators. Moreover, we prove that under certain conditions, one can add elements to a [Formula: see text]-bounded set without losing [Formula: see text]-boundedness. In particular, this allows us to include the character of the fundamental representation, proving strong [Formula: see text]-boundedness.

An Introduction to κ-Deformed Symmetries, Phase Spaces and Field Theory

In this review, we give a basic introduction to the κ-deformed relativistic phase space and free quantum fields. After a review of the κ-Poincaré algebra, we illustrate the construction of the κ-deformed phase space of a classical relativistic particle using the tools of Lie bi-algebras and Poisson–Lie groups. We then discuss how to construct a free scalar field theory on the non-commutative κ-Minkowski space associated to the κ-Poincaré and illustrate how the group valued nature of momenta affects the field propagation.