Ferroelectric materials, both in single crystal and ceramic form, are being used and studied for their applications in various devices. Ferroelectric ceramic thin films have received increasing interest during recent years due to the possibility of their use in thin film capacitors [1], piezoelectric transducers [2], SAW devices [3], IR detectors [4], electro-optic wave guides and other optically non linear devices [5, 6]. Various preparation techniques such as evaporation [7], sputtering [8], CVD, sol-gel [9, 10] etc., have been developed to deposit thin films. The main advantage of the sol-gel technique is that it gives optical quality films without expensive infrastructure, at a fairly low processing temperature. In the sol-gel technique, films are prepared using metal alkoxide precursors by either spin coating the sol on a substrate or dip coating the substrate. The films are sintered at 500 to 600 8C. The film thickness can be increased by increasing the number of coatings. However, it has been observed that as the film thickness increases beyond a few micrometres, film adhesion becomes poor and cracks also start to develop. Moreover, the substrate on which the film is being deposited also plays an important role in its characteristics. For non-linear optical devices, thicker films are required to increase the optical interaction length, and, as such, sol-gel derived films are not very suitable, especially for transversal exposure. To increase the thickness of the films without compromising the mechanical properties, we have prepared ceramic:polymer composite films. The polymer used for this purpose is polyimide, which can withstand the desired sintering temperatures [11]. This paper deals with the preparation of LiNbO3:Polyimide composite films. Structural, optical and electrical characterization of these films is also reported. Polyimide (PI) films were prepared by dissolving equimolecular proportions of 4-4 diamino diphenyl methane and tetracarboxylic acid in DMF to obtained polyamic acid. The viscosity of polyamic acid was adjusted to give films of about 40–50 im thickness. Films of polyamic acid were cast on glass substrates and were dried in a vacuum oven at 60 8C. Imidisation was done by sintering these films at 350 8C for two hours. To prepare polyimide:LiNbO3 composite films, ammonium salt of polyamic acid was prepared by adding ammonium hydroxide to polyamic acid. This ammonium salt of polyamic acid was dissolved in alcohol and was used for composite film preparation. A sol of LiNbO3 was prepared by dissolving lithium hydroxide in absolute ethanol and adding an equimolecular amount of niobium ethoxide to it. This sol was added dropwise to the prepared alcoholic solution of polyamic acid with continuous stirring to avoid gelation or lump formation. Composite films were then cast from this solution. Drying of the composite film and imidisation were carried out as mentioned earlier for the polyimide films. The thickness of the films thus obtained was about 35 im. A weighed portion of the film was burnt at 700 8C in a crucible. The residue, which was LiNbO3, was weighed and the weight percentage of LiNbO3 in the composite was determined to be about 15%. The X-ray diffractogram of the film was taken on a Rigaku diffractometer, while the optical transmission was recorded on a Hitachi spectrophotometer. A scanning electron micrograph was taken on a Philips scanning electron microscope. Aluminium electrodes of 1 cm diameter were vacuum deposited on the film for electrical measurements. Dielectric measurements were carried out on a Hewlett Packard impedance analyzer. Optical phase conjugation was carried out using a 35 mW He-Ne laser. The X-ray diffractogram of the film is shown in Fig. 1. The presence of LiNbO3 crystallites in the composite is clearly indicated by the presence of broad and clear peaks. The planes responsible for these peaks are marked on the diffractogram. The broadness of the peaks suggests that the crystallisation of LiNbO3 has just begun.