Formation Of Twins Research Articles

High-cycle and low-cycle fatigue characteristics of multilayered dissimilar titanium alloys

Multilayered structures of dissimilar titanium alloys can achieve excellent fracture ductility and strength, while their fatigue characteristics especially dislocation networks and twin formation are rarely reported. Heterogeneous microstructures are observed in the multilayered TC4/TB8 alloys, including fine acicular α grains, continuous α layer at prior β grain boundaries (αGB) and β matrix on the TB8 layer, together with equiaxed α grains on the TC4 layer. High-cycle fatigue (HCF) and low-cycle fatigue (LCF) tests show that the initial fatigue damage appears at the αGB/β matrix interfaces on the TB8 layer instead of the boned TC4/TB8 interfaces. Since the stress concentration induced by dislocation pile-up is prone to micro-void formation and crack propagation at the αGB/β interfaces. For LCF, the αGB/β interfaces can not only act as impenetrable barriers and sources of lattice dislocations, but also allow the dislocations cross boundaries during cyclic tension and compression because of the high boundary energy. The formation characteristic of deformation twins that is beneficial for the plastic deformation of α grains in TC4 layer during cyclic strain is investigated. Furthermore, the hexagonal dislocation networks are also found within the equiaxed α grains of TC4 layer after LCF, and the role between interface barrier and slip direction in the formation mechanism is analyzed.

Five-fold twin formation in face-centered cubic metals under impact loading

Five-fold twins (FFTs) are unique microstructural features in face-centered cubic (FCC) metals that significantly influence their mechanical strength. This study examines FFT formation in Cu, Au, and Ni under high-strain rate conditions induced by cold spray and compression shock impact loading, using atomistic simulations. We reveal a sequential twinning mechanism for FFT formation under impact loading, where the specific growth path varies, leading to inherently unstable FFTs that decompose post-formation. Interestingly, impact velocity had minimal influence, while elevated temperatures suppressed FFT formation, suggesting a dependency on the twinning mechanism. The stacking fault energy of the FCC metal greatly affected FFT propensity; metals with lower stacking fault energy (e.g., Au) readily formed FFTs, while those with higher stacking fault energy (e.g., Ni) encountered greater difficulty. These findings provide new insights into the behavior of FFTs under dynamic loading conditions, with implications for the design of high-strength nanocrystalline materials.

Impact of hot rolling on the evolution of microstructure and mechanical properties of sintered commercially pure Ti compacts

While titanium (Ti) alloys offer significant advantages, such as high strength and corrosion resistance, their widespread utilization in various engineering sectors is hindered by their prohibitively high cost, which is attributed to expensive equipment and complex preparation processes. The present study centered on assessing the influence of multi-pass hot rolling, a commonly available industrial process, on the microstructure and mechanical properties of sintered powder metallurgy commercially pure Ti (cp-Ti). With increasing levels of accumulated deformation, the rolled materials exhibited a refined grain size, the formation of twins, and a reduced residual porosity, resulting in a tailored microstructure that enhanced the material's balance between strength and ductility. The ultimate tensile strength reached 574.8 MPa, with an elongation at break of 28.1%. The hardness peaked at 196.4 HV.

Multiscale simulation combined with experimental investigation on residual stress and microstructure of TC6 titanium alloy treated by laser shock peening

The evolution behavior of residual stress and microstructure of TC6 titanium alloy under laser shock peening (LSP) were investigated using finite element (FE) and molecular dynamics (MD) simulations combined with experiments. The propagation process of laser-induced stress wave and plastic deformation behavior of TC6 titanium alloy model were studied using FE software with ABAQUS. The FE simulation results showed that increasing laser energy and impact time could increase the amplitude of compressive residual stress (CRS) to a certain extent, while a higher overlapping rate improved the CRS uniformity. The experimental results of residual stress testing based on XRD technology were consistent with the FE simulation results. Based on the piston shock method, the microstructural evolution process of α phase of titanium alloy under different shock velocities was simulated using MD software with LAMMPS. Laser shock wave promoted the transformation of hexagonal close-packed (HCP) structure to body-centered cubic (BCC) and face-centered cubic (FCC) structures in titanium alloy, and the generated dislocation density increased with increasing shock velocity. The severe plastic deformation caused by laser shock wave induced the formation of mechanical twin, subgrain and stacking fault, which was consistent with the (transmission electron microscope) TEM characterization results.

Anisotropic mechanism of cold-rolled pure titanium plate during the two-step tensile process of the variable path

The effects of pre-deformation on the macro-mesoscopic deformation characteristics of the titanium plate during variable path tensile were studied by a two-step tensile test and electron backscatter diffraction (EBSD). The Schmid law, Kernel Average Misorientation (KAM), Taylor axis, and In-Grain Misorientation Axis (IGMA) were used to forecast and identify the types and change laws of the activated deformation modes under different loading conditions. The results demonstrated that dislocation slip is the primary cause of the evolution of the basal split texture components. The nucleation and de-twinning of {10–12}ET resulted in the sudden appearance and disappearance of the <0001>//RD texture. The pre-tensile causes a texture redirection that reduces the activability of both prismatic <a> slip and pyramidal <a> slip in the following variable path tensile. Among them, prismatic <a> slip is the dominant deformation mechanism that causes yield and hardening behavior during RD tensile and TD-RD tensile (rolling direction-RD, transeverse direction-TD). A portion of the prismatic <a> slip is preferentially activated in TD tensile and RD-TD tensile deformation, and the deformation is subsequently jointly controlled by the prismatic <a> slip and the pyramidal <a> slip. The pre-tensile along RD promotes nucleation of {10–12} extension twin (ET) during subsequent RD-TD variable path tensile, while tensile along TD-RD coordinates plastic deformation by consuming a significant quantity of {10–12}ET generated during pre-tensile along TD. The formation of slip-assisted twins in neighboring grains is facilitated by the dislocation pile-up at grain boundaries, and the de-twinning phenomenon also cause the local dislocation pile-up to weaken.

Hardness and microstructural evolution of CoCrFeNi high-entropy alloys during severe plastic deformation

In this study, the evolution of hardness and microstructure in a CoCrFeNi high-entropy alloy processed by high-pressure torsion was investigated. An initial increase in hardness was attributed to the rapid increase in low-angle grain boundaries (LAGBs), accompanied by a high density of dislocations. With continuous straining, some LAGBs evolved into high-angle grain boundaries and completed the grain boundary strengthening. A remarkable increase in hardness was achieved in the final stage of hardness enhancement, primarily due to the formation of numerous twins within nanograins, which were mainly formed by the emission of Shockley partial dislocations emerging from grain boundaries. Furthermore, a twin trailing the stacking fault was found in the nanograin, and a critical stress for twin nucleation was estimated to be about 2.16 GPa. Defects with low-energy configurations are closely correlated with the thermal stability of nanocrystalline CoCrFeNi alloys. The defects within nanograins yielded an average strain of about 1.1 % and the corresponding strain energy was identified to about 17 J g−1.

Tuning generalized planar fault energies to enable deformation twinning in nanocrystalline aluminum alloys

As deformation twins have a profound impact on the plastic flow and mechanical properties of metallic materials, enhancing deformation twinning in face-centered cubic (FCC) metallic materials has long served as a unique microstructure design strategy to attain an extraordinary strength-ductility synergy. Deformation twinning, however, rarely occurs in pure FCC Al and its alloys since its generalized planar fault energies (GPFEs) are almost unaffected by most soluble alloying elements such as Mg, Zn and Cu. Here we successfully tune the GPFEs of a nanocrystalline Al-Mg alloy by alloying with Zr, Fe or Y element, and enable deformation twinning in the Zr-, Fe- and Y-containing alloys. Based on a combined analysis of microscopic observations, modeling and ab initio calculations, we find a strong grain-size-dependent twinning (i.e., twinning occurs in preferable grains having sizes in the range ∼20–40 nm), as well as only one single twinning plane (i.e., twinning occurs in single, parallel atomic planes) for twin formation rather than intersecting twinning planes (i.e., twinning occurs in multiple, unparallel atomic planes) usually observed in coarse-grained FCC materials. This interesting twinning behavior is further observed to be accompanied by grain rotations, producing defective twin boundaries. Our experimental results extend the current understanding of the plastic deformation mechanisms in nanograined metallic materials, and will guide microstructure design of twinnable nanograined Al alloys with an improved strength-ductility synergy.

Spatially varied stacking fault energy induced low twinning ability in high entropy alloys

Nanostructured high-entropy alloys (HEAs) are promising candidates for extreme load-bearing applications due to their superior performance. In this work, we investigate the deformation behaviors of CoCrFeMnNi HEA under high-speed impact by molecular dynamics simulations. Compared with Al, Ni, and Cu representing pure metals with low to high stacking fault energies, it is found that the CoCrFeMnNi HEA exhibits remarkably low twinning density under shock, despite its extremely low stacking fault energy. Shear loading is then applied to stacking-faulted HEAs and these pure metals to study the evolution of stacking faults under shear stress. The results further show a low tendency for stacking faults to transform into deformation twinning in HEAs, regardless of the initial density of stacking faults. The energy path for deformation twins and stacking faults was calculated, and a direct comparison of fault energies could not explain the deformation mechanism of HEA. We reveal that the inhomogeneous energy profile of dislocation slip caused by the inherent heterogeneity of HEA leads to dispersed stacking fault propagation, which suppresses twinning formation. These results address the spatially tunable defects and further urgent need for the synergistic design of components and microstructures in HEAs.

The mechanism of twins formation

What events in pregnant woman underlie twins formation? What do zygosity, chorionicity and amnionicity depend on? It seems that the answer is very clear. As early as in 1955, the works by G.W. Corner were published, which served as the basis for proposing the traditional model of twins formation, still remains widely acknowledged. But whether is everything so obvious? In order to answer this question, it is necessary to go back to the roots and understand of how the overall idea about fertilization and formation of multiple pregnancies has evolved since the XVII century till the present time.

Modification and strengthening mechanism of high strength-toughness as-cast Al–11Si–3Cu alloy modified with minor Sr and Er content

The strength of Al–11Si–3Cu requires improvement to meet the growing demands of manufacturing and expand its application in the automotive market. A new high strength-toughness as-cast Al–11Si–3Cu alloy with the ultimate tensile strength and elongation up to 294 MPa and 3.5 % was developed by using minor Sr and Er modifiers. The TEM and the first principles calculations showed that Sr and Er atoms adsorbed on the eutectic Si surface and prompted the formation of twins that branched in 70.5° and 39° directions, and the synergistic effects of Sr and Er atoms significantly reduced the size of eutectic Si to ∼500 nm. Moreover, the ∼10 nm Al3Er and ∼200 nm Al8Cu4Er particles formed in the alloy, which have positive effects on enhancing the mechanical properties of the alloy. The dislocation lines were stretched when passing through the Al3Er particles and eventually formed dislocation rings, while the motion of the grain boundary was hindered by the Al8Cu4Er particle. Additionally, the modification mechanism of Sr and Er modifiers on the eutectic Si and the strengthening mechanism of the modified alloy were discussed.

Hydrogen-enhanced densified deformation twins in 304L austenitic stainless steel fabricated by selective laser melting

Twin boundaries are the preferred site for crack nucleation and propagation in a hydrogen-rich environment. The relationship among hydrogen, cellular structure, and deformation twins is significant in further enhancing the resistance to hydrogen embrittlement of austenitic stainless steels produced by SLM. It has been demonstrated that cellular structures with high dislocation densities play a positive role in increasing stress above a critical level for deformation twin formation. The cellular structure affects the distribution of hydrogen, with hydrogen presence at cellular boundaries reducing its accumulation at grain boundaries. Hydrogen increases the density of deformation twins and reduces the thickness of individual deformation twins. This phenomenon can be attributed to an increase in nucleation sites for the deformation twin, which is closely related to the decrease in stacking fault energy and the increase in dislocation density caused by hydrogen. Both cellular structure and deformation twins play a positive role in improving the hydrogen embrittlement resistance of austenitic stainless steels.

Increase in interplanar distances and formation of amorphous shear bands in deformed diamond

Amorphous transformation-deformation bands have been observed in diamond under cyclic loading (at planetary ball milling) near the graphite-diamond equilibrium line at temperatures below the Debye temperature. The maximum stresses and temperature in the diamond do not exceed 6 GPa and 420 K, respectively. These bands add to the set of plastic deformation mechanisms in diamond. TEM methods and conventional X-rays were used to investigate the mechanisms of plastic deformation of diamond. The observed mechanisms include amorphous deformation bands, bond breaking, twin formation, and phase transitions of diamond-lonsdaleite and diamond-onions. The increased interplanar distances provide evidence of the plastic deformation mechanism due to bond breaking. The distances of 0.222 and 0.255 nm are significantly larger than the initial value of 0.206 nm, which is characteristic of d111 diamond. This increase in distance cannot be attributed to lattice expansion caused by point defects, but rather to the breakage of interatomic bonds.

Atomic scale mechanism of reorientation induced plasticity in titanium alloys - experimental and first principles investigation of the mobile [formula omitted] interfaces

Recent experiments identified a new type of stress induced structural transformation allowing to combine high strength, great work hardening and good ductility in multiphase Ti alloys. These properties are achieved through reorientation of the α′ martensite plates being in specific self accommodating 〈54‾1‾3〉 type II twin relation, i.e. under applied load one martensite variant reconfigure to its twinned configuration with visible motion of the {134‾1} twin boundary. This mechanism of plastic deformation was never observed before thus, its current understanding is fragmentary. In this article we present the results of experimental observations and ab initio calculations of 〈54‾1‾3〉 type II twins determining the crystallography of twin formation, structure and energy of the {134‾1} interface as well as mobility of the corresponding twinning disconnections. It was found that the investigated boundary has one of the lowest energies among known twinning modes in hexagonal Ti. Moreover, the 〈54‾1‾3〉{134‾1} disconnections have the smallest Burgers vector and step height in comparison to other active twinning systems. As a result, these disconnections are highly mobile which rationalize migration of the {134‾1} twin boundaries at straining. Furthermore, energy of the twin boundary and mobility of disconnections can be adjusted by particular alloying elements enabling the conscious development of new alloys exhibiting reorientation induced plasticity.

Optimization of hot-rolling parameters for a powder metallurgy Ti–47Al–2Cr–2Nb-0.2W alloy based on processing map and microstructure evolution

In this work, a two-stage rolling method with varied temperature and strain rate was proposed for powder metallurgy (PM) Ti–47Al–2Cr–2Nb-0.2W alloy sheets based on the guidance of processing map and microstructure evolution. Compared with conventional rolling at a high temperature and a low strain rate, the TiAl alloy exhibited enhanced plastic deformability through the implementation of the two-stage rolling method, resulting in a higher cumulative true strain. Microstructure analysis revealed significant grain refinement in the rolled sheet. During the first stage of hot rolling with high temperatures and low strain rates, the softening behavior caused by dynamic recovery (DRV) and dynamic recrystallization (DRX) is conducive to the plastic deformation in the second stage rolling (low temperatures and high strain rates). In addition, the formation of mechanical twins further promotes DRX behavior. The softening mechanism of α2 phase is DRV, and that of γ phase is continuous dynamic recrystallization (CDRX) and discontinuous dynamic recrystallization (DDRX).

Temperature study of deformation twinning behaviour in nickel-base Superalloy 625

Deformation behaviour in the Nickel-base superalloy 625 has been studied by tensile testing at four temperatures: 295, 223, 173 and 77 K. The microstructure has been investigated using TEM, FIB-SEM, EBSD and ECCI techniques. Deformation in the alloy turns out to be a competitive course of events between at least two deformation mechanisms, namely dislocation slip and deformation twinning. Slip is the predominant deformation mechanism at higher temperatures. While at 77 K, deformation induced twinning gives an extra degree of freedom as one of the main deformation mechanisms, i.e., the material shows a twin induced plasticity, TWIP, behaviour. Ab initio calculations indicate that the influence of cryogenic/sub-zero temperatures on the stacking fault energy of this alloy can be limited and therefore the formation of deformation twins cannot be determined solely by the stacking fault energy. The results implies that critical strain and strain hardening rate influences the deformation twinning onset and twinning rate.

Analysis of Cu-decorated Ti particles as a reinforcement for AZ91 alloys prepared using the powder metallurgy method

Magnesium (Mg) matrix composites (Mg-MMCs) with high strength and ductility properties are crucial for the development of lightweight automobiles. In this study, a novel method is proposed for fabricating Mg-MMCs by incorporating nanocopper (Cu) decorated titanium (Ti) particles (Cu@Ti) to reinforce AZ91 alloys. The in-situ generation of the AlCuMg phase at the interface between the Ti particles and the Mg matrix enhances interface integration and promotes the formation of massive twins. The 5.0 wt% Cu@Ti/AZ91 composite exhibits notable mechanical properties, with a yield strength of 238 MPa, ultimate tensile strength of 368 MPa, elongation of 12%, and modulus of elasticity of 46 GPa. These values represent increases of 8.9%, 5.3%, 50.0%, and 2.0%, respectively, compared to those of AZ91 alloys. The strengthening mechanism is mainly attributed to grain refinement strengthening, thermal expansion coefficient mismatch strengthening, Orowan strengthening, and load transfer strengthening. The plasticity improvement benefits from the optimization of the interface structure, grain refinement and twin formation.

3D Twin Formation Mechanism from Onion Carbon

3D Twin Formation Mechanism from Onion Carbon

Modeling of stakeholder influence on effectiveness of team decisions in the digital network space of crisis management centres of the EMERCOM of Russia

The article deals with issues related to modeling of stakeholder influence on effectiveness (sustainability) of teamwork in crisis management centres (hereinafter referred to as CMC) of the Ministry of the Russian Federation for Civil Defence, Emergencies and Elimination of Consequences of Natural Disasters (hereinafter referred to as EMERCOM of Russia) while analysing, forecasting development and resolving/reducing conflictness of social emergencies (hereinafter referred to as SE). The problem is considered from the perspective of using a nonlinear approach in modeling in the form of the Verhulst equation which allows to analyse complex social processes. The influence of different stakeholder groups is modeled at different values of the “a” parameter of its intensity– weak, medium, strong. The article presents the results of practical research on assessing the influence of stakeholders, primarily the external ones, on effectiveness (sustainability) of the CMC teamwork in the analysis, forecast of development, and resolution/reduction of conflictness of SE. The definition of SE is given as an attractor that has emerged due to unresolved social contradictions which have caused an imbalance in public relations. The work of the CMC teams is conducted in the digital network environment of the centres, and it introduces certain specifics into its activities. The research shows the general scheme of the stakeholder approach implementation in team management in the analysis, forecast of development and resolution/reduction of conflictness of SE. The author presents the results of the nonlinear modeling of effectiveness (sustainability) of the CMC teamwork, depending on the intensity of stakeholder influence on decisions made by the team. A system of indicators characterising the regression model of the “a” coefficient of stakeholder influence is proposed, the specific values of which can be measured during field research. Three modes (three types of attractors) of teamwork are investigated. The key objective of the study is to create prerequisites for the formation of a digital twin of the CMC teamwork of the EMERCOM of Russia in SE.

A bimodal microstructure to improve the strength-ductility properties of Ti-Cu alloys by using eutectoid reactive laser depositing

A novel bimodal structure was achieved in Ti-6wt%Cu by laser metal deposition. The microstructures and tensile behaviors of this heterostructure, comparing with typical colony structure, were examined to understand the mechanisms of strengthening and deformation. The bimodal structure consisting of nano-scale eutectoid lamellae and fine Widmanstätten-α exhibits the strength-ductility combination and excellent strain hardening ability. The shear deformation mechanism in ultrafine lamellae and hetero-deformation induced hardening in bimodal structure contribute to the high strain hardening. In contrast, the colony structure with coarse laths and Ti2Cu precipitates show inferior dislocation strengthening leading to a lower tensile strength, while the formation of deformation twins ensures a higher ductility.

Achieving ultrahigh strength and ductility via high-density nanoprecipitates triggering multiple deformation mechanisms in a dual-aging high-entropy alloy with precold deformation

How to achieve high-entropy alloys (HEAs) with ultrahigh strength and ductility is a challenging issue. Precipitation strengthening is one of the methods to significantly enhance strength, but unfortunately, ductility will be lost. To overcome the strength–ductility trade-off, the strategy of this study is to induce the formation of high-density nanoprecipitates through dual aging (DA), triggering multiple deformation mechanisms, to obtain HEAs with ultrahigh strength and ductility. First, the effect of precold deformation on precipitation behavior was studied using Ni35(CoFe)55V5Nb5 (at.%) HEA as the object. The results reveal that the activation energy of recrystallization is 112.2 kJ/mol. As the precold-deformation amount increases from 15 % to 65 %, the activation energy of precipitation gradually decreases from 178.8 to 159.7 kJ/mol. The precipitation time shortens, the size of the nanoprecipitate decreases, and the density increases. Subsequently, the thermal treatment parameters were optimized, and the DA process was customized based on the effect of precold deformation on precipitation behavior. High-density L12 nanoprecipitates (∼3.21 × 1025 m−3) were induced in the 65 % precold-deformed HEA, which led to the simultaneous formation of twins and stacking fault (SF) networks during deformation. The yield strength (YS), ultimate tensile strength, and ductility of the DA-HEA are ∼2.0 GPa, ∼2.2 GPa, and ∼12.3 %, respectively. Compared with the solid solution HEA, the YS of the DA-HEA increased by 1,657 MPa, possessing an astonishing increase of ∼440 %. The high YS stems from the precipitation strengthening contributed by the L12 nanoprecipitates and the dislocation strengthening contributed by precold deformation. The synergistically enhanced ductility stems from the high strain-hardening ability under the dual support of twinning-induced plasticity and SF-induced plasticity.