Biomass gasification co-firing is a technology that can be implemented instantly in almost all coal-fired power plants in a relatively short period to reduce the consumption of fossil fuel. Most studies have focused on improving the system according to variations in the gasification conditions, biomass types, co-firing ratio, and boiler loads. However, the whole system process analysis and structural improvement based on the matter and energy of the co-firing system require further investigation. In this study, a novel biomass air–steam circulating fluidized bed gasification co-firing system based on waste heat and flue gas water recovery with different co-firing ratios (approximately 10 %–40 %) was simulated and compared with the original air gasification co-firing system using Aspen Plus software. The impacts of recovered water participate in gasification process and the optimal steam to biomass ratio (S/B) when it varied from 0.5 to 2, on the syngas quality, thermal characteristics of flue gas, recovered water, coal consumption, exergy loss, and efficiency of the system were analyzed. Compared with the air gasification co-firing system, the results showed that the N2 content in syngas reduced from 41.14 % to 28.92 %, and the heat yield of syngas increased by 7.73 %, along with a 110 t/h recovered water surplus at a 40 % co-firing ratio when steam to biomass ratio was equal to 1. The maximum coal saving amount was 2.26–9.11 t/h and the volume of atmospheric pollutants emissions, such as carbon dioxide (CO2), sulfur oxides (SOx) and nitrogen oxides (NOx), reduced by 0.95 %–6.02 %, 0.91 %–0.95 %, and 11.38 %–36.47 % at a co-firing ratio of approximately 10 %–40 %. Furthermore, the exergy loss can be reduced by 4.35 %–10 % with a 1.72 %–3.96 % increase in exergy efficiency, indicating that the new system mode improves the comprehensive performance of the co-firing system.
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