Systems coupling Mg(OH)2/MgO thermochemical reactor with parabolic dish solar collector (PDSC) have a potential application prospect in solar seasonal heat storage. However, their working mechanism has not been systematically studied and not well understood either. In this study, Mg(OH)2-based thermochemical reactor, which was coupled with PDSC, was numerically studied for the first time using a three-dimensional model. The various working conditions and influencing factors of PDSC system were investigated, and a comprehensive analysis and optimization for the heat storage performance of the reactor such as the reaction time and energy storage rate were conducted. Effects of the fluid inflow temperature, velocity, and fluid pipe distribution on heat storage performance were also unfolded. For instance, when the heating pipe was arranged at 70 mm from the central axis, the reaction time was 15.9 % less than that of evenly arranged at R/2 from the center. Moreover, fins were added to the reactor and the fin shape was optimized using the density-based topology optimization method. It was found that the reaction time was reduced by 42.4 % and was only 12614 s.
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