A combination of fluorescent SiC (f‐SiC) and porous f‐SiC is a promising phosphor material for pure white light emission. Herein, the anodic oxidation condition is optimized to produce porous f‐SiC. Furthermore, a hybridly packaged white light emitting diode (LED) package composed of f‐SiC/porous f‐SiC stacks with a nitride‐based NUV‐LED as an excitation source is fabricated. A distinct pure white light emission and the peak luminous efficacy of 11.6 lm W−1 at a forward current of 10 mA in the NUV‐LED are observed. At the peak luminous efficacy, the estimated internal quantum efficiency of the f‐SiC/porous f‐SiC stacks is ≈80% as the package involved several types of optical and energy losses.