Fluctuation-dissipation Theorem Research Articles

Dynamical fluctuations of a tracer coupled to active and passive particles

We study the induced dynamics of an inertial tracer particle elastically coupled to passive or active Brownian particles. We integrate out the environment degrees of freedom to obtain the exact effective equation of the tracer—a generalized Langevin equation in both cases. In particular, we find the exact form of the dissipation kernel and effective noise experienced by the tracer and compare it with the phenomenological modeling of active baths used in previous studies. We show that the second fluctuation-dissipation relation (FDR) does not hold at early times for both cases. However, at finite times, the tracer dynamics violate (obeys) the FDR for the active (passive) environment. We calculate the linear response formulas in this regime for both cases and show that the passive medium satisfies an equilibrium fluctuation response relation, while the active medium does not—we quantify the extent of this violation explicitly. We show that though the active medium generally renders a nonequilibrium description of the tracer, an effective equilibrium picture emerges asymptotically in the small activity limit of the medium. We also calculate the mean squared velocity and mean squared displacement of the tracer and report how they vary with time.

Frequency-Dependent Impedance of Nanocapacitors from Electrode Charge Fluctuations as a Probe of Electrolyte Dynamics.

The frequency-dependent impedance is a fundamental property of electrical components. We show that it can be determined from the equilibrium dynamical fluctuations of the electrode charge in constant-potential molecular simulations, extending in particular a fluctuation-dissipation relation for the capacitance recovered in the low-frequency limit and provide an illustration on water-gold nanocapacitors. This Letter opens the way to the interpretation of electrochemical impedance measurements in terms of microscopic mechanisms, directly from the dynamics of the electrolyte, or indirectly via equivalent circuit models as in experiments.

Tuning nonequilibrium phase transitions with inertia.

In striking contrast to equilibrium systems, inertia can profoundly alter the structure of active systems. Here, we demonstrate that driven systems can exhibit effective equilibrium-like states with increasing particle inertia, despite rigorously violating the fluctuation-dissipation theorem. Increasing inertia progressively eliminates motility-induced phase separation and restores equilibrium crystallization for active Brownian spheres. This effect appears to be general for a wide class of active systems, including those driven by deterministic time-dependent external fields, whose nonequilibrium patterns ultimately disappear with increasing inertia. The path to this effective equilibrium limit can be complex, with finite inertia sometimes acting to accentuate nonequilibrium transitions. The restoration of near equilibrium statistics can be understood through the conversion of active momentum sources to passive-like stresses. Unlike truly equilibrium systems, the effective temperature is now density dependent, the only remnant of the nonequilibrium dynamics. This density-dependent temperature can in principle introduce departures from equilibrium expectations, particularly in response to strong gradients. Our results provide additional insight into the effective temperature ansatz while revealing a mechanism to tune nonequilibrium phase transitions.

Work statistics in slow thermodynamic processes.

We apply the adiabatic approximation to slow but finite-time thermodynamic processes and obtain the full counting statistics of work. The average work consists of change in free energy and the dissipated work, and we identify each term as a dynamical- and geometric-phase-like quantity. An expression for the friction tensor, the key quantity in thermodynamic geometry, is explicitly given. The dynamical and geometric phases are proved to be related to each other via the fluctuation-dissipation relation.

Linear Response and Fluctuation-Dissipation Relations for Brownian Motion under Resetting.

We consider fluctuation-dissipation relations (FDRs) for a Brownian motion under renewal resetting with arbitrary waiting time distribution between the resetting events. We show that if the distribution of waiting times of the resetting process possesses the second moment, the usual (generalized) FDR and the equivalent generalized Einstein's relation (GER) apply for the response function of the coordinate. If the second moment of waiting times diverges but the first one stays finite, the static susceptibility diverges, the usual FDR breaks down, but the GER still applies. In any of these situations, the fluctuation dissipation relations define the effective temperature of the system which is twice as high as the temperature of the medium in which the Brownian motion takes place.

Time-translational symmetry in statistical dynamics dictates Einstein relation, Green-Kubo formula, and their generalizations.

A stochastic dynamics has a natural decomposition into a drift capturing mean rate of change and a martingale increment capturing randomness. They are two statistically uncorrelated, but not necessarily independent, components contributing to the overall fluctuations of the dynamics, representing the uncertainties in the past and in the future. We show that fluctuation-dissipation relations of the two aforementioned components, such as the Einstein relation and the Green-Kubo formula, can be formulated for any stochastic process with a steady state, without additional supposition of the process being Markovian, reversible, or linear. Further, by considering the adjoint process defined by the time reversal at the steady state, we show that reversibility in equilibrium leads to an additional symmetry in the covariance between system's state and drift. Potential directions of further generalizing our results to processes without steady states is briefly discussed.

Kinetic theory of two-dimensional point vortices and fluctuation–dissipation theorem

We complete the kinetic theory of two-dimensional (2D) point vortices initiated in previous works. We use a simpler and more physical formalism. We consider a system of 2D point vortices submitted to a small external stochastic perturbation and determine the response of the system to the perturbation. We derive the diffusion coefficient and the drift by polarization of a test vortex. We introduce a general Fokker–Planck equation involving a diffusion term and a drift term. When the drift by polarization can be neglected, we obtain a secular dressed diffusion equation sourced by the external noise. When the external perturbation is created by a discrete collection of N point vortices, we obtain a Lenard–Balescu-like kinetic equation reducing to a Landau-like kinetic equation when collective effects are neglected. We consider a multi-species system of point vortices. We discuss the process of kinetic blocking in the single and multi-species cases. When the field vortices are at statistical equilibrium (thermal bath), we establish the proper expression of the fluctuation–dissipation theorem for 2D point vortices relating the power spectrum of the fluctuations to the response function of the system. In that case, the drift coefficient and the diffusion coefficient satisfy an Einstein-like relation and the Fokker–Planck equation reduces to a Smoluchowski-like equation. We mention the analogy between 2D point vortices and stellar systems. In particular, the drift of a point vortex in 2D hydrodynamics (Chavanis in Phys Rev E 58:R1199, 1998) is the counterpart of the Chandrasekhar dynamical friction in astrophysics. We also consider a gas of 2D Brownian point vortices described by N coupled stochastic Langevin equations and determine its mean and mesoscopic evolution. In the present paper, we treat the case of unidirectional flows, but our results can be straightforwardly generalized to axisymmetric flows.

Periodic potential can enormously boost free-particle transport induced by active fluctuations.

Active fluctuations are detected in a growing number of systems due to self-propulsion mechanisms or collisions with an active environment. They drive the system far from equilibrium and can induce phenomena that are forbidden at equilibrium states by, e.g., fluctuation-dissipation relations and detailed balance symmetry. Understanding their role in living matter is emerging as a challenge for physics. Here we demonstrate a paradoxical effect in which a free-particle transport induced by active fluctuations can be boosted by many orders of magnitude when the particle is additionally subjected to a periodic potential. In contrast, within the realm of only thermal fluctuations, the velocity of a free particle exposed to a bias is reduced when the periodic potential is switched on. The presented mechanism is significant for understanding nonequilibrium environments such as living cells, where it can explain from a fundamental point of view why spatially periodic structures known as microtubules are necessary to generate impressively effective intracellular transport. Our findings can be readily corroborated experimentally, e.g., in a setup comprising a colloidal particle in an optically generated periodic potential.

Linear response functions respecting Ward-Takahashi identity and fluctuation-dissipation theorem within the GW approximation

Fundamental equalities, such as the Ward-Takahashi identity (WTI) and the fluctuation-dissipation theorem (FDT), are important in the calculation of the response functions, which are defined as the variations of physical quantities with respect to the external sources. In this paper, the formalism of calculating the response functions according to their original definitions is presented, based on the generalized $GW$ (GGW) method which was developed for the electronic systems including spin-dependent interaction. This formalism automatically ensures the FDT, and is theorectically proved to respect the WTI. By contrast, the commonly used random phase approximation (RPA) within the GGW method violates both the WTI and the FDT, and the Bethe-Salpeter equation (BSE) satisfies the WTI but does not fulfill the FDT. The validity of this methodology is demonstrated on the two-dimensional one-band Hubbard model, and the results show that our formalism makes significant improvements over the RPA formula. Due to the similar computational cost to the BSE, our formalism is expected to be applied to realistic materials.

Direct Modeling of Thermal-Radiation Reception by Antenna in Close Range

In this work, an interesting near-field propagation problem in the microwave radiometer calibration is addressed, which is the antenna reception of thermal radiation from calibration target. Efforts in simultaneously modeling the target and antenna within the same 2-D full-wave scenario are reported. Specifically, the coated pyramids and horn antennas are considered. Based on the incoherent nature of local thermal sources in the coating layer and the fluctuation-dissipation theorem (FDT), the direct modeling of receiving power and further brightness temperature ( <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$BT$ </tex-math></inline-formula> ) at the antenna waveguide port can be achieved. The direct modeling is then quantified based on the classic concept of antenna reception in an ideal blackbody chamber. Further, it is shown in the results that mutual coupling affects the antenna reception in a fluctuating manner, and the target structural radiation raises the antenna reception in a very close distance. That means, the thermal reception can be affected by both the antenna and target structures in the near field. Also, the Lambertian radiation properties of the coated pyramidal blackbody are clarified in the direct calculated results. This work reveals the complex scenario of close range <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$BT$ </tex-math></inline-formula> transfer, and opens the possibility of quantitatively modeling it for practical applications with further investigations.

Formalism for stochastic perturbations and analysis in relativistic stars

Perturbed Einstein’s equations with a linear response relation and a stochastic source, applicable to a relativistic star model are worked out. These perturbations which are stochastic in nature, are of significance for building a non-equilibrium statistical mechanics theory in connections with relativistic astrophysics. A fluctuation dissipation relation for a spherically symmetric star in its simplest form is obtained. The FD relation shows how the random velocity fluctuations in the background of the unperturbed star can dissipate into Lagrangian displacement of fluid trajectories of the dense matter. Interestingly in a simple way, a constant (in time) coefficient of dissipation is obtained without a delta correlated noise. This formalism is also extended for perturbed TOV equations which have a stochastic contribution, and show up in terms of the effective or root mean square pressure perturbations. Such contributions can shed light on new ways of analysing the equation of state for dense matter. One may obtain contributions of first and second order in the equation of state using this stochastic approach.

Quantum Bounds on the Generalized Lyapunov Exponents

We discuss the generalized quantum Lyapunov exponents Lq, defined from the growth rate of the powers of the square commutator. They may be related to an appropriately defined thermodynamic limit of the spectrum of the commutator, which plays the role of a large deviation function, obtained from the exponents Lq via a Legendre transform. We show that such exponents obey a generalized bound to chaos due to the fluctuation-dissipation theorem, as already discussed in the literature. The bounds for larger q are actually stronger, placing a limit on the large deviations of chaotic properties. Our findings at infinite temperature are exemplified by a numerical study of the kicked top, a paradigmatic model of quantum chaos.

Fluctuation-Dissipation Relation for a Bose-Einstein Condensate of Photons

For equilibrium systems, the magnitude of thermal fluctuations is closely linked to the dissipative response to external perturbations. This fluctuation-dissipation relation has been described for material particles in a wide range of fields. Here, we experimentally probe the relation between the number fluctuations and the response function for a Bose-Einstein condensate of photons coupled to a dye reservoir, demonstrating the fluctuation-dissipation relation for a quantum gas of light. The observed agreement of the scale factor with the environment temperature both directly confirms the thermal nature of the optical condensate and demonstrates the validity of the fluctuation-dissipation theorem for a Bose-Einstein condensate.

Third-Order Elastic Constants of Germanium and Silicon using Adiabatic-Connection Fluctuation-Dissipation Theorem in Random Phase Approximation

Third-Order Elastic Constants of Germanium and Silicon using Adiabatic-Connection Fluctuation-Dissipation Theorem in Random Phase Approximation

Equilibrium and out-of-equilibrium realistic phonon self-energy free from overscreening

In model Hamiltonians, like Fr\"ohlich's, the electron-phonon interaction is assumed to be screened from the beginning. The same occurs when this interaction is obtained by using the state-of-the-art density functional perturbation theory as starting point. In this work I formally demonstrate that these approaches are affected by a severe overscreening error. By using an out-of-equilibrium many-body technique I discuss how to merge the many-body approach with density functional perturbation theory in order to correct the overscreening error. A symmetric statically screened phonon self-energy is obtained by downfolding the exact Baym-Kadanoff equations. The statically screened approximation proposed here is shown to have the same long-range spatial limit of the exact self-energy and to respect the fluctuation-dissipation theorem. The doubly screened approximation, commonly used in the literature, is shown, instead, to be overscreened, to violate several many-body properties and to have a wrong spatial long-range decay. The accuracy of the proposed approximation is tested against the exact solution of an extended model Fr\"ohlich Hamiltonian and it is applied to a paradigmatic material: ${\mathrm{MgB}}_{2}$. I find that the present treatment enhances the linewidths by $57%$ with respect to what has been previously reported for the anomalous ${E}_{2g}$ mode. I further discover that the ${A}_{2u}$ mode is also anomalous (its strong coupling being completely quenched by the overscreened expression). The present results deeply question methods based on state-of-the-art approaches and impact a wide range of fields such as thermal conductivity, phononic instabilities, and nonequilibrium lattice dynamics.

Revisiting thermal charge carrier refractive noise in semiconductor optics for gravitational-wave interferometers

The test masses in next-generation gravitational-wave interferometers may have a semiconductor substrate, most likely silicon. The stochastic motion of charge carriers within the semiconductor will cause random fluctuations in the material's index of refraction, introducing a noise source called thermal charge carrier refractive (TCCR) noise. TCCR noise was previously studied in 2020 by Bruns et al., using a Langevin force approach. Here we compute the power spectral density of TCCR noise by both using the fluctuation-dissipation theorem and accounting for previously neglected effects of the standing wave of laser light produced by reflections along the direction of beam propagation. We quantify our results with parameters from Einstein Telescope, and we show that at temperatures of 10 K the amplitude of TCCR noise is up to a factor of $\sqrt{2}$ times greater than what was previously claimed. From 77 K to 300 K the amplitude is around 5 to 7 orders of magnitude lower than previously claimed when we choose to neglect the standing wave, and is up to a factor of 6 times lower if the standing wave is included. Despite these differences, we still conclude like Bruns et al. that TCCR noise should not be a limiting noise source for next-generation gravitational-wave interferometers.

Bounding Variance and Skewness of Fluctuations in Nonlinear Dynamical Systems with Stochastic Thermodynamics*

Fluctuations arising in nonlinear dissipative systems (diode, transistors, chemical reaction, etc.) subject to an external drive (voltage, chemical potential, etc.) are well known to elude any simple characterisation such as the fluctuation-dissipation theorem (also called Johnson-Nyquist law, or Einstein's law in specific contexts). Using results from stochastic thermodynamics, we show that the variance of these fluctuations exceeds the variance predicted by a suitably extended version of Johnson-Nyquist's formula, by an amount that is controlled by the skewness (third moment) of the fluctuations. As a consequence, symmetric fluctuations necessarily obey the extended Johnson-Nyquist formula. This shows the physical inconsistency of Gaussian approximation for the noise arising in some nonlinear models, such as MOS transistors or chemical reactions. More generally, this suggests the need for a stochastic nonlinear systems theory that is compatible with the teachings of thermodynamics.

Fluctuation-dissipation in thermoelectric sensors

Thermoelectric materials exhibit correlated transport of charge and heat. The Johnson-Nyquist noise formula 4k B T R for the spectral density of voltage fluctuations accounts for fluctuations associated solely with Ohmic dissipation. Applying the fluctuation-dissipation theorem, we generalize the Johnson-Nyquist formula for thermoelectrics, finding an enhanced voltage fluctuation spectral density 4k B T R(1 + Z D T) at frequencies below a thermal cut-off frequency f T , where Z D T is the dimensionless thermoelectric device figure of merit. The origin of the enhancement in voltage noise is thermoelectric coupling of temperature fluctuations. We use a wideband , integrated thermoelectric micro-device to experimentally confirm our findings. Measuring the Z D T enhanced voltage noise, we experimentally resolve temperature fluctuations with a root mean square amplitude of at a mean temperature of 295 K. We find that thermoelectric devices can be used for thermometry with sufficient resolution to measure the fundamental temperature fluctuations described by the fluctuation-dissipation theorem.

Adiabatic limit collapse and local interaction effects in non-linear active microrheology molecular simulations of two-dimensional fluids.

Nonlinear active microrheology molecular dynamics simulations of high-density two-dimensional fluids show that the presence of strong confining forces and an external pulling force induces a correlation between the velocity and position dynamics of the tracer particle. This correlation manifests in the form of an effective temperature and an effective mobility of the tracer particle, which is responsible for the breaking of the equilibrium fluctuation-dissipation theorem. This fact is shown by measuring the tracer particle's temperature and mobility directly from the first two moments of the velocity distribution of a tracer particle and by formulating a diffusion theory in which effective thermal and transport properties are decoupled from the velocity dynamics. Furthermore, the flexibility of the attractive and repulsive forces in the tested interaction potentials allowed us to relate the temperature and mobility behaviors to the nature of the interactions and the structure of the surrounding fluid as a function of the pulling force. These results provide a refreshing physical interpretation of the phenomena observed in non-linear active microrheology.

Qubit dynamics driven by dipole field in thermal noise environment

Quantum computing is a new way to process quantum information by using superposition and entanglement of the quantum system. Quantum state’s vast Hilbert space allows it to perform operations that classical computers cannot. The quantum computing has unique advantages in dealing with some complex problems, so it has attracted wide attention. Computing a single qubit is the first of seven fundamental stages needed to achieve a large-scale quantum computer that is universal, scalable and fault-tolerant. In other words, the primary task of quantum computing is the careful preparation and precise regulation of qubits. At present, the physical systems that can be used as qubits include superconducting qubits, semiconductor qubits, ion trap systems and nitrogen-vacancy (NV) color centers. These physical systems have made great progress of decoherence time and scalability. Owing to the vulnerability of qubits, ambient thermal noise can cause quantum decoherence, which greatly affects the fidelity of qubits. Improving the fidelity of qubits is therefore a key step towards large-scale quantum computing. Based on the dipole field driven qubit, the stochastic dynamic structure decomposition method is adopted and the Kubo-Einstein fluctuation-dissipation theorem is used to study the qubit control in a thermal noise environment. The dipole field has components in three directions, not just in one plane, which allows more flexible control of quantum states. Without considering the noise, the quantum state can reach the target state 100%. In the noisy environment, thermal noise will cause the deviation between the actual final state and the target final state caused by thermal fluctuation, which becomes the main factor affecting the quantum fidelity. The influence of thermal noise is related to temperature and the evolution trajectory of quantum state. Therefore, this paper proposes an optimal scheme to improve the qubit fidelity in the thermal noise environment. The feasibility of this method is verified by numerical calculation, which can provide a new solution for further guiding and evaluating the experiment. The scheme is suitable for qubit systems of various physical control fields, such as semiconductor qubits and nitrogen vacancy center qubits. This work may have more applications in the development of quantum manipulation technology and can also be extended to multi-qubit systems, the details of which will appear in the future work.