Nonequilibrium fluctuation relation lies at the heart of the quantum thermodynamics. Many previous studies have demonstrated that the heat exchange between a quantum system and a thermal bath initially prepared in their own Gibbs states at different temperatures obeys the famous Jarzynski-Wójcik fluctuation theorem. However, this conclusion is obtained under the assumption of Born-Markovian approximation. In this paper, going beyond the Born-Markovian limitation, we investigate the statistics of quantum heat in an exactly non-Markovian relaxation process described by the well-known Caldeira-Leggett model. It is revealed that the Jarzynski-Wójcik fluctuation theorem breaks down in the strongly non-Markovian regime. Moreover, we find the steady-state quantum heat within the non-Markovian framework can be widely tunable by using the quantum reservoir-engineering technique. These results are sharply contrary to the common Born-Markovian predictions. Our results presented in this paper may update the understanding of the quantum thermodynamics in strongly coupled and low-temperature systems. Moreover, the controllable heat may have some potential applications in improving the performance of a quantum heat engine.