Formation Of Coatings Research Articles

Initial Stages of Electrocrystallization of Coatings with Tin and Tin-Copper and Tin-Copper-Ultradisperse Diamond Alloys

The need of modern microelectronics in the development of technological processes for the formation of nanostructured layers puts forward the necessity of understanding the mechanisms of nucleation and growth of deposits. The article considers the features of the initial stages of electrocrystallization of coatings with tin and tin-copper and tin-copper-ultradisperse diamond alloys. The kinetic regularities of electrode processes were studied by the voltammetry method. Based on the experimental data, the nucleation parameters (nucleation energy, effective interphase surface energy, radius and volume of the nucleus) were calculated. SEM images were obtained and the features of the roughness of the coating surfaces after deposition for 10, 20, 30 and 60 s were studied. It was found that co-deposition of tin-copper alloys and tin-copper-ultradisperse diamond particles increases the value of the limiting current from 2.8 · 10–2 to 5.0 · 10–2 A/cm2. With an increase in electrocrystallization over-voltage, the rate of nucleation increases and their size decreases, while fine-grained and dense deposits are formed. With an increase in the deposition duration, crystallites grow and gradually coalesce with each other, the value of the equivalent diameter of the grain coatings increases, respectively, for: Sn – from 1 ⋅ 10–6 to 4 ⋅ 10–6 m, Sn-Cu – from 0.3 ⋅ 10–6 to 1.3 ⋅ 10–6 m, Sn-Cu-ultradispersed diamond – from 0.9 ⋅ 10–6 to 1.4 ⋅ 10–6 m. The established patterns make it possible to control the structure of the coatings and obtain deposits with specified properties. The presented results may be of interest to specialists involved in the formation of solderable galvanic coatings.

Electrodeposition of Ni-WC composite coatings: formation, structure and properties

Currently, electroplating is actively developing, and one of its promising areas is the study of composite electrochemical coatings (CEC). They are of great interest to the industrial sector, especially for mechanical engineering, due to their unique properties. CEC contain microscopic particles as additives that can significantly improve coating properties such as hardness and wear resistance. This is especially important for the manufacturing of high-quality parts of industrial mechanisms. These areas can lead to new advances in the development of better and more durable materials. In this work, composite coatings of nickel-tungsten carbide were obtained by the method of electrodeposition. The deposition was carried out in a sulfuric acid electrolyte with different concentrations of tungsten carbide. Formation of composite coatings was carried out at a concentration of dispersed particles in a sulfate electrolyte of 10 g/L. The coatings have no pores or cracks. Nickel and tungsten carbide phases were detected in the coatings by X-ray phase and micro-X-ray spectral analyses. Inclusions of WC in the nickel matrix lead to an increase in the microhardness of the coating by 10–15 times. Wear resistance was assessed under dry sliding friction with reciprocating motion; a decrease in the volume of worn material by 2–3 times was noted when tungsten carbide was added into the nickel matrix.

On the Role of Substrate in Hydroxyapatite Coating Formation by Cold Spray

The deposition of agglomerated hydroxyapatite (HAp) powders by low-pressure cold spray has been a topic of interest in recent years. Key parameters influencing the deposition of HAp powders include particle morphology and impact kinetic energy. This work examines the deposition of HAp powders on various metal surfaces to assess the impact of substrate properties on the formation of HAp deposits via cold spray. The substrates studied here encompass metals with varying hardness and thermal conductivities, including Al6061, Inconel alloy 625, AISI 316 stainless steel, H13 tool steel, Ti6Al4V, and AZ31 alloy. Single-track experiments offer insights into the initial interactions between HAp particles and different substrate surfaces. In this study, the results indicate that the ductility of the substrate may enhance HAp particle deposition only at the first deposition stages where substrate/particle interaction is the most critical factor for deposition. Features on the substrate associated with the first deposition sprayed layer include localized substrate deformation and the formation of clusters of HAp agglomerates, which aid in HAp deposition. Furthermore, after multiple spraying passes on the various metallic surfaces, deposition efficiency was significantly reduced when the build-up process of HAp coatings shifted from ceramic/metal to ceramic/ceramic interactions. Overall, this study achieved agglomerated HAp deposits with high deposition efficiencies (30–60%) through single-track experiments and resulted in the preparation of HAp coatings on various substrates with thickness values ranging from 24 to 53 µm. These coatings exhibited bioactive behavior in simulated body fluid.

Composite electrochemical coatings of Ni-CrB2 from sulfuric acid and sulfamate electrolytes: formation, structure and properties

Electrodeposited coatings are in demand in many industries: due to the high adhesive strength to the base metal, they can be applied to complex-shaped products, and the thickness of the deposited coating can be controlled. However, standard electrolytic coatings do not always meet the necessary operating requirements. In this case, the formation of composite electrolytic coatings, which consist in the modification of electrolytes by various dispersed particles, becomes an urgent task. These particles are introduced into the electrolyte and deposited together with the precipitate metals, which leads to changes in the coating properties. In this article, the structure, adhesive and corrosion properties of nickel-chromium diboride composite coatings obtained in the electrodeposition process are studied. Precipitation was carried out in sulfuric acid and sulfamate electrolytes with a concentration of dispersed chromium diboride particles of 10-40 g/l. The coatings consist of nickel and CrB2 phases. The adhesive strength of the coating with a steel base is satisfactory; chipping and peeling were not observed. The corrosion resistance of sulfamate electrolyte coatings is higher than that of the coatings obtained from sulfuric acid electrolyte due to the compactness of nickel precipitates. Chromium diboride in the coating provides 1.5-2 times greater corrosion resistance.

Metals geochemistry and ecological risk assessment in lateritic soils and their transfer to tea plants

ABSTRACT Tea plant cultivation has been demonstrated to change the physicochemical properties of soils and metal bioavailability. The present study reported the geochemistry of four selected metals (Fe, Mn, Cr, and Ni) in lateritic soil cores regarding various depths cultivated with tea plants of different ages (3, 6, and 10 years old). The ecological risk and bioaccumulation of these metals in tea plants were also evaluated. The results indicate the acidic property of tea plant cultivation soils (pH < 4.5) and highlight further soil acidification due to long-term cultivation. The soils were strongly affected by farming methods and showed high levels (average from all soil cores) of total organic carbon contents (4.0% w/w), total nitrogen (2806 mg kg−1), and total phosphorus (1730 mg kg−1). We suggest that the selected metals originated naturally, supported by a high percentage in residual fractions from the results of soil sequential extraction (over 95% for Mn, Fe, and Ni and ∼ 90% for Cr). These metals exhibited no ecological risk to the adjacent environment. Mn showed the highest bioavailability, possibly due to the acidic soils and nitrogen fertiliser applications, increasing the release of Mn from soils. Mn also exhibited the highest bioconcentration factor (BCF) among four metals and 2.4 ÷ 6.5-folds higher BCFs in tea leaves than in roots. Despite the dominant content of Fe in soils (average of 20% w/w), Fe indicated lower amounts in tea leaves than Mn (average of 513 mg kg−1 vs 1354 mg kg−1). This could be attributed to the formation of Fe-rich root coatings on the tea plant root surface as a barrier to prevent Fe from translocating to other higher tea plant parts. Ni and Cr, as potentially toxic metals, were found at the lowest contents in tea leaves with low BCFs, indicating consumer safety in terms of exposure by these metals.

Effect of adding Sr(OH)2 on the formation process of 2024 aluminum alloy micro-arc oxidation coatings

Micro-arc oxidation coatings with oxidation times of 15 S, 30 S, 60 S, 120 S, 240 S and 1800 S were prepared on 2024 aluminum alloy using silicate-phosphate electrolytes containing 0 g/L and 0.5 g/L Sr(OH)2, respectively. The effects of adding Sr(OH)2 on the oxidation voltage, surface morphology and phase composition of the 2024 aluminum alloy MAO coatings formation process were investigated using SEM, XRD and XPS. The results show that adding Sr(OH)2 increases and then decreases the oxidation voltage compared with that of the unadded Sr(OH)2, which has little effect on the morphology of the oxide coatings, the Sr2+ and PO43- in the solution are jointly involved in the formation of the MAO coatings. The main phase composition of the coating is γ-Al2O3, and the Sr element is uniformly distributed as SrCO3 in the coating.

Step-by-Step Tuning of Tribological and Anticorrosion Performance of Zinc Phosphate Conversion Coatings through Effective Integration of Spherical P-Doped MoS2 Nanoparticles.

Surface coatings with enhanced mechanical stability, improved tribological performance, and superior anticorrosion performance find immense application in various industrial sectors. Herein, we report the development of multifunctional composite zinc phosphate coatings by the effective integration of a structurally and morphologically tuned P-doped MoS2 nanoparticle additive (3P-MoS2) into the zinc phosphate matrix to offer attractive characteristics suitable for industrial applications. The integration of spherical nanoparticles as additive leads to the formation of homogeneous and compact coatings with a densely packed crystalline microstructure having enhanced microhardness, distinctive leaf-like morphology, and comparatively smooth topographical features. The attractive lubricity of the additive (3P-MoS2), coupled with its spherical morphology, facilitates a transition from sliding to rolling friction and contributes significantly toward the performance enhancement of the tuned composition of the composite zinc phosphate coating (0.3-PMS). Thus, the tuned 0.3-PMS coating delivers the lowest specific wear rate (1.334 × 10-5 mm3/Nm) and coefficient of friction (0.114) that significantly outperform bare-zinc phosphate coating. Further, the electrochemical corrosion study results indicate the improvement in corrosion resistance behavior of the composite zinc phosphate coatings with reduced corrosion current density (icorr) and charge transfer resistance (Rct) values, as compared to the bare-zinc phosphate coating. The effect of passivation in conjunction with the barrier protection characteristics of the composite coatings induced by the optimal composition of the integrated additive nanoparticles (3P-MoS2) can efficiently prevent the infiltration of corrosive ions and thereby significantly reduce the rate of corrosion.

Aqueous Electrophoretic Deposition of Yttrium-Doped Nanobioactive Glass/Collagen/Chitosan Orthopedic Coatings on 316L SS

The current study used yttrium-doped nano bioactive glass (Y-nBG, based on 62 SiO2 – (33 – x) CaO – 5 P2O5 – x Y2O3 mole %), collagen and chitosan composites for coating stainless steel 316L by an electrophoretic deposition (ED) method. x = 0, 1 and 3 moles % and the corresponding samples encoded as SS/Col-Chit, SS/BG-Y0/Col-Chit and SS/BG-Y3/Col-Chit, respectively. TGA, FTIR, SEM-EDX, contact angle, adhesion strength and in vitro bioactivity in SBF. Following SBF immersion, FTIR and SEM-EDX investigations were carried out. Furthermore, the coatings were loaded with gentamicin drug, the drug-releasing profile and mechanism of release were evaluated. Coatings' antibacterial efficacy was also assessed. The results showed formation of homogeneous coatings with good adhesion strengths, 1.39 MPa, 0.55 MPa and 0.81 MPa and enhanced the wettability by decreasing the contact angle 36.4, 21.8 and 11.7for SS/BG-Y0/Col-Chit and SS/BG-Y3/Col-Chit coatings, respectively. Also, in vitro bioactivity of coatings containing nBG was demonstrated by promoted apatite formation after immersion in SBF through the presence of calcium and phosphorus in SEM-EDX analysis. Furthermore, the antibiotic gentamicin was showed sustained release profile over time by diffusion mechanisms based on the Higuchi, Fickian and Weibull models. As well, all coatings containing drugs have an antibacterial effect. Overall, these findings suggest that the prepared coatings have potential for orthopedic applications.

Formation of Hydrophobic Coatings on the Surface of Track-Etched Membranes Using Magnetron Sputtering of Polymers in Vacuum

Formation of Hydrophobic Coatings on the Surface of Track-Etched Membranes Using Magnetron Sputtering of Polymers in Vacuum

Microstructure and properties of plasma sprayed NbC-Al2O3 composite coatings

Niobium carbide has received widespread attention due to its high melting point, high strength, high chemical stability and high wear resistance, but the current preparation of niobium carbide coatings using plasma spraying technology suffers from low deposition efficiency, poor fusibility of the composite powders, high porosity, and high defects in the coating microstructure. Therefore, the microstructure and properties of NbC-Al2O3 composite coatings prepared by plasma spraying NbC-Al2O3-SiC composite powder and reactive plasma spraying Nb2O5-SiC-Al composite powder were comparatively investigated in this paper. The reaction mechanism of Nb2O5-SiC-Al composite powder during plasma spraying as well as the mechanism of the formation of coatings were analyzed in detail. The results showed that compared with the ex-situ NbC-Al2O3-SiC coating fabricated by plasma spraying, the in-situ Nb2O5-SiC-Al composite coating prepared by reactive plasma spraying had an obvious layer structure, low porosity (5.8%), high hardness (1141 HV0.1), high toughness (22.94 J/m2), and good scratch resistance properties.

STRUCTURE FORMATION OF Ni−P ALLOY ELECTROCOATINGS WITH INCREASED CORROSION RESISTANCE

Purpose of research. The main factors that reduce the protective properties of electrocrystallized coatings are the formation of volumetric defects − pores, as well as the occurrence of microgalvanic couples at grain boundaries, that is, on surface defects of the crystalline structure. Creating a non-porous structure in electrocoatings, eliminating the formation of surface defects in metal/alloy layers, as well as the possibility of replacing chromium coatings, which are obtained from toxic electrolytes, are urgent tasks. Materials and methodology. In the work, it was proposed to use electrocoatings with Ni−P alloy as protective layers on products that increase corrosion resistance. An X-ray determination of the phase composition of Ni−P electrochemical deposits was carried out. The surface morphology and corrosion resistance of coatings were studied. Results. Samples of electrochemical coatings of pure nickel and nickel-phosphorus alloy were studied. It has been established that during the formation of nickel coatings with the addition of phosphorus ions, the surface morphology has practically no pores, amorphization of deposits occurs, due to which the protective properties, namely, corrosion resistance, are improved. Scientific novelty. Factors have been identified that influence the increase in corrosion resistance of coatings − the absence of a porous structure and the formation of an amorphous state. Conclusions. The influence on the structure and properties of electrochemical coatings of a nickel-phosphorus alloy has been studied. It has been established that the addition of phosphorus ions to the nickel plating electrolyte leads to the formation of an amorphous structure in the coatings, and layers of the Ni−P alloy appear practically without the presence of pores. It has been established that the effect of increasing the corrosion resistance of the electrochemical coating with a nickel-phosphorus alloy (by 30 %) is due to the formation of an amorphous structure of the solidifying metal liquid while preventing the crystallization process during electrochemical deposition.

Influence of variable valence metal oxides on physico-chemical and antibacterial properties of semi-coated glazes

The paper presents the results of studies on the production of semi-coated glazes with antibacterial activity by introducing variable valence oxides CeO2, WO3, Bi2O3, Fe2O3, MnO2 and MoO3 into their composition. The raw polycomponent compositions were comprised of aluminosilicate multi-calcium glass frit, dolomite powder, feldspar, alumina, quartz sand, wet-enriched kaolin and refractory clay. The coatings were obtained by single firing on a ceramic-based porcelain stoneware at a temperature of 1 200 ± 5 °C in a high-speed mode for 60 ± 2 minutes. The study focused on the processes of glaze formation of coatings and the influence of the components of glaze charges on decorative and aesthetic characteristics of coatings (color, texture, gloss and whiteness). Parameters of physical and chemical properties were determined in accordance with the existing specification for the products, i. e. temperature coefficient of linear expansion, heat resistance, chemical resistance, microhardness, frost resistance, wear resistance, etc. Antibacterial activity of the coatings towards Escherichia coli ATCC 8739 and Staphylococcus aureus ATCC 6538 test strains was studied.

Comprehensive study of plasma polymerization parameters on thiol-coated LDPE films for effective fibronectin adsorption targeting biomedical applications

In the realm of biomedical applications, biocompatible materials with optimized surface properties are crucial for facilitating cellular interactions. To attain the perfect balance of these properties, surface modification of non-toxic and stable bulk materials is often required. Within this context, this research aimed to improve the physiochemical and cell-responsive properties of a low-density polyethylene film. This was achieved by depositing thiol-rich coatings using a dielectric barrier discharge plasma reactor operating at medium pressures, with 1-propanethiol serving as polymerization precursor. The study systematically investigated the impact of key plasma polymerization parameters, including DBD chamber pressure, treatment time, and the combination of precursor flow rate and discharge power represented by the Yasuda parameter, to identify optimal plasma processing conditions for the formation of thiol-rich coatings. To characterize the coating thickness, hydrophilicity and surface chemical composition, atomic force microscopy, water contact angle measurements, and X-ray photoelectron spectroscopy were employed. The findings indicated that reducing the chamber pressure to 10 kPa led to more hydrophilic and thicker deposits possessing a higher sulphur content. Deposition time (5 to 15 min) also significantly impacted coating thickness and surface chemistry, where long times increased thickness, but also led to a reduced sulphur and increased oxygen content because of more pronounced etching. The optimal deposition time was therefore set at 10 min resulting in the deposition of dense coatings possessing a high number of sulphur-containing functionalities. The Yasuda parameter (W/FM) analysis demonstrated optimal thiol incorporation in combination with high coating stability at an intermediate W/FM value of 72 MJ/kg. Following the determination of the optimal plasma polymerization parameters, the effectiveness of thiol plasma polymerization and subsequent fibronectin immobilization for enhancing cell adhesion and proliferation was investigated. The thiol-coated substrates were found to exhibit superior protein immobilization, because of the high affinity for protein binding of the available thiol groups. To assess cellular responses, Schwann cells were cultured on uncoated and coated samples before and after fibronectin immobilization. The results revealed a superior cellular response of the thiol-coated samples after fibronectin immobilization, showing the highest cell viability and significantly enhanced cell adhesion and proliferation. Collectively, these results underscore the synergistic effect of thiol plasma polymerization and fibronectin immobilization in promoting the cellular response of LDPE substrates, thus highlighting their potential as a surface modification strategy of biomaterials.

Effect of pH on hydroxyapatite coatings obtained by spray pyrolysis and their use as matrices for antibiotic adsorption by spin coating and release properties.

Calcium phosphate materials, particularly hydroxyapatite (HA), are extensively used in biomedical applications because of their prominence as primary inorganic constituents of human hard tissues. This study investigates the synthesis of HA coatings via spray pyrolysis using various precursors, including HA derived from bovine bone. The effects of pH on the formation and properties of HA coatings were systematically examined. Samples exposed to acidic conditions or left without pH adjustment led to the formation of HA, contrasting with the outcomes observed through dissolution methods. Different characterization techniques, such as scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray diffraction (XRD), were employed to evaluate the quality and crystallinity of the coatings. Among the samples, those exhibiting superior crystallinity and nanostructured features, including bovine HA, were selected for further surface functionalization with the antibiotic enrofloxacin using spin coating. As expected, the antibiotic loading on each material's surface depended on the amount of HA deposited on the substrate. However, the desorption results indicated that, in all cases, desorption persisted beyond 38 h, implying that HA-loaded matrices could be effective systems for controlled and prolonged drug release, which could be useful in dental or orthopedic implants for inhibiting the growth of bacterial biofilms.

Treelike PS-PVD coating: Hierarchical branching by shading and sintering

A structure zone model (SZM) with columnar structures for conventional physical vapor deposition (PVD) has been assigned to plasma spray-physical vapor deposition (PS-PVD) coatings. However, many different comprehensive properties between PS-PVD and conventional PVD coatings reveal the essential different microstructures. In this work, an impact-diffusion model was established based on the impact and diffusion behavior of depositing units. The microstructure formation of PS-PVD coatings was simulated. Results clearly display that the PS-PVD coating shows a novel treelike structure with hierarchical branches rather than a well-known columnar structure. The hierarchical branching is determined by the shadowing effect. Besides, temperature-promoting diffusion of vapor units can generate the in-situ sintering of the coatings. In-situ sintering happens during the deposition process and can govern the branching behavior. A novel treelike SZM is established as an enlargement of the conventional one, marked by successive transformations in branching and densifying. The treelike SZM is experimentally proved by the electron microscopy images and mechanical properties of typical PS-PVD YSZ coatings.

Mechanism of Ag-SiO2-TiO2 Nanocomposite Coating Formation on NiTi Substrate for Enhanced Functionalization

The functionality of the NiTi shape memory alloy was improved through engineering Ag-SiO2-TiO2 nanocomposite coatings. For this purpose, an anaphoretic deposition process, conducted at a constant voltage of 40 V and deposition times ranging from 1 to 10 min, was used. Scanning electron microscopy (SEM) analysis demonstrated that the deposition parameters significantly impacted the morphology of the coatings. Complementary Raman Spectroscopy and X-ray diffraction (XRD) analyses confirmed the successful formation of distinct nanocomposite layers, and revealed the details of their crystalline structure and chemical composition. After that, the adhesion between the NiTi substrate and the electrophoretically deposited ceramic coatings was improved through a post-deposition heat treatment. To prevent excessive shrinkage and cracking of the coating, tests were carried out to characterize the behavior of the coating material at elevated temperatures. The nanocomposite coatings were exposed to a temperature of 800 °C for 2 h. The annealing induced significant structural and morphological transformations, resulting in layers that were distinctly different from both the original materials and those produced solely through electrophoretic deposition. The thermal treatment resulted in the formation of a new kind of nanocomposite structure with enhanced reactivity.

Research on the Structural–Phase and Physical–Mechanical Characteristics of the Cr3C2-NiCr Composite Coating Deposited by the HVOF Method on E110 Zirconium Alloy

Composite coatings based on chromium carbide (Cr3C2) and nickel–chromium alloys (NiCr) are widely used due to their unique properties, including high heat resistance, wear resistance and corrosion resistance. This article studies the structural–phase and physical–mechanical characteristics of Cr3C2-NiCr composite coatings applied by high-velocity oxygen fuel to E110 zirconium alloy. The HVOF method was chosen to create coatings with high adhesion to the substrate and excellent performance properties. Analysis of the microstructure of the cross-section showed the thickness of the modified surface layer from 75 to 110 μm, depending on the processing modes. Energy dispersive X-ray spectral analysis revealed the presence of elements Cr, Ni, C and O in the coating composition. Structural–phase analysis confirmed the formation of coatings with a high concentration of Cr3C2 carbide particles and NiCr (nickel–chromium) phases. The resulting composite coatings based on Cr3C2-NiCr had a significantly high microhardness, ranging from HV 1190 to HV 1280, and the friction coefficient varied in a significant range from 0.679 to 0.502 depending on the processing conditions. The maximum adhesion strength was 9.19 MPa per square centimeter.

Porous Dielectric Structure and Response Speed of Moisture Sensors

Humidity sensors are typically made of alpha-alumina films as porous dielectric materials deposited through the anodic spark deposition (ASD) technique, a unique anodic oxidation method to deposit ceramic coatings on the exterior of metals. Close attention to the precise composition of electrolyte solution is crucial when mixing chemical compounds. Moreover, the ASD process, which happens during dielectric breakdown at the anode surface in an electrochemical cell, is clearly followed by visible sparking at the anode/electrolyte interface, leading to the formation of various ceramic coatings on metal substrates. Electrical breakdown happens over an anodized barrier layer, typically amorphous aluminum oxide, which has been produced on the metal anode. The local high temperature (>2000°C) produced by electrical sparks melts the amorphous aluminum oxide and converts it to alpha-aluminum oxide, forming the stable foundation for a reliable humidity sensor.In this study, we produced a variety number of small pores to investigate the response speed of moisture sensors. The ASD current can be adjusted to control the number of small pores. The smaller current gives a greater number of small pores. We focused on low-humidity sensors, often referred to as dew-point sensors. In fabrication of dew-point sensors, Scanning Electron Microscopy (SEM) was used to examine and determine the size of pores. Three different currents, 30 mA, 25 mA, and 10 mA, have been tried for comparative analysis of small pores existing within large pores. Two pores have been measured for current 10 mA, resulting in sizes of 47 nanometer (nm) and 71 nm, respectively. Similarly, three small pores for current 30 mA were measured with sizes of 32 nm, 42 nm, and 31 nm respectively. After the testing of low-humidity (dew-point) sensors, we found that the number of small pores does not significantly affect the response speed of the sensors.

Reactive magnetron deposition of YAG:Ce phosphor coatings in the metallic mode

The possibility of YAG:Ce3+ coatings phosphor formation by reactive magnetron deposition during sputtering of metal targets in an atmosphere of argon and oxygen activated by a radio-frequency source of inductively coupled plasma has been studied. The installation consists of three middle-frequency magnetrons with Y, Al and Ce targets with power of 1000, 1570 and 150 W, respectively. The (Y–Al–O):Ce coatings were deposited in metal and oxide sputtering modes of yttrium and aluminium targets. The coating deposition rate on the planetary rotating substrates in the metallic sputtering mode reaches of 0.67 nm/s. This is about an order of magnitude higher compared to the oxide sputtering mode and the method of radio-frequency magnetron sputtering of ceramic targets commonly used to deposit such coatings.Characterization of the elemental and phase composition of the coatings showed the YAG:Ce crystal structure formation during annealing both in air at 1100 °C and in a nitrogen atmosphere at 1200 °C. Cathodo- and photoluminescent spectroscopy was used for study of YAG:Ce thin films emission properties. The emission properties of YAG:Ce correspond to the radiation transition in Ce3+ ions. It was found that the intensity of both types of luminescence turned out to be slightly higher for samples annealed in air. It enhanced with increasing coating thickness in the considered range from 1.8 to 7.0 μm. The suggested approach could be potentially used for luminescent coatings formation with high level of the emission properties.

Review of Cathode Plasma Electrolysis Treatment: Progress, Applications, and Advancements in Metal Coating Preparation.

Cathodic plasma electrolytic treatment (CPET) is an emerging surface modification and coating preparation technology. By utilizing plasma discharge induced through electrolysis and the cooling impact of electrolyte, metal cleaning, saturation, and coating preparation are efficiently achieved. In this review, the principle, application, and development of the CPET process are briefly summarized based on the past literature. Detailed insights are provided into the influence of electrolyte parameters (pH, metal salt concentration, and temperature), electrical parameters (voltage, duty cycle, and frequency), and process parameters (electrode area ratio, material, roughness, and deposition time) on plasma discharge and coating formation for metal coatings. The interaction mechanism between plasma and material surfaces is also investigated. Recommendations and future research avenues are suggested to propel CPET and its practical implementations. This review is expected to provide assistance and inspiration for researchers engaged in CPET.