Blend Formulation Research Articles

Quality Characteristics of Bread Produced with Blends of Flour from Cassava, Wheat and Bambara Groundnut (Vigna subterranea)

Food fortification targeted at increasing the micronutrient contents of food with the view to improving its nutritional quality is a pragmatic approach in combating malnutrition which consequently engenders the achievement of ‘sustainable development’ goal three (SDG-3). Hence, this research assessed the quality attributes of bread produced with blends of flour from cassava, Bambara groundnut and wheat. Wheat flour was obtained from production line while low postharvest physiologically deteriorated cassava root (IITA-TMS-IBA011368) and Bambara groundnut were processed into HQCF and Bambara flour, respectively. The flours were blended together as depicted by D-Optimal mixture using Design Expert software (Version 12.0) and total of sixteen (16) samples were generated. The bread baked with the blended flours were analyzed for physical, proximate, sensory and microbiological properties. Range of value for crusts’ lightness (L*), redness-bluishness (a*), yellowness-greenness (b*), browning index, crumb density, crumb porosity, loaf weight and overall acceptability was 29.57-39.52, 0.10-3.96, 8.28-15.27, 0.36-0.41, 0.15-0.29, 0.45-0.52, 56.30-66.30 g and 5.60-7.38, respectively. Moisture, ash, crude fibre, fat, crude protein, carbohydrate and energy value ranged from 1.26-1.87%, 0.31-0.59%, 7.25-26.56%, 4.46-9.91%, 30.98-56.34% and 314.51-415.67 kcal. Crumb elasticity, softness, crust appearance, color, flavor, taste and overall acceptability was 5.12-7.64, 4.96-7.88, 5.68-7.52, 6.28-7.36, 5.84-7.72, 5.44-7.72 and 5.60-7.96. The bread samples were acceptable sensorially as adjudged by the panels. Lower count (load) of viable organism found in composite bread was due to the lethal effect of baking temperature and good hygiene practice. Bread of acceptable quality was produced with blends of flours from cassava, Bambara groundnut and wheat but the optimized ingredient blend formulation obtained was high quality casava flour of 15.10%, wheat flour of 63.67% and Bambara nut flour 21.23% while the calculated desirability was 0.53.

Kinetics of elastic recovery in roll compaction

Elastic recovery (ER) has been investigated and discussed extensively in the field of tableting. However, until now only limited data is available regarding ER in roll compaction. Therefore, a previously established in-line measurement technique was rolled out to further investigate the kinetics of ER in roll compaction and the effects of specific compaction force (SCF) and roll speed (RS). In-line laser triangulation measurements at different positions within a roll rotation as well as measurement over time after the process has been stopped were utilized. Pure microcrystalline cellulose (MCC) and two placebo powder blend formulations were analysed. Successful fit of the contained ER profiles emphasized that the ER on the roll surface is build out of two exponential kinetics. Starting with a dominating fast ER (ERA), characterized by a high increase of the ribbon thickness after passing the gap width, followed by a slower ER (ERB). Sigma minus plot analysis showed that increasing RS led to an accelerated ERA and ERB which was related to the viscoelastic behaviour of MCC. The SCF only had an effect on the kinetics of ER if a brittle filler was added to the mixture. The conducted study established the first approach in literature to characterize the kinetics of ER in roll compaction. It supports the understanding and characterization of relaxation times and the effect of the RS and SCF in roll compaction.

Magnesium Stearate Fatty Acid Composition, Lubrication Performance and Tablet Properties

Magnesium stearate (MgSt) is a common tablet lubricant. As variations in MgSt properties are known to influence tablet attributes, the impact of MgSt fatty acid composition, particularly the significance of the stearate and palmitate contents, and its effects on tablet properties warrant further investigation. This study investigated the effect of MgSt with different stearate and palmitate contents but comparable physical properties (e.g. particle size, crystallinity, specific surface area and morphology) on lubrication performance and resulting tablet quality attributes, including mechanical strength, disintegratability and drug release. The influence of MgSt concentration and blending duration on the resulting tablet properties was also examined. Tablets produced using the lower stearate content MgSt had slightly higher tensile strength. The effect of MgSt stearate content was more apparent in the disintegration time and drug release, whereby MgSt of lower stearate content resulted in tablets with longer disintegration time and slower drug release. The lower stearate content also resulted in a lower lubrication performance, leading to a lesser reduction in tablet ejection force. As expected, a longer blending time of the tablet formulation blend with MgSt yielded tablets with reduced tensile strength, shorter disintegration time and slower drug release. Tablets with higher MgSt concentration showed a greater reduction in tensile strength, longer disintegration time and faster drug release. The study findings reinforced observations by other researchers and provided a better understanding of the fatty acid composition effects of MgSt on lubrication performance and the resulting tablet properties.Graphical

Bio-Based and Biodegradable Polymeric Materials for a Circular Economy.

Nowadays, plastic contamination worldwide is a concerning reality that can be addressed with appropriate society education as well as looking for innovative polymeric alternatives based on the reuse of waste and recycling with a circular economy point of view, thus taking into consideration that a future world without plastic is quite impossible to conceive. In this regard, in this review, we focus on sustainable polymeric materials, biodegradable and bio-based polymers, additives, and micro/nanoparticles to be used to obtain new environmentally friendly polymeric-based materials. Although biodegradable polymers possess poorer overall properties than traditional ones, they have gained a huge interest in many industrial sectors due to their inherent biodegradability in natural environments. Therefore, several strategies have been proposed to improve their properties and extend their industrial applications. Blending strategies, as well as the development of composites and nanocomposites, have shown promising perspectives for improving their performances, emphasizing biopolymeric blend formulations and bio-based micro and nanoparticles to produce fully sustainable polymeric-based materials. The Review also summarizes recent developments in polymeric blends, composites, and nanocomposite plasticization, with a particular focus on naturally derived plasticizers and their chemical modifications to increase their compatibility with the polymeric matrices. The current state of the art of the most important bio-based and biodegradable polymers is also reviewed, mainly focusing on their synthesis and processing methods scalable to the industrial sector, such as melt and solution blending approaches like melt-extrusion, injection molding, film forming as well as solution electrospinning, among others, without neglecting their degradation processes.

Structural Build-Up and Stability of Hybrid Monoglyceride-Triglyceride Oleogels.

Oleogelation is an alternative oil structuring route to formulate (semi-)solid fats with a reduced amount of saturated fats. Monoglycerides have been identified as effective gelators; however, their application potential can be limited due to challenges regarding mechanical strength and long-term stability. Therefore, the formulation of hybrid fat blends is a promising way to improve the functionality of oleogels. This research focuses on the interaction between mono- and triglycerides (MAGs and TAGs) in hybrid oleogels. A total gelator concentration of 10% (w/w) with changing MAGs-TAGs ratios (increase by 25% on a molar basis; M0-T100, M25-T75, M50-T50, M75-T25, M100-T0) was used. First, the oleogels were produced without shear to unravel the crystallization behavior (DSC, SAXS, WAXS). Next, the oleogels were crystallized with shear to assess the interactions between MAGs and TAGs on macroscale properties (rigidity, oil binding capacity) during storage of 1 day, 1 week, and 4 weeks. A clear distinction could be made between the MAG crystals and TAG crystals in the blends M50-T50 and M75-T25 based on WAXS, SAXS, and phase contrast microscopy. This indicates that both gelators crystallize separately. During the follow-up study of the dynamically produced samples, a synergistic effect was found for Dy-M50-T50 and Dy-M75-T25; however, it was not maintained upon storage. The initial rigidity of 2.4 × 104 Pa and 2.0 × 104 Pa decreased to 1.5 × 104 Pa and 1.0 × 104 Pa for Dy-M50-T50 and Dy-M75-T25, respectively.

Irreversible, in situ, self-healing and self-glazing of geopolymers

Geopolymers are the result of the reaction of alkaline activators with reactive aluminosilicates. By dissolving these aluminosilicates and undergoing processes of polycondensation and geopolymerization, they form robust structures with distinct properties compared to other ceramics. These non-crystalline materials exhibit notable resistance to corrosion, heat, and environmental conditions, such as changes in pressure and temperature. Consequently, geopolymers, e.g., of stoichiometric composition (M2O•Al2O3•4SiO2•11H2O (or 13H2O)), find a place between cement and ceramics regarding mechanical properties. Considering the formulation of geopolymer blends, this study demonstrates that these materials have self-healing and self-glazing properties under high-temperature conditions. Through systematic experimentation and considering the specific properties of sodium-based (Na-GP) and potassium-based (K-GP) geopolymers, a combination of sodium and potassium waterglass compounds with different weight percentages were used to achieve geopolymer materials with optimum self-healing and self-glazing properties. Moreover, these samples were subjected to heat treatment under various time and temperature conditions to optimize their properties in terms of crystallization, and the best results were reported from among these variables. Based on the findings, the specific combination consisting of 75 wt% sodium waterglass and 25 wt% potassium waterglass were the best mixtures. This mixture was heated at a rate of 5 °C per minute to a temperature of 1000 °C and held isothermally for 6 h before being cooled at the same rate. As a result, an amorphous geopolymer turned into a ceramic with irreversible, self-healing, and self-glazing capabilities.

Impact of biopolymer-based Trichoderma harzianum seed coating on disease incidence and yield in oilseed crops

The use of microbe-based biological control for crop pests is recognized as an environmentally safe substitute for conventional chemical pesticides. However, the practical application of microbial inoculants in large-scale agriculture is underexplored, impeding their widespread commercial adoption. This study addresses the scarcity of research on effective delivery methods for microbial inoculants, particularly through seed coating, which has the potential to be a cost- and time-efficient strategy in crop management. In this research, the Trichoderma harzianum strain Th4d, a biological control agent (BCA), was incorporated into specially formulated biopolymeric compositions based on chitosan and cellulose. The efficacy of this seed coating approach was tested against various soil- and seed-borne pathogens in oilseed crops, including soybean, groundnut, and safflower. Results indicate that safflower treated with the biopolymer chitosan-based T. harzianum Th4d 1 % liquid formulation blend exhibited a higher seed yield of 793 kg/ha, seed germination of 84.7 %, and a significant reduction in wilt and root rot by 64.7 %. In groundnut crops, the seed coating led to a seed germination rate of 88.6 %, a 72 % reduction in root rot incidence, and a seed yield of 3040 kg/ha. Similarly, soybean crops treated with the biopolymer chitosan and T. harzianum Th4d displayed 83.4 % seed germination, a 70.9 % reduction in root rot, and a seed yield of 1239 kg/ha. Further on-farm evaluations demonstrated promising results, with the biopolymer chitosan-based T. harzianum Th4d 1 % liquid formulation blend seed treatment showing a high incremental cost-benefit ratio in safflower (1:4.5), soybean (1:2.5), and groundnut crops (1:3.3). This study underscores the potential of microbe-based seed coating as a sustainable and economically viable strategy for pest management in oilseed crops."

Evaluating Engine Performance, Emissions, Noise, and Vibration: A Comparative Study of Diesel and Biodiesel Fuel Mixture

This study investigates the performance, emissions, noise, and vibration characteristics of a single-cylinder, air-cooled, four-stroke diesel engine running on pure diesel (D100) and biodiesel blends (B10: 90% diesel, 10% biodiesel; B20: 80% diesel, 20% biodiesel) at 1800 rpm, where the engine delivers maximum torque. Key metrics such as torque, power, brake specific fuel consumption (BSFC), exhaust gas temperature, noise, vibration, and emissions (CO, CO2, HC, O2, NOx, and smoke opacity) were analyzed. The findings indicate that B10 enhances torque, power output, and overall fuel efficiency, especially at low to medium loads, with a significant 17.54% reduction in BSFC compared to D100 at 40% engine load. Vibration levels generally increased with biodiesel addition, while B10 and B20 both reduced smoke opacity, with B20 having a more substantial effect. HC emissions decreased at idle with B10 but increased at higher loads, suggesting more complete combustion with potential thermal stress on engine components. Noise and vibration results were mixed; B20 reduced noise at higher loads but increased vibration. At 100% load, B20 decreased noise by 1.42% compared to D100. Despite benefits such as improved torque and reduced particulate emissions, biodiesel blends, particularly B20, led to increased NOx and CO2 emissions, emphasizing the need for further op-timization of blend formulations and emission control strategies. This study provides valuable insights into the tradeoffs and potential of biodiesel blends as sustainable diesel alternatives.

Bioplastic Production Using Aloe vera Gel as Plasticizer: A Sustainable Approach

The utilization of bioplastics has garnered considerable interest because of their capacity to alleviate environmental issues related to conventional petroleum-based plastics. This study explores the feasibility of utilizing Aloe vera gel as a plasticizer in bioplastic production, aiming to enhance biodegradability and sustainability. Aloe vera gel, a natural polysaccharide-rich material, offers promising characteristics such as biocompatibility, non-toxicity, and abundant availability. This research involves the formulation of bioplastic blends comprising biodegradable polymers such as starch from Cassava, along with varying concentrations of Aloe vera gel as a plasticizer. The resulting bioplastics' mechanical, thermal, and biodegradation properties are systematically evaluated using standard testing methods. Preliminary results demonstrate that Aloe vera gel effectively improves the flexibility and processability of bioplastic materials while maintaining adequate mechanical strength. Thermal analysis reveals enhanced thermal stability in some formulations, indicating the potential for diverse applications. The bioplastic film had a tensile strength of determined to be 5.53 N. Additionally, the percent mean breaking elongation was found to be 1.2%, indicating the extent to which the film can stretch before reaching its breaking point. The thickness yields a result of 0.05 mm. Moreover, biodegradation studies indicate accelerated degradation rates in composting conditions, highlighting the eco- friendly nature of Aloe vera-based bioplastics. This research underscores the possibility of Aloe vera gel as a sustainable alternative plasticizer in bioplastic production, offering a promising avenue for reducing reliance on fossil-based materials and addressing environmental concerns associated with plastic waste pollution.

Optimizing Antioxidant Potential: Factorial Design-Based Formulation of Fucoidan and Gallic Acid-Conjugated Dextran Blends.

The role of oxidative stress in health and homeostasis has generated interest in the scientific community due to its association with cardiovascular and neurodegenerative diseases, cancer, and other diseases. Therefore, extensive research seeks to identify new exogenous antioxidant compounds for supplementation. Polysaccharides are recognized for their antioxidant properties. However, polysaccharide chemical modifications are often necessary to enhance these properties. Therefore, dextran was conjugated with gallic acid (Dex-Gal) and later combined with fucoidan A (FucA) to formulate blends aimed at achieving superior antioxidant activity compared to individual polysaccharides. A factorial design was employed to combine FucA and Dex-Gal in different proportions, resulting in five blends (BLD1, BLD2, BLD3, BLD4, and BLD5). An analysis of surface graphs from in vitro antioxidant tests, including total antioxidant capacity (TAC), reducing power, and hydroxyl radical scavenging, guided the selection of BLD4 as the optimal formulation. Tests on 3T3 fibroblasts under various conditions of oxidative stress induced by hydrogen peroxide revealed that BLD4 provided enhanced protection compared to its isolated components. The BLD4 formulation, resulting from the combination of Dex-Gal and FucA, showed promise as an antioxidant strategy, outperforming its individual components and suggesting its potential as a supplement to mitigate oxidative stress in adverse health conditions.

ARCHIVE PAPER: Micro worlds versus boundary objects in group model building: evidence from the literature on problem definition and model conceptualization (2007)

Foreword by David AndersenWhen I saw the call for papers for the Special Issue on Qualitative Aspects of System Dynamics Modeling, I immediately thought of the unpublished work completed by my graduate student Aldo Zagonel. I nominated it for consideration as an Archives paper. I believe this 2007 working paper (originally posted on the Sandia website) may be one of the best unpublished pieces of early work on the qualitative nature of our client‐based modeling efforts. (Although Dr. Zagonel included me as an author of the 2007 working paper, my involvement was simply that of a graduate advisor. He deserves all the credit for this work and manuscript.) Zagonel developed this work in his doctoral program and presented an earlier version at the 2002 International System Dynamics Conference (Zagonel 2002). That version of the paper won the Dana Meadows Award for the best student paper.Zagonel's doctoral work was part of our early efforts at UAlbany to develop group model building (GMB) as a technique in system dynamics. These approaches to model conceptualization and formulation blend quantitative and qualitative methods with strong scripted facilitation techniques. Zagonel was the first to note how this combination of approaches creates the ideal‐type dichotomy between “micro worlds” and “boundary objects” that he describes in this paper. His suggestion that much of the good work in system dynamics draws on both of these ideal types was prescient. The ideas discussed here have influenced many others over the years. I am pleased they will now be more easily accessible for our field.I am especially pleased that this paper is being published in the same issue as Laura Black's (2024) thoughtful reflection on Dr. Zagonel's paper and extension of the ideal‐type dichotomy he presents. Her paper offers an update on the idea of Zagonel's “straw man” comparison of micro worlds and boundary objects, suggesting that these are two points on a continuum of models that contribute to decision making and stakeholder interaction. She shows how this aspect of our field has developed in the last few decades and provides a clear framework for how to think about our work.Black, LJ. 2024. Reflecting on Zagonel's Dichotomy of Microworlds and Boundary Objects. System Dynamics Review.Zagonel AA. 2002. Model conceptualization in Group Model Building: A review of the literature exploring the tension between representing reality and negotiating a social order. Proceedings of the 20th International Conference of the System Dynamics Society. Palermo, Italy (July 28‐August 1).AbstractBased upon participant observation in group model building and content analysis of the system dynamics literature, I postulate that modeling efforts have a dual nature. On one hand, the modeling process aims to create a useful representation of a real‐world system. This must be done, however, while aligning the clients' mental models around a shared view of the system. There is significant overlap and confusion between these two goals and how they play out on a practical level. This research clarifies these distinctions by establishing an ideal‐type dichotomy. To highlight the differences, I created two straw men: “micro world” characterizes a model that represents reality and “boundary object” represents a socially negotiated model. Using this framework, the literature was examined, revealing evidence for several competing views on problem definition and model conceptualization. The results are summarized in the text of this article, substantiated with strikingly polarized citations, often from the same authors. I also introduce hypotheses for the duality across the remaining phases of the modeling process. Understanding and appreciation of the differences between these ideal types can promote constructive debate on their balance in system dynamics theory and practice. © 2024 System Dynamics Society.

Preparation and characterization of starch carbamate modified natural sodium alginate composite hydrogel blend formulation and its application for slow-release fertilizer

The exploration of environmentally friendly slow-release fertilizer (SRF) based on natural bio-polymers is of great importance in the development of modern agriculture and horticulture. Herein, a novel starch carbamate (SC) modified sodium alginate (SA) hydrogel (SC/SAH) was prepared utilizing as-synthesized SC and natural SA through the cationic ions crosslinking method and ultimately the corresponding slow-release fertilizer (SC/SAH-SRF) was successfully developed by immersing the dried SC/SAH matrix into saturated urea solution. Due to the low gelation temperature and high viscosity of the synthesized SC, the formed SC/SAH exhibits significantly enhanced properties including excellent water absorbency up to 8.02 g/g with considerable repeatability, abundant pore structure and high hydrophilicity compared with the neat SAH and natural starch based hydrogel (NS/SAH). Accordingly, the SC/SAH leads to higher urea loading amount ∼ 1.28 g/g. Importantly, the resultant SC/SAH-SRF also shows superior slow-release performance, yielding a cumulative urea release of only 61.6 % within 10 h and almost completely release >16 h in water, what's more, only 58.5 % of the urea releases within 25 days and exceeding 50 days for complete release in soil column assays. The slow-release of urea from SC/SAH-SRF well complies for the first-order kinetics and accomplishes via a non-Fickian diffusion process. Moreover, the pot experiment demonstrates that the SC/SAH-SRF has higher growth promotion role for the maize seedlings than those of others. Consequently, this work provides a novel strategy for preparing environmentally friendly SRF by blending modified starch and hydrogel.

Empirical Model Variability: Developing a new global optimisation approach to populate compression and compaction mixture rules

This study systematically evaluated the predictive accuracy of common empirical models for pharmaceutical powder compaction. A dataset of nine placebo and twelve active pharmaceutical ingredient (API) loaded blend formulations (four APIs at three drug loadings) was fitted to the widely used empirical tablet compression (Gurnham, Heckel, and Kawakita) and compaction (Ryshkewitch-Duckworth and Leuenberger) models. At low API loadings (<20w/w%), all models achieved R2 above 90 % and RRMSE (relative root mean squared error) below 0.1. However, as API loads increased, overall model performance decreased, notably in the Heckel model. A parameter variability analysis identified multiple parameter pairs achieving acceptable fits. Consequently, a novel global optimization approach was developed populating arithmetic, geometric, and harmonic mixture rules for empirical tuning parameters. This method outperformed the traditional line of best fit approach. A cross validation study revealed that this method is capable of predicting tuning parameters which achieve an acceptable Goodness of Fit for new blends. Finally, with the restriction of maintaining consistent parameters for the placebo blend, the proposed method could substantially reduce the experimental requirements and API consumption for the exploration of new blends.

Influence of long-term supplementation of a formulated botanical blend on growth performance and carcass traits in feedlot steers.

The objective of this study was to determine if a formulated blend of capsicum oleoresin, clove essential oil, and garlic essential oil (Fytera Advance - Selko USA, Indianapolis IN, USA; CCG) influences measures of cattle growth, efficiency, or carcass traits, during the finishing phase in steers fed a concentrate-based diet. Charolais×Angus steers (n = 96; initial shrunk body weight [BW] = 391±34.0 kg) were used in a 144-d (16 February 2023 to 9 July 2023) finishing feedlot experiment in Brookings, SD, USA. Steers were individually weighed and allotted to one of 14 pens (6 to 7 steers; 7 pens/treatment) in a randomized complete block design and randomly assigned to 1 of 2 treatments: control diet without the test product (CON) or a diet including CCG at 500 mg/steer daily (CCG). Steers were fed twice daily, and bunks were managed according to a slick bunk system. There were no differences (p≥0.10) in any growth performance outcomes from d 1 to 35, 36 to 70, or 71 to 98. From d 99 to 144 steers from CCG tended to have 5% greater average daily gain (p = 0.09) and 8% improved feed conversion (G:F) (p = 0.01). No differences (p≥0.15) were noted for cumulative growth performance measures. No differences were noted for any carcass measurements or categorical carcass outcomes, nor lung or liver health outcomes (p≥0.15). The use of CCG had no influence on cumulative growth performance responses. However, the use of CCG improved G:F during the late feeding period.

Pre-oxidation and coagulation-flocculation as a pretreatment to UF-RO applied for surface water treatment and arsenic removal

In this paper, the effects of applying pre-oxidation, coagulation, and flocculation (C/F) as pretreatment of an ultrafiltration (UF) - reverse osmosis (RO) system treating water containing arsenic were assessed. For this, the performance of a pilot scale – with a maximum treatment capacity of 2.25 m3/h - UF-RO system with and without pretreatment was evaluated. The membranes were able to generate high-quality permeates, even when the feed presented a remarkable increase in color (>2100 uH) and turbidity (>300 NTU) due to the beginning of the rainy season. UF was not efficient for arsenic removal, so RO was essential to guarantee safe water, generating permeates with concentrations below 0.5 μg/L of arsenic. The effective removal of iron and manganese, among other ions, was verified using membranes. Given the high quality of the permeates, blend formulation strategies were carried out, mixing filtered water from the conventional water treatment plant and RO permeate (Strategy I) and mixing filtered water, UF permeate, and RO permeate (strategy II). Strategy II was viable for arsenic concentrations in filtered water of 13 and 15 μg/L. Pretreatment was important in maintaining a higher membrane permeability and ensured a more stable performance in the face of variations in feed quality, which may be seasonal in some places, as in the present case, where feed quality is significantly altered by the rainy season. Overall, although UF and RO membranes are effective processes for treating surface water containing arsenic, the results suggested that pretreatment, which is already part of the treatment of several water treatment plants, guarantees more robustness to the treatment concerning a higher and more stable membrane permeability, directly impacting operational expenses with membranes operation.

A Novel image processing technique for weighted particle size distribution assessment

The objective of the study was to create a reliable method that could be used to evaluate the particle size distribution of samples and pre-mixes in real-world situations, particularly those consisting of typical formulation blends. The goal was to use this method to assess the uniformity of the samples and ensure that they met the required quality standards. The researchers aimed to create a method that could be easily incorporated into the manufacturing process, providing a practical and efficient solution. This study demonstrates the use of ImageJ software to analyze the particle size distribution (PSD) of powders. The technique produces qualitative data from microscopy images and quantitative data from analysis of parameters including average diameter, D 10, D 50 , D 90, and standard deviation. The method was tested with various treatments, showing differentiating outcomes in all cases. The alternate technique provides a rapid and cost-effective method for PSD analysis, surpassing the limitations of sieve analysis. Extensive testing of the method, using a variety of sample types, including typical formulation blends, was performed. The results suggest that the method can effectively assess the morphology of changing materials during batch manufacturing and characterize uniformity in blends. The methodology has the capability to identify attributes related to PSD that are typically required to be monitored during manufacturing. The technique allows for accurate and reliable quantification of the attributes through image capture technology. The technique has future potential and has important implications for material science, powder rheology, pharmaceutical formulation development, and continual process monitoring.

Hydrolytic degradation behaviors of polylactides/poly(propylene carbonate blends: Monolayers and bulk films

The study investigates the hydrolytic degradation behaviors of blends comprising polylactides (PLA) and poly(propylene carbonate) (PPC) in the form of monolayers and bulk films. PLA is a biodegradable polymer widely used in various applications, while PPC offers unique properties, making it a promising candidate for blend formulations. The research explores the degradation kinetics and mechanical properties under controlled hydrolysis conditions. The finding focuses on the compatibility of PLA and PPC, their degradation mechanisms, and the impact of blend composition on degradation rates. Understanding the hydrolytic behavior of these blends is crucial for designing eco-friendly materials with tailored degradation profiles for diverse applications.

58 Evaluation of a phytogenic blend on growth performance, health, carcass traits, and efficiency of dietary net energy utilization in finishing beef steers

Abstract The objective of this study was to determine if a formulated blend of capsicum oleoresin, clove essential oil, and garlic essential oil (CCG; Fytera Advance - Selko USA, Indianapolis IN) influences measures of cattle growth, efficiency, health, or carcass traits, during the finishing phase in steers fed a concentrate-based diet. Charolais × Angus steers [n = 96; initial shrunk body weight (BW) = 391 ± 34.0 kg] were used in a 144-d finishing experiment at the Ruminant Nutrition Center in Brookings, SD. Steers were individually weighed and allotted to one of 14 pens (n = 6 to 7 steers; 7 pens/treatment) in a randomized complete block design and randomly assigned to 1 of 2 treatments: control diet without the test product (CON) or a diet including CCG at 500 mg/steer daily (CCG). The average nutrient content of the finishing diet was: 13.5% CP; 18.7% NDF; 2.06 Mcal/kg NEm; and 1.39 Mcal/kg NEg; monensin sodium was included in the diet at 30 g/907 kg. Steers were fed twice daily, and bunks were managed according to a slick bunk system. There were no differences (P ≥ 0.10) in any growth performance outcome from d 1 to 35, 36 to 70, or 71 to 98. The within pen standard deviation for average daily gain (ADG) from d 71 to 98 tended to be reduced (P = 0.10) for CCG steers compared with CON. From d 99 to 144 steers supplemented CCG had 5% greater dietary energy utilization (P = 0.01), tended to have 5% greater ADG (P = 0.09), and 8% improved feed efficiency (P = 0.01). Experimental periods when improved pen gain uniformity and feed efficiency were observed coincided with increased summertime temperatures. No differences (P ≥ 0.15) were noted for cumulative growth performance. No differences were noted for any carcass measurements or categorical carcass outcomes, nor lung or liver health outcomes (P ≥ 0.15). Use of CCG had no appreciable influence on any cumulative growth performance responses. However, the use of CCG decreased within pen variation in ADG indicating more uniform nutrient intake among cattle and increased feed efficiency during summertime heat events.

PSVI-13 Formulated botanical preparation improves passive immunity from sows to piglets

Abstract The medicinal plant turmeric increases immunoglobulin production in livestock and rodents. The purpose of this investigation was to determine the effect of a formulated blend of turmeric, capsicum, and black pepper oleoresins (TCB) on colostrum and milk quality of sows and health of piglets. Twenty-four sows (Parity 2+) were assigned to one of the following dietary treatments (n = 8 sows/treatment): 1) unsupplemented control (CON); 2) 100 ppm of TCB (TCB-100), and 3) 150 ppm of TCB (TCB-150). Supplementation was from 87 d of gestation until weaning (d 28). During gestation and lactation, individually housed sows were fed fortified corn and soybean meal diets at 2.5 kg/d and 2.5 + 0.25 * piglet kg/d, respectively, with ad libitum access to water. Blood and colostrum samples were collected from the sow within 24 h of farrowing for IgG and IgA analysis, and milk samples were collected weekly for IgA analysis. Piglet blood samples were collected at weaning (d 28) for IgG and IgA analysis and at 4-wk post weaning for IgA analysis. Data were subjected to a one-way ANOVA (or two-way in the case of repeated measures), with tests for linear trend of the dose response. Serum IgG and IgA in sows at farrowing were linearly increased with TCB supplementation (Table). Similarly, colostrum IgG, and colostrum and milk IgA were linearly increased with TCB, with greatest concentration in TCB-150 relative to CON (Table). Serum IgG in piglets was not affected by sow supplementation, but serum IgA was linearly increased. Interestingly, the increase in serum IgA persisted through 4-wk post-weaning. Diarrhea frequency in piglets 1 to 4 wk post-weaning was linearly decreased with TCB supplementation (Table). A follow-up study with a similar design was conducted with supplementation of TCB-150 starting at 108 d of gestation to represent a commercial application in lactating diets only. Sow serum IgG and IgA at farrowing were measured, and both were significantly increased with TCB-150 (Table). In conclusion, supplementation of TCB at 150 ppm improves colostrum and milk quality, and passive immunity from sows to piglets. Furthermore, enteric health of the piglets was improved. Additional experiments to determine the implications of this response on sow and piglet health and performance in commercial conditions are warranted.

Properties of biopolymer blends based on Rugulopteryx okamurae and hydrophobic polycaprolactone (PCL) and hydrophilic acylated soy protein isolated (SPIa)

The present study explored the utilization of Rugulopteryx okamurae (RO), an invasive brown seaweed, as a renewable raw material for plastic materials based on biopolymer blends. The goal of this study was to improve the previously observed poor mechanical properties of materials based on single biopolymer RO. To enhance these properties, two polymers with distinct hydrophobicities were incorporated into the formulation of different blends: hydrophobic polycaprolactone (PCL) and hydrophilic acylated soy protein isolate (SPIa). SPIa was derived from soy protein through a chemical modification process, introducing hydrophilic carboxyl groups. The addition of PCL significantly strengthened the blend, increasing the storage modulus (E′1 Hz) from ~ 110 to ~ 250 MPa. Conversely, SPIa incorporation resulted in softening, with E′ values around 40 MPa. Both additives enhanced deformability proportionally to their concentrations, with SPIa exhibiting notably higher deformability, reaching a maximum deformation of ~ 23% for a RO/SPIa ratio of 25/75. In summary, the study demonstrates the feasibility of producing environmentally friendly blend materials based on RO, tailored for specific applications by incorporating suitable additives into the formulation. Therefore, PCL is recommended for applications susceptible to moisture effects, such as packaging, while SPIa is suggested for highly absorbent applications such as personal care or horticulture.