The C4F7N/CO2 mixed gas is most expected to replace SF6 in high-voltage power equipment, and the generation of free metal particles in gas-insulated equipment is unavoidable and highly susceptible to inducing insulation failures. In this paper, the effects of flaky, spherical, and mixed shape aluminum particle defects on the breakdown characteristics of C4F7N/CO2 mixed gas are investigated and compared to those of SF6 under the same conditions. The experimental results show that the effect of particle defects on the insulating properties of C4F7N/CO2 gas mixtures is visualized by the fact that particle defects reduce the breakdown voltage of C4F7N/CO2 gas mixtures, increase their stochasticity, and reduce the enhancement of the insulating properties of C4F7N/CO2 gas mixtures by increasing the air pressure. The greater the number of particles, the greater is the degree of influence. Comparison of the SF6 and C4F7N/CO2 gas mixtures reveals that, in the case of flake defects, increasing the air pressure improves the insulation performance of the SF6 gas better than that of the C4F7N/CO2 gas mixture. Under the condition of the same number of particles, the larger the proportion of spherical particles in the hybrid particles, the smaller is the influence of metal particles on the C4F7N/CO2 mixed gas and on SF6 gas.