The traditional introduction of the chemical potential is through the assumption that the entropy is a differentiable function of U, V and the molar quantities of the chemical components; but entropy and energy functions are defined only for states of closed systems. An alternative introduction is accordingly given here. It meets this difficulty, and is in accordance with recent axiomatizations. An outline of the proposal is given, followed by a critical analysis of the assumptions involved. Traditional thermodynamics introduces the chemical potential starting from the assumption that the entropy S of an open system can be regarded as a differentiable function of the internal energy U, the volume V and the molar quantities of the different components Na, N However, the definitions of S and U refer to adiabatic linkage, and this presumes closed systems. Landsberg1 meets this criticism by the introduction of a fourth law which implies that for a certain class of systems (more precisely: for certain sets of states) the entropy is a first order homogeneous function of U, V, Na, N Tisza2 introduces a phase postulate: a simple system exists potentially in a number of phases, which are spatially homogeneous material extensions, for which a continuous first order homogeneous phase entropy function S(U, V. Na, Np,...) is defined. Both assume the existence of a function S(U, V, Na, Na,...) for a precisely defined class of open systems, abandoning an operational definition of entropy and internal energy. This paper intends to give an alternative, which does not take refuge in an assumption of the above kind, and is in accordance with the operational approach to entropy and internal energy of recent axiomatizations37: the domains of definition of entropy and energy functions remain restricted to closed systems. The approach is so simple, that it can serve to introduce the chemical potential in undergraduate courses. I will start with an outline, suitable for teaching; afterwards I will justify the assumptions which are involved and in doing so prepare a more formal theory. Outline of a simple introduction of the chemical potential Consider a system, which is materially connected with respect to the