Flue Gas Research Articles

Comprehensive Analysis of Biomass from Chlorella sorokiniana Cultivated with Industrial Flue Gas as the Carbon Source.

Chlorella sorokiniana, isolated from a pond adjacent to a cement plant, was cultured using flue gas collected directly from kiln emissions using 20 L and 25000 L photobioreactors. Lipids, proteins, and polysaccharides were analyzed to understand their overall composition for potential applications. The lipid content ranged from 17.97% to 21.54% of the dry biomass, with carotenoid concentrations between 8.4 and 9.2 mg/g. Lutein accounted for 55% of the total carotenoids. LC/MS analysis led to the identification of 71 intact triacylglycerols, 8 lysophosphatidylcholines, 10 phosphatidylcholines, 9 monogalactosyldiacylglycerols, 12 digalactosyldiacylglycerols, and 1 sulfoquinovosyl diacylglycerol. Palmitic acid, oleic acid, linoleic acid, and α-linolenic acid were the main fatty acids. Polyunsaturated fatty acid covers ≥ 56% of total fatty acids. Protein isolates and polysaccharides were also extracted. Protein purity was determined to be ≥75% by amino acid analysis, with all essential amino acids present. Monomer analysis of polysaccharides suggested that they are composed of mainly D-(+)-mannose, D-(+)-galactose, and D-(+)-glucose. The results demonstrate that there is no adverse effect on the metabolite profile of C. sorokiniana biomass cultured using flue gas as the primary carbon source, revealing the possibility of utilizing such algal biomass in industrial applications such as animal feed, sources of cosmeceuticals, and as biofuel.

Experimental study on CO2 sequestration capacity and mechanical characteristics evolution of solid wastes based carbon-negative backfill materials

The employment of solid waste, notably coal gangue, in carbon-negative backfill mining technology for mineralization and filling in coal mine gobs, is recognized as a productive method for carbon sequestration and waste management, with research primarily dedicated to engineering advanced mineralized backfill materials. Under this background, four variables, including the ratio of gangue to solids (RG-S), water-cement ratio (RW-C), ratio of fly ash to solid wastes providing calcium (Ca) (RA-Ca), and ratio of flue gas desulfurization (FGD) gypsum to carbide slag (RF-CS) were defined to formulate gangue-based mineralized backfill materials, with orthogonal experiments assessing their effects on CO2 sequestration and mechanical characteristics. The results indicate that RW-C consistently emerges as the primary factor influencing both the amount of sequestered CO2 and the mechanical properties of gangue-based solid waste mineralized backfill materials. The amount of sequestered CO2 demonstrates a direct proportionality to RW-C and mechanical strength demonstrates an inverse relationship with RW-C. After 45 minutes of stirring and carbon sequestration, samples in various groups exhibited an maximum sequestered CO2 amount of 18.96 g·kg−1, with a maximum sequestration rate of 0.20 g·kg−1·min−1. The process of CO2 sequestration enhances the compressive properties of mineralized backfill materials derived from gangue based solid wastes.

An energy-efficient cyclic amine system developed for carbon capture from both flue gas and air

High energy consumption is a major barrier to the large-scale deployment of carbon capture processes from flue gases or air (direct air capture, DAC). The non-aqueous amines reported in literature possess a high energy efficiency for CO2 capture from flue gases, they struggle with gas streams containing ultra-dilute CO2, like air, due to poor absorption kinetics. This study developed novel 2-PE (2-piperidineethanol)/APZ (Aminoethylpiperazine) based CO2 absorbents to address these problems. The experiments and MD simulation results showed that the 2-PE/APZ-based absorbents possessed a superior absorption performance both in flue gas and air. Among the developed absorbents, when 2-PE/APZ mixed with DMF (Dimethylformamide), the CO2 loading reached to 1.004 mol/mole, as the theoretical maximum. In DAC tests, 87.31 % CO2 from the air was captured in 24 h experiments. The regeneration heat duty of 2-PE/APZ/DMF decreased to 1.694 KJ/g CO2, a 55.89 % reduction compared to the benchmark 30 wt% MEA. The CO2 absorption/desorption mechanism was analysed by NMR, In-situ FT-IR, and DFT calculation. It indicated that this significant improvement in CO2 absorption performance and the reduction in energy consumption are due to the synergistic effect of 2-PE and APZ. During CO2 absorption, CO2 reacts with APZ forming APZ zwitterion rapidly, then deprotonation to the 2-PE. The formation of protonated 2-PEH+ ion pairs with APZCOO- reduces hydrogen bonds and van der Waals forces among the amine-CO2 complex, facilitating easy regeneration at mild conditions while maintaining high reactivity. The combination of theoretical and experimental results indicates that 2-PE/APZ-based absorbents can serve as a promising alternative for carbon capture from flue gas to air with low energy usage.

Sustainable synergistic approach to chemolithotrophs—supported bioremediation of wastewater and flue gas

Flue gas emissions are the waste gases produced during the combustion of fuel in industrial processes, which are released into the atmosphere. These identical processes also produce a significant amount of wastewater that is released into the environment. The current investigation aims to assess the viability of simultaneously mitigating flue gas emissions and remediating wastewater in a bubble column bioreactor utilizing bacterial consortia. A comparative study was done on different growth media prepared using wastewater. The highest biomass yield of 3.66 g L−1 was achieved with the highest removal efficiencies of 89.80, 77.30, and 80.77% for CO2, SO2, and NO, respectively. The study investigated pH, salinity, dissolved oxygen, and biochemical and chemical oxygen demand to assess their influence on the process. The nutrient balance validated the ability of bacteria to utilize compounds in flue gas and wastewater for biomass production. The Fourier Transform–Infrared Spectrometry (FT–IR) and Gas Chromatography–Mass Spectrometry (GC–MS) analyses detected commercial-use long-chain hydrocarbons, fatty alcohols, carboxylic acids, and esters in the biomass samples. The nuclear magnetic resonance (NMR) metabolomics detected the potential mechanism pathways followed by the bacteria for mitigation. The techno-economic assessment determined a feasible total capital investment of 245.74$ to operate the reactor for 288 h. The bioreactor’s practicability was determined by mass transfer and thermodynamics assessment. Therefore, this study introduces a novel approach that utilizes bacteria and a bioreactor to mitigate flue gas and remediate wastewater.

CO2-to-CO conversion with over 10% efficiency using earth abundant system in a single-compartment reactor with oxygen tolerant Mn complex catalyst.

The direct conversion of CO2 in flue gas to value-added chemicals is a potentially important cost-effective solar-driven CO2 reduction technology. The present work demonstrates the solar-powered conversion of CO2 to CO with greater than 10% efficiency using a Mn complex cathode and an Fe-Ni anode in a single-compartment reactor without an ion exchange membrane in conjunction with a Si solar cell. Reactors separated by ion exchange membranes are typically used to prevent any effects of oxygen generated by the counter electrode. However, the present Mn complex catalyst maintained its activity even in the presence of 15% O2. Operando surface-enhanced Raman spectroscopy established that the present Mn catalyst preferentially reacted with CO2 without adsorbing O2. This unique characteristic enabled solar-driven CO2 reduction using a single-compartment reactor. In contrast, catalytic metals such as Ag tend to lose activity in such systems as a consequence of reaction with oxygen produced at the anode.

Optimal configuration of low‐grade waste heat driven seawater desalination using data envelopment analysis: A case study of industrial application

AbstractWater supply challenges are caused by population growth, industrialization, as well as the scarcity of freshwater resources. Low‐grade waste heat‐driven seawater desalination technologies may improve the water‐energy nexus issues of desalination systems by different configurations. The data envelopment analysis is used to determine the best final decision to achieve a better comparison of different parameters. The optimal configuration of low‐grade waste heat driven seawater desalination is studied using flue gas waste heat in heat recovery boilers of an industrial oil refinery. Nine different types of multistage flash and multi‐effect distillation (MED) desalination plants have been considered. The results show that the multistage flash brine recirculation may produce more desalinated water while the multi‐effect distillation with three stages (3‐stage MED) has the best payback period. Using 3‐stage MED with a production of approximately 19,630 kg/h of water from 5.3 MW exhaust gas is more suitable for this design. Thus, the proposed strategy guides us toward the best decisions to configure low‐grade waste heat‐driven desalination plants for better design considering rigorous simulations for the plants. Moreover, this framework enables us to consider different criteria of technical, economic, and environmental issues for optimal configuration.

The enduring world forest carbon sink.

The uptake of carbon dioxide (CO2) by terrestrial ecosystems is critical for moderating climate change1. To provide a ground-based long-term assessment of the contribution of forests to terrestrial CO2 uptake, we synthesized in situ forest data from boreal, temperate and tropical biomes spanning three decades. We found that the carbon sink in global forests was steady, at 3.6 ± 0.4 Pg C yr-1 in the 1990s and 2000s, and 3.5 ± 0.4 Pg C yr-1 in the 2010s. Despite this global stability, our analysis revealed some major biome-level changes. Carbon sinks have increased in temperate (+30 ± 5%) and tropical regrowth (+29 ± 8%) forests owing to increases in forest area, but they decreased in boreal (-36 ± 6%) and tropical intact (-31 ± 7%) forests, as a result of intensified disturbances and losses in intact forest area, respectively. Mass-balance studies indicate that the global land carbon sink has increased2, implying an increase in the non-forest-land carbon sink. The global forest sink is equivalent to almost half of fossil-fuel emissions (7.8 ± 0.4 Pg C yr-1 in 1990-2019). However, two-thirds of the benefit from the sink has been negated by tropical deforestation (2.2 ± 0.5 Pg C yr-1 in 1990-2019). Although the global forest sink has endured undiminished for three decades, despite regional variations, it could be weakened by ageing forests, continuing deforestation and further intensification of disturbance regimes1. To protect the carbon sink, land management policies are needed to limit deforestation, promote forest restoration and improve timber-harvesting practices1,3.

Improving the activity of CO2 capturing from flue gas by membrane gas – solvent absorption process

This work is focused on increasing the capturing efficiency of carbon dioxide (CO2) through flue gas purification systems. To maximize the CO2 capture process, many process variables such as temperature, flow rates, absorbent concentrations, and nanoparticles were investigated. This study describes the use of a polypropylene hollow fiber membrane contactor to separate CO2 from nitrogen using different solvents, including Potassium carbonate (K2CO3), N-methyl diethanolamine (MDEA), and monoethanolamine (MEA). Also, the presence of silica nanoparticles and piperazine (PZ) enhances the process performance. On the other hand, the amine and mixed amino absorbents MDEA-PZ and MDEA-MEA were prepared and compared based on the absorption capacity. The optimal order of amine absorbent performance when applied to CO2 membrane absorption is MDEA-MEA followed by MDEA-PZ. At a solute concentration of 9%, MDEA-MEA exhibits the highest CO2 removal efficiency, which is 74.12%. However, at a concentration of 11%, MEA, MDEA-PZ, and MDEA have the highest CO2 removal efficiencies of 80.15%, 75.13%, and 63.12%, respectively.

Geopolymer Materials from Fly Ash-A Sustainable Approach to Hazardous Waste Management.

This study explores the utilisation challenges of fly ash from municipal waste incineration, specifically focusing on ash from a dry desulphurisation plant (DDS), which is categorised as hazardous due to its high heavy metal content. The ash's low silicon and calcium contents restrict its standalone utility. Laboratory investigations initially revealed that geopolymers derived solely from fly ash after flue gas treatment (FGT), in combination with coal combustion fly ash, exhibited low compressive strength (below 0.6 MPa). However, the study demonstrated significant improvements by modifying the FGT ash through water leaching. This process enhanced its performance when mixed with high-silica and -aluminium fly ash, resulting in geopolymers achieving compressive strengths of up to 18 MPa. Comparable strength outcomes were observed when the modified ash was blended with commercial cement. Leachability tests conducted for heavy metals (HMs) such as copper, zinc, lead, cadmium, and nickel indicated that their concentrations fell below the regulatory limits for landfill disposal: 2, 4, 0.5, 0.04, and 0.4 mg/kg, respectively. These results underscore the effectiveness of water-washing FGT ash in conjunction with other materials for producing geopolymers, contributing to sustainable waste management practices.

Ultramicroporous metal-organic framework for efficient carbon dioxide capture from flue gas and natural gas

Carbon dioxide capture from flue gas (CO2/N2) and natural gas (CO2/CH4) is a challenging and cost-effective task. In this paper, ultramicroporous metal-organic frameworks (MOFs) (Co-norf and Ni-norf) are synthesized to realize the efficient separation of CO2/N2 and CO2/CH4 by metal ion regulation. The Ideal Adsorption Solution Theory (IAST) was calculated to evaluate the adsorption selectivity of activated Co-norf and Ni-norf for CO2/N2 (v/v = 15/85) mixtures and CO2/CH4 mixtures. The CO2/N2 selectivity of Co-norf and Ni-norf at 100 kPa was 734 and 96, respectively, which corresponds to an almost 7.6-fold increase by metal ion modulation. The specific binding sites of CO2 molecules within the pore channels were obtained by grand canonical Monte Carlo simulation (GCMC). Dynamic breakthrough experiments respond to the actual separation in systems simulating flue gas and natural gas, where the higher saturation adsorption and longer retention time proved that Co-norf is an ideal material for CO2 capture and separation. The present work provides a feasible approach for the application of MOF in gas separation.

Hybrid EOR Performance Optimization through Flue Gas–Water Alternating Gas (WAG) Injection: Investigating the Synergistic Effects of Water Salinity and Flue Gas Incorporation

Hybrid EOR Performance Optimization through Flue Gas–Water Alternating Gas (WAG) Injection: Investigating the Synergistic Effects of Water Salinity and Flue Gas Incorporation

Study on the Effects of Fe Doping on C‐ZFe Catalyst for Catalytic Removal of NO from the Low‐Temperature Flue Gas

AbstractThe denitrification efficiency of carbon‐based zero valent iron catalyst (C‐ZFe) for low‐temperature selective catalytic reduction (SCR) (<140°C) highly depends on the structural species of iron oxide (FexOy) and the physicochemical properties of the catalyst. In the study, we investigated the main factors affecting the low‐temperature denitrification efficiency of C‐ZFe such as temperature, iron content and O2. The results showed that the average NOX conversion was 72.6 % at 135°C when the space velocity was 459 h−1 and the mass ratio of carbon to iron was 15 % to 85 %. The surface morphology and structure of C‐ZFe were characterized by the surface area and pore size distribution measurements, X‐ray diffraction (XRD), fourier transform infrared spectroscopy (FTIR) and X‐ray photoelectron spectroscopy (XPS). The results indicated that the iron on the catalyst surface was oxidized by O2 to Fe2O3, which could retain NO and then formed intermediate products. NO entered the mesoporous structure along C‐ZFe surface and proceeded a catalytic reduction reaction with the adjacent carbon.

Changes in the Microstructure and Wettability of Water-Containing Coal after Hot Flue Gas (CO2–N2) Injection

Changes in the Microstructure and Wettability of Water-Containing Coal after Hot Flue Gas (CO₂–N₂) Injection

Research on Ozone-Enhanced Oxidation of Industrial Zinc Sulfite from Flue Gas Desulfurization

ABSTRACT This study investigates the air oxidation and ozone-enhanced oxidation of zinc sulfite. Zinc sulfite was prepared by reacting pure or industrial zinc oxide with SO2 in water. The oxidation experiments were conducted under constant temperature conditions, with slurry, oxygen, and ozone concentrations in the ranges of 0.5–4%, 10–60%, and 1100–1920 ppm, respectively. The experiments involved determining the zinc ion concentration, sulfite concentration, dissolved oxygen, ozone concentration in the exhaust gas, and total organic carbon value for analysis of the oxidation process. The findings revealed that the mass transfer rate of O2 and/or O3 determined the reaction rate in the main stage of the oxidation process, while ozone affected the non-mass transfer control stage, resulting in an average enhancement of 15% in the oxidation rate. Furthermore, ozone causes organic matter attached to industrial zinc sulfite particles to fall off into the solution, significantly improving the oxidation ratio of industrial zinc sulfite.

Enhancing submicron dust capture in high-temperature flue gases: A computational study on gradient pore-buried tube granular bed filters

Granular bed filters (GBF) represent a highly effective technology for purifying high-temperature dusty flue gases, although their efficiency in capturing submicron particles remains limited. A novel gradient porosity GBF model with varying bed structures and heat exchange capabilities was proposed. In this research, we employed CFD software to elucidate the movement and heat transfer process of 1 μm dust particles within gradient porosity GBFs and heat exchanger tubes. By optimizing the model under the conditions of a 0.5 m/s inlet flue gas flow rate and 1 μm dust particle size, we achieved a 345.62% increase in filtration efficiency and a 76.61% reduction in pressure drop. The findings indicate that the proposed GBF outperforms other models across various flue gas flow rates in terms of filtration efficiency. The impact of the flue gas flow rate on the combined filtration efficiency for submicron dust on the proposed GBF model was notably significant.

Vapor absorption, compression and cascade heat pumps for carbon capture plants: Multi-criteria analysis and techno-economic assessment with different working fluids

Post-combustion CO2 capture plants include high costs that are associated with intense energy consumption. Heat pumps can recover heat from the flue gas and other sources in the CO2 emitting plant and upgrade it to reduce the use of fossil-based steam. The few studies regarding heat pumps in CO2 capture systems include arbitrary selection among limited working fluids, without optimizing the underlying cycle. This work implements a multi-criteria investigation of the performance of 20 working fluids for vapor compression heat pumps (VCHP) and 21 refrigerant/absorber pairs for absorption heat transformers (AHT), considering the operating optimization of each cycle for each fluid. A cascade cycle combining the two configurations (AHT-VCHP) is proposed, using the optimum fluids cyclopentane and water/potassium nitrate identified for the VCHP and the AHT. The annual operating costs are higher than the annualized capital expenditures. The proposed fluids outperform the conventional options. The VCHP with cyclopentane covers 58 % (2.68 GJ/t CO2) of the reboiler duty with recovered heat and exhibits the lowest cost of $33.8/tCO2. This is $18.7/tCO2 lower than the cost of the conventional direct contact cooling unit that is used in capture plants. The VCHP remains competitive for up to 57 % increase in the electricity price.

Efficient separation of SO2/NO2 on in-situ synthesized NaA zeolite membrane

SO2 and NO2 mixture widely exists in the desorbed gas from industrial flue gas adsorption purification process, separating the mixture into pure gas provides the key step for success in recycling them into profitable chemicals. However, effective SO2/NO2 separation is challenged due to the similar properties of both gases. In this work, we report the synthesis of an industrially-favored NaA zeolite membrane and the utilization of this membrane for SO2/NO2 separation in order to address the above-mentioned challenge. Various characterizations illustrate that the in-situ synthesis endows the NaA zeolite membrane with well-intergrown crystals, high continuity, and crystal-comparable thickness. The separation measurements at different feed pressure, temperature, and gas composition demonstrate that the NaA zeolite membrane shows superior separation performance (SO2/NO2 separation factor of 40.0, SO2 permeance of 2.93 × 10−7 mol m−2 Pa−1 s−1 at 293 K and 0.2 MPa) with strong stability (more than 7 d) compared to the previous best-performing zeolite membrane. The strong competitiveness of SO2 over NO2 on the low-silica membrane is revealed through molecular simulation, showing that the great affinity of SO2 with highly-polar zeolite structure benefits the SO2 gas preferential adsorption and energetically barrier-free permeation through the eight-membered ring of NaA zeolite. This work not only showcases an efficient strategy for the SO2/NO2 separation, but also expands the gas separation application of zeolite membranes.

Recent progress in the operational flexibility of 1 MW circulating fluidized bed combustion

In this study, various experimental tests were carried out with a 1 MWth circulating fluidized bed pilot plant at the Technical University of Darmstadt to investigate the combustion and co-combustion behaviour of different fuels under load change conditions in air and oxyfuel mode. The combustion tests were carried out with low-calorific lignite and hard coal as reference cases for co-combustion. In the co-combustion experimental tests, straw pellets, and refuse-derived fuels (high and low calorific) were used as co-fuels for coal. In addition, a comprehensive dynamic 1.5-D process simulation model was established for a 1 MWth circulating fluidized bed pilot plant. The model created with the “APROS” software precisely reproduces both the gas/solids and the water/steam side of the 1 MWth pilot plant. The dynamic process simulation model was first validated at various steady-state operation points and, in a second step, at various dynamic load changes. The numerical results, such as the pressure drop and temperature profiles along the fluidized bed riser as well as the flue gas concentrations at the cyclone outlet, were compared with the measurements and showed agreement during the long-term tests of the combustion and co-combustion processes.

Phase separation behavior and CO2 absorption kinetic analysis of DETA/DEA/DMAC biphasic absorbent

Lower regeneration energy and superior cyclic capacity have enabled biphasic absorbents great potential in the area of flue gas CO2capture. The liquid film mass transfer coefficient(kL) is a vital parameter in the development of absorbents with efficient CO2 absorption mass transfer performance, while the phase separation behavior of biphasic solutions could be an essential factor for the absorption mass transfer and the stability of absorber. However, systemic kinetic research towards biphasic absorbents, especially the impact of phase separation behavior, is limited. In this study, a typical amide-based biphasic absorbent diethylenetriamine(DETA)/diethanolamine(DEA)/N, N-dimethylacetamide(DMAC) which has achieved great reduction in regeneration energy, was selected as the subject of kinetic investigation in a wetted wall column. The CO2 overall mass transfer coefficient(KG) of DETA/DEA/DMAC exceeded other biphasic solvents, blended amine solution, and 40% K2CO3 solution, with 3 times that of 40% K2CO3 solution. Moreover, various operational conditions including absorption temperature, gas flow rate, and water content of solution were taken into account to build a multiple-condition kinetic mechanism to offer guidance for biphasic absorbents. Furthermore, phase separation behavior was revealed as the main blame for the deterioration in the liquid film chemical mass transfer process of biphasic solvents in the CO2 absorption process, resulting in the kL of DETA/DEA/DMAC before phase separation decreased by 75.3% at the phase separation stage. Therefore, it is crucial to ensure that the CO2 loading of the solution entering absorber is lower than the phase separation point in applications. After phase separation, DETA/DEA/DMAC split into the organic and aqueous phases, the kL of the aqueous phase gradually exceeded that of the organic phase as CO2 loading increased for its higher chemical enhancement factor(E).

Biofuel–Electric Hybrid Aircraft Application—A Way to Reduce Carbon Emissions in Aviation

As global warming intensifies, the world is increasingly concerned about carbon emissions. As an important industry that affects carbon emissions, the air transportation industry takes on the important task of energy saving and emission reduction. For this reason, major airlines have designed or will design different kinds of new-energy aircraft; however, each aircraft has a different scope of application according to its energy source. Biofuels have an obvious carbon emission reduction effect in the whole life cycle, which can offset the drawback of the high pollutant emission of traditional fossil fuels in the preparation and combustion stages. At the same time, a battery has zero emissions in the operating condition, while the low energy density also makes it more applicable to short-range navigation in small aircraft. In this paper, the development direction of a biofuel–electric hybrid aircraft is proposed based on the current development of green aviation, combining the characteristics of biofuel and electric aircraft.