Fly Ash-based Geopolymer Research Articles

Role of bentonite in improving the anti-seepage durability of fly ash-based geopolymer cutoff wall backfill under dry–wet cycles

Role of bentonite in improving the anti-seepage durability of fly ash-based geopolymer cutoff wall backfill under dry–wet cycles

Studying the metakaolin content, fiber type, and high-temperature effects on the physico-mechanical properties of fly ash-based geopolymer composites

Studying the metakaolin content, fiber type, and high-temperature effects on the physico-mechanical properties of fly ash-based geopolymer composites

The Effect of Fiber Type on The Shear Capacity of Beams Manufactured By Using Geopolymer Concrete Based on Fly Ash

Ordinary Portland cement is currently generally used cementitious material in the construction industry. However, it has significant drawbacks as it not only depletes natural resources but also releases a substantial amount of carbon dioxide during its production process. On the other hand, alkali-activated cement is an alternative option that is derived from raw materials like slag, fly ash, and metakaolin, which contain silicon dioxide (SiO2) and aluminum oxide (Al2O3). This study investigates the shear capacity of fibre-reinforced geopolymer concrete (GPC) beams under shear loads. In the study, the shear behavior of beams produced from fly ash-based geopolymer of three different fiber types was determined by applying a three-point shear test. Four beams of 100x100x400 mm dimensions were produced: reference, steel fiber, basalt fiber and glass fiber. The results showed that using steel fiber has the greatest impact on shear capacity. In addition, the shear capacity of fibrous samples is greater than the shear capacity of the reference sample. The steel fiber sample has 203% more shear capacity than the reference sample.

Synchronous vacuum hot pressing ultra-high performance geopolymer: Ultrafast polymerization and early strength development

To overcome the application bottleneck of geopolymer in high-end industries, this study aims to develop ultra-high performance geopolymer products. By employing Synchronous Vacuum Hot Pressing, we have significantly enhanced the rate of polymerization and mechanical properties of Geopolymer based on Metakaolin-Fly Ash. The influence of Si/Al ratio, alkali equivalent, and molding time on the geopolymerization process, mechanical properties, and microstructure of geopolymers was investigated, while elucidating the underlying mechanisms. The compressive strength of SVHP-MFG reaches 90.92 MPa when the Si/Al ratio is 2, alkali equivalent is 8 %, and molding time is 30 min, owing to increased production of aluminosilicate gels and matrix structure densification. The ongoing reaction of unreacted particles and the subsequent transformation from "alumina-rich gel" to "silica-rich gel" in later stages further enhance the mechanical properties of the material. Additionally, the mean pore diameter of Synchronous vacuum hot pressing of metakaolin-fly ash geopolymer measures below 13.24 nm, thereby significantly enhancing the pore structure of the geopolymer. The synchronous vacuum hot pressing metakaolin fly ash-based geopolymers synthesized in this study represents a novel category of ultra-high performance ceramic-like geopolymers, exhibiting exceptional early strength and early stability. The research aims to promote the application of geopolymer in high-end industry and provide technical and theoretical support for the development of ultra-high performance geopolymer based products.

Durability and steel corrosion resistance of Fly ash-based geopolymer concrete exposed to water of Lake Qaroun

Durability and steel corrosion resistance of Fly ash-based geopolymer concrete exposed to water of Lake Qaroun

Mechanical property and microstructure of fly ash-based geopolymer by calcium activators

Geopolymer is a green and environmentally friendly new type of gel material generated from the reaction of activators with silica-alumina raw materials, possessing extensive research and application value. Fly ash can be used as reaction material, enabling the industrial solid waste to be recycled and reused. In this paper, unconfined compressive strength test, X-ray diffraction analysis, Fourier transform infrared light, 29Si nuclear magnetic resonance, scanning electron microscope and energy disperse spectroscopy, and physisorption experiment were carried out to study the effects of the type and dosage on the mechanical property and microstructure of fly ash-based geopolymer activated by calcium hydroxide, calcium sulfate and their compound. The results indicated that calcium hydroxide and calcium sulfate can promote the dissolution of fly ash crystals, providing adequate Ca2+ for the formation of gel products. The products of calcium hydroxide and calcium sulfate activation are hydrated calcium aluminate, hydrated calcium sulfate, and ettringite, respectively. The effect of the compound activator is superior to that of single activators. With the increase of the proportion of calcium hydroxide, the reorganization and polymerization of gel products were accelerated so that the integrity and continuity of the microstructure of geopolymer were improved, and then the strength increased. When the ratio of calcium hydroxide to calcium sulfate was 3:1 and the total dosage was 20 %, the unconfined compressive strength reached the maximum value. According to this study, it was investigated that type and dosage of calcium activators had evident influence on the geopolymerization of fly ash. And the reutilization and resource utilization of fly ash waste can be achieved, which can provide an engineering theoretical basis for using fly ash-based geopolymer to alter the physical and chemical properties of special soils and achieve solidification effect.

Effect of Magnetized Water on Self-Compacted Fly Ash-Based Geopolymer Concrete

Effect of Magnetized Water on Self-Compacted Fly Ash-Based Geopolymer Concrete

The Correlation Between Compressive Strength and The Size of Pore Fly Ash and Perlite Concrete Geopolymer at High Temperature

Abstract Burned material experiences a decrease in yield strength and elasticity modulus. Fire supervision is required. One of the sustainable material is geopolymer. In this study, fly ash and perlite-based concrete geopolymer have been burned for 900°C for 2 hours. It is followed by Surface Area Analyzer test equipment. The size of pore changes for burned concrete geopolymer. Meanwhile, one of the strength of concrete geopolymer indicator is compressive strength. Both of the results of compressive strength and the pore size are conducted through experimental study. Bet method has been used to measure pore size of it. UTM machine has been used to calculate compressive strength. The surface area analyzer test results show that the addition of perlite to fly ash-based geopolymer concrete will decrease the value of surface area, pore volume, and pore distribution in burned geopolymer concrete, but the addition of perlite to fly ash-based geopolymer concrete will increase the value of pore distribution and decrease the value of surface area and pore volume in unburned geopolymer concrete.

Simultaneously Enhancing the Dynamic Damping and Static Strength Capabilities of Structures: A Case Study Conducted on Fly Ash-based Geopolymer Concrete Specimens using Modal, Mechanical and Microstructural Investigations

Enhancing both the dynamic damping and static strength of ordinary Portland cement (OPC) concrete simultaneously is a significant challenge. Geopolymer concrete (GPC), particularly fly ash-based GPC, offers a promising alternative. This study explores the relationship between damping and strength in heat-cured, low-calcium fly ash-based GPC using sodium silicate (SS) and sodium hydroxide (SH) activators. The findings reveal that SS activators demonstrate stronger positive correlations between damping and strength compared to SH activators. Microstructural analysis indicated that increasing SS dosage from 55 kg/m³ to 98 kg/m³ resulted in a 17% increase in dynamic damping ratios and a 39% increase in static compressive strength. These results highlight the potential of GPC to surpass OPC concrete in applications requiring both enhanced damping and strength, offering a dual benefit not typically achievable with OPC. The study contributes to a deeper understanding of GPC's capabilities, paving the way for its broader adoption in construction projects.

High-temperature mechanical performance and damage behavior of molybdenum tailings modified fly ash-based geopolymers

Molybdenum tailings modified fly ash based geopolymers were an eco-friendly building material with excellent mechanical performance and fracture toughness. In this work, cubic compressive test and acoustic emission technique were used to evaluate the effect patterns of molybdenum tailings contents and thermal temperature conditions on the high-temperature mechanical performance and damage behaviors of molybdenum tailings modified fly ash-based geopolymers. The molybdenum tailings contents were 0 %, 10 %, 20 %, 30 % and 40 %, and the target temperatures were 300 °C, 600 °C and 900 °C, respectively. The results of compressive tests showed that the low contents of molybdenum tailings could limit the growth of macroscopic cracks during the loading process and improve the compressive strength of fly ash-based geopolymers when the heat treatment temperature did not exceed 600 °C. The acoustic emission results showed that 20 % molybdenum tailings contents could improve the structural stability and high-temperature mechanical performance of fly ash-based geopolymers, reduced the growth of microcracks in the specimen during the loading process, and delayed the formation and cracking of macrocracks, but did not change the specimen's compressive damage mode. The 40 % contents of molybdenum tailings changed the compressive damage mode of the fly ash-based geopolymers, delayed the cracking of the matrix structure under the peak loading, and significantly improved its resistance to plastic deformation.

Compressive Strength and Water Flux Performance of Type C and Type F Fly Ash-Based Geopolymer Membrane

Compressive Strength and Water Flux Performance of Type C and Type F Fly Ash-Based Geopolymer Membrane

Innovative assessment of reactivity in fly ash: The role of particle size distribution characteristics

The relationship between the intrinsic properties of seven different types of fly ash and the compressive strength of the resulting geopolymers was investigated. A comprehensive examination of the effect of chemical and mineralogical compositions, particle size distribution, on the compressive strength of the fly ash-based geopolymers were performed. Results revealed that particle size distribution had a more significant impact on reaction activity than amorphous phase content or average particle size alone. Therefore, a novel concept of 'reaction volume' based on the geopolymerization reaction mechanism was proposed, which reveals a high correlation between the reactivity of fly ash and the compressive strength of geopolymers, thereby enhancing the predictability of the process. The degree of reactivity, formulated through the integration of reaction volume and amorphous silica-aluminum content, was identified as a robust predictor of compressive strength, which can serve as a crucial tool for evaluating fly ash for the production of alkali-activated materials.

Sustainable Geopolymer Concrete for Pavements: Performance Evaluation of Recycled Concrete Aggregates in Fly Ash-Based Mixtures

This study investigates the feasibility of incorporating recycled concrete aggregates (RCA) into fly ash-based geopolymer concrete for sustainable pavement applications. The research evaluates RCA’s physical and mechanical properties compared to virgin coarse aggregates (VCA) and assesses the performance of geopolymer concrete mixtures with up to 40% RCA replacement. Aggregate characterization revealed that RCA exhibited higher water absorption (4.39%), crushing value (20.9%), impact value (28.2%), and abrasion value (26.1%) compared to VCA, yet these values remained within acceptable limits for pavement applications. Geopolymer concrete specimens were tested for compressive strength, water absorption, abrasion resistance, and chloride ion permeability. Results indicated that increasing RCA content led to a gradual decrease in compressive strength, from 40.16 MPa to 33.52 MPa, while water absorption increased from 5.2% to 6.8%. Abrasion resistance declined as RCA content rose, and chloride ion penetrability increased from 1687 to 2196 coulombs. However, mixtures with up to 20% RCA replacement met the strength and durability criteria required for pavement construction. This study demonstrates the potential for utilizing RCA in geopolymer concrete pavements, offering a sustainable solution for waste management and resource conservation in the construction industry.

A rapid immersion measurement for the diffusion constant of chloride ions in the geopolymer concrete

Accurate measurement of chloride ion diffusion coefficient, without external interference, is essential for obtaining data that closely reflects practical conditions. The diffusion constants of chloride ions within fly ash-based geopolymer concrete (FGPC) with a one-dimension immersion method employed to record the time taken for diffusion to occur over a specific distance were investigated in this work. The results showed a clear relationship between the diffusion constant and the strength of FGPC. Within the same strength of FGPC, the diffusion distance (thickness) is proportional to the square root of diffusion time. The minimum diffusion constant is approximately 8.90 × 10−11 m2/s which is close to the result in an immersion test. The method employed in this study is demonstrated to be both feasible and applicable for assessing the diffusion constant of chloride ions in FGPC quickly. It promotes a rapid evaluation method to predict the diffusion process under practical conditions.

Role of particle size on the mechanical and microstructural properties of fly ash-based geopolymer

Role of particle size on the mechanical and microstructural properties of fly ash-based geopolymer

Innovative Pavement Materials: Utilizing Corn Stover and Fly Ash in Geopolymers

The development of each nation is evaluated by its infrastructure, and each nation is competing with the others in infrastructure advancement, especially in the construction of roadways, since they play a vital role in the economic and social development of the nation. The conventional materials used for road construction are concrete and asphalt, which pose significant environmental challenges. This research gives insight into the potential of fly ash (FA) and corn stover (CS) in synthesizing geopolymer, as an alternative material for the construction of roads. This study examines the impact of three FA and CS mixture percentages and the particle size of CS on the compressive strength and porosity of geopolymer. The results indicate that incorporating larger amounts of CS in fly ash-based geopolymer may decrease the compressive strength of the geopolymer. Smaller CS particle sizes also tend to lead to lower compressive strength. Porosity of the geopolymer tended to increase with the incorporation of higher percentages of CS, particularly for smaller corn stover sizes. As a fine aggregate replacement for geopolymer, CS incorporation has the potential to reduce mined aggregate obtained from a process that harms the environment.

Sustainable enhancement of fly ash-based geopolymers: Impact of Alkali thermal activation and particle size on green production

Addressing the challenges posed by the slow reactivity of fly ash (FA) with alkali at ambient temperatures, this study delves into the enhancement of FA-based geopolymers through alkali thermal activation (ATA). The ATA process, conducted at 550°C for 1 h, significantly increases the availability of reactive silica and alumina, which are essential for geopolymerization. A critical focus of the research is the influence of FA particle size on ATA’s efficacy and the resultant mechanical properties of the geopolymers. Findings reveal that the ATA process facilitates the rapid dissolution of the vitreous phase in FA. This leads to a sequential release of silica and alumina, which is pivotal for the geopolymer’s matrix development. Notably, geopolymers synthesized from finely milled FA, post-ATA, demonstrate a marked increase in compressive strength, escalating from 30.51 MPa to an impressive 38.46 MPa. The study meticulously delineates geopolymerization into four distinct stages—initial dissolution, depolymerization, geopolycondensation and gelation, and final diffusion, with the initial dissolution and final diffusion stages being paramount in defining the reaction kinetics and the ultimate strength of the geopolymer. This enhanced understanding paves the way for optimizing FA utilization in geopolymers, promising a more sustainable and efficient pathway for producing construction materials with superior mechanical properties.

Development of Fly Ash-Based Geopolymer Lightweight Aggregates

This research delves into the utilization of microwave hybrid heating as a curing technique for producing fine aggregates from fly ash. Various concentrations of alkali activator solutions were employed as binders to pelletize the fly ash (ranging from 0% to 10%). The resultant green fly ash-based geopolymer (FAG) aggregates were subjected to a 15-minute microwave kiln treatment. The microwave-sintered FAG fine aggregates, varying in sizes from 0.60 to 2.36 mm, were then utilized to fabricate 50 mm cubic cement mortar samples. Findings indicated that the density of FAG aggregates was approximately 36% lower than that of natural sand, while the water absorption capacity of FAG aggregates exhibited a fivefold increase compared to natural sand. Notably, cement mortar samples made with FAG aggregate of 4% alkali activator exhibited maximum compressive strengths of 31, 37, and 42 MPa at 7, 14, and 28 days of curing, respectively. These compressive strengths were only 12% lower than those of cement mortars made with natural sand across all curing periods. The use of microwave hybrid heating to transform fly ash into aggregates with sufficient strength appears viable, suggesting that these manufactured FAG aggregates could serve as substitutes for natural aggregates in concrete production

Effect of additional Al sources on early-age strength of fly ash-based geopolymer containing calcium carbide residue and Glauber’s salt as activators

Alkali-activated materials are more environmentally friendly than cementitious composites and are used in the construction and building sector. However, their intrinsic low early strength under ambient temperatures hinders their practical applicability. More research is needed on the possibilities of increasing early strength at ambient temperatures. In this study, aluminum sulfate (AS) was used as an additional aluminum source to improve the early-age properties of fly ash (FA)-based geopolymers incorporating calcium carbide residue (CCR) and Glauber’s salt (GS) as activators. XRD, TG, SEM, ICP and isothermal calorimetry analyses were carried out to characterize the phase composition, microstructure and hydration process of the prepared materials. The results showed that the 1d strength of AS1-CCR10 was increased by 260.7 % compared with the control material, and the effect on the late strength was negligible. The relative content of AFt increased by 2.97 %, creating a more compact microstructure. During the extraction process, insufficient dissolved Al3+ in the composite led to a decrease in initial strength. In the hydration process, the induction period of AS1-CCR10 was advanced by 40.92 % and that of t50 was advanced by 57.74 %, which accelerated the early reaction rate. However, the Krstulovic-Dabic model could not accurately describe the initial stage of the hydration reaction of composite materials. This study is helpful to broaden the utilization of geopolymer composites and provide a theoretical basis for the preparation and reaction mechanism of alkali-activated materials.

Permeability and self-healing behavior of alkali activated geopolymers for well cementing applications

Geopolymers, also identified as alkali-activated materials (AAM), are alternative well-cementing materials with a lower carbon footprint than traditional ordinary Portland cement (OPC). Geopolymers are formed by combining an aluminosilicate precursor, such as fly ash (FA), with an alkaline activator solution. Among their merits is an ability to self-heal after becoming damaged, which can be exploited to restore permeability, sealing ability, zonal isolation, and well integrity in wells that suffer from cracking, fracturing, or debonding in their annular cement sheaths and abandonment plugs.This study investigates the self-healing ability of various alkali-activated Class F fly ash-based geopolymers. Liquid sodium hydroxide (LSH), liquid sodium silicate (LSS), and solid sodium silicate (SSS) were used as activators for the preparation of geopolymer specimens, while Class H OPC was used as the control material. Permeability was characterized using pressure transmission tests (PTT). The tested samples were of different compositions, curing ages (7-day and 28-day), damage stages (pristine, damaged after freeze-thaw cycling, self-healed after post-damage curing), and damage severity (low, medium, and high). Fourier-transform infrared-spectroscopy (FTIR) and loss on ignition (LOI) tests were performed to examine the geopolymer reaction over time, in an attempt to relate the various permeability results to the geopolymerization process. The experimental results show that geopolymers possess low permeability, comparable to – or lower than – OPC, and that effective permeability restoration occurs in geopolymers, even after high degrees of damage. The implication of this work is that geopolymers are promising alternative barrier materials to OPC with a superior ability to guarantee low barrier permeability and appropriate zonal isolation, keys to wellbore integrity over the entire lifecycle of wells, even if those wells suffer from damage.