AbstractWe study frequency domain acoustic scattering at a bounded, penetrable, and inhomogeneous obstacleΩ−⊂Rd\Omega^{-}\subset\mathbb{R}^{d},d=2,3d=2,3. By defining constant reference coefficients, a representation formula for the pressure field is derived. It contains a volume integral operator, related to the one in the Lippmann–Schwinger equation. Besides, it features integral operators defined on∂Ω−\partial\Omega^{-}and closely related to boundary integral equations of single-trace formulations (STF) for transmission problems with piecewise constant coefficients. We show well-posedness of the continuous variational formulation and asymptotic convergence of Galerkin discretizations. Numerical experiments in 2D validate our expected convergence rates.